期刊文献+
共找到197篇文章
< 1 2 10 >
每页显示 20 50 100
Calculation of effective temperature for pavement rutting using numerical simulation methods 被引量:1
1
作者 祝谭雍 马涛 黄晓明 《Journal of Southeast University(English Edition)》 EI CAS 2016年第3期362-367,共6页
In order to predict the long-term rutting of asphalt pavement, the effective temperature for pavement rutting is calculated using the numerical simulation method. The transient temperature field of asphalt pavement wa... In order to predict the long-term rutting of asphalt pavement, the effective temperature for pavement rutting is calculated using the numerical simulation method. The transient temperature field of asphalt pavement was simulated based on actual meteorological data of Nanjing. 24-hour rutting development under a transient temperature field was calculated in each month. The rutting depth accumulated under the static temperature field was also estimated and the relationship between constant temperature parameters was analyzed. Then the effective temperature for pavement rutting was determined based on the rutting equivalence principle. The results show that the monthly effective temperature is above 40 t in July and August, while in June and September it ranges from 30 to 40 Rutting development can be ignored when the monthly effective temperature is less than 30 t. The yearly effective temperature for rutting in Nanjing is around 38. 5 t. The long-term rutting prediction model based on the effective temperature can reflect the influences of meteorological factors and traffic time distribution. 展开更多
关键词 transient temperature field long-term rutting effective temperature numerical simulation finite element method
下载PDF
Extending a release-and-recapture scheme to single atom optical tweezer for effective temperature evaluation 被引量:3
2
作者 何军 杨保东 +1 位作者 张天才 王军民 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第7期151-157,共7页
By recording the fluorescence fraction of the cold atoms remaining in the magneto-optical trap (MOT) as a function of the release time, the release-and-recapture (R&R) method is utilized to evaluate the effective... By recording the fluorescence fraction of the cold atoms remaining in the magneto-optical trap (MOT) as a function of the release time, the release-and-recapture (R&R) method is utilized to evaluate the effective temperature of the cold atomic ensemble. We prepare a single atom in a large-magnetic-gradient MOT and then transfer the trapped single atom into a 1064-nm microscopic optical tweezer. The energy of the single atom trapped in the tweezer is further reduced by polarization gradient cooling (PGC) and the effective temperature is evaluated by extending the R-R technique to a single atom tweezer. The typical effective temperature of a single atom in the tweezer is improved from about 105 μK to about 17 μK by applying the optimum PGC phase. 展开更多
关键词 single atom optical tweezer effective temperature release-and-recapture technique
下载PDF
Utilizing a new soil effective temperature scheme and archived satellite microwave brightness temperature data to estimate surface soil moisture in the Nagqu region, Tibetan Plateau of China 被引量:1
3
作者 TIAN Hui Mudassar IQBAL 《Journal of Arid Land》 SCIE CSCD 2018年第1期84-100,共17页
Since the early 2000s, many satellite passive microwave brightness temperature (BT) archives, such as the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR-E) BTs, have become the useful ... Since the early 2000s, many satellite passive microwave brightness temperature (BT) archives, such as the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR-E) BTs, have become the useful resources for assessing the changes in the surface and deep soil moistures over both arid and semi-arid regions. In this study, we used a new soil effective temperature (T scheme and the archived AMSR-E BTs to estimate surface soil moisture (SM) over the Nagqu region in the central Tibetan Plateau, China. The surface and deep soil temperatures required for the calculation of regional-scale T were obtained from outputs of the Community Land Model version 4.5 (CLM4.5). In situ SM measurements at the CEOP-CAMP/Tibet (Coordinated Enhanced Observing Period Asia-Australia Monsoon Project on the Tibetan Plateau) experimental sites were used to validate the AMSR-E-based SM estimations at regional and single-site scales. Furthermore, the spatial distribution of monthly mean surface SM over the Nagqu region was obtained from 16 daytime AMSR-E BT observations in July 2004 over the Nagqu region. Results revealed that the AMSR-E-based surface SM estimations agreed well with the in situ-based surface SM measurements, with the root mean square error (RMSE) ranging from 0.042 to 0.066 m3/m3 and the coefficient of determination (R2) ranging from 0.71 to 0.92 during the nighttime and daytime. The regional surface soil water state map showed a clear spatial pattern related to the terrain. It indicated that the lower surface SM values occurred in the mountainous areas of the northern, mid-western and southeastern parts of Nagqu region, while the higher surface SM values appeared in the low elevation areas such as the Tongtian River Basin, Namco Lake and bog meadows in the central part of Nagqu region. Our analysis also showed that the new T^scheme does not require special fitting parameters or additional assumptions, which simplifies the data requirements for regional-scale applications. This scheme combined with the archived satellite passive microwave BT observations can be used to estimate the historical surface SM for hydrological process studies over the Tibetan Plateau regions. 展开更多
关键词 soil effective temperature archived AMSR-E brightness temperature CLM4.5 soil temperature output Cumulative Distribution Function (CDF) matching surface soil moisture Tibetan Plateau
下载PDF
The Effective Temperature and the Absolute Magnitude of the Stars
4
作者 Angel Fierros Palacios 《Journal of High Energy Physics, Gravitation and Cosmology》 2016年第1期66-74,共9页
The theoretical framework developed by A.S. Eddington for the study of the inner structure and stability of the stars has been modified by the author and used in this work to show that knowing the effective temperatur... The theoretical framework developed by A.S. Eddington for the study of the inner structure and stability of the stars has been modified by the author and used in this work to show that knowing the effective temperature and the absolute magnitude, the basic parameters of any gaseous star can be calculated. On the other hand, a possible theoretical explanation of the Hertzsprung-Russel Diagram is presented. 展开更多
关键词 The effective temperature and the Absolute Magnitude of the Stars
下载PDF
Phase-field simulations of the effect of temperature and interface for zirconiumδ-hydrides
5
作者 陈子航 盛杰 +8 位作者 刘瑜 施小明 黄厚兵 许可 王越超 武帅 孙博 刘海风 宋海峰 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期701-710,共10页
Hydride precipitation in zirconium cladding materials can damage their integrity and durability.Service temperature and material defects have a significant effect on the dynamic growth of hydrides.In this study,we hav... Hydride precipitation in zirconium cladding materials can damage their integrity and durability.Service temperature and material defects have a significant effect on the dynamic growth of hydrides.In this study,we have developed a phasefield model based on the assumption of elastic behaviour within a specific temperature range(613 K-653 K).This model allows us to study the influence of temperature and interfacial effects on the morphology,stress,and average growth rate of zirconium hydride.The results suggest that changes in temperature and interfacial energy influence the length-to-thickness ratio and average growth rate of the hydride morphology.The ultimate determinant of hydride orientation is the loss of interfacial coherency,primarily induced by interfacial dislocation defects and quantifiable by the mismatch degree q.An escalation in interfacial coherency loss leads to a transition of hydride growth from horizontal to vertical,accompanied by the onset of redirection behaviour.Interestingly,redirection occurs at a critical mismatch level,denoted as qc,and remains unaffected by variations in temperature and interfacial energy.However,this redirection leads to an increase in the maximum stress,which may influence the direction of hydride crack propagation.This research highlights the importance of interfacial coherency and provides valuable insights into the morphology and growth kinetics of hydrides in zirconium alloys. 展开更多
关键词 zirconium hydride phase-field method temperature effect mismatch degree
下载PDF
Effective(kinetic freeze-out) temperature, transverse flow velocity, and kinetic freeze-out volume in high energy collisions 被引量:2
6
作者 Muhammad Waqas Fu-Hu Liu +1 位作者 Li-Li Li Haidar Mas’ud Alfanda 《Nuclear Science and Techniques》 SCIE CAS CSCD 2020年第11期36-49,共14页
The transverse momentum spectra of different types of particles produced in central and peripheral gold–gold(Au–Au)and inelastic proton–proton(pp)collisions at the Relativistic Heavy Ion Collider,as well as in cent... The transverse momentum spectra of different types of particles produced in central and peripheral gold–gold(Au–Au)and inelastic proton–proton(pp)collisions at the Relativistic Heavy Ion Collider,as well as in central and peripheral lead-lead(Pb–Pb)and pp collisions at the Large Hadron Collider,are analyzed by the multi-component standard(Boltzmann–Gibbs,Fermi–Dirac,and Bose–Einstein)distributions.The obtained results from the standard distribution give an approximate agreement with the measured experimental data by the STAR,PHENIX,and ALICE Collaborations.The behavior of the effective(kinetic freeze-out)temperature,transverse flow velocity,and kinetic freeze-out volume for particles with different masses is obtained,which observes the early kinetic freezeout of heavier particles as compared to the lighter particles.The parameters of emissions of different particles are observed to be different,which reveals a direct signature of the mass-dependent differential kinetic freeze-out.It is also observed that the peripheral nucleus–nucleus(AA)and pp collisions at the same center-of-mass energy per nucleon pair are in good agreement in terms of the extracted parameters. 展开更多
关键词 Transverse momentum spectra effective temperature Kinetic freeze-out temperature Transverse flow velocity Kinetic freeze-out volume
下载PDF
Effective accumulated temperature and developmental threshold temperature for Semanotus bifasciatus(Motschulsky) in Beijing 被引量:6
7
作者 MA Li-qin GAO Shi-ji +2 位作者 WEN Jun-bao ZONG Shi-xiang XU Zhi-chun 《Forestry Studies in China》 CAS 2008年第2期125-129,共5页
In order to understand the occurrence and development of Semanotus bifasciatus (Motschulsky), a borer insect of Platycladus orientalis in parts of northern and eastern China and to improve its prediction, the develo... In order to understand the occurrence and development of Semanotus bifasciatus (Motschulsky), a borer insect of Platycladus orientalis in parts of northern and eastern China and to improve its prediction, the developmental threshold temperature (C1) and effective accumulated temperature (K) of S. bifasciatus were determined under conditions of constant and variable temperatures. The results show that under constant temperatures the value of C1 has a range of 8.90±1.77℃and the value of K lies between 95.19±13.14 degree-day for eggs; the values for larvae are C1= 13.26±3.06℃ and the number of degree-day is K 2,885.07±187.87 degree-day; for pupae the ranges are C1 = 8.93±2.49℃ and K= 131.20±25.63 degree-day. Under the condition of ambient temperatures, the values for eggs are C1= 17.33±1.24℃ and K= 70.79±8.99 degree-day. It is suggested that S. bifasciatus adults over-winter in a state of dormancy, not at a diapause. Warm winter may accelerate the life cycle ofS. bifasciatus. Equations can be used to predict an early occurrence ofS. bifasciatus. 展开更多
关键词 Semanotus bifasciatus (Motschulsky) developmental threshold temperature effective accumulated temperature eggs larvae PUPAE
下载PDF
Effects of effective stress and temperature on permeability of sandstone from CO2-plume geothermal reservoir 被引量:5
8
作者 Y.Z.Sun L.Z.Xie +2 位作者 B.He C.Gao J.Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2016年第6期819-827,共9页
Rock is generally complex and heterogeneous,therefore the heterogeneity effects of effective stress and temperature on permeability should be taken into account.In this study,two-part Hooke’s model(TPHM) is introdu... Rock is generally complex and heterogeneous,therefore the heterogeneity effects of effective stress and temperature on permeability should be taken into account.In this study,two-part Hooke’s model(TPHM) is introduced to understand the influences of effective stress and temperature on permeability of soft and hard parts(two parts) of rock based on coupling thermo-hydro-mechanical tests.Under a fixed temperature level(25 ℃.35 ℃.50 ℃.65 ℃.80 ℃.90 ℃ and 95 ℃).the tests were carried out in a conventional triaxial system whereas the confining pressure was remained at 50 MPa.and the pore pressure was increased to the specified levels step by step.i.e.8 MPa,18 MPa.28 MPa.38 MPa.41 MPa,44 MPa.46 MPa and 48 MPa.The temperature-dependent relationships for two parts permeabilities are proposed on the basis of the initial test results.We point out that temperature of 65 ℃-90 ℃ is the threshold for the development of CO2-plume geothermal(CPC) reservoir sandstone cracking under low effective stress(2-9 MPa) based on the relationship between temperature and soft part permeability.Furthermore,we discuss the effect of temperature on the two parts in the rock.The results indicate that as the temperature increases from 25 ℃ to 65 ℃.the flow channel in the hard part has a stronger response to temperature than that in the soft part at a fixed effective stress level,which is opposite to the situation of effective stress.Considering that natural rock is generally heterogeneous with non-uniform pore structure,we suggest a physical interpretation of the phenomenon that before the thermal cracking threshold the two parts have different responses to temperature. 展开更多
关键词 Sandstone from CO2-plume geothermal (CPG) reservoir temperature and effective stress Flow channel Two parts permeabilities
下载PDF
Simulations and Measurement of Electron Energy and Effective Electron Temperature of Nanosecond Pulsed Argon Plasma
9
作者 WEN Xueqing XIN Yu +1 位作者 FENG Chunlei DING Hongbin 《Plasma Science and Technology》 SCIE EI CAS CSCD 2012年第1期40-47,共8页
The behavior of argon plasma driven by nanosecond pulsed plasma in a low-pressure plasma reactor is investigated using a global model, and the results are compared with the experimental measurements. The time evolutio... The behavior of argon plasma driven by nanosecond pulsed plasma in a low-pressure plasma reactor is investigated using a global model, and the results are compared with the experimental measurements. The time evolution of plasma density and the electron energy probability function are calculated by solving the energy balance and Boltzmann equations. During and shortly after the discharge pulse, the electron energy probability function can be represented by a bi-Maxwellian distribution, indicating two energy groups of electrons. According to the effective electron temperature calculation, we find that there are more high-energy electrons that play an important role in the excitation and ionization processes than low-energy electrons. The effective electron temperature is also measured via optical emission spectroscopy to evaluate the simulation model. In the comparison, the simulation results are found to be in agreement with the measure- ments. Furthermore, variations of the effective electron temperature are presented versus other discharge parameters, such as pulse width time, pulse rise time and gas pressure. 展开更多
关键词 effective electron temperature model optical emission spectrum nanosecond pulsed glow discharge GLOBAL
下载PDF
Developmental Threshold Temperature and Effective Accumulated Temperature of Potosia brevitarsis Lewis
10
作者 Liu Zheng Sun Yan +3 位作者 Chen Bing Zhang Xuekun Wang Shaoshan Li Guoying 《Plant Diseases and Pests》 CAS 2013年第5期29-32,共4页
[ Objective] The paper was to study the relationship between temperature and development of Potosia brevitarsis Lewis. [ Methods] Six constant tem- peratures (21, 24, 27, 30, 33 and 36 ℃ ) were set in the laborator... [ Objective] The paper was to study the relationship between temperature and development of Potosia brevitarsis Lewis. [ Methods] Six constant tem- peratures (21, 24, 27, 30, 33 and 36 ℃ ) were set in the laboratory to study developmental threshold temperature and effective accumulated temperature of P. brevitarsis. [ Result] The developmental durations of various states of P. brevitarsis were shortened with the increasing temperature ranged from 21 ℃ to 36 ℃ ; the developmental rates were accelerated with the increasing temperature. The developmental threshold temperatures of egg, larva, pupa and pre-ovipesition of adult were estimated to be 12.79, 9.15, 14.86 and 13.80 ℃, respectively; the effective accumulated temperature were 136.25, 3 031.31,308.92 and 98.35 d · ℃, respectively. The developmental threshold temperature and effective amcumulated temperature for one complete generation were 9.96 ℃ and 3 628.73 d · ℃, re- spectively. Combined with meteorological data, the theoretical generation number of P. brevitarsis occurred in Shihezi was presumed to be one per year, which was basically coincided with actual occurrence generations in fields. [ Conclusion] The paper provided theoretical basis for effective control against P. brevitarsis. 展开更多
关键词 Potosia brevitarsis Lewis Developmental threshold temperature effective accumulated temperature
下载PDF
Interface bond degradation and damage characteristics of full-length grouted rock bolt in tunnels with high temperature
11
作者 Yunpeng Hu Mingming Zheng +5 位作者 Wenkai Feng Jianjun Tong Yicheng Wang Qiling Wang Kan Liu Longzhen Ye 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第10期2639-2657,共19页
Full-length grouted bolts play a crucial role in geotechnical engineering thanks to their excellent stability.However,few studies have been concerned with the degrading performance of grouted rock bolts caused by exte... Full-length grouted bolts play a crucial role in geotechnical engineering thanks to their excellent stability.However,few studies have been concerned with the degrading performance of grouted rock bolts caused by extensive and continuous heat conduction from surrounding rocks in high-geothermal tunnels buried more than 100 m(temperature from 28C to 100C).To investigate the damage mechanism,we examined the time-varying behaviors of grouted rock bolts in both constant and variable temperature curing environments and their damage due to the coupling effects of high temperature and humidity through mechanical and micro-feature tests,including uniaxial compression test,pull-out test,computed tomography(CT)scans,X-ray diffraction(XRD)test,thermogravimetric analysis(TGA),etc.,and further analyzed the relationship between grout properties and anchorage capability.In order to facilitate a rapid assessment and control of the anchorage performance of anchors in different conditions,results of the interface bond degradation tests were correlated to environment parameters based on the damage model of interfacial bond stress proposed.Accordingly,a thermal hazard classification criterion for anchorage design in high-geothermal tunnels was suggested.Based on the reported results,although high temperature accelerated the early-stage hydration reaction of grouting materials,it affected the distribution and quantity of hydration products by inhibiting hydration degree,thus causing mechanical damage to the anchorage system.There was a significant positive correlation between the strength of the grouting material and the anchoring force.Influenced by the changes in grout properties,three failure patterns of rock bolts typically existed.Applying a hot-wet curing regime results in less reduction in anchorage force compared to the hot-dry curing conditions.The findings of this study would contribute to the design and investigations of grouted rock bolts in high-geothermal tunnels. 展开更多
关键词 High-geothermal tunnels Anchoring structure Coupling effect of temperature and humidity Bond degradation Interfacial damage mechanism
下载PDF
Comparison of mechanical properties in high temperature and thermal treatment granite 被引量:20
12
作者 尹土兵 舒荣华 +2 位作者 李夕兵 王品 刘希灵 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第7期1926-1937,共12页
Static mechanical experiments were carried out on granite after and under different temperatures using an electro-hydraulic and servo-controlled material testing machine with a heating device. Variations in obvious fo... Static mechanical experiments were carried out on granite after and under different temperatures using an electro-hydraulic and servo-controlled material testing machine with a heating device. Variations in obvious form, stress-strain curve, peak strength, peak strain and elastic modulus with temperature were analyzed and the essence of rock failure modes was explored. The results indicate that, compared with granite after the high temperature treatment, the brittle-ductile transition critical temperature is lower, the densification stage is longer, the elastic modulus is smaller and the damage is larger under high temperature. In addition, the peak stress is lower and the peak strain is greater, but both of them change more obviously with the increase of temperature compared with that of granite after the high temperature treatment. Furthermore, the failure modes of granite after the high temperature treatment and under high temperature show a remarkable difference. Below 100 ℃, the failure modes of granite under both conditions are the same, presenting splitting failure. However, after 100 ℃, the failure modes of granite after the high temperature treatment and under high temperature present splitting failure and shear failure, respectively. 展开更多
关键词 GRANITE thermal treatment high temperature effect static mechanical properties failure properties
下载PDF
Research on the influence of ocean temperature on XCTD profiler single-mode fiber transmission channel 被引量:2
13
作者 郑羽 付孝洪 +4 位作者 高宇 方静 王金海 李红志 刘宁 《Marine Science Bulletin》 CAS 2015年第1期50-60,共11页
XCTD, as one of the most important instruments for the deep sea exploration, is an important device for deep-sea hydrological data acquisition. But some difficult technical problems of traditional metal enameled wire ... XCTD, as one of the most important instruments for the deep sea exploration, is an important device for deep-sea hydrological data acquisition. But some difficult technical problems of traditional metal enameled wire channel have become the major bottleneck for XCTD development. Aiming at this problem, this paper puts forward with using single-mode fiber as the transmission channel of XCTD. Firstly, this paper makes a brief analysis on the problems of using enameled wire as transmission channel faces. Secondly, it analyzes the advantages of the single mode fiber technology. Finally, it makes theoretical research and experimental verification of the influence of seawater temperature change on the optical fiber transmission channel. The experimentat results show that the error rate at the transmission rate of 10 MB/S is 0, and the loss can be negligible when the single-mode fiber channel is used in the sea water and the seawater temperature changes from 0 to 20℃. This method will greatly increase the rate of signal transmission and the transmission stability. And this paper shows that using the single-mode fiber as the transmission channel of XCTD has certain feasibility. 展开更多
关键词 XCTD profiler signal-mode optical fiber effect of ocean temperature transmission performance
下载PDF
Kinetic Implication from Temperature Effect on Hydrogen Evolution Reaction at Ag Electrode
14
作者 康婧 林楚红 +1 位作者 姚瑶 陈艳霞 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第1期63-68,I0003,I0004,共8页
Hydrogen evolution reaction (HER) at polycrystalline silver electrode in 0.1 mol/L HClO4 solution is investigated by cyclic voltammetry in the temperature range of 278-333 K. We found that at electrode potential φa... Hydrogen evolution reaction (HER) at polycrystalline silver electrode in 0.1 mol/L HClO4 solution is investigated by cyclic voltammetry in the temperature range of 278-333 K. We found that at electrode potential φa,app decreases with φ, while pre-exponential factor A remains nearly unchanged,which conforms well the prediction from Butler-Volmer equation. In contrast, with φ nega-tive shifts from the onset potential for HER to the potential of zero charge (PZC≈-0.4 V), both Ea,app and A for HER increase (e.g., Ea,app increases from 24 kJ/mol to 32 kJ/mol). The increase in Ea,app and A with negative shift in φ from -0.25 V to PZC is explained by the increases of both internal energy change and entropy change from reactants to the transition states, which is correlated with the change in the hydrogen bond network during HER. The positive entropy effects overcompensate the adverse effect from the increase in the activation energy, which leads to a net increase in HER current with the activation energy negative shift from the onset potential of HER to PZC. It is pointed out that entropy change may contribute greatly to the kinetics for electrode reaction which involves the transfer of electron and proton, such as HER. 展开更多
关键词 Hydrogen evolution reaction Ag electrode temperature effect Activation energy Pre-exponential factor Internal energy Entropy change
下载PDF
Determination of Effective Degree-Day for Supporting Chemical Control Against Cutworms (Lep. Noctuinae) in the Sugar Beet
15
作者 Magdalena Jakubowska Felicyta Walczak JerzyJ6zefatLipa 《Journal of Agricultural Science and Technology(A)》 2012年第3期314-326,共13页
The aim of the research was to connect two methods of the chemical control. The first chemical treatments were applied according to the signalling method. The second method was applied according to the phonological cr... The aim of the research was to connect two methods of the chemical control. The first chemical treatments were applied according to the signalling method. The second method was applied according to the phonological criterion i.e., on the basis of the values of effective temperatures sums or heat sums for cutworms. The studies on cutworms infesting sugar beet crops were carried out in the years 2005-2008. The observation performed during the moth flights from May to September included two species, turnip moth (Agrotis segetum Den. & Schiff.) and heart-and-dart moth (A. exclamationis L.). The dynamics of moth flights was recorded in reference to readings of climatic conditions registered with the field meteorological stations set up near the light traps. Observations on cutworm occurrence during the vegetation season were done every 5-7 days. Moreover, additional studies were conducted under control conditions in the growth chambers at three programmed temperatures (17°C, 20 °C, 24 °C) and relative humidity (50%-70%). Based on the results the values for the heat sum of 501.1 °C and effective temperatures sum of 230.0 °C were determined for the developmental stages of cutworm. On the base of the results obtained it can be stated that the improved method of short-term forecasting can be an alternative solution in the integrated protection management against pest. 展开更多
关键词 Cutworms monitoring DEGREE-DAY sums of effective temperatures light trap sugar beet (Beta vulgaris L.).
下载PDF
Detailed Temperature-dependent Study of n-Heptane Pyrolysis at High Temperature 被引量:3
16
作者 丁俊霞 何国钟 张亮 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第3期329-336,I0004,共9页
n-Heptane is the most important straight chain paramn in the fossil-fuel industry. In this work, pyrolysis behavior of n-heptane at high temperature is investigated by a se- ties of ReaxFF based reactive molecular dyn... n-Heptane is the most important straight chain paramn in the fossil-fuel industry. In this work, pyrolysis behavior of n-heptane at high temperature is investigated by a se- ties of ReaxFF based reactive molecular dynamics simulations. Temperature effects on the n-heptane pyrolysis and related products distributions have been detailedly analyzed. The simulation results indicate that the temperature effect is characterized in stages. High tern- perature can accelerate the decomposition of n-heptane, but the influence becomes small after it reaches a certain level. According to the different reaction behaviors, pyrolysis of n-heptane could be divided into three stages. The variation trends of the mass fraction evolu- tion of ethylene (C2H4), C3, and C4 calculated from reactive molecular dynamics simulations are in good agreement with the previous experimental results. The apparent activation en- ergy extracted from the first-order kinetic analysis is 53.96 kcal/mol and a pre-exponential factor is 55.34×10^13 s-1, which is reasonably consistent with the experimental results. 展开更多
关键词 N-HEPTANE PYROLYSIS temperature effect REAXFF
下载PDF
Temperature Effect on Hydrogen Evolution Reaction at Au Electrode
17
作者 汤志强 廖玲文 +2 位作者 郑勇力 康婧 陈艳霞 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第4期469-474,I0004,共7页
The temperature dependence of hydrogen evolution reaction (HER) at a quasi-single crystalline gold electrode in both 0.1 mol/L HCl04 and 0.1 mol/L KOH solutions was investigated by cyclic voltammetry. HER current di... The temperature dependence of hydrogen evolution reaction (HER) at a quasi-single crystalline gold electrode in both 0.1 mol/L HCl04 and 0.1 mol/L KOH solutions was investigated by cyclic voltammetry. HER current displays a clear increase with reaction overpotential (η) and temperature from 278-333 K. In 0.1 mol/L HClO4 the Tafel slopes are found to increases slightly with temperature from 118 mV/dec to 146 mV/dec, while in 0.1 mol/L KOH it is ca. 153±15 mV/dec without clear temperature-dependent trend. The apparent activation energy (Ea) for HER at equilibrium potential is ca. 48 and 34 kJ/mol in 0.1 mol/L HC104 and 0.1 mol/L KOH, respectively. In acid solution, Ea decreases with increase in η, from Ea-37 kJ/mol (η=0.2 V) to 30 kJ/mol (η=0.35 V). In contrast, in 0.1 mol/L KOH, Ea does not show obvious change with U. The pre-exponential factor (A) in 0.1 mol/L HC104 is ca. 1 order higher than that in 0.1 mol/L KOH. Toward more negative potential, in 0.1 mol/L HC104 A changes little with potential, while in 0.1 mol/L KOH it displays a monotonic increase with U. The change trends of the potential-dependent kinetic parameters for HER at Au electrode in 0.1 mol/L HClO4 and that in 0.1 mol/L KOH are discussed. 展开更多
关键词 Hydrogen evolution reaction Au electrode temperature effect Activation energy Symmetric factor
下载PDF
Temperature effect on aerobic denitrification and nitrification 被引量:11
18
作者 XIE Shu guang ZHANG Xiao jian WANG Zhan sheng 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2003年第5期669-673,共5页
Nitrogen loss without organic removal in biofilter was observed and its possible reason was explained. A lower hydraulic loading could improve aerobic denitrification rate. Aerobic denitrification was seriously affect... Nitrogen loss without organic removal in biofilter was observed and its possible reason was explained. A lower hydraulic loading could improve aerobic denitrification rate. Aerobic denitrification was seriously affected by low temperature(below 10℃). However, nitrification rate remained high when the temperature dropped from 15℃ to 5℃. It seemed the autotrophic biofilm in BAF could alleviate the adverse effect of low temperature. 展开更多
关键词 aerobic denitrification NITRIFICATION BIOFILTER temperature effect
下载PDF
Properties of failure mode and thermal damage for limestone at high temperature 被引量:13
19
作者 MAO Xian-biao ZHANG Lian-ying +1 位作者 LI Tian-zhen LIU Hai-shun 《Mining Science and Technology》 EI CAS 2009年第3期290-294,共5页
The mechanical properties of limestone such as the stress-strain curve, the variable characteristics of peak strength and the modulus of elasticity of limestone were studied under the action of temperatures ranging fr... The mechanical properties of limestone such as the stress-strain curve, the variable characteristics of peak strength and the modulus of elasticity of limestone were studied under the action of temperatures ranging from room temperature to 800 °C.Our results show that:1) the temperature has not clear effect on the mechanical properties of limestone from room temperature to 600 °C.However, the mechanical properties of limestone deteriorate rapidly when the temperature is above 600 °C.In this case, the peak stress and modulus of elasticity decrease rapidly.When the temperature reaches 800 °C, the entire process, showing the stress-strain curve is displayed indicating an obvious state of plastic-deformation;2) the failure mode of limestone shows the breakdown of tensile strength from room temperature to 600 °C, as well as the compress shearing damage over 600 °C;3) combining our test results with the concept of thermal damage, a thermal damage equation was derived. 展开更多
关键词 LIMESTONE high temperature effect mech-anical properties clamage
下载PDF
Effect of Temperature on Gas Hold-up in Aerated Stirred Tanks 被引量:7
20
作者 高正明 施力田 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2003年第2期204-207,共4页
Gas holdups in ambient gassed and hot sparged systems with multiple modern impellers and the effect of temperature on gas holdup are reported. The operating temperature has a great impact on gas holdup though the gas ... Gas holdups in ambient gassed and hot sparged systems with multiple modern impellers and the effect of temperature on gas holdup are reported. The operating temperature has a great impact on gas holdup though the gas dispersion regime in the hot sparged system is similar to the ambient gassed condition. The gas holdup under the elevated temperature and the ambient gassed operation is successfully correlated. With the same total gas flow rate and power input, the gas holdup in the hot sparged system (say near the boiling point) is only about half of that in the ambient system. The results imply that almost all existing hot sparged reactors have been designed on the basis of incorrect estimates of the gas holdup during operation. 展开更多
关键词 gas holdup temperature effect gas dispersion hot sparged reactors radar probe stirred tank
下载PDF
上一页 1 2 10 下一页 到第
使用帮助 返回顶部