Effect of Different Titanium Surface Treatments on the Adhesion Test Result:Dental Application

The aim of the study was to investigate the effect of different surface treatment of titanium(Ti)on the adhesion test results for dental application.Ti substrates roughened by 400 to 1500-grit SiC polish papers and alumina blasting,alkali treated by 5 molar(M)NaOH and KOH solutions and heat treated at the temperature range of 400-800℃were used in this study.The treated samples were subjected to the adhesion test.According to the results of the adhesion test,the adhesive strength showed the highest value for the blasted titanium among all polished and blasted samples.The Ti samples heated at 650℃showed the highest adhesive strength among all heat-treated samples.Further,the adhesion test results indicated the higher adhesive strength of chemically treated samples treated by NaOH rather than that by KOH.The polished and heated Ti samples showed the highest adhesive strength among all samples.

Surface treatment effect on the photocatalytic hydrogen generation of CdS/ZnS core-shell microstructures

CdS/ZnS core-shell microparticles were prepared by a simple two-step method combining ultrasonic spray pyrolysis and chemical bath deposition.The core-shell structures showed enhanced photocatalytic properties compared with those of CdS or ZnS spherical particles.CdS/ZnS photocatalysts with different amount of ZnS loaded as shells were prepared by adjusting the concentrations of Zn and S precursors during synthesis.The optical properties and photocatalytic activity for hydrogen production were investigated and the amount of ZnS loaded as shell was optimized.Thermal annealing and hydrothermal sulfurization treatments were applied to the core-shell structure and both treatments enhanced the material＇s photocatalytic activity and stability by eliminating crystalline defects and surface states.The result showed that thermal annealing treatment improved the bulk crystallinity and hydrothermal sulfurization improved the surface properties.The sample subjected to both treatments showed the highest photocatalytic activity.These results indicate that CdS/ZnS core-shell microspheres are a simple structure that can be used as efficient photocatalysts.The hydrothermal sulfurization treatment may also be a useful surface treatment for metal sulfide photocatalysts.The simple two-step method provides a promising approach to the large-scale synthesis of core-shell microsphere catalysts.

Corrosion behavior and surface treatment of superlight Mg-Li alloys

Mg-Li alloy,as a superlight metallic engineering material,shows great potential in the fields of aerospace and militarydue to its high specific strength,better formability,and excellent electromagnetic shielding performance.The research process ofMg-Li alloys is reviewed and three main problems are pointed out.Aimed at the poor corrosion resistance of Mg-Li alloys,thecorrosion behavior is mainly summarized.The surface treatment technologies,including electroplating,electroless plating,plasmaspraying,molten salt replacement,conversion coating,anodizing,micro-arc oxidation,organic coating,and organic-inorganic hybridcoating,are introduced in detail.Finally,the future development of corrosion and protection of Mg?Li alloys is discussed.

Effect of rare earths surface treatment on tribological properties of carbon fibers reinforced PTFE composite under oil-lubricated condition

The effect of rare earths （RE） surface treatment of carbon fibers （CF） on tribological properties of CF reinforced polytetrafluoroethylene （PTFE） composites under oil-lubricated condition was investigated. Experimental results revealed that RE treated CF reinforced PTFE （CF/PTFE） composite had the lowest friction coefficient and wear under various applied loads and sliding speeds compared with untreated and air-oxidated composites. X-ray photoelectron spectroscopy （XPS） study of carbon fiber surface showed that, after RE treatment, oxygen concentration increased obviously, and the amount of oxygen-containing groups on CF surfaces were largely increased. The increase in the amount of oxygen-containing groups enhanced interfacial adhesion between CF and PTFE matrix. With strong interfacial adhesion of the composite, stress could be effectively transmitted to carbon fibers; carbon fibers were strongly bonded with VITE matrix, and large scale rubbing-off of PTFE be prevented, therefore, tribological properties of the composite was improved.

Effects of surface finish and treatment on the fatigue behaviour of vibrating cylinder block using frequency response approach

This paper presents the effects of surface finish and treatment on the high cycle fatigue behaviour of vibrating cylinder block of a new two-stroke free piston engine at complex variable amplitude loading conditions using frequency response approach. Finite element modelling and frequency response analysis was conducted using finite element analysis software Package MSC.PATRAN/MSC.NASTRAN and fatigue life prediction was carded out using MSC.FATIGUE software. Based on the finite element results, different frequency response approach was applied to predict the cylinder block fatigue life. Results for different load histories and material combinations are also discussed. Results indicated great effects for all surface finish and treatment. It is concluded that polished and cast surface finish conditions give the highest and lowest cylinder block lives, respectively; and that Nitrided treatment leads to longest cylinder block life. The results were used to draw contour plots of fatigue life and damage in the worst or most damaging case.

Effect of surface treatment for aluminum foils on discharge properties of lithium-ion battery

Aluminum foils having thicknesses of 10-20 μm are commonly employed as current collectors for cathode electrodes in Li-ion batteries. The effects of the surface morphology of the foil on battery performance were investigated by using a foil with roughened surface by chemical etching and a plain foil with smooth surface on both sides. For high-conductivity LiCoO2 active materials with large particle size, there are no significant differences in battery performance between the two types of foils. But for low-conductivity LiFePO4 active materials with small particle size, high-rate discharge properties are significantly different. The possibility shows that optimizing both the surface morphology of the aluminum foil and particle size of active material leads to improvement of the battery performance.

Surface Treatment of Polyethylene Terephthalate Film Using Atmospheric Pressure Glow Discharge in Air

Non-thermal plasmas under atmospheric pressure are of great interest in polymer surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of Polyethylene terephthalate (PET) film surface for improving hydrophilicity using the non-thermal plasma generated by atmospheric pressure glow discharge (APGD) in air is conducted. The discharge characteristics of APGD are shown by measurement of their electrical discharge parameters and observation of light-emission phenomena, and the surface properties of PET before and after the APGD treatment are studied using contact angle measurement, x-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It is found that the APGD is homogeneous and stable in the whole gas gap, which differs from the commonly filamentary dielectric barrier discharge (DBD). A short time (several seconds) APGD treatment can modify the surface characteristics of PET film markedly and uniformly. After 10 s APGD treatment, the

Surface modification of titanium using steel slag ball and shot blasting treatment for biomedical implant applications

Surface modification is often performed using grit or shot blasting treatment for improving the performances of biomedical implants. The effects of blasting treatments using steel slag balls and spherical shots on the surface and subsurface of titanium were studied in this paper. The treatments were conducted for 60-300 s using 2-5 mm steel slag bails and 3.18 mm spherical shots. The surface morphology, roughness, and elemental composition of titanium specimens were examined prior to and after the treatments. Irregular and rough titanium surfaces were formed after the treatment with the steel slag balls instead of the spherical shots. The former treatment also introduced some bioactive elements on the titanium surface, but the latter one yielded a harder surface layer. In conclusion, both steel slag ball and shot blasting treatment have their own specialization in modifying the surface of metallic biomaterials. Steel slag ball blasting is potential for improving the osseointegration quality of implants; but the shot blasting is more appropriate for improving the mechanical properties of temporary and load bearing implants, such as osteosynthesis plates.

Effect of surface treatment on the structure and high-rate dischargeability properties of AB_5-type hydrogen storage alloy

Surface-treated MmNi3.55Co0.75Mn0.4Al0.3 alloy as negative electrode material of nickel-metal hydride battery was employed to improve the high-rate dischargeability. Surface treatment was realized by dipping and stirring the alloy into a HCl aqueous solution with various concentrations at room temperature. The microstructure of the alloy before and after surface treatment was analyzed by X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The electrochemical properties before and after surface treatment were compared, and the alloy treated in 0.025 mol/L HCl solution showed the optimal high-rate dischargeability.

Plasma surface treatment of Cu by nanosecond-pulse diffuse discharges in atmospheric air

Nanosecond-pulse diffuse discharges could provide high-density plasma and high-energy electrons at atmospheric pressure. In this paper, the surface treatment of Cu by nanosecond-pulse diffuse discharges is conducted in atmospheric air. Factors influencing the water contact angle （WCA）, chemical composition and microhardness, such as the gap spacing and treatment time, are investigated. The results show that after the plasma surface treatment, the WCA considerably decreases from 87~ to 42.3~, and the surface energy increases from 20.46 mJ m-2 to 66.28 mJ m-2. Results of energy dispersive x-ray analysis show that the concentration of carbon decreases, but the concentrations of oxygen and nitrogen increase significantly. Moreover, the microhardness increases by approximately 30% after the plasma treatment. The aforementioned changes on the Cu surface indicate the plasma surface treatment enhances the hydrophilicity and microhardness, and it cleans the carbon and achieves oxidization on the Cu surface. Furthermore, by increasing the gap spacing and treatment time, better treatment effects can be obtained. The micmhardness in the case of a 2.5 cm gap is higher than that in the case of a 3 cm gap. More oxygen and nitrogen species appear on the Cu surface for the 2.5 cm gap treatment than for the 3 cm gap treatment. The WCA significantly decreases with the treatment thne when it is no longer than 90 s, and then it reaches saturation. In addition, more oxygen-containing and nitrogen-containing groups appear after extended plasma treatment time. They contribute to the improvement of the hydrophilicity and oxidation on the Cu surface.

Effect of surface treatment to inserted ring on Al–Fe bonding layer of aluminium piston with reinforced cast iron ring

In order to improve the bonding strength between piston alloys and cast iron ring of aluminum piston with reinforced cast iron ring,the different methods of the surface treatments(shot blasting and sand blasting) to the cast iron ring are experimented.The optical micrograph shows that an intermetallic layer and a ligulate shaped structure are formed between piston alloys and cast iron base ring.After sand blasting treatment,the ring surface is non-metal shiny,matte-like and has no obvious pits.The intermetallic layer thickness formed between piston alloys and cast iron is thinner and more equally distributed after sand blasting to the ring.The content of the graphite distributed the interfacial zone after the shot blasting treatment is little.With the increase of time by sand blasting,the hardness starts to slightly descend.The bonding strength of the sample by sand blasting is obviously higher than that by shot blasting and increases from 9.32 MPa to 19.53 MPa.

Influence of Different Surface Treatments of H13 Hot Work Die Steel on Its Thermal Fatigue Behaviors

Thermal fatigue checking is the general failure of hot work die steels, which is relative with the structures and properties of the steels and the stress alternated during the employment. The Uddeholm test method on thermal fatigue is used to compare the behaviors of different samples, which are treated with plasma nitriding、plasma sulfur carbon nitriding、boronizing or not treated. The results show that the nitriding improves the thermal fatigue property of the tool steel, while the plasma sulfur carbon nitriding and the boronizing impair the property. The mechanisms are induced as follows. By increasing the hardness and changing the stress distribution in the surface layer, surface treatment can decrease the plastic deformation and the tensile stress during the cycling. Therefore, the generation and growth of the cracks are restrained. On the other hand, as results of surface treating, in the surface layer the toughness declines and the expanding coefficient ascendes; the latter change caused the strengthening of the tensile and compressive stress during the cycling. Thus the resistance to thermal fatigue is weakened. Whether or not the surface treatment is favor to thermal fatigue of tool steels relies on which factor is dominant.

Microstructural characterization of Inconel 718 alloy after pulsed laser surface treatment at different powers

An annealed Inconel 718 alloy was surface-treated by pulsed laser at three different powers（100, 50 and 25 W）. Microstructural changes induced by the laser treatments were characterized by use of electron backscatter diffraction and electron channeling contrast imaging techniques. Results show that both annealing twins and strengthening precipitates profusely existing in the as-received specimen are dissolved at elevated temperatures during the laser irradiation. Meanwhile, in the melting zone（MZ）, densities of low angle boundaries（LABs） are greatly increased with a large number of Laves phases preferentially distributed along such LABs. For different specimens, widths and depths of their MZs are found to be gradually reduced with decreasing the laser powers. Orientation analyses reveal that the columnar grains in the MZ of the 100 W specimen could inherit orientations existing in the matrix while lower laser powers promote the formation of more nuclei with scattered orientations to grow to be granular grains in the MZ. Hardness tests reveal that the MZs of all laser-treated specimens are softer than the matrix probably due to both precipitate dissolution and grain coarsening.

Surface Nanocrystallization of C45E4 Steel by Ultrafast Electropulsing-ultrasonic Surface Treatment

The effect of high-energy electropulsing-ultrasonic surface treatment（EUST） on the surface properties and the microstructure evolution of C45 E4 steel was investigated. Refined microstructure and reduced surface roughness were obtained owing to the surface nanocrystallization process. Compared with the ultrasonic surface treatment（UST）, the impact depth of the surface strengthened layer was increased by 40% to 700 μm after EUST. The average grain size of the surface nanocrystallization layer was reduced to 30-50 nm. The surface roughness of the C45 E4 steel was reduced to 0.25 μm, and the surface microhardness was dramatically enhanced to 460 HV. The improvement of microstructure and micro-hardness at ambient temperature was likely attributed to the acceleration of atomic diffusion and the enhancement of plastic deformation ability in the surface strengthened layer under the influence of electropulsing. Due to the electropulsing-assisted ultrasonic strengthening effect, the surface nanocrystallization in this ultrafast procedure was noticeably enhanced.

Effect of Low-Pressure Nitrogen DC Plasma Treatment on the Surface Properties of Biaxially Oriented Polypropylene, Poly (Methyl Methacrylate) and Polyvinyl Chloride Films

In this study, commercial biaxially oriented polypropylene （BOPP）, polyvinyl chlo- ride （PVC） and poly （methyl methacrylate） （PMMA） films were treated with nitrogen plasma over different exposure times in a Pyrex tube surrounded by a DC variable magnetic field. The chemi- cal changes that appeared on the surface of the samples were investigated using Fourier transform infrared （FT4R） spectroscopy and attenuated total reflectance Fourier transform infrared （ATR- FTIR） spectroscopy after treatment for 2 min, 4 min and 6 rain in a nitrogen plasma chamber. Effects of the plasma treatment on the surface topographies and contact angles of the untreated and plasma treated films were also analyzed by atomic force microscopy （AFM） and a contact angle measuring system. The results show that the plasma treated films become more hydrophilic with an enhanced wettability due to the formation of some new polar groups on the surface of the treated films. Moreover, at higher exposure times, the total surface energy in all treated films increased while a reduction in contact angle occurred. The behavior of surface roughness in each sample was completely different at higher exposure times.

Electrical properties and reliability of HfO2 gate-dielectric MOS capacitors with trichloroethylene surface pretreatment

Trichloroethylene （TCE） pretreatment of Si surface prior to HfO2 deposition is employed to fabricate HfO2 gatedielectric MOS capacitors. Influence of this processing procedure on interlayer growth, HfO2/Si interface properties, gate-oxide leakage and device reliability is investigated. Among the surface pretreatments in NH3, NO, N2O and TCE ambients, the TCE pretreatment gives the least interlayer growths the lowest interface-state density, the smallest gate leakage and the highest reliability. All these improvements should be ascribed to the passivation effects of Cl2 and HC1 on the structural defects in the interlayer and at the interface, and also their gettering effects on the ion contamination in the gate dielectric.

Study on Surface Treatments on CdSe Wafers

The surface treatments on CdSe wafers were studied by means of SEM,XPS and micro-current test instrument.The relations between electrical properties of CdSe wafers and surface topography,composition and structure were analyzed.The results show that the change of surface composition by etching is beneficial to decrease leakage current.Meanwhile,the increase of oxygen on surface caused by passivation can largely decrease leakage current.When passivating time is 40 min,the wafers surface appears smooth and compact,which will decrease the density of surface state,the optimal electrical property of the wafer is therefore obtained.

Surface treatment of titanium dioxide nanopowder using rotary electrode dielectric barrier discharge reactor

Titanium dioxide(Ti O_(2))nanopowder(P-25;Degussa AG)was treated using dielectric barrier discharge(DBD)in a rotary electrode DBD(RE-DBD)reactor.Its electrical and optical characteristics were investigated during RE-DBD generation.The treated TiO_(2)nanopowder properties and structures were analyzed using x-ray diffraction(XRD)and Fourier-transform infrared spectroscopy(FTIR).After RE-DBD treatment,XRD measurements indicated that the anatase peak theta positions shifted from 25.3°to 25.1°,which can be attributed to the substitution of new functional groups in the TiO_(2)lattice.The FTIR results show that hydroxyl groups(OH)at 3400 cm-1 increased considerably.The mechanism used to modify the TiO_(2)nanopowder surface by air DBD treatment was confirmed from optical emission spectrum measurements.Reactive species,such as OH radical,ozone and atomic oxygen can play key roles in hydroxyl formation on the TiO_(2)nanopowder surface.

Influence of Surface Treatment on the Corrosion Resistance of Stainless Steel in Simulated Human Body Environment

In the present research, the influence of chromium enrichment by surface treatment on corrosion resistance of type 316L stainless steel in body environment was investigated. For this study, weight loss test during 18 months, cyclic and liner polarization tests before and after surface treatment and metallography by electron and light microscopy were used to evaluate the effectiveness of the proposed method. In addition, X-ray photoelectron spectroscopy （XPS） method was used to determine the chromium concentration in the surface layer after surface treatment. Results show that the surface treatment has improved corrosion resistance of the type 316L stainless steel in body environment.

Influence of Surface Nano-structured Treatment on Pack Boriding of H13 Steel

In order to lower the boriding temperature of hot work steel H13, method of surface mechanical attrition treatment （SMAT）, which can make the grain size of the surface reach nano-scale, was used before pack boriding. The growth of the boride layer was studied in a function of boriding temperature and time. By TEM （transmission electron microscopy）, SEM （scanning electron microscopy）, XRD （x-ray diffraction） and microhardness tests, the grain size, thermal stability of the nano-structured （NS） surface and the thickness,appearance, phases of the surface boride layer were studied. Kinetic of boriding was compared between untreated samples and treated samples. Results showed that after SMAT, the boride layer was thicker and the hardness gradient was smoother. Furthermore, after boriding at a low temperature of 700℃ for 8 h, a boride layer of about 5 μm formed on the NS surface. This layer was toothlike and wedged into the substrate, which made the surface layer combine well with the substrate. The phase of the boride layer was Fe2B. Research on boriding kinetics indicated that the activation energy was decreased for the treated samples.