Laser Properties of Nd_2O_3 Doped Na_2O–CaO–SiO_2 Transparent Glass-Ceramics for Space Solar Energy

A series of Na20-CaO-SiO2 glass ceramics containing different content of Nd3＋ ions were prepared by the method of high temperature melting and subsequent crystallization. The absorption, excitation and emis- sion spectra of these glass ceramics were investigated; effects of Nd3＋ content and crystallization behavior on the laser properties of this material had been studied. The results show that the emission bands origi- nating from the 4F3/2 state of Nd3＋ were firstly enhanced with the increase of the Nd2O3 doping content and the crystallinity degree, and then decreased with more doping content and deepened crystalliza- tion. The possible reasons of this phenomenon were analyzed. Research will be favored to promote the development of glass ceramics laser materials for space solar energy.

Phase Control of Transient Optical Properties of Double Coupled Quantum-Dot Nanostructure via Gaussian Laser Beams

We theoretically analyze the transient properties of a probe field absorption and dispersion in a coupled semiconductor double-quantum-dot nanostructure.We show that in the presence of the Gaussian laser beams,absorption and dispersion of the probe field can be dramatically influenced by the relative phase between applied fields and intensity of the Gaussian laser beams.Transient and steady-state behaviors of the probe field absorption and dispersion are discussed to estimate the required switching time.The estimated range is between 5-8 ps for subluminal to superluminal light propagation.

Simulation of Far-Field Properties of Coherent Vertical Cavity Surface Emitting Laser Array

Far-field properties dependent on array scale, separation, element width and emitted wavelength are system atically analyzed theoretically and experimentally. An array model based on the finite-difference method is established to simulate the far-field profile of the coherent arrays. Some important conclusions are obtained. To achieve a higher quality beam, it is necessary to decrease separation between elements, or to increase the element width. Higher brightness can be achieved in the array with larger scale. Emitted wavelength also has an influence on the far-field profile. These analyses can be extended to the future design of coherent vertical cavity surface emitting laser arrays.

Temperature-Dependent Fluorescence Properties and Diode-Pumped Deep Red Laser Performance of Pr:LiGdF4 Crystal

We demonstrate the temperature-dependent fluorescence properties of Pr：LiGdF4 crystal tor the first time, to the best of our knowledge, and its blue diode pumped cw red laser at 720 nm at room temperature. The fluorescence lifetime and polarized emission cross sections in the visible range are measured and calculated in a temperature range from 77K to 300 K, and the variations of the fluorescence lifetime and spectra are discovered. The reasons for these changes are explained accordingly. The output wavelength of the 720nm laser is first reported on the laser performance by using a fiber-coupled laser diode at the wavelength of 442nm as the pump source, and the maximum cw output power is about 303roW.

Effect of Oxygen Partial Pressure on Epitaxial Growth and Properties of Laser-Ablated AZO Thin Films

Al-doped ZnO（AZO） thin films were grown on c-sapphire substrates by laser ablation under different oxygen partial pressures（P_（O2））.The effect of P_（O2） on the crystal structure,preferred orientation as well as the electrical and optical properties of the films was investigated.The structure characterizations indicated that the as-grown films were single-phased with a wurtzite ZnO structure,showing a significant c-axis orientation.The films were well crystallized and exhibited better crystallinity and denser texture when deposited at higher P_（O2）.At the optimum oxygen partial pressures of 10- 15 Pa,the AZO thin films were epitaxially grown on c-sapphire substrates with the（0001） plane parallel to the substrate surface,i e,the epitaxial relationship was AZO（000 1） // A1_2O_3（000 1）.With increasing P_（O2）,the value of Hall carrier mobility was increased remarkably while that of carrier concentration was decreased slightly,which led to an enhancement in electrical conductivity of the AZO thin films.All the films were highly transparent with an optical transmittance higher than 85%.

Spectral and Lasing Properties of Er^(3+0/Yb^(3+) Co-Doped Phosphate Glasses Pumped by LD

Er^3 ＋/Yb^3 ＋ phosphate glasses were fabricated. According to McCumber theory, the stimulated emission cross-section of Er^3＋ ions at 1533 nm was calculated on the basis of absorption spectrum, and 0.84 × 10^-20 cm^2 is derived, the fluorescence lifetime of ^4I13/2 level is 8.5 ms. An Er^3＋/Yb^3＋ co-doped phosphate glass CW laser pumped by LD was demonstrated at room temperature. The maximum output power is 80 mW and slope efficiency is 16.5%.

硼酸钇铝(NAB)——LD泵浦微型激光器的好材料——再谈自激活激光晶体在激光技术上的应用

Starting from the data obtained recently,that the crystal yttrium aluminum borat e(NAB)is an ideal material for LD pumped microchip laser is demonstrated.Coopera ting with Material Physics Department of Autonoma University of Madrid,Ti:sappir e laser was used to simulate laser diode to pump a NAB crystal sample of 0.3mm t hickness.For incident pump power of 375mW,laser output power at 1.064μm reach 1 57mW with optical to optical efficiency as high as 42%.The corresponding effici e ncy at 1.341μm is 25%.Output laser beams belong to TEM 00 mode.The thresho ld of laser oscillation at 1.064μm were 13,18,30,100 and 140mW for output mirr ors with transmittance of 0.36%,1%,2%,4% and 6% respectively.NAB crystal has a wide and flat absorption band with half high width of 45nm for pump light and so th e temperature shift of the laser diode wavelength will not affect the pumping effi ciency.All the advantages mentioned show the this crystal is obviously an ideal material for LD pumped microchip laser. Therefrom,the possible application of a series of self ativated laser crystal developed in the seventies years 20th century will be discussed in the case of L D lasers have been well developed.

Tribological properties of FeCoCrNiAlB_x high-entropy alloys coating prepared by laser cladding

FeCoCrNiA1Bx（x=0, 0.25, 0.50, 0.75） coatings were prepared by laser cladding to study the effects of boron on the structure and properties of high-entropy alloys coatings. The microstructure, microhardness, and wear resistance properties of the samples were investigated by scanning electron microscopy, X-ray diffraction, metallographic micro-hardness test, and friction wear test, respectively, and the mechanism of the wear behavior was also analyzed. The results showed that the high-entropy alloys consisted of BCC phase and eutectic structure, which contained FCC phase and M2B. With boron addition, the content of BCC phase increased while that of eutectic structure decreased. The wear resistance of the high-entropy coatings was considerably improved with increasing addition of horon, and accordingly, the FeCoCrNiAlB0.75 coating showed the best wear resistance.

CsPbBr_3 perovskite quantum dots: saturable absorption properties and passively Q-switched visible lasers

This work presents the saturable absorption(SA) properties of CsPbBr_3 perovskite quantum dots(QDs). The perovskite QDs show excellent SA performance with a nonlinear absorption coefficient of-35 × 10^(-2) cm∕GW and a figure of merit of 3.7 × 10^(-14) esu cm. Further, their use as saturable absorbers in a passively Q-switched visible solid-state laser for the generation of soliton pulses is demonstrated. These results demonstrate thepotential for the perovskite QDs to act as saturable absorbers.

Properties of 3Cr2W8V Die Steel With Striations Processed by Laser

The striations on the surface of 3Cr2W8V die steel were processed by laser. The microstructure, hardness, wear resistance and thermal fatigue behavior of the specimens processed by laser were measured. The appearance and mechanism of thermal fatigue crack propagation in the zone processed by laser were observed and discussed. The results show that the wear resistance and thermal fatigue resistance of materials processed by laser are all better than those of the unprocessed material. The processed zone by laser plays a role in baffling wearing process and crack propagation. The pile-nail effect of processed zone is the main factor for improving the wear resistance and thermal fatigue resistance of material.

Microstructure and properties in dissimilar/similar weld joints between DP780 and DP980 steels processed by fiber laser welding

The microstructure and mechanical properties（strength, fatigue and formability） of dissimilar/similar weld joints between DP780 and DP980 steels were studied. The microstructure in fusion zone（FZ） was lath martensite（LM）, and alloying elements in the FZ were uniformly distributed. The hardness in the FZ of dissimilar weld joint was similar to the average value（375 HV） of the two similar weld joints. The microstructural evolution in heat affected zone（HAZ） of dissimilar/similar weld joints was as follows：LM（coarse-grained HAZ） →finer LM（fine-grained HAZ） →M-A constituent and ferrite（intercritically HAZ） →tempered martensite（TM） and ferrite（sub-critical HAZ）. Lower hardness in intercritically HAZ and sub-critical HAZ（softening zones） was observed compared to base metal（BM） in dissimilar/similar weld joints. The size of softening zone was 0.2-0.3 mm and reduction in hardness was ~7.6%-12.7% of BM in all the weld joints, which did not influence the tensile properties of weld joints such that fracture location was in BM. Formability of dissimilar weld joints was inferior compared to similar weld joints because of the softening zone, non-uniform microstructure and hardness on the two sides of FZ. The effect of microstructure on fatigue life was not influenced due to the presence of welding concavity.

Microstructure and Mechanical Properties of Galvanized Steel/AA6061 Joints by Laser Fusion Brazing Welding

Laser fusion brazing welding was proposed.Galvanized steel/AA6061 lapped joint was obtained by laser fusion brazing welding technique using the laser-induced aluminium molten pool spreading and wetting the solid steel surface.Wide joint interface was formed using the rectangular laser beam coupled with the synchronous powder feeding.The result showed that the tiny structure with the composition of a-Al and Al–Si eutectic was formed in the weld close to the Al side.And close to the steel side,a layer of compact Fe–Al–Si intermetallics,including the Al-rich FeAl3,Fe2Al5 phases and Al–Fe–Si s1 phase,was generated with the thickness of about 10–20 lm.Transverse tensile shows the brittlefractured characteristic along to the seam/steel interface with the maximum yield strength of 152.5 MPa due to the existence of hardening phases s1 and Al–Fe intermetallics.

Effect of Powder Particle Shape on the Properties of In Situ Ti–TiB Composite Materials Produced by Selective Laser Melting

This work studied the preparation of starting powder mixture influenced by milling time and its effect on the particle morphology （especially the shape） and, consequently, density and compression properties of in situ Ti-TiB composite materials produced by selective laser melting （SLM） technology. Starting powder composite system was prepared by mixing 95 wt% commercially pure titanium （CP-Ti） and 5 wt% titanium diboride （TiB2） powders and subsequently milled for two different times （i.e. 2 h and 4 h）. The milled powder mixtures after 2 h and 4 h show nearly spherical and irregular shape, respectively. Subsequently, the resultant Ti-5 wt% TiB2 powder mixtures were used for SLM processing. Scanning electron microscopy image of the SLM-processed Ti-TiB composite samples show needle-shape TiB phase distributed across the Ti matrix, which is the product of an in-situ chemical reaction between Ti and TiB2 during SLM. The Ti-TiB composite samples prepared from 2 h and 4 h milled Ti-TiB2 powders show different relative densities of 99.5% and 95.1%, respectively. Also, the compression properties such as ultimate strength and compression strain for the 99.5% dense composite samples is 1421 MPa and 17.8%, respectively, which are superior to those （883 MPa and 5.5%, respectively） for the 95.1% dense sample. The results indicate that once Ti and TiB2 powders are connected firmly to each other and powder mixture of nearly spherical shape is obtained, there is no additional benefit in increasing the milling time and, instead, it has a negative effect on the density （i.e. increasing porosity level） of the Ti-TiB composite materials and their mechanical properties.

Influence of α/β interface phase on the tensile properties of laser cladding deposited Ti–6Al–4V titanium alloy

Laser cladding deposited Ti-6Al-4V titanium alloy universally shows more complex microstructures,each of which has significant effect on mechanical properties. Of particular α/β interface phase has been observed in this paper under certain conditions. It demonstrates that the influence of the α/β interface phase on the tensile properties is closely associated with dislocations and twin substructure through comparison experiments. The results show that the α/β interface phase hinders dislocation motion and decreases effective slip length. In addition, the twin substructure has been activated in the α/β interface phase during tensile process and has acted somehow like grain boundaries. Therefore, the strength and the work-hardening rate of the laser cladding deposited Ti-6Al-4V titanium alloy have been significantly improved due to the dynamic Hall-Petch effect. Besides, the α/β interface phase leads to more uniform dislocations distribution, which implies that relative lower local concentrated stress will be produced along the α/β interface phase or colony boundary after the same amount of plastic deformation. Moreover,the twinning-induced plasticity effects in the α/β interface phase further increase the plastic deformation capacity. These results in higher elongation for the laser cladding deposited Ti-6Al-4V titanium alloy.It can be concluded that the current work suggests an effective method to simultaneously improve the strength and plasticity of laser cladding deposited Ti-6Al-4V titanium alloy based on the α/β interface phase.

Effects of processing parameters on fatigue properties of LY2 Al alloy subjected to laser shock processing

We address the effects of processing parameters on residual stresses and fatigue properties of LY2 Al alloy by laser shock processing （LSP）. Results show that compressive residual stresses are generated near the surface of samples due to LSP. The maximum compressive residual stress at the surface by two LSP impacts on one side is higher than that by one LSP impact. The maximum value of tensile residual stress is found at the mid-plane of samples subjected to two-sided LSP. Compared with fatigue lives of samples treated by single-sided LSP, lives of those treated by two-sided LSP are lower. However, these are higher than untreated ones.

Effect of Nd^(3+) on spectroscopic properties of lithium borate glasses

The spectroscopic properties of lithium borate glasses as a function of Nd3＋ ions concentration were reported.Optical absorption spectra of these glasses showed a number of absorption bands in ultra violet and visible region.Optical absorption edge was found to shift towards the longer wavelength（red shift） with increase in Nd2O3.Luminescence spectra revealed three major bands at 902, 1063 and 1334 nm which was due to 4F3/2→4I9/2, 11/2 ＆13/2 transitions of Nd3＋ ions.Luminescence intensity was maximum for 1 mol.% Nd2O3 and further increase in Nd2O3 resulted in luminescence quenching.The luminescence quenching behavior at higher concentration of Nd2O3 was attributed to the Nd3＋-Nd3＋ interaction in the glass matrix.An absorption and emission property of these glasses suggested that these glasses could be useful for 1.06 μm infrared laser applications.

Growth Characteristics and Reinforcing Behavior of In-situ NbCp in Laser Cladded Fe-based Composite Coating

Over the past decade, researchers demonstrated much interest in laser cladded metal matrix composite coatings for its good wear resistance. In this paper, in-situ NbCp reinforced Fe-based wear-resistance coatings with different designed NbC contents were produced by laser cladding. The formation mech- anism of NbC particle was analyzed. The effects of NbC content on the microstructure and mechanical properties of coatings were investigated. It was revealed that α-（Fe, Cr）, （Fe, Cr）7C3, NbC existed in all coatings. NbC particles formed by the chemical reaction of Nb and C dissolved in the molten pool. The increase of designed NbC content led to the growth of the porosity amount, and the increase of the size and the area ratio of the particle, as well as the transformation of the NbCp morphology from quadrangle to petaloid shape. Moreover, the micro-hardness and the wear resistance of the coating were improved with the increase of NbC. When NbCp content was 30 wt%, the mechanical properties decreased slightly. Copyright @ 2015, The editorial office of Journal of Materials Science ＆ Technology. Published by Elsevier

Laser processed micro-supercapacitors based on carbon nanotubes/manganese dioxide nanosheets composite with excellent electrochemical performance and aesthetic property

Micro-supercapacitors with excellent electrochemical performance and aesthetic property are realized using the carbon nanotubes/manganese dioxide nanosheets（CNTs/δ-MnO2） composite as electrodes.This CNTs/d-MnO2 nanocomposite is excellently compatible with the slurry dispensing process for electrode fabrication, and thus is conducive for preparing thick electrode films, which exhibits a specific capacitance of 257 F/g with an electrode thickness of 13μm. By involving laser-scribing technique, the electrode film can be patterned with a high resolution and fabricated into a planar micro-supercapacitor,showing the maximum energy density of 6.83 mWh/cm^3 at the power density of 154.3 mW/cm^3, and maintained a value of 2.71 mWh/cm^3 at the maximum power density of 2557.5 mW/cm^3. Considering the versatility of the laser-scribing technical platform, the micro-supercapacitors fabricated in this way exhibit excellent aesthetic property and can cater to various miniaturized wearable electronic applications. This technology opens up opportunities for facile and scalable fabrication of high performance energy devices with shape diversity and a meaning of art.