Influences of burial process on diagenesis and high-quality reservoir development of deep-ultra-deep clastic rocks:A case study of Lower Cretaceous Qingshuihe Formation in southern margin of Junggar Basin,NW China

Taking the Lower Cretaceous Qingshuihe Formation in the southern margin of Junggar Basin as an example,the influences of the burial process in a foreland basin on the diagenesis and the development of high-quality reservoirs of deep and ultra-deep clastic rocks were investigated using thin section,scanning electron microscope,electron probe,stable isotopic composition and fluid inclusion data.The Qingshuihe Formation went through four burial stages of slow shallow burial,tectonic uplift,progressive deep burial and rapid deep burial successively.The stages of slow shallow burial and tectonic uplift not only can alleviate the mechanical compaction of grains,but also can maintain an open diagenetic system in the reservoirs for a long time,which promotes the dissolution of soluble components by meteoric freshwater and inhibits the precipitation of dissolution products in the reservoirs.The late rapid deep burial process contributed to the development of fluid overpressure,which effectively inhibits the destruction of primary pores by compaction and cementation.The fluid overpressure promotes the development of microfractures in the reservoir,which enhances the dissolution effect of organic acids.Based on the quantitative reconstruction of porosity evolution history,it is found that the long-term slow shallow burial and tectonic uplift processes make the greatest contribution to the development of deep-ultra-deep high-quality clastic rock reservoirs,followed by the late rapid deep burial process,and the progressive deep burial process has little contribution.

Impacts of Depositional Facies and Diagenesis on Reservoir Quality:A Case Study from the Rudist-bearing Sarvak Formation,Abadan Plain,SW Iran

An integrated geological-petrophysical analysis of the rudist-bearing sequence of the Cretaceous Sarvak Formation is given one giant oilfield,and provides an improved understanding of this main reservoir in the Abadan Plain,in the Zagros Basin,SW Iran.The main objective of this study is to evaluate reservoir potential of the Sarvak Formation,and then to utilize the calibrated well log signature to correlate reservoir potential in un-cored wells.Eight main facies are recognized and categorized in five facies groups:lagoon,shoal,rudist-biostrome,slope,and shallow open marine,deposited on a shelf carbonate platform.Given the distribution of diagenetic products and their effects on pore systems,three diagenetic facies namely,(DF-1)low dissolution and cementation;(DF-2);high dissolution;and(DF-3)high cementation are differentiated.The initial sedimentary characteristics in combination with distribution of diagenetic products play an important role in reservoir quality heterogeneity.The effect of diagenetic processes related to disconformities mainly depends on the facies nature below these surfaces.Grain-dominated facies of shoal and rudist debris,observed below the Cenomanian–Turonian disconformity,are mostly characterized by high dissolution and interconnected pore systems.Finally,depositional and diagenetic facies in the studied wells are correlated by petrophysical well log data,leading to distribution of the reservoir zones.Data obtained can be utilized for efficient reservoir characterization of the Sarvak Formation and its equivalent units in the Arabian Plate.

Diagenesis of the Paleogene Sandstones in the DN2 Gas Field,Kuqa Foreland Basin and its Link to Tectonics

We investigated diagenesis of the sandstones from the DN2 Gas Field of the Kuqa Foreland Basin(KFB),in order to infer the timing of fluid migration and discuss the linkage between fluids and tectonics.The textures and chemical composition of authigenic minerals,fluid evidence from fluid inclusions and formation water measurements were all used to fulfill this aim.Eodiagenesis occurred with the participation of meteoric water and connate water.Mesodiagenesis is related to high salinity fluids,which were attributed as originating from the overlying Neogene Jidike Formation evaporite(principal minerals including halite,anhydrite,glauberite,carnallite and thenardite).The onset of high salinity fluid migration is inferred to occur during the late Miocene(12.4-9.2 Ma)through the use of homogenization temperatures measured in the present study and K-Ar dating of authigenetic illites from previous work.This period is consistent with the crucial phase(13-10 Ma)that witnessed the rapid uplift of the southern Tianshan Mts and the stage when calcite and anhydrite veins formed in the studied strata.We thus argue that diagenesis related to high salinity fluids occurred as a response to the Tianshan Mts'rapid uplift and related tectonic processes.The flow of high salinity fluids was probably driven by a density gradient and channeled and focused by fractures formed contemporaneously.

Sandstone Diagenesis and Porosity Evolution of Paleogene in Huimin Depression

The sandstones of the paleogene in the Huimin Depression have undergone numerous diagenetic processes, such as compaction, cementation, dissolution, metasomasis and recrystallization. The first three — compaction, cementation and dissolution — affect reservoir properties most intensively. An average porosity loss due to compaction is 0.78% per 100 meters, slightly higher in the central and southern parts and lower in the northern. Cementation has resulted in the porosity loss from 8% to 20% at a depth below 1,500 meters. Dissolution, which in most cases is the dissolution of feldspar and of carbonate cement, primarily occurs in two depth intervals, from 1,400 to 2,500 meters and 2,700 to 4,000 meters respectively. New porosity is created through dissolution from 4% to 14%. The sandstones experienced stage A and stage B of early diagenesis and stage A of late diagenesis. At present, most of them are experiencing Phase A2 of late diagenesis. The types of pores in the sand reservoir can be grouped into primary and secondary ones.

Diagenesis and Its Effect on Reservoir Quality of Silurian Sandstones,Tabei Area,Tarim Basin,China

The diagenetic processes of the Tabei sandstones in the Tarim Basin include compaction, cementation （quartz overgrowths, calcite, clay minerals and a minor amount of pyrite）, and dissolution of the feldspar and calcite cement. Porosity was reduced by compaction from an assumed original 40% to about 22.1%. Cementation reduced porosity to 26.6%. The Tabei sandstones lost a little more porosity by compaction than by cementation. Quartz cementation, especially syntaxial quartz overgrowth, is a major cause of porosity-loss in many reservoirs in moderately to deeply buried sandstone. Calcite cementation played a key role in the porosity evolution of sandstones. At the early stage of burial, the early calcite cement occupied most of the pore spaces resulting in significant porosity. On the other hand, some primary porosity has been preserved due to incomplete filling or the presence of scattered patches of calcite cement. In addition to calcite, several clay minerals, including illite and chlorite occurred as pore-filling and pore-lining cements. The pore-lining chlorite may have helped in retaining the porosity by preventing the precipitation of syntaxial quartz overgrowths. Illite, which largely occurred as hair-like rims around the grains and bridges on the pore throats, caused a substantial deterioration of penetrability of the reservoir. Calcite cement dissolution was extensive and contributed significantly to the development of secondary porosity.

The role of provenance in the diagenesis of siliciclastic reservoirs in the Upper Triassic Yanchang Formation,Ordos Basin,China

A better understanding of the controls on reservoir quality has become essential in the petroleum exploration in recent years. Determining the original composition of tile sediment framework is important not only for paleogeographic reconstructions, but it is also vital tbr predicting the nature of physical and chemical diagenesis of the potential reservoirs. Depositional setting and diagenesis are important factors in controlling the type and quality of most siliciclastic reservoirs. We studied the Upper Triassic Chang 8 and 6 members, where the relationship between sediment provenance and diagenesis was examined. The study attempts to clarify sediment provenance and post-depositional diagenetic modifications of the sandstones through systematic analytical methods including petrographic macro- and microscopic analysis of grain and heavy mineral types, and measurements of the palaeocurrent direction of the Yanchang Formation sediments in the outcrops in order to determine the provenance of the studied sediments. Furthermore, the relationship between framework grains, pore types and diagenesis of the sediments was analyzed by thin section petrographic characterization using a polarizing microscope. Additionally, a JEOL JSM-T330 scanning electron microscope （SEM） equipped with a digital imaging system was used to investigate the habits and textural relationships of diagenetic minerals. On the basis of our results, we believe that sediment provenance is a significant factor which controls the type and degree of diagenesis which may be expected in sandstones. In the Chang 8 and 6 members, tile formation of chlorite rims and laumontite cement was observed where volcanic rock fragments constitute a large part of the framework grains. Furthermore, high biotite content provides abundant iron and magnesium and enables the tbnnation of chlorite rims due to biotite hydrolysis. In addition, ductile deformation of biotite leads to strong mechanical compaction of the sediments. Conversely, high feldspar content diminishes the degree of mechanical compaction, however the dissolution of feldspar minerals in sandstones is commonly observed. Apart from feldspars, quartz and other rigid fi＇amework grains highly control the degree of mechanical compaction during the initial stage of burial （0-2 km）.

Diagenesis of the Triassic Yanchang Formation Tight Sandstone Reservoir in the Xifeng–Ansai Area of Ordos Basin and its Porosity Evolution

This work aims to reveal the evolution of the porosity in the Triassic Yanchang Formation tight sandstone reservoir of the Xifeng-Ansai area of Ordos Basin. Based on destructive diagenesis （compaction and cementation） and constructive diagenesis （dissolution） of sandstone reservoirs, this study analyzed the diagenesis characteristics of the tight sandstone reservoirs in this area, and discussed the relationship between sandstone diagenesis and porosity evolution in combination with present porosity profile characteristics of sandstone reservoir. The effect simulation principle was employed for the mathematical derivation and simulation of the evolution of porosity in the Yanchang Formation tight sandstone reservoirs. The result shows that compaction always occurs in tight sandstone reservoirs in the Yanchang Formation, and cementation occurs when the burial depth increases to a certain value and remains ever since. Dissolution occurs only at a certain stage of the evolution with window features. In the corresponding present porosity profile, diagenesis is characterized by segmentation. From the shallow to the deep, compaction, compaction, cementation and dissolution, compaction and cementation occur successively. Therefore, the evolution of sandstone porosity can be divided into normal compaction section, acidification and incremental porosity section, and normal compaction section after dissolution. The results show that the evolution of sandstone porosity can be decomposed into porosity reduction model and porosity increase model. The superposition of the two models at the same depth in the three stages or in the same geological time can constitute the evolution simulation of the total porosity in sandstone reservoirs. By simulating the evolution of sandstone reservoir porosity of the eighth member in Xifeng area and the sixth member in Ansai area, it shows that they are similar in the evolution process and trend. The difference is caused by the regional uplift or subsidence and burial depth.

Diagenesis and Metamorphism of Triassic Flysch Along Profile Zoige-Lushan,Northwest Sichuan,China

We used illite and chlorite crystaHinities, index minerals, mineral assemblages, polytype and domain size of white mica, electron microprobe analysis （EMPA）, b0 geobarometer and chlorite geothermometer to quantify the diagenetic and metamorphic overprint on the Triassic flysch formations in the Songpan-Garze orogen along profile Zoige-Lushan, northwest Sichuan. Two anchizones, two epizones, one diagenetic zone and a transition belt in-between them are defined on the basis of the obtained data. lllite crystallinity correlates strongly with the best mean domain size of mica and moderately with chlorite crystallinity. 2M1 white mica polytype are observed within the epizone whilst 2M1 and 1M polytypes occur in the anchizone and diagenetic zone. Epizonal metamorphism reached maximum temperatures of 370℃±21℃ at low-to intermediate pressure conditions. Clay minerals underwent Ostwald ripening during metamorphism. Rocks from both sides of the Longmenshan fault reveal contrasting degrees of metamorphic overprint： on the northwest side of the Longmenshan fault, epimetamorphic conditions contrast with diagenetic rocks on the southeast side.

Diagenesis and Their Succession of Gas-bearing and Non-gas-bearing Reservoirs in the Sulige Gas Field of Ordos Basin,China

Comparisons have been made among lithology, diagenesis, and reservoir characteristics of gas-bearing and non-gas-bearing ones in the Sulige gas field of the Ordos Basin based on the laboratory analysis of thin sections, scanning electron microscope, and liquid inclusion of the reservoirs. The reservoirs of the Sulige gas field are now in the middle stage of diagenesis and have undergone compaction, cementation and dissolution. The secondary pore of the reservoir originated from the dissolution of the feldspar and tuff because of the organic acid action from the source rocks during the diagenetic middle stage. Gas-bearing reservoirs are common in soluble pore diagenetic facies of coarse detritus quartzose sandstone, whereas non-gas-bearing ones are common in tense compaction diagenetic facies of mud-bearing medium-fine detritus quartzose sandstone and residual intergranular pore diagenetic facies of mud-bearing medium-coarse detritus quartzose sandstone. The secondary pore is developed in gas-bearing reservoirs of the Sulige gas-field as the medium-coarse grain reservoirs formed in a powerful sedimentary environment and experienced strong dissolution. However, the sediments of fine grain size form the non-gas-bearing reservoirs because of less residual primary pore and secondary pore.

Genesis Types and Diagenesis Compaction Mechanisms of Sandstone Rreservoirs in Dynamic Environments in Oil/Gas Basins in China

The diversity of sandstone diagenesis mechanisms caused by the complex geological conditions of oil/gas basins in China could hardly be reasonably explained by the traditional concept of burial diagenesis. Three genesis types of thermal diagenesis, tectonic diagenesis and fluid diagenesis are presented on the basis of the dynamic environment of the oil/gas basins and.the controlling factors and mechanisms of sandstone diagenesis. Thermal diagenesis of sandstone reservoirs is related not only to the effect of formation temperature on diagenesis, but also to the significant changes in diagenesis caused by geothermal gradients. The concept of thermal compaction is presented. Thermal compaction becomes weaker with increasing depth and becomes stronger at a higher geothermal gradient. At the same formation temperature, the sandstone porosity in the region with a lower geothermal gradient is e^0.077＋0.0042T times higher than that in the region with a higher geothermal gradient. Both sudden and gradual changes are observed in diagenetic evolution caused by structural deformation. Average sandstone compaction increased by 0.1051% for every 1.0MPa increase of lateral tectonic compressional stress, while late tectonic napping helped to preserve a higher porosity of underlying sandstone reservoir. Fluid diagenesis is a general phenomenon. The compaction caused by fluid properties is significant. The coarser the grain size, the stronger the fluid effect on compaction. The greater the burial depth, the weaker the fluid effect on compaction for the specific reservoir lithology and the greater the difference in the fluid effects on compaction between different grain sizes.

Applications of Light Stable Isotopes(C, O, H) in the Study of Sandstone Diagenesis: A Review

This article reviews the applications of light stable isotope, including carbon, oxygen and hydrogen, in thestudies on origin and formation temperature of authigenic carbonate, quartz and clay minerals. Theoretical knowledge andanalytical methods for major light stable isotopes are introduced in detail. Negative and positive δ^(13)C values indicatesignificant differences on the origin of carbonate cements. The δ^(18)O value is an effective palaeotemperature scale forauthigenic minerals formation. Various fractionation equations between δ^(18)O and temperature are proposed for carbonatecements, quartz cements and clay minerals, whose merit and demerit, applicable conditions are clarified clearly. Clumpedisotope analysis can reconstruct the temperature of carbonate precipitation with no requirement on the δ^(18)O of initial waters,which makes temperature calculation of carbonate cements formation more convenient and accurate. Hydrogen and oxygenisotopes mainly reflect the origin of diagenetic fluid for clay mineral formation, providing reliable evidence for diageneticenvironment analysis. This work aims at helping researchers for better understanding the applications of light stable isotopein sandstone diagenesis.

Alkaline diagenesis and its genetic mechanism in the Triassic coal measure strata in the Western Sichuan Foreland Basin,China

The reservoir of the upper Triassic Xujiahe Formation (T3x) in the Western Sichuan Foreland Basin is a set of terrigenous clastic rocks in an environment of coal measure sediments. Diagenesis greatly controls the physical properties of the reservoir through different responses of minerals to acidic and alkaline diagenetic environment. The dissolution of unstable components such as feldspar, rock fragments, carbonate cement, and clay minerals is the major source of secondary pores under acidic diagenesis, while the dissolution of quartz increases the reservoir space in the fault-fold zone of Longmen Mountain and Leikoupo paleo-hills. The dissolution of quartz is a result of cross-formation flow of fluid in the Himalaya epoch and the invasion of alkaline formation water from the Triassic Leikoupo and Jialingjiang formations through fault and fracture systems. In the vertical succession, acidic dissolution occurs at a shallow depth of less than 2,180 m, and alkaline dissolution occurs at a greater depth of more than 2,280 m. The reservoir space is formed by the influence of both acidic and alkaline dissolution in the depth interval of 2,180–2,280 m.

Diagenesis and reservoir quality of the fourth member sandstones of Shahejie formation in Huimin depression,eastern China

Petrographic analysis combined with various techniques, such as scanning electron microscopy and X-ray diffraction, was used to assess the timing of growth and original mineral cements, the controls on reservoir and reservoir quality of the fourth member sandstones of Shahejie formation (Es4). The Es4 sandstones are mostly arkose and lithic arkose, rarely feldspathic litharenite, with an average mass fraction of quartz 51.6%, feldspar 33.8% and rock fragments 14.6% (Q51.6F33.8R14.6). They have an average framework composition (mass fraction) of quartz 57.10%, K-feldspar 5.76%, sodium-calcium feldspar 13.00%, calcite 5.77%, dolomite 5.63%, siderite 0.95%, pyrite 0.30%, anhydrite 0.04%, and clay mineral 11.46%. The diagenentic minerals typically include kaolinite, illite-smectite (I/S), illite, chlorite, authigenetic quartz and feldspar, and carbonate and pyrite. Es4 sandstone has undergone stages A and B of eodiagenesis, and now, it is experiencing stage A of mesodiagenesis. Reservoir quality is predominantly controlled by the mechanical compaction, for example, 45.65% of the original porosity loss is related to compaction. The original porosity loss related with cementation is only 26.00%. The reservoir quality is improved as a result of dissolution of feldspar, rock fragment and so forth. The porosity evolved from dissolution varies from 3% to 4%.

Characteristics of Mesozoic-Cenozoic tectonic diagenesis in the Kuqa area of the Tarim Basin,China

Tectonic diagenesis is a common and important geological phenomenon. We can fully understand the diagenesis of compressional basins through studying tectonic diagenesis. In this paper, we presented the tectonic diagenetic characteristics in the Kuqa area of the Tarim Basin by integrated method of geological analysis and paleotectonic stress. The results showed that the Mesozoic-Cenozoic tectonic diagenesis affected sandstone compaction evolution mainly through physical mechanisms. It showed characteristics of abrupt change and nonthermal indicator (it means that sandstone compaction can not be explained by thermal diagenetic compaction alone because actual sandstone compaction was larger than thermal compaction), which were different from the thermal and fluid diagenesis. Compared with thermal diagenesis, tectonic diagenesis had a typical tectonic compaction in very short time, and many phases of tectonic deformation showed multiple abrupt changes of compaction. There are obvious differences between tectonic and thermal diagenetic compaction, leading to sandstone compaction being larger than the thermal compaction under the same thermal evolution stage in the areas where tectonic deformation happened. The stronger the tectonic deformation, the more obvious the difference. Tectonic process changed the stress distribution through changing the tectonic deformation styles, resulting in different tectonic diagenesis effects. Therefore, tectonic diagenesis of Mesozoic-Cenozoic in the Kuqa area can be divided into four types including rigid rock restraint, fault ramp, low angle fault slippage, and napping.

Division of diagenesis reservoir facies and its control——Case study of Chang-3 reservoir in Yangchang formation of Fuxian exploration area in northern Shaanxi

By dividing the diagenetic reservoir facies and studying its distribution,we can effectively evaluate reservoirs.Using an analytical method for mutual relationships among diagenesis of reservoirs,structural characteristics and the origin of types of sand,we classified the diagenetic reservoir of the Yanchang formation Chang-3 oil layer into different types and analyzed the factors controlling this high quality reservoir.The results show that:1) the catagenesis of the Chang-3 oil layer in the Fuxian region is complex and variable;2) mechanical compaction,pressure solutions and cementation of all kinds of authogenous minerals decreases porosity by 28.13% and 3) corrosion increases porosity by 3.39%.Cementation and corrosion of laumontite is a kind of catagenesis which makes this region different from other exploratory regions.The original amount and rate of corrosion of laumontite are the main factors for the increase in laumontite porosity.The Chang-3 oil layer developed four kinds of diagenetic reservoir facies,of which the weak compaction facies,i.e.,laumontite corrosion and overgrowth,of the original pore reservoir facies has the most promising diagenesis.Its distribution is controlled by a sedimentary facies zone and is widely developed in the original truncated tributary channel facies belt of the delta plain.The development of this high quality reservoir is controlled by the distribution of sedimentary sand bodies and secondarily-eroded porosity of laumontite in the Chang-3 oil layer of the Fuxian exploratory region.

Lincang Superlarge Germanium Deposit in Yunnan Province,China: Sedimentation,Diagenesis,Hydrothermal Process and Mineralization

The mineralization is related closely to sedimentation, diagenesis and hydrothermal processes. In this paper, investigations are carried out on coal occurrence, maceral composition, inorganic minerals, trace elements and huminite reflectance. It is concluded that the source of Lincang superlarge deposit is mainly the muscovite granite in the west edge of the basin. During sedimentation, Ge (germanium) was leached out and entered the basin. Ge was adsorbed by lower organism and humic substances in water. Lincang lignite underwent three thermal processes: peatification, early diagenesis and hydrothermal transformation. During peatification, Ge was adsorbed or complexed by humic colloids. During early diagenesis, the Ge associated with humic acids was hard to mobilize or transport. Most of Ge entered the structure of huminite while a small amount of Ge was associated with residual humic acids as complex or humate. During hydrothermal transformation, the heated natural water or deep fluid from basement encountered the coal layer within tectonic weak zone. SO 2- 4 was reduced by coal organic matter. Pyrite and calcite formed. Hydrothermal process did not contribute significantly to mineralization.

Carbonate Diagenesis Controlled by Glacioeustatic Sea-Level Changes: A Case Study from the Carboniferous-Permian Boundary Section at Xikou, China

The platform-facies carbonate rocks of the Carboniferous-Permian boundary strata are well developed and outcropped in Xikou （西口）, Zhen＇an （镇安） County, Shaanxi （ 陕西 ） Province, China. The carbonate diagencsis in the Carboniferous-Permian boundary section at Xikou contains many processes with conspicuous effects, including micritization, cementation, mechanical and chemical compaction, neomorphism, and dissolution. Based on mineralogical composition and microfabrics, the diagenetic environments are distinguished into marine, near surface meteoric and burial environments. Detailed petrographical observation of abundant thin sections integrated with previous studies on sequence stratigraphy reveals that the carbonate diagenesis in the Carboniferous-Permian boundary section is related to the relative stratigraphic position of the rocks in the high-frequency cycles and controlled by the glacioeustatic sea-level changes. There are distinctive differences in diagenetic patterns between the lower transgressive sequence and the upper regressive sequence in a cyclothem. The diagenesis in the lower transgressive sequence is mainly characterized by pressure dissolution and recrystallization of mudstone and wackstone in a burial environment, and the diagenesis in the upper regressive sequence by cementation and leaching of freshwater in a meteoric environment.

Quantitative research of diagenesis:its effect on pore evolution of the Fuyu oil reservoir in the north Qijia region

From observing cores of 18 wells,identifying 175 ordinary thin sections and 61 thin casting sections,energy spectrum analyses of 37 samples,homogenization temperature measurement of fluid inclusions of 11 samples,we determine the types of diagenesis and pores of the Fuyu oil reservoir in the north Qijia region.We classified the pores and measured their plane porosity using CIA 2000,the software of rock image analysis,calculated the effect of different kinds of diagenesis on porosity,studied the controlling actions of diagenesis to pore evolution quantitatively,combined with burial history,thermal history and their diagenetic environments.Our results show that mechanical compaction and carbonate cementation are the major destructive diagenesed,developed during early diagenesis stages.The reduction in porosity by mechanical compaction and carbonate cementation are about 25% and 8%,while the destructive intensity of siliceous cementation and clay mineral cementation is relatively much smaller,i.e.,the reduction of porosity is about 2% and 0.2% Dissolution is constructive diagenesis,the increment of porosity is about 6%.There are four diagenesis evolution stages,during which the porosity reduced from 30%～38% to 2%～20%.Mechanical compaction and early cementation are the main diageneses in the early diagenesis stages,when porosity was reduced to 2%～10%.Dissolution is the main diagenesis of an A I substage of the middle diagenesis stage,when porosity increased 1%～8%.The dissolution of the A Ⅱ substage of the middle diagenesis stage affected by late cementation,raised porosity 1%～5%.The porosity varied slightly during the middle stage B.

Geochemistry of Sedimentation and Diagenesis in Qixia Formation (Early Permian) of Badong, Hubei Province, China: Implications for T-R Cycle Interpretation

Combined with sedimentary observation and mineralogical research on a type of drusy celestite of early diagenesis in origin, this geochemical study on the Qixia Formation at the Shuibuya Section, Badong County, Hubei Province of south China evaluates the contribution of sedimentation and diagenesis to the mass fractions of CaO, Al 2O 3, MgO, SiO 2, Fe 2O 3, Na 2O, K 2O, Mn, Sr, P and Ba in the carbonates. The Sr, initially released from the stabilization of carbonate calcium mineral, precipitated with sulfate ion as celestite in early diagenetic environment, where sulfate reduction was the minimum. Then it redistributed in burial diagenetic environment, where celestite was replaced by calcite. The fractions of the MgO and SiO 2 in the carbonates were mainly modified by the early dolomitization and silicification respectively. That of the Na 2O was overprinted by the burial diagenesis. Multivariate statistical analysis on data of sixty bulk rocks indicates that the mass fractions of the Al 2O 3, K 2O, Fe 2O 3, Mn, CaO, P and Ba were affiliated with the sedimentary factor despite the obvious decrease of CaO during early dolomitization and silicification. Among them, the Al 2O 3 and K 2O mainly represent the detrital components. In addition, a dysaerobic sedimentary background was confirmed by trace element measurement and information derived from the formation of the celestite. This genetic discrimination facilitates the interpretation of the transgressive regressive (T R) cycle and specialities featured this unusual carbonate unit.

Early diagenesis of redox-sensitive trace metals in the northern Okinawa Trough

The early diagenesis processes of several redox-sensitive trace metals(RSMs)(Mo, U and V) were studied with several short sediment cores(~25 cm) collected in the northern Okinawa Trough(OT). Pore water vertical profiles indicated that the sedimentary environments in all cores were between oxic and suboxic, not yet reaching anoxic sulfidic conditions. The recycling process of Mo in sediments was clearly associated with Mn and yielded little authigenic accumulation, while U showed a downcore increase in sediment and its authigenic mass accumulation rate(MAR) was estimated to be ~23% of the Changjiang(Yangtze) and Huanghe(Yellow) riverine flux. Benthic diffusive fluxes and MAR were calculated and the comparison of them showed that U and V fluxes matched relatively well both in direction and in magnitude, implying that diffusion processes at the sedimentwater interface is the dominant process controlling the remobilization or burial of V and U in northern OT. This work provided a systematic study(both in pore water and solid phase) on the RSMs geochemical behaviors during early diagenesis process, yielding a quantitative assessment of the remobilization or burial fluxes of the RSMs in northern OT. Such studies are in general lacking in the coastal margin of Northwest Pacific Ocean.