This study explores the corrosion issues arising from the coupled combustion of coal and biomass and proposes potential solutions.Biomass,as a renewable energy source,offers advantages in energy-saving and carbon redu...This study explores the corrosion issues arising from the coupled combustion of coal and biomass and proposes potential solutions.Biomass,as a renewable energy source,offers advantages in energy-saving and carbon reduction.However,the corrosive effects of alkali metal compounds,sulfur(S)and chlorine(Cl)elements in the ash after combustion cannot be underestimated due to the high volatile content of biomass fuels.We investigate the corrosion mechanisms,as well as the transfer of Cl and alkali metal elements during this process.Comparative corrosion analyses are conducted among coal-fired boilers,pure biomass boilers and boilers with coupled combustion.Various biomass types in co-firing are studied to understand different corrosion outcomes.The main factors influencing corrosion include the physicochemical properties of biomass feedstock,furnace temperature and heating surface materials,with the chemical composition and ash content of biomass playing a dominant role.Currently,the methods used for anti-corrosion include water washing pretreatment of biomass feedstock,application of novel alloys and coatings and the development of additives to inhibit fouling,ash deposition and corrosion.Efficient inhibitors are economical and easy to produce.Additionally,biomass can be converted into biomass gasification gas,although challenges related to tar still need to be addressed.展开更多
The long-term stability of a prestressed anchored slope might be influenced by the durability of the anchorage structure.To understand long-term stability of anchored rock slopes,the research presented herein evaluate...The long-term stability of a prestressed anchored slope might be influenced by the durability of the anchorage structure.To understand long-term stability of anchored rock slopes,the research presented herein evaluated the performance evolution of a prestressed anchored bedding slope system in a corrosive environment by model test.The corrosion process in a prestressed anchor bar was monitored in terms of its open-circuit potential(OCP),corrosion current density(CCD),and electrochemical impedance spectroscopy(EIS).The stability of the prestressed anchored slope was evaluated by monitoring changes in anchorage force and displacements.The experimental results show that prestress and oxygen could reduce the corrosion resistance of the anchor bar,and anchor bars in a chloride-rich environment are very susceptible to corrosion.Prestressed tendons in a corrosive environment suffer a loss of anchorage force,the prestress decreases rapidly after locking,and the rate thereof decreases until stabilising;in the later stage,corrosion leads to the reduction of the cross-sectional area of the steel bar which may cause the reduction in anchorage force again.Anchorage force controls the deformation and stability of the anchored slope,the prestress loss caused by later corrosion may lead to an increased rate of displacement and stability degradation of the prestressed anchored rock slope.展开更多
A Kelvin probe was used as reference in this study on electrochemical measurements of a simulatedmarine atmospheric corrosion system (electrode covered by a very thin electrolyte layer). The experimentalsetups for imp...A Kelvin probe was used as reference in this study on electrochemical measurements of a simulatedmarine atmospheric corrosion system (electrode covered by a very thin electrolyte layer). The experimentalsetups for improved measurements proved satisfactory for the conventional steady-state electrochemicalmeasurements in atmospheric studies.展开更多
The present study examines the behavior of three major categories of organic coatings which are applied on the surface of concrete structures and specifically conventional, high performance and nanotechnology paint sy...The present study examines the behavior of three major categories of organic coatings which are applied on the surface of concrete structures and specifically conventional, high performance and nanotechnology paint systems. The comparison is achieved in the means of anticorrosion properties under the presence of chloride ions and carbonation resistance. The evaluation methods included electrochemical measurements in order to assess corrosion properties and the determination of steel’s mass loss after the end of the experimental procedure. Carbonation depth was measured using phenolphthalein as indicator after accelerated and physical exposure. From the results so far it can be shown nanocoatings gave promising results regarding induced chloride ion corrosion.展开更多
Electrochemical techniques of the corrosion measurements of reinforcing steeI in concrete have been evaluated. These techniques include half-cell potential measurements, impressed voltage method, impressed current met...Electrochemical techniques of the corrosion measurements of reinforcing steeI in concrete have been evaluated. These techniques include half-cell potential measurements, impressed voltage method, impressed current method and potentiostatic polarization technique. The results of corrosion behaviour of the steel in both 5%NaCl and 5%MgSO4 show that each electrochemical technique provides some information about the condition of the steel bar or the corrosivity of the environment being evaluated, yet none provides a complete data regarding the corrosion resistance of reinforcing steel in aggressive media展开更多
The deterioration of concrete over time is the result of various mechanical, physical, chemical and biological processes, with the corrosion of reinforcement being the most serious problem of durability of reinforced ...The deterioration of concrete over time is the result of various mechanical, physical, chemical and biological processes, with the corrosion of reinforcement being the most serious problem of durability of reinforced concrete structures. Over the last 50 years, a tremendous effort has been spent by the international scientific community with laboratory research and experimental field studies in order to increase the resistance of concrete over corrosion. This paper presents an experimental study of the corrosion behaviour of reinforced concrete beams with simultaneous sustained flexural loading. For this purpose, 40 reinforced concrete beams of 5 different compositions were constructed and exposed in simulated harmful environmental conditions in 3 different stress ratios for a total period of 42 months. Their behavior against corrosion was determined via regular measurements of the electrical resistance of concrete (according to ASTM G57) and the corrosion potential of the steel-reinforced bars with the use of copper sulphate (CSE) as reference electrode (according to ASTM C876). A theoretical calculation of the corrosion rate was conducted based on the electrochemical measurements of the beams. The results indicate that the corrosion potential of steel decreased in time and more rapidly after the initiation of the corrosion process;the electrical resistance firstly increased, remained stable for a short period and then decreased with the corrosion development, as expected. An inversely proportional relationship of the water/cement ratio of a composition with its corrosion behaviour as well as an analogous relationship between the cement content of a composition and its corrosion behaviour was observed. Also, the corrosion rate of steel is increased gradually with increasing load.展开更多
In Quepos, Pacific of Costa Rica, it was finished on 2010 the first phase of a marina, including two mix breakwaters, with rubble mound (rocks and concrete units), and 25 circular steel sheet piles cofferdam cells, ...In Quepos, Pacific of Costa Rica, it was finished on 2010 the first phase of a marina, including two mix breakwaters, with rubble mound (rocks and concrete units), and 25 circular steel sheet piles cofferdam cells, filled with sand and gravel. The maintenance plan, considers tracking sheet pile corrosion, comparing "actual" against expected rates, checking structural limits, and programming countermeasures if accelerated corrosion is identified. Specific control sections, along the breakwaters, both inside and outside the basin, were established. In each section, thicknesses were measured every meter from the top of the steel cell to seabed using an ultrasonic equipment, and an underwater transducer. Both land crew, and divers for submerged portions, were used. The measurements campaigns are for several years from 2011 to 2016. Sectors of the breakwater with varied corrosion attack levels could be differentiated. Also, corrosion rates and lifespans were estimated, both general for the structures, and specific for each section and level. In turn, this allowed to identify maintenance priorities, defining sites where measures of corrosion protection should initiate, as well, to have confidence in the structural capacity and safety of the breakwaters.展开更多
In Quepos,Pacific of Costa Rica,it was finished on 2010 the first phase of a marina,including two mix breakwaters,with rubble mound(rocks and concrete units),and 25 circular steel sheet piles cofferdam cells,filled wi...In Quepos,Pacific of Costa Rica,it was finished on 2010 the first phase of a marina,including two mix breakwaters,with rubble mound(rocks and concrete units),and 25 circular steel sheet piles cofferdam cells,filled with sand and gravel.The maintenance plan,considers tracking sheet pile corrosion,comparing'actual'against expected rates,checking structural limits,and programming countermeasures if accelerated corrosion is identified.Specific control sections,along the breakwaters,both inside and outside the basin,were established.In each section,thicknesses were measured every meter from the top of the steel cell to seabed using an ultrasonic equipment,and an underwater transducer.Both land crew,and divers for submerged portions,were used.The measurements campaigns are for several years from 2011 to 2016.Sectors of the breakwater with varied corrosion attack levels could be differentiated.Also,corrosion rates and lifespans were estimated,both general for the structures,and specific for each section and level.In turn,this allowed to identify maintenance priorities,defining sites where measures of corrosion protection should initiate,as well,to have confidence in the structural capacity and safety of the breakwaters.展开更多
Copper is susceptible to producing corrosion problems in corrosive environments, which leads to serious safety problems. Thus, investigating the corrosion behavior of copper is of great significance. The effects of ro...Copper is susceptible to producing corrosion problems in corrosive environments, which leads to serious safety problems. Thus, investigating the corrosion behavior of copper is of great significance. The effects of rotating electromagnetic field on corrosion behavior of T2 copper in 3.5% sodium chloride solution with electrochemical measurements were investigated. The results showed that rotating electromagnetic field changed properties of 3.5% sodium chloride solution by increasing the values of temperature and pH and decreasing the values of conductivity and dissolved oxygen. The rotating electromagnetic field improved the corrosion resistance of T2 copper. The corrosion products of T2 copper in treated 3.5% sodium chloride solution were composed of Cu20 and CuCl. The low corrosion rate of T2 copper was resulted from the decrease of dissolved oxygen in 3.5% sodium chloride solution treated by rotating electromagnetic field.展开更多
In this paper, the mechanism of corrosion between flexible graphite which is used as a sealing material and metal is in-vestigated, the anticorrosive measures are introduced, and some mordern measures which should be ...In this paper, the mechanism of corrosion between flexible graphite which is used as a sealing material and metal is in-vestigated, the anticorrosive measures are introduced, and some mordern measures which should be paid attention are provided.展开更多
文摘This study explores the corrosion issues arising from the coupled combustion of coal and biomass and proposes potential solutions.Biomass,as a renewable energy source,offers advantages in energy-saving and carbon reduction.However,the corrosive effects of alkali metal compounds,sulfur(S)and chlorine(Cl)elements in the ash after combustion cannot be underestimated due to the high volatile content of biomass fuels.We investigate the corrosion mechanisms,as well as the transfer of Cl and alkali metal elements during this process.Comparative corrosion analyses are conducted among coal-fired boilers,pure biomass boilers and boilers with coupled combustion.Various biomass types in co-firing are studied to understand different corrosion outcomes.The main factors influencing corrosion include the physicochemical properties of biomass feedstock,furnace temperature and heating surface materials,with the chemical composition and ash content of biomass playing a dominant role.Currently,the methods used for anti-corrosion include water washing pretreatment of biomass feedstock,application of novel alloys and coatings and the development of additives to inhibit fouling,ash deposition and corrosion.Efficient inhibitors are economical and easy to produce.Additionally,biomass can be converted into biomass gasification gas,although challenges related to tar still need to be addressed.
基金strongly supported by the National Natural Science Foundation of China(Project No.41672320 and 41877280)the National Key R&D Program of China(NO.2018YFC0407002)+3 种基金the Foreign experts Program of Hubei Province(WGZJ2020000011)the Fundamental Research Funds for Central Public Welfare Research Institutes(CKSF 2019180/YT)the Research and Transformation Project of the Changjiang River Scientific Research Institute(CKZS2017007/YT)the Innovation Team Project of the Changjiang River Scientific Research Institute(CKSF2017066/YT)。
文摘The long-term stability of a prestressed anchored slope might be influenced by the durability of the anchorage structure.To understand long-term stability of anchored rock slopes,the research presented herein evaluated the performance evolution of a prestressed anchored bedding slope system in a corrosive environment by model test.The corrosion process in a prestressed anchor bar was monitored in terms of its open-circuit potential(OCP),corrosion current density(CCD),and electrochemical impedance spectroscopy(EIS).The stability of the prestressed anchored slope was evaluated by monitoring changes in anchorage force and displacements.The experimental results show that prestress and oxygen could reduce the corrosion resistance of the anchor bar,and anchor bars in a chloride-rich environment are very susceptible to corrosion.Prestressed tendons in a corrosive environment suffer a loss of anchorage force,the prestress decreases rapidly after locking,and the rate thereof decreases until stabilising;in the later stage,corrosion leads to the reduction of the cross-sectional area of the steel bar which may cause the reduction in anchorage force again.Anchorage force controls the deformation and stability of the anchored slope,the prestress loss caused by later corrosion may lead to an increased rate of displacement and stability degradation of the prestressed anchored rock slope.
文摘A Kelvin probe was used as reference in this study on electrochemical measurements of a simulatedmarine atmospheric corrosion system (electrode covered by a very thin electrolyte layer). The experimentalsetups for improved measurements proved satisfactory for the conventional steady-state electrochemicalmeasurements in atmospheric studies.
文摘The present study examines the behavior of three major categories of organic coatings which are applied on the surface of concrete structures and specifically conventional, high performance and nanotechnology paint systems. The comparison is achieved in the means of anticorrosion properties under the presence of chloride ions and carbonation resistance. The evaluation methods included electrochemical measurements in order to assess corrosion properties and the determination of steel’s mass loss after the end of the experimental procedure. Carbonation depth was measured using phenolphthalein as indicator after accelerated and physical exposure. From the results so far it can be shown nanocoatings gave promising results regarding induced chloride ion corrosion.
文摘Electrochemical techniques of the corrosion measurements of reinforcing steeI in concrete have been evaluated. These techniques include half-cell potential measurements, impressed voltage method, impressed current method and potentiostatic polarization technique. The results of corrosion behaviour of the steel in both 5%NaCl and 5%MgSO4 show that each electrochemical technique provides some information about the condition of the steel bar or the corrosivity of the environment being evaluated, yet none provides a complete data regarding the corrosion resistance of reinforcing steel in aggressive media
文摘The deterioration of concrete over time is the result of various mechanical, physical, chemical and biological processes, with the corrosion of reinforcement being the most serious problem of durability of reinforced concrete structures. Over the last 50 years, a tremendous effort has been spent by the international scientific community with laboratory research and experimental field studies in order to increase the resistance of concrete over corrosion. This paper presents an experimental study of the corrosion behaviour of reinforced concrete beams with simultaneous sustained flexural loading. For this purpose, 40 reinforced concrete beams of 5 different compositions were constructed and exposed in simulated harmful environmental conditions in 3 different stress ratios for a total period of 42 months. Their behavior against corrosion was determined via regular measurements of the electrical resistance of concrete (according to ASTM G57) and the corrosion potential of the steel-reinforced bars with the use of copper sulphate (CSE) as reference electrode (according to ASTM C876). A theoretical calculation of the corrosion rate was conducted based on the electrochemical measurements of the beams. The results indicate that the corrosion potential of steel decreased in time and more rapidly after the initiation of the corrosion process;the electrical resistance firstly increased, remained stable for a short period and then decreased with the corrosion development, as expected. An inversely proportional relationship of the water/cement ratio of a composition with its corrosion behaviour as well as an analogous relationship between the cement content of a composition and its corrosion behaviour was observed. Also, the corrosion rate of steel is increased gradually with increasing load.
文摘In Quepos, Pacific of Costa Rica, it was finished on 2010 the first phase of a marina, including two mix breakwaters, with rubble mound (rocks and concrete units), and 25 circular steel sheet piles cofferdam cells, filled with sand and gravel. The maintenance plan, considers tracking sheet pile corrosion, comparing "actual" against expected rates, checking structural limits, and programming countermeasures if accelerated corrosion is identified. Specific control sections, along the breakwaters, both inside and outside the basin, were established. In each section, thicknesses were measured every meter from the top of the steel cell to seabed using an ultrasonic equipment, and an underwater transducer. Both land crew, and divers for submerged portions, were used. The measurements campaigns are for several years from 2011 to 2016. Sectors of the breakwater with varied corrosion attack levels could be differentiated. Also, corrosion rates and lifespans were estimated, both general for the structures, and specific for each section and level. In turn, this allowed to identify maintenance priorities, defining sites where measures of corrosion protection should initiate, as well, to have confidence in the structural capacity and safety of the breakwaters.
文摘In Quepos,Pacific of Costa Rica,it was finished on 2010 the first phase of a marina,including two mix breakwaters,with rubble mound(rocks and concrete units),and 25 circular steel sheet piles cofferdam cells,filled with sand and gravel.The maintenance plan,considers tracking sheet pile corrosion,comparing'actual'against expected rates,checking structural limits,and programming countermeasures if accelerated corrosion is identified.Specific control sections,along the breakwaters,both inside and outside the basin,were established.In each section,thicknesses were measured every meter from the top of the steel cell to seabed using an ultrasonic equipment,and an underwater transducer.Both land crew,and divers for submerged portions,were used.The measurements campaigns are for several years from 2011 to 2016.Sectors of the breakwater with varied corrosion attack levels could be differentiated.Also,corrosion rates and lifespans were estimated,both general for the structures,and specific for each section and level.In turn,this allowed to identify maintenance priorities,defining sites where measures of corrosion protection should initiate,as well,to have confidence in the structural capacity and safety of the breakwaters.
基金Projects(51207031,51177022)supported by the National Natural Science Foundation of ChinaProject(2013M541368)supported by the China Postdoctoral Science Foundation+1 种基金Project(BS2011NJ002)supported by the Promotive Research Fund for Excellent Young and Middle-Aged Scientists of Shandong Province,ChinaProject(2008DFR60340)supported by the International Science and Technology Cooperation of China
文摘Copper is susceptible to producing corrosion problems in corrosive environments, which leads to serious safety problems. Thus, investigating the corrosion behavior of copper is of great significance. The effects of rotating electromagnetic field on corrosion behavior of T2 copper in 3.5% sodium chloride solution with electrochemical measurements were investigated. The results showed that rotating electromagnetic field changed properties of 3.5% sodium chloride solution by increasing the values of temperature and pH and decreasing the values of conductivity and dissolved oxygen. The rotating electromagnetic field improved the corrosion resistance of T2 copper. The corrosion products of T2 copper in treated 3.5% sodium chloride solution were composed of Cu20 and CuCl. The low corrosion rate of T2 copper was resulted from the decrease of dissolved oxygen in 3.5% sodium chloride solution treated by rotating electromagnetic field.
文摘In this paper, the mechanism of corrosion between flexible graphite which is used as a sealing material and metal is in-vestigated, the anticorrosive measures are introduced, and some mordern measures which should be paid attention are provided.