Determination of omethoate by cathodically sweeping oscillopolarography is described. The product of the alkaline hydrolysis exhibited a sensitive second derivative wave at ?0.50 V (vs. SCE) in a 1.0 ×10?5mol/L s...Determination of omethoate by cathodically sweeping oscillopolarography is described. The product of the alkaline hydrolysis exhibited a sensitive second derivative wave at ?0.50 V (vs. SCE) in a 1.0 ×10?5mol/L sodium dodecylbenzene sulfonate (SDBS)+0.1 mol/L HAc-NaAc (pH 4.0) buffer. The peak current was linearly proportional to the concentration of omethoate in the range from 6.4×10?7 to 5.1×10?5 mol/L. The detection limit is 2.0×10?7 mol/L with the relative standard derivation (RSD) of 3.5%. The hydrolysis procedure and the electrode reaction were studied by voltammetry.展开更多
文摘Determination of omethoate by cathodically sweeping oscillopolarography is described. The product of the alkaline hydrolysis exhibited a sensitive second derivative wave at ?0.50 V (vs. SCE) in a 1.0 ×10?5mol/L sodium dodecylbenzene sulfonate (SDBS)+0.1 mol/L HAc-NaAc (pH 4.0) buffer. The peak current was linearly proportional to the concentration of omethoate in the range from 6.4×10?7 to 5.1×10?5 mol/L. The detection limit is 2.0×10?7 mol/L with the relative standard derivation (RSD) of 3.5%. The hydrolysis procedure and the electrode reaction were studied by voltammetry.
