Self-oscillating systems abound in the natural world and offer substantial potential for applications in controllers,micro-motors,medical equipments,and so on.Currently,numerical methods have been widely utilized for ...Self-oscillating systems abound in the natural world and offer substantial potential for applications in controllers,micro-motors,medical equipments,and so on.Currently,numerical methods have been widely utilized for obtaining the characteristics of self-oscillation including amplitude and frequency.However,numerical methods are burdened by intricate computations and limited precision,hindering comprehensive investigations into self-oscillating systems.In this paper,the stability of a liquid crystal elastomer fiber self-oscillating system under a linear temperature field is studied,and analytical solutions for the amplitude and frequency are determined.Initially,we establish the governing equations of self-oscillation,elucidate two motion regimes,and reveal the underlying mechanism.Subsequently,we conduct a stability analysis and employ a multi-scale method to obtain the analytical solutions for the amplitude and frequency.The results show agreement between the multi-scale and numerical methods.This research contributes to the examination of diverse self-oscillating systems and advances the theoretical analysis of self-oscillating systems rooted in active materials.展开更多
Magnetorheological elastomers(MREs)hold significant promise in various fields such as automotive engineering,and civil engineering,where they serve as intelligent materials.Depending on the application of an external ...Magnetorheological elastomers(MREs)hold significant promise in various fields such as automotive engineering,and civil engineering,where they serve as intelligent materials.Depending on the application of an external magnetic field,these materials exhibit varying magnetorheological and viscoelastic properties,including shear stress,yield stress,dynamic moduli,and damping.In this work,a new type of MRE,termed self-healing MREs(SH-MREs),has been developed by adding a novel self-healing agent into existing MREs.The dynamic modulus and loss factor of SH-MREs with different compositions have been characterized under various conditions of frequency,temperature,and strain.The results show that as the strain value increases,the loss factor also increases.Moreover,the loss factor initially increases and then decreases with increasing magnetic field strength.Although higher concentrations of ferromagnetic particles increase the loss factor,they enhance the operational range due to their better responsiveness to magnetic fields.SH-MREs demonstrate improved damping capabilities,attributed to the formation of coordination bonds between ferromagnetic particles and the self-healing agent.The stable structure increases the viscosity of MREs.The results of the regression model suggest a direct proportionality between sensitivity to the magnetic field and the ferromagnetic particle concentration.展开更多
Dielectric elastomers(DEs)require balanced electric actuation performance and mechanical integrity under applied voltages.Incorporating high dielectric particles as fillers provides extensive design space to optimize ...Dielectric elastomers(DEs)require balanced electric actuation performance and mechanical integrity under applied voltages.Incorporating high dielectric particles as fillers provides extensive design space to optimize concentration,morphology,and distribution for improved actuation performance and material modulus.This study presents an integrated framework combining finite element modeling(FEM)and deep learning to optimize the microstructure of DE composites.FEM first calculates actuation performance and the effective modulus across varied filler combinations,with these data used to train a convolutional neural network(CNN).Integrating the CNN into a multi-objective genetic algorithm generates designs with enhanced actuation performance and material modulus compared to the conventional optimization approach based on FEM approach within the same time.This framework harnesses artificial intelligence to navigate vast design possibilities,enabling optimized microstructures for high-performance DE composites.展开更多
[Objectives] This study was conducted to develop a polyurea elastomer which can be sprayed on the surface of expanded polystyrene (EPS) floating balls, so as to improve the surface strength and service life of the flo...[Objectives] This study was conducted to develop a polyurea elastomer which can be sprayed on the surface of expanded polystyrene (EPS) floating balls, so as to improve the surface strength and service life of the floating balls. [Methods] The effects of the types and amounts of isocyanate, chain extenders and polyether polyols on the gelation rate, adhesion and wear resistance of polyurea elastomer were investigated, and it was finally determined the preparation process of polyurea elastomer using liquid isophorone diisocyanate (IPDI) and amino-terminated polyether (D2000) as the main raw materials, dimethylthiotoluene diamine (E300) as the chain extender and silica as the wear resistance modifier through two-step solution polymerization of prepolymerization and chain extension. [Results] The physical properties and chemical resistance tests of spray polyurea elastomer showed that it had good physical properties and acid and alkali resistance, and could meet the requirements of spraying and protection of EPS floating ball surface in marine environment. [Conclusions] Polyurea elastomer coating can improve the aging resistance, wear resistance and acid and alkali resistance of EPS floating balls, and prevent them from being fragile and floating randomly to form marine floating garbage which results in "white pollution".展开更多
During the production of nitrile rubber, significant amounts of nitrogen in the form of ammonium are generated in the wastewater. The discharge of this high-nitrogen wastewater can lead to serious environmental issues...During the production of nitrile rubber, significant amounts of nitrogen in the form of ammonium are generated in the wastewater. The discharge of this high-nitrogen wastewater can lead to serious environmental issues, including eutrophication, disruption of aquatic ecosystems, and groundwater contamination. To mitigate these impacts, this research explored the bioremediation capabilities of the macroalgae Ulva lactuca (Chlorophyta) for removing nitrogen from nitrile rubber production wastewater. The study employed single-phase and Michaelis-Menten decay models based on ammonium consumption, using various dilutions of wastewater to identify the optimal concentration for treatment. The physiological state of the macroalgae was monitored by measuring the photosynthetic capacity and specific growth rate during the experiments. In the presence of U. lactuca, ammonium concentrations decreased in all treatment groups, confirming that the ammonium kinetics conformed to both applied models. Our results show that U. lactuca effectively reduces ammonium concentrations, with an approximate removal rate of 0.020 µM·g−1·min−1 across different wastewater concentrations (70%, 80%, 90%, and 100%). Notably, the treatments with 70%, 80%, and 90% wastewater strength achieved about 67% reduction in ammonium, demonstrating the alga’s capacity to treat high-nitrogen wastewater. The photosynthetic performance of U. lactuca initially declined in control conditions but stabilized across all treatments, highlighting its adaptability. The kinetic analysis using the Michaelis-Menten model indicated a Vmax of 1342 μM·g−1·DMh−1, suggesting a robust capacity for ammonium uptake when fully saturated. Our study underscores the potential of Ulva lactuca as a cost-effective and efficient agent for wastewater bioremediation, particularly in settings with high nitrogen loads.展开更多
Two types of elastomeric vibration isolators used for equipment vibration isolation in aerospace vehicles are considered for the present study. These isolators are constructed using elastomers mounted in steel encasin...Two types of elastomeric vibration isolators used for equipment vibration isolation in aerospace vehicles are considered for the present study. These isolators are constructed using elastomers mounted in steel encasings. These isolators are initially deformed statically and dynamic loads are applied on the deformed configuration. To capture the static deformation, equivalent static load corresponding to its load rating and specified displacements are created. Static deformation is computed using Finite Element methods with four node axi-symmetric element which include the geometric non-linear effect for steel and with standard Yeoh hyper-elastic material model for elastomers(Muhammed and Zu, 2012) [1]. Yeoh material constants are derived from uni-axial tension test data of the elastomer specimen. These isolators are subjected to harmonic and random excitations in the pre-deformed state. For numerical analysis, elastomeric constants at dynamic conditions are obtained as complex function of frequency using Dynamic Mechanical Analyzer(DMA) for a range of frequencies. The standard material model of Yeoh is modified incorporating frequency dependant material characteristics and damping in the range of frequencies of interest. A multiplicative non-separable variables law is derived for Yeoh material model to include the effect of static pre-stress, based on the methodology given in literature(Nashif et al.,1985;Beda et al., 2014) [2,3]. The modifications of Yeoh model suitable for frequency domain analysis is the novelty in the present study. In the analysis, while dynamic loads are applied, the configuration is updated considering initial static loading. The frequency response of the isolators is computed using material properties evaluated at progressive dynamic strains until a match in natural frequency is observed. Appropriate damping corrections are then incorporated to match the test observed transmissibility. Then updated material properties are used to compute the random response which showed good agreement with results of experiments, validating the approach taken for the development of this model.展开更多
Electrically conductive elastomer composites(CECs)with segregated networks of conductive nanofillers show high potential in stretchable strain sensors due to balanced mechanical and electrical properties,yet the sensi...Electrically conductive elastomer composites(CECs)with segregated networks of conductive nanofillers show high potential in stretchable strain sensors due to balanced mechanical and electrical properties,yet the sensitivity at low strain is generally insufficient for practical application.Herein,we report an easy and effective way to improve the resistive response to low strain for CECs with segregated network structure via adding stiff alumina into carbon nanostructures(CNS).The CEC containing 0.7 wt%CNS and 5 wt%Al_(2)O_(3) almost sustains the same elasticity(elongation at break of~900%)and conductivity(0.8 S/m)as the control,while the piezoresistive sensitivity is significantly improved.Thermoplastic polyurethane(TPU)composites with a segregated network of hybrid nanofillers(CNS and Al_(2)O_(3))show much higher strain sensitivity(Gauge factor,GF-566)at low strain(45%strain)due to a local stress concentration effect,this sensitivity is superior to that of TPU/CNS composites(GF-11).Such a local stress concentration effect depends on alumina content and its distribution at the TPU particle interface.In addition,CECs with hybrid fillers show better reproducibility in cyclic piezoresistive behavior testing than the control.This work offers an easy method for fabricating CECs with a segregated filler network offering stretchable strain sensors with a high strain sensitivity.展开更多
Stretchable elastomer-based electrodes are considered promising energy storage electrodes for next-generation wearable/flexible electronics requiring various shape designs.However,these elastomeric electrodes suffer f...Stretchable elastomer-based electrodes are considered promising energy storage electrodes for next-generation wearable/flexible electronics requiring various shape designs.However,these elastomeric electrodes suffer from the limited electrical conductivity of current collectors,low charge storage capacities,poor interfacial interactions between elastomers and conductive/active materials,and lack of shape controllability.In this study,we report hierarchically micro/nano-wrinkle-structured elastomeric electrodes with notably high energy storage performance and good mechanical/electrochemical stabilities,simultaneously allowing various form factors.For this study,a swelling/deswelling-involved metal nanoparticle(NP)assembly is first performed on thiol-functionalized polydimethylsiloxane(PDMS)elastomers,generating a micro-wrinkled structure and a conductive seed layer for subsequent electrodeposition.After the assembly of metal NPs,the conformal electrodeposition of Ni and NiCo layered double hydroxides layers with a homogeneous nanostructure on the micro-wrinkled PDMS induces the formation of a micro/nano-wrinkled surface morphology with a large active surface area and high electrical conductivity.Based on this unique approach,the formed elastomeric electrodes show higher areal capacity and superior rate capability than conventional elastomeric electrodes while maintaining their electrical/electrochemical properties under external mechanical deformation.This notable mechanical/electrochemical performance can be further enhanced by using spiral-structured PDMS(stretchability of~500%)and porous-structured PDMS(areal capacity of~280μAh cm^(-2)).展开更多
In the past decades,ion conductive polymers and elastomers have drawn worldwide attention for their advanced functions in batteries,electroactive soft robotics,and sensors.Stretchable ionic elastomers with dispersed s...In the past decades,ion conductive polymers and elastomers have drawn worldwide attention for their advanced functions in batteries,electroactive soft robotics,and sensors.Stretchable ionic elastomers with dispersed soft ionic moieties such as ionic liquids have gained remarkable attention as soft sensors,in applications such as the wearable devices that are often called electric skins.A considerable amount of research has been done on ionic-elastomer-based strain,pressure,and shear sensors;however,to the best of our knowledge,this research has not yet been reviewed.In this review,we summarize the materials and performance properties of engineered ionic elastomer actuators and sensors.First,we review three classes of ionic elastomer actuators—namely,ionic polymer metal composites,ionic conducting polymers,and ionic polymer/carbon nanocomposites—and provide perspectives for future actuators,such as adaptive four-dimensional(4D)printed systems and ionic liquid crystal elastomers(iLCEs).Next,we review the state of the art of ionic elastomeric strain and pressure sensors.We also discuss future wearable strain sensors for biomechanical applications and sports performance tracking.Finally,we present the preliminary results of iLCE sensors based on flexoelectric signals and their amplification by integrating them with organic electrochemical transistors.展开更多
Ethylene propylene diene elastomers (EPDM) of various side chains and molecular weights were prepared as thin discs and the effects of electric field strength and temperature on the electromechanical properties were i...Ethylene propylene diene elastomers (EPDM) of various side chains and molecular weights were prepared as thin discs and the effects of electric field strength and temperature on the electromechanical properties were investigated. The electrical conductivity, the dielectric constant, the storage and loss moduli (G' and G'), the storage modulus response (ΔG’1000 V/mm), and the storage modulus sensitivity (ΔG’1000 V/mm/G’0) of the elastomers of different ethylene norbornene (ENB) contents and molecular weights were measured under electric field strengths varying from 0 V/mm to 1000 V/mm and at temperatures between 300 K and 380 K. The storage modulus response and sensitivity increase with increasing molecular weight and dielectric constant, consistent with the existing theory. However, for the case of EPDMs with different ENB contents, the storage modulus response and sensitivity vary inversely with the dielectric constant. EDPM is potentially a new type of electroactive materials.展开更多
Elastomers are used in numerous engineering applications such as sealing components, it is therefore important to devise a method that can accurately predict elastomers’ response to load. Many applications that emplo...Elastomers are used in numerous engineering applications such as sealing components, it is therefore important to devise a method that can accurately predict elastomers’ response to load. Many applications that employ the use of these materials subject them to a nonlinear large strain;therefore the simple Hooke’s law is not sufficient to describe their material behaviour. This paper presents an approach to obtain material properties of elastomer under compression loading, based on hyperelastic strain formulation, through experimental test and finite element modelling. The paper focuses on the isotropic incompressible behaviour exhibited by elastomers, and obtains strain energy functions that satisfy the characteristic properties of a hyperelastic model. Data obtained from compression test on a nitrile rubber (NBR) specimen were used as material input into ABAQUS®—a finite element analysis software. A least square fitting technique was used to determine the coefficients of various stable hyperelastic models, based on Drucker’s stability criteria within the software. The strain energy functions obtained concentrate on material parameters which are related to physical quantities of the material molecular network they are subjected to in practical application. The approach benefits from mathematical simplicity, and possesses the property of the deformation mode dependency. Furthermore, a model validation procedure using a step-by-step method for parameters estimation is explained. The work herein is a nonlinear finite element modelling process that leads to an optimal solution and can be employed not only for elastomeric seals, but also for similar engineering assets.展开更多
Dielectric elastomer actuator (DEA) show promise for mechatronic applications due to the advantages of dielectric elastomer, such as lightweight, flexible, low cost, high strain, etc, and many configurations of DEAs...Dielectric elastomer actuator (DEA) show promise for mechatronic applications due to the advantages of dielectric elastomer, such as lightweight, flexible, low cost, high strain, etc, and many configurations of DEAs have been demonstrated. As a kind of linear actuator, cone DEAs are studied in some laboratory prototypes due to easy manufacturing, however, their performance have not been exploited fully. Based on the working principle of DEA, a four-bar linkage mechanism is designed to provide negative stiffness preload, which can increase displacement output of actuator (outer diameter 100 mm) to 17 mm. Three cone actuating units are assembled in parallel to enhance the maximum force output to 5.07 N. Loading experiments of actuator in forward and backward strokes are performed, the experimental results show that backward stroke has stronger actuating capability than forward stroke, accordingly application of actuator is recommended. Four factors rather than applied voltage, i.e., number of actuating units, pre-stretch ratio, inner diameter, and outer diameter, are determined as influencing factors for Taguchi method. Then the performance objectives of actuator, i.e., displacement output, maximum force output, and maximum work in backward stroke, are investigated based on L9(34) Taguchi orthogonal design. The mean signal-to-noise (S/N) ratio based on the larger-the-better criterion is calculated according to the acquired displacement and force output. Analytical results show that outer diameter has the most significant influence on displacement output, and maximum force out and work output are influenced most by number of actuating units. Inner diameter also has an important effect on the performance objectives of actuator, while pre-stretch ratio has the least influence. The proposed performance investigation is helpful for the design and application of cone actuator in mechatronic system.展开更多
Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare e...Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare earth - containing composite elastomer. It is found that mechanical performance can be improved remarkably. Analyzed by infrared spectrometry (IR), differential scanning calorimetry (DSC) and cross-linking densitometry, the relationship between structure and performance was discussed.展开更多
When air is pumped in, a tubular balloon initially inflates slightly and homogeneously. A short section of the balloon then forms a bulge, which coexists with the unbulged section of the balloon. As more air is pumped...When air is pumped in, a tubular balloon initially inflates slightly and homogeneously. A short section of the balloon then forms a bulge, which coexists with the unbulged section of the balloon. As more air is pumped in, the bulged section elongates at the expense of the unbulged section, until the entire balloon is bulged. The phenomenon is analogous to the liquid-to-vapor phase transition. Here we study the bulging transition in a dielectric elastomer tube as air is pumped into the balloon and a voltage is applied through the thickness of the membrane. We formulate the condition for coexistent budged and unbulged sections, and identify allowable states set by electrical breakdown and mechanical rupture. We find that the bulging transition dramatically amplifies electromechanical energy conversion. Energy converted in an electromechanical cycle consisting of unbulged and bulged states is thousands of times that in an electromechanical cycle consisting of only unbulged states.展开更多
A sandwich beam specimen was fabricated by treating with MR elastomers between two thin aluminum face-plates.Experiment was carried out to investigate the vibration responses of the sandwich beam with respect to the i...A sandwich beam specimen was fabricated by treating with MR elastomers between two thin aluminum face-plates.Experiment was carried out to investigate the vibration responses of the sandwich beam with respect to the intensity of the magnetic field and excitation frequencies.The results show that the sandwich beams with MR elastomers cores have the capabilities of shifting natural frequencies and the vibration amplitudes decrease with the variation of the intensity of external magnetic field.展开更多
A new adaptive variable stiffness absorber was proposed based on a smart material, magnetorheological elastomer (MRE), and its vibration control performance was investigated. Before developing the proposed absorber, t...A new adaptive variable stiffness absorber was proposed based on a smart material, magnetorheological elastomer (MRE), and its vibration control performance was investigated. Before developing the proposed absorber, the MREs were firstly fabricated by curing a mixture of 704 silicon rubber, carbonyl iron particles and a small amount of silicone oil under an external magnetic field. Then the mechanical properties of the fabricated MREs were measured. On the basis of the measured mechanical characteristics, the MRE absorber was developed and its working characteristics were also tested under various input currents and excited frequencies. Finally, the control responses of a two-degree-of-freedom dynamic system with a MRE absorber were presented under a chirp input and used to evaluate the effectiveness of the MRE absorber.展开更多
Magneto-rheological elastomers (MILEs) are used to construct composite structures for micro-vibration control of equipment under stochastic support-motion excitations. The dynamic behavior of MREs as a smart viscoel...Magneto-rheological elastomers (MILEs) are used to construct composite structures for micro-vibration control of equipment under stochastic support-motion excitations. The dynamic behavior of MREs as a smart viscoelastic material is characterized by a complex modulus dependent on vibration frequency and controllable by external magnetic fields. Frequency-domain solution methods for stochastic micro-vibration response analysis of the MRE-based structural systems are developed to derive the system frequency-response function matrices and the expressions of the velocity response spectrum. With these equations, the root-mean-square (RMS) velocity responses in terms of the one-third octave frequency band spectrum can be calculated. Further, the optimization problem of the complex moduli of the MRE cores is defined by minimizing the velocity response spectra and the RMS velocity responses through altering the applied magnetic fields. Simulation results illustrate the influences of MRE parameters on the RMS velocity responses and the high response reduction capacities of the MRE-based structures. In addition, the developed frequency-domain analysis methods are applicable to sandwich beam structures with arbitrary cores characterized by complex shear moduli under stochastic excitations described by power spectral density functions, and are valid for a wide frequency range.展开更多
According to the structural characteristics of embedded fluid elastomeric damper and dynamic modeling method of bearingless rotor(BR)system,a time-domain dynamic model based on multilayer elastomeric theory and fluid ...According to the structural characteristics of embedded fluid elastomeric damper and dynamic modeling method of bearingless rotor(BR)system,a time-domain dynamic model based on multilayer elastomeric theory and fluid dynamic equations is developed.The parameters contained in the analysis model are identified by dynamic experiment data of embedded fluid elastomeric damper.The dynamic characteristics curves calculated through dynamic model are compared with those derived from experimental data.The consistent results illustrate that the model can describe the nonlinear relationship between stress and strain of embedded fluid elastomeric damper under different displacement amplitude and frequency.Due to the validity and reliability of the dynamic analysis model,it can be used in aeroelastic characteristics calculation of BR with embedded fluid elastomeric damper for helicopters.展开更多
The damping property of magnetorheological elastomers(MREs) is characterized by a modified dynamic mechanical-magnetic coupled analyzer.The influence of external magnetic flux density,damping of matrix,content of iron...The damping property of magnetorheological elastomers(MREs) is characterized by a modified dynamic mechanical-magnetic coupled analyzer.The influence of external magnetic flux density,damping of matrix,content of iron particles,dynamic strain and driving frequency on the MREs' damping was investigated experimentally.The results indicate that the MREs' damping property depends on the interfacial slip between the inner particles and the matrix.Different from the general composite materials,the interfacial slip in MRE is affected by the external applied magnetic field.展开更多
CaSO 4 whisker reinforcing and toughening mechanisms for polyurethane elastomer were studied. The effects of dispersity of CaSO 4 whisker and interfacial bonding state on reinforcement and toughness were discussed.T...CaSO 4 whisker reinforcing and toughening mechanisms for polyurethane elastomer were studied. The effects of dispersity of CaSO 4 whisker and interfacial bonding state on reinforcement and toughness were discussed.The microanalyses showed that CaSO 4 whisker reinforcing mechanism for polyurethane elastomer mainly was load transferring and its toughening mechanism involved crack deflection and whisker pullout.The results indicated that composites with 5%-10% CaSO 4 whisker exhibited the best mechanical properties. Good bonding interface was formed between whisker and matrix after the surface of CaSO 4 whisker was treated by silane coupling agent.The fairly improved strength and toughness are attributed to the better interfacial bonding state.展开更多
基金Project supported by the National Natural Science Foundation of China (No.12172001)the Anhui Provincial Natural Science Foundation of China (No.2208085Y01)+1 种基金the University Natural Science Research Project of Anhui Province of China (No.2022AH020029)the Housing and Urban-Rural Development Science and Technology Project of Anhui Province of China (No.2023-YF129)。
文摘Self-oscillating systems abound in the natural world and offer substantial potential for applications in controllers,micro-motors,medical equipments,and so on.Currently,numerical methods have been widely utilized for obtaining the characteristics of self-oscillation including amplitude and frequency.However,numerical methods are burdened by intricate computations and limited precision,hindering comprehensive investigations into self-oscillating systems.In this paper,the stability of a liquid crystal elastomer fiber self-oscillating system under a linear temperature field is studied,and analytical solutions for the amplitude and frequency are determined.Initially,we establish the governing equations of self-oscillation,elucidate two motion regimes,and reveal the underlying mechanism.Subsequently,we conduct a stability analysis and employ a multi-scale method to obtain the analytical solutions for the amplitude and frequency.The results show agreement between the multi-scale and numerical methods.This research contributes to the examination of diverse self-oscillating systems and advances the theoretical analysis of self-oscillating systems rooted in active materials.
基金the National Natural Science Foundation of China(No.52003142).
文摘Magnetorheological elastomers(MREs)hold significant promise in various fields such as automotive engineering,and civil engineering,where they serve as intelligent materials.Depending on the application of an external magnetic field,these materials exhibit varying magnetorheological and viscoelastic properties,including shear stress,yield stress,dynamic moduli,and damping.In this work,a new type of MRE,termed self-healing MREs(SH-MREs),has been developed by adding a novel self-healing agent into existing MREs.The dynamic modulus and loss factor of SH-MREs with different compositions have been characterized under various conditions of frequency,temperature,and strain.The results show that as the strain value increases,the loss factor also increases.Moreover,the loss factor initially increases and then decreases with increasing magnetic field strength.Although higher concentrations of ferromagnetic particles increase the loss factor,they enhance the operational range due to their better responsiveness to magnetic fields.SH-MREs demonstrate improved damping capabilities,attributed to the formation of coordination bonds between ferromagnetic particles and the self-healing agent.The stable structure increases the viscosity of MREs.The results of the regression model suggest a direct proportionality between sensitivity to the magnetic field and the ferromagnetic particle concentration.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFB3707803)the National Natural Science Foundation of China(Grant Nos.12072179 and 11672168)+1 种基金the Key Research Project of Zhejiang Lab(Grant No.2021PE0AC02)Shanghai Engineering Research Center for Inte-grated Circuits and Advanced Display Materials.
文摘Dielectric elastomers(DEs)require balanced electric actuation performance and mechanical integrity under applied voltages.Incorporating high dielectric particles as fillers provides extensive design space to optimize concentration,morphology,and distribution for improved actuation performance and material modulus.This study presents an integrated framework combining finite element modeling(FEM)and deep learning to optimize the microstructure of DE composites.FEM first calculates actuation performance and the effective modulus across varied filler combinations,with these data used to train a convolutional neural network(CNN).Integrating the CNN into a multi-objective genetic algorithm generates designs with enhanced actuation performance and material modulus compared to the conventional optimization approach based on FEM approach within the same time.This framework harnesses artificial intelligence to navigate vast design possibilities,enabling optimized microstructures for high-performance DE composites.
基金Supported by Special Project for High-quality Development of Marine Services and Fishery in Fujian Province in 2023(FJHY-YYKJ-2023-1-3)。
文摘[Objectives] This study was conducted to develop a polyurea elastomer which can be sprayed on the surface of expanded polystyrene (EPS) floating balls, so as to improve the surface strength and service life of the floating balls. [Methods] The effects of the types and amounts of isocyanate, chain extenders and polyether polyols on the gelation rate, adhesion and wear resistance of polyurea elastomer were investigated, and it was finally determined the preparation process of polyurea elastomer using liquid isophorone diisocyanate (IPDI) and amino-terminated polyether (D2000) as the main raw materials, dimethylthiotoluene diamine (E300) as the chain extender and silica as the wear resistance modifier through two-step solution polymerization of prepolymerization and chain extension. [Results] The physical properties and chemical resistance tests of spray polyurea elastomer showed that it had good physical properties and acid and alkali resistance, and could meet the requirements of spraying and protection of EPS floating ball surface in marine environment. [Conclusions] Polyurea elastomer coating can improve the aging resistance, wear resistance and acid and alkali resistance of EPS floating balls, and prevent them from being fragile and floating randomly to form marine floating garbage which results in "white pollution".
文摘During the production of nitrile rubber, significant amounts of nitrogen in the form of ammonium are generated in the wastewater. The discharge of this high-nitrogen wastewater can lead to serious environmental issues, including eutrophication, disruption of aquatic ecosystems, and groundwater contamination. To mitigate these impacts, this research explored the bioremediation capabilities of the macroalgae Ulva lactuca (Chlorophyta) for removing nitrogen from nitrile rubber production wastewater. The study employed single-phase and Michaelis-Menten decay models based on ammonium consumption, using various dilutions of wastewater to identify the optimal concentration for treatment. The physiological state of the macroalgae was monitored by measuring the photosynthetic capacity and specific growth rate during the experiments. In the presence of U. lactuca, ammonium concentrations decreased in all treatment groups, confirming that the ammonium kinetics conformed to both applied models. Our results show that U. lactuca effectively reduces ammonium concentrations, with an approximate removal rate of 0.020 µM·g−1·min−1 across different wastewater concentrations (70%, 80%, 90%, and 100%). Notably, the treatments with 70%, 80%, and 90% wastewater strength achieved about 67% reduction in ammonium, demonstrating the alga’s capacity to treat high-nitrogen wastewater. The photosynthetic performance of U. lactuca initially declined in control conditions but stabilized across all treatments, highlighting its adaptability. The kinetic analysis using the Michaelis-Menten model indicated a Vmax of 1342 μM·g−1·DMh−1, suggesting a robust capacity for ammonium uptake when fully saturated. Our study underscores the potential of Ulva lactuca as a cost-effective and efficient agent for wastewater bioremediation, particularly in settings with high nitrogen loads.
文摘Two types of elastomeric vibration isolators used for equipment vibration isolation in aerospace vehicles are considered for the present study. These isolators are constructed using elastomers mounted in steel encasings. These isolators are initially deformed statically and dynamic loads are applied on the deformed configuration. To capture the static deformation, equivalent static load corresponding to its load rating and specified displacements are created. Static deformation is computed using Finite Element methods with four node axi-symmetric element which include the geometric non-linear effect for steel and with standard Yeoh hyper-elastic material model for elastomers(Muhammed and Zu, 2012) [1]. Yeoh material constants are derived from uni-axial tension test data of the elastomer specimen. These isolators are subjected to harmonic and random excitations in the pre-deformed state. For numerical analysis, elastomeric constants at dynamic conditions are obtained as complex function of frequency using Dynamic Mechanical Analyzer(DMA) for a range of frequencies. The standard material model of Yeoh is modified incorporating frequency dependant material characteristics and damping in the range of frequencies of interest. A multiplicative non-separable variables law is derived for Yeoh material model to include the effect of static pre-stress, based on the methodology given in literature(Nashif et al.,1985;Beda et al., 2014) [2,3]. The modifications of Yeoh model suitable for frequency domain analysis is the novelty in the present study. In the analysis, while dynamic loads are applied, the configuration is updated considering initial static loading. The frequency response of the isolators is computed using material properties evaluated at progressive dynamic strains until a match in natural frequency is observed. Appropriate damping corrections are then incorporated to match the test observed transmissibility. Then updated material properties are used to compute the random response which showed good agreement with results of experiments, validating the approach taken for the development of this model.
基金The authors greatly acknowledge the financial support from the National Natural Science Foundation of China(No.51873126)the Fundamental Research Funds for the Central Universities,as well as the funding from the Science&Technology Department(No.2021YFH0123)of Sichuan Province.
文摘Electrically conductive elastomer composites(CECs)with segregated networks of conductive nanofillers show high potential in stretchable strain sensors due to balanced mechanical and electrical properties,yet the sensitivity at low strain is generally insufficient for practical application.Herein,we report an easy and effective way to improve the resistive response to low strain for CECs with segregated network structure via adding stiff alumina into carbon nanostructures(CNS).The CEC containing 0.7 wt%CNS and 5 wt%Al_(2)O_(3) almost sustains the same elasticity(elongation at break of~900%)and conductivity(0.8 S/m)as the control,while the piezoresistive sensitivity is significantly improved.Thermoplastic polyurethane(TPU)composites with a segregated network of hybrid nanofillers(CNS and Al_(2)O_(3))show much higher strain sensitivity(Gauge factor,GF-566)at low strain(45%strain)due to a local stress concentration effect,this sensitivity is superior to that of TPU/CNS composites(GF-11).Such a local stress concentration effect depends on alumina content and its distribution at the TPU particle interface.In addition,CECs with hybrid fillers show better reproducibility in cyclic piezoresistive behavior testing than the control.This work offers an easy method for fabricating CECs with a segregated filler network offering stretchable strain sensors with a high strain sensitivity.
基金the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT,Ministry of Science and ICT)(NRF-2021R1A2C3004151)Ministry of Education(NRF-2022R1A6A3A01086019)the KU-KIST School Program.
文摘Stretchable elastomer-based electrodes are considered promising energy storage electrodes for next-generation wearable/flexible electronics requiring various shape designs.However,these elastomeric electrodes suffer from the limited electrical conductivity of current collectors,low charge storage capacities,poor interfacial interactions between elastomers and conductive/active materials,and lack of shape controllability.In this study,we report hierarchically micro/nano-wrinkle-structured elastomeric electrodes with notably high energy storage performance and good mechanical/electrochemical stabilities,simultaneously allowing various form factors.For this study,a swelling/deswelling-involved metal nanoparticle(NP)assembly is first performed on thiol-functionalized polydimethylsiloxane(PDMS)elastomers,generating a micro-wrinkled structure and a conductive seed layer for subsequent electrodeposition.After the assembly of metal NPs,the conformal electrodeposition of Ni and NiCo layered double hydroxides layers with a homogeneous nanostructure on the micro-wrinkled PDMS induces the formation of a micro/nano-wrinkled surface morphology with a large active surface area and high electrical conductivity.Based on this unique approach,the formed elastomeric electrodes show higher areal capacity and superior rate capability than conventional elastomeric electrodes while maintaining their electrical/electrochemical properties under external mechanical deformation.This notable mechanical/electrochemical performance can be further enhanced by using spiral-structured PDMS(stretchability of~500%)and porous-structured PDMS(areal capacity of~280μAh cm^(-2)).
基金This work was supported by the National Science Foundation(DMR-1904167).
文摘In the past decades,ion conductive polymers and elastomers have drawn worldwide attention for their advanced functions in batteries,electroactive soft robotics,and sensors.Stretchable ionic elastomers with dispersed soft ionic moieties such as ionic liquids have gained remarkable attention as soft sensors,in applications such as the wearable devices that are often called electric skins.A considerable amount of research has been done on ionic-elastomer-based strain,pressure,and shear sensors;however,to the best of our knowledge,this research has not yet been reviewed.In this review,we summarize the materials and performance properties of engineered ionic elastomer actuators and sensors.First,we review three classes of ionic elastomer actuators—namely,ionic polymer metal composites,ionic conducting polymers,and ionic polymer/carbon nanocomposites—and provide perspectives for future actuators,such as adaptive four-dimensional(4D)printed systems and ionic liquid crystal elastomers(iLCEs).Next,we review the state of the art of ionic elastomeric strain and pressure sensors.We also discuss future wearable strain sensors for biomechanical applications and sports performance tracking.Finally,we present the preliminary results of iLCE sensors based on flexoelectric signals and their amplification by integrating them with organic electrochemical transistors.
文摘Ethylene propylene diene elastomers (EPDM) of various side chains and molecular weights were prepared as thin discs and the effects of electric field strength and temperature on the electromechanical properties were investigated. The electrical conductivity, the dielectric constant, the storage and loss moduli (G' and G'), the storage modulus response (ΔG’1000 V/mm), and the storage modulus sensitivity (ΔG’1000 V/mm/G’0) of the elastomers of different ethylene norbornene (ENB) contents and molecular weights were measured under electric field strengths varying from 0 V/mm to 1000 V/mm and at temperatures between 300 K and 380 K. The storage modulus response and sensitivity increase with increasing molecular weight and dielectric constant, consistent with the existing theory. However, for the case of EPDMs with different ENB contents, the storage modulus response and sensitivity vary inversely with the dielectric constant. EDPM is potentially a new type of electroactive materials.
文摘Elastomers are used in numerous engineering applications such as sealing components, it is therefore important to devise a method that can accurately predict elastomers’ response to load. Many applications that employ the use of these materials subject them to a nonlinear large strain;therefore the simple Hooke’s law is not sufficient to describe their material behaviour. This paper presents an approach to obtain material properties of elastomer under compression loading, based on hyperelastic strain formulation, through experimental test and finite element modelling. The paper focuses on the isotropic incompressible behaviour exhibited by elastomers, and obtains strain energy functions that satisfy the characteristic properties of a hyperelastic model. Data obtained from compression test on a nitrile rubber (NBR) specimen were used as material input into ABAQUS®—a finite element analysis software. A least square fitting technique was used to determine the coefficients of various stable hyperelastic models, based on Drucker’s stability criteria within the software. The strain energy functions obtained concentrate on material parameters which are related to physical quantities of the material molecular network they are subjected to in practical application. The approach benefits from mathematical simplicity, and possesses the property of the deformation mode dependency. Furthermore, a model validation procedure using a step-by-step method for parameters estimation is explained. The work herein is a nonlinear finite element modelling process that leads to an optimal solution and can be employed not only for elastomeric seals, but also for similar engineering assets.
基金supported by National Natural Science Foundation of China (Grant No. 50975139, Grant No. 50605031)Provincial Natural Science Foundation of Jiangsu, China (Grant No. 2008395)+1 种基金Foundation of State Key Laboratory of Robotics, China (Grant No. RLO200912)China Postdoctoral Science Foundation (Grant No. 20080441319, Grant No. 200902684)
文摘Dielectric elastomer actuator (DEA) show promise for mechatronic applications due to the advantages of dielectric elastomer, such as lightweight, flexible, low cost, high strain, etc, and many configurations of DEAs have been demonstrated. As a kind of linear actuator, cone DEAs are studied in some laboratory prototypes due to easy manufacturing, however, their performance have not been exploited fully. Based on the working principle of DEA, a four-bar linkage mechanism is designed to provide negative stiffness preload, which can increase displacement output of actuator (outer diameter 100 mm) to 17 mm. Three cone actuating units are assembled in parallel to enhance the maximum force output to 5.07 N. Loading experiments of actuator in forward and backward strokes are performed, the experimental results show that backward stroke has stronger actuating capability than forward stroke, accordingly application of actuator is recommended. Four factors rather than applied voltage, i.e., number of actuating units, pre-stretch ratio, inner diameter, and outer diameter, are determined as influencing factors for Taguchi method. Then the performance objectives of actuator, i.e., displacement output, maximum force output, and maximum work in backward stroke, are investigated based on L9(34) Taguchi orthogonal design. The mean signal-to-noise (S/N) ratio based on the larger-the-better criterion is calculated according to the acquired displacement and force output. Analytical results show that outer diameter has the most significant influence on displacement output, and maximum force out and work output are influenced most by number of actuating units. Inner diameter also has an important effect on the performance objectives of actuator, while pre-stretch ratio has the least influence. The proposed performance investigation is helpful for the design and application of cone actuator in mechatronic system.
文摘Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare earth - containing composite elastomer. It is found that mechanical performance can be improved remarkably. Analyzed by infrared spectrometry (IR), differential scanning calorimetry (DSC) and cross-linking densitometry, the relationship between structure and performance was discussed.
基金supported by ARO(W911NF-09-1-0476)DARPA (W911NF-10-1-0113)+2 种基金MRSECsupported by China Scholarship Council as a visiting scholar for two years at Harvard Universitythe Alexander von Humboldt Foundation for the Humboldt Award
文摘When air is pumped in, a tubular balloon initially inflates slightly and homogeneously. A short section of the balloon then forms a bulge, which coexists with the unbulged section of the balloon. As more air is pumped in, the bulged section elongates at the expense of the unbulged section, until the entire balloon is bulged. The phenomenon is analogous to the liquid-to-vapor phase transition. Here we study the bulging transition in a dielectric elastomer tube as air is pumped into the balloon and a voltage is applied through the thickness of the membrane. We formulate the condition for coexistent budged and unbulged sections, and identify allowable states set by electrical breakdown and mechanical rupture. We find that the bulging transition dramatically amplifies electromechanical energy conversion. Energy converted in an electromechanical cycle consisting of unbulged and bulged states is thousands of times that in an electromechanical cycle consisting of only unbulged states.
基金Project(10602033) supported by the National Natural Science Foundation of ChinaProject(07B012) supported by Scientific Research Fund of Education Department of Hunan ProvinceProject(VSN-2007-01) supported the Research Fund of State Key Laboratory of Mechanical System and Vibration
文摘A sandwich beam specimen was fabricated by treating with MR elastomers between two thin aluminum face-plates.Experiment was carried out to investigate the vibration responses of the sandwich beam with respect to the intensity of the magnetic field and excitation frequencies.The results show that the sandwich beams with MR elastomers cores have the capabilities of shifting natural frequencies and the vibration amplitudes decrease with the variation of the intensity of external magnetic field.
基金Projects(60804018, 50830202) supported by the National Natural Science Foundation of ChinaProject (20070420719) supported by the Post doctoral Fund of ChinaProject(CSTC.2008BB6184) supported by Chongqing Natural Science Foundation, China
文摘A new adaptive variable stiffness absorber was proposed based on a smart material, magnetorheological elastomer (MRE), and its vibration control performance was investigated. Before developing the proposed absorber, the MREs were firstly fabricated by curing a mixture of 704 silicon rubber, carbonyl iron particles and a small amount of silicone oil under an external magnetic field. Then the mechanical properties of the fabricated MREs were measured. On the basis of the measured mechanical characteristics, the MRE absorber was developed and its working characteristics were also tested under various input currents and excited frequencies. Finally, the control responses of a two-degree-of-freedom dynamic system with a MRE absorber were presented under a chirp input and used to evaluate the effectiveness of the MRE absorber.
基金Research Grants Council of the Hong Kong Special Administrative Region,China Under Grant No.PolyU 5252/07EThe Hong Kong Polytechnic University through the Development of Niche Areas Programme Under Grant No.1-BB95Zhejiang Provincial Natural Science Foundation of China Under Grant No.Y607087)
文摘Magneto-rheological elastomers (MILEs) are used to construct composite structures for micro-vibration control of equipment under stochastic support-motion excitations. The dynamic behavior of MREs as a smart viscoelastic material is characterized by a complex modulus dependent on vibration frequency and controllable by external magnetic fields. Frequency-domain solution methods for stochastic micro-vibration response analysis of the MRE-based structural systems are developed to derive the system frequency-response function matrices and the expressions of the velocity response spectrum. With these equations, the root-mean-square (RMS) velocity responses in terms of the one-third octave frequency band spectrum can be calculated. Further, the optimization problem of the complex moduli of the MRE cores is defined by minimizing the velocity response spectra and the RMS velocity responses through altering the applied magnetic fields. Simulation results illustrate the influences of MRE parameters on the RMS velocity responses and the high response reduction capacities of the MRE-based structures. In addition, the developed frequency-domain analysis methods are applicable to sandwich beam structures with arbitrary cores characterized by complex shear moduli under stochastic excitations described by power spectral density functions, and are valid for a wide frequency range.
文摘According to the structural characteristics of embedded fluid elastomeric damper and dynamic modeling method of bearingless rotor(BR)system,a time-domain dynamic model based on multilayer elastomeric theory and fluid dynamic equations is developed.The parameters contained in the analysis model are identified by dynamic experiment data of embedded fluid elastomeric damper.The dynamic characteristics curves calculated through dynamic model are compared with those derived from experimental data.The consistent results illustrate that the model can describe the nonlinear relationship between stress and strain of embedded fluid elastomeric damper under different displacement amplitude and frequency.Due to the validity and reliability of the dynamic analysis model,it can be used in aeroelastic characteristics calculation of BR with embedded fluid elastomeric damper for helicopters.
基金Project(10672154) supported by the National Natural Science Foundation of ChinaProject(20050358010) supported by the SRFDP of China
文摘The damping property of magnetorheological elastomers(MREs) is characterized by a modified dynamic mechanical-magnetic coupled analyzer.The influence of external magnetic flux density,damping of matrix,content of iron particles,dynamic strain and driving frequency on the MREs' damping was investigated experimentally.The results indicate that the MREs' damping property depends on the interfacial slip between the inner particles and the matrix.Different from the general composite materials,the interfacial slip in MRE is affected by the external applied magnetic field.
基金FundedbytheNaturalScienceFoundationofShanxiProvince (No .9910 2 4 )
文摘CaSO 4 whisker reinforcing and toughening mechanisms for polyurethane elastomer were studied. The effects of dispersity of CaSO 4 whisker and interfacial bonding state on reinforcement and toughness were discussed.The microanalyses showed that CaSO 4 whisker reinforcing mechanism for polyurethane elastomer mainly was load transferring and its toughening mechanism involved crack deflection and whisker pullout.The results indicated that composites with 5%-10% CaSO 4 whisker exhibited the best mechanical properties. Good bonding interface was formed between whisker and matrix after the surface of CaSO 4 whisker was treated by silane coupling agent.The fairly improved strength and toughness are attributed to the better interfacial bonding state.