The field of electromagnetic wave absorption(EWA)requires the adaptability,tenability,and multifunction of high-performance materials in the future.The design and preparation of EWA materials aiming at performance req...The field of electromagnetic wave absorption(EWA)requires the adaptability,tenability,and multifunction of high-performance materials in the future.The design and preparation of EWA materials aiming at performance requirements is the latest research hotspot.Here,a performancedriven strategy for simultaneously coordinating different target performances was proposed to optimize the structure of the periodical long continuous carbon/glass fiber fabric(PCGF)materials through algorithm and simulation.The optimized structure of the PCGF not only improves the impedance matching,but also introduces the induced orientation effect for a high cooperative loss of conductivity,resonance,and periodic structure.The flexible PCGF shows a broad effective absorption bandwidth(EAB)of 32.7 GHz covering a part of the C-band and the whole X-,Ku-,K-,and Ka-bands with a thickness(d)of only 0.92 mm and a density of 5.6×10^(−4) kg·cm^(−3).This highly designable fabric is promising for the EWA practical application owing to integrating the characteristics of good flexibility,acid and alkali resistance,bending resistance,excellent mechanical properties,and easy large-scale preparation.展开更多
Self-lubrication is one of the smart material properties required for producing components with enhanced wear resistance and low coefficient of friction.Bidirectional(BD)satin weave polyacrylonitrile(PAN)based carbon ...Self-lubrication is one of the smart material properties required for producing components with enhanced wear resistance and low coefficient of friction.Bidirectional(BD)satin weave polyacrylonitrile(PAN)based carbon fiber(Cf)fabric preform was successfully infiltrated with Al 6061 alloy by squeeze infiltration process.The infiltrated composite shows uniform distribution of carbon fibers in the matrix with the elimination of porosities,fiber damage and close control on the formation of deleterious aluminum carbide(Al4C3)phase.Cf/Al composite exhibits remarkable wear resistance compared to unreinforced alloy due to the formation of self-lubricating tribolayer on the pin surface,which intercepts the contact of matrix metal to counter surface.The BD carbon fiber enhanced the hardness and compressive strength of the composite by restraining the plastic flow behavior of matrix.High resolution transmission electron microscopy shows the presence of Al2O3 and MgAl2O4 spinel,confirmed by EDS and SAD pattern,at the composite interface.The composite shows a lower density of 2.16 g/cm^3 which is a major ad vantage for weight reduction compared to the monolithic alloy(2.7 g/cm^3).展开更多
Carbon fibers(CFs)are widely used in various cutting-edge fields,such as aerospace,military,automobiles,and sports,owing to their unique combination of excellent mechanical properties,good thermal stability,and lightw...Carbon fibers(CFs)are widely used in various cutting-edge fields,such as aerospace,military,automobiles,and sports,owing to their unique combination of excellent mechanical properties,good thermal stability,and lightweight.However,their inherent super-black appearance makes it difficult to satisfy the aesthetic/fashion requirements of the colorful world,and the flammability of CFs severely limits their practical utilization in high-temperature and other extreme environments.Herein,we fabricated full-color tunable colored CFs on a large-scale via atomic layer deposition,based on the monolayer film interference strategy.CFs exhibited brilliant colors and excellent environmental durability in extreme environments,such as intense ultraviolet(UV)irradiation,accelerated laundering,friction,high-temperature,and low-temperature treatments.Colored CFs also exhibited excellent fire-retardant performance that could withstand alcohol-lamp flame burning for 60 min.Our work provides insights into an innovative material/structural design that can help achieve rapid development of the CF industry and global carbon neutrality/sustainability.展开更多
基金supported by the National Natural Science Foundation of China (51772060,51672059,and 51621091)financially sponsored by Heilongjiang Touyan Team Program and the Fundamental Research Funds for the Central Universities (HIT.OCEF.2021003).
文摘The field of electromagnetic wave absorption(EWA)requires the adaptability,tenability,and multifunction of high-performance materials in the future.The design and preparation of EWA materials aiming at performance requirements is the latest research hotspot.Here,a performancedriven strategy for simultaneously coordinating different target performances was proposed to optimize the structure of the periodical long continuous carbon/glass fiber fabric(PCGF)materials through algorithm and simulation.The optimized structure of the PCGF not only improves the impedance matching,but also introduces the induced orientation effect for a high cooperative loss of conductivity,resonance,and periodic structure.The flexible PCGF shows a broad effective absorption bandwidth(EAB)of 32.7 GHz covering a part of the C-band and the whole X-,Ku-,K-,and Ka-bands with a thickness(d)of only 0.92 mm and a density of 5.6×10^(−4) kg·cm^(−3).This highly designable fabric is promising for the EWA practical application owing to integrating the characteristics of good flexibility,acid and alkali resistance,bending resistance,excellent mechanical properties,and easy large-scale preparation.
文摘Self-lubrication is one of the smart material properties required for producing components with enhanced wear resistance and low coefficient of friction.Bidirectional(BD)satin weave polyacrylonitrile(PAN)based carbon fiber(Cf)fabric preform was successfully infiltrated with Al 6061 alloy by squeeze infiltration process.The infiltrated composite shows uniform distribution of carbon fibers in the matrix with the elimination of porosities,fiber damage and close control on the formation of deleterious aluminum carbide(Al4C3)phase.Cf/Al composite exhibits remarkable wear resistance compared to unreinforced alloy due to the formation of self-lubricating tribolayer on the pin surface,which intercepts the contact of matrix metal to counter surface.The BD carbon fiber enhanced the hardness and compressive strength of the composite by restraining the plastic flow behavior of matrix.High resolution transmission electron microscopy shows the presence of Al2O3 and MgAl2O4 spinel,confirmed by EDS and SAD pattern,at the composite interface.The composite shows a lower density of 2.16 g/cm^3 which is a major ad vantage for weight reduction compared to the monolithic alloy(2.7 g/cm^3).
基金We thank Y.Huang from Tsinghua University for the help in characterizing colored CFs samplessupported by the National Natural Science Foundation of China(Grant Nos.51903008 and U1910209)+6 种基金Science and Technology Research Project of the Educational Commission of Hubei Province(D20211703)Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant No.2023433)Natural Science Foundation of Shanxi Province(Grant No.20210302124128)Open Foundation of State Key Laboratory of Bio-Fibers and Eco-Textiles from Qingdao University(Grant No.2020105)Hubei Key Laboratory of Digital Textile Equipment,Wuhan Textile University(Grant No.DTL 2022006)National Engineering Laboratory for Modern Silk,Soochow University(Grant No.SDGC2148)National Local Joint Laboratory for Advanced Textile Processing and Clean Production(Grant No.17).
文摘Carbon fibers(CFs)are widely used in various cutting-edge fields,such as aerospace,military,automobiles,and sports,owing to their unique combination of excellent mechanical properties,good thermal stability,and lightweight.However,their inherent super-black appearance makes it difficult to satisfy the aesthetic/fashion requirements of the colorful world,and the flammability of CFs severely limits their practical utilization in high-temperature and other extreme environments.Herein,we fabricated full-color tunable colored CFs on a large-scale via atomic layer deposition,based on the monolayer film interference strategy.CFs exhibited brilliant colors and excellent environmental durability in extreme environments,such as intense ultraviolet(UV)irradiation,accelerated laundering,friction,high-temperature,and low-temperature treatments.Colored CFs also exhibited excellent fire-retardant performance that could withstand alcohol-lamp flame burning for 60 min.Our work provides insights into an innovative material/structural design that can help achieve rapid development of the CF industry and global carbon neutrality/sustainability.