The role of the intersection between two potential energy surfaces has been more generally emphasizing on than before.In the present system,the intersections between S1,T1 and S0 surfaces were optimized with the state...The role of the intersection between two potential energy surfaces has been more generally emphasizing on than before.In the present system,the intersections between S1,T1 and S0 surfaces were optimized with the state-averaged CAS(8,7)/6-31G method.The comparison of their optimized structures demonstrates that the intersection points of S1/S0 and S1/T1 locate in the same region,referred to as S1/T1/S0 point.The existence of S1/T1/S0 point and its high possibility of radiationless transition via intersystem crossing or internal conversion,would make the system have the most efficient funnel to generate the ground- and triplet-state products,which is consistent with the experimental facts.展开更多
The stress on a test specimen during tensile testing is generally measured by a strain gauge. This method has some problems in that it would influence the measurement conditions of the tensile test and can evaluate on...The stress on a test specimen during tensile testing is generally measured by a strain gauge. This method has some problems in that it would influence the measurement conditions of the tensile test and can evaluate only the position at which the strain gauge is attached. The acoustoelastic method is proposed as a method replacing the strain gauge method. However, an ultrasonic sensor with a piezoelectric oscillator requires a coupling medium to inject an ultrasonic wave into a solid material. This condition, due to the error factor of the stress measurement, makes it difficult for the ultrasonic sensor to move on the specimen. We then tried to develop a non-contact stress measurement system during tensile testing using an electromagnetic acoustic transducer (EMAT) with an SH0-plate wave and S0-Lamb wave. The EMAT can measure the propagation time in which the ultrasonic wave travels between a receiver and a transmitter without a coupling medium during the tensile testing and can move easily. The interval between the transmitter and the receiver is 10mm and can be moved along the parallel direction or the vertical direction of the tensile load. The transit time was measured by a cross-correlation method and converted into the stress on the test specimen using the acoustoelastic method. We confirmed that the stress measurement using an SH0-plate wave was superior to that with an S0-Lamb wave.展开更多
In this paper, the application of a homemade Nafion and Co(Salen) modified platinum microelec-trode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is repor...In this paper, the application of a homemade Nafion and Co(Salen) modified platinum microelec-trode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nafion and Co(Salen) modified platinum microelectrode.展开更多
仪器正确定向是保证仪器观测质量的一个重要环节。由于地磁场的长期变化,仪器需要定期重新定向。本文应用全国44个地磁台站2008—2012年观测数据,研究了各台站D分量的长期变化特征。结果表明,仪器定向位置和被测磁场位置产生较大偏离时...仪器正确定向是保证仪器观测质量的一个重要环节。由于地磁场的长期变化,仪器需要定期重新定向。本文应用全国44个地磁台站2008—2012年观测数据,研究了各台站D分量的长期变化特征。结果表明,仪器定向位置和被测磁场位置产生较大偏离时,必须重新定向。同时首次提出影响定向精度的零场漂移S0,并根据理论计算在红山地磁台实地开展测量,测量结果表明,零场漂移S0数值达到50.3 n T,超出D分量定向输出范围(磁静日时日变缓慢时间段为-50n T—+50n T)。展开更多
文摘The role of the intersection between two potential energy surfaces has been more generally emphasizing on than before.In the present system,the intersections between S1,T1 and S0 surfaces were optimized with the state-averaged CAS(8,7)/6-31G method.The comparison of their optimized structures demonstrates that the intersection points of S1/S0 and S1/T1 locate in the same region,referred to as S1/T1/S0 point.The existence of S1/T1/S0 point and its high possibility of radiationless transition via intersystem crossing or internal conversion,would make the system have the most efficient funnel to generate the ground- and triplet-state products,which is consistent with the experimental facts.
文摘The stress on a test specimen during tensile testing is generally measured by a strain gauge. This method has some problems in that it would influence the measurement conditions of the tensile test and can evaluate only the position at which the strain gauge is attached. The acoustoelastic method is proposed as a method replacing the strain gauge method. However, an ultrasonic sensor with a piezoelectric oscillator requires a coupling medium to inject an ultrasonic wave into a solid material. This condition, due to the error factor of the stress measurement, makes it difficult for the ultrasonic sensor to move on the specimen. We then tried to develop a non-contact stress measurement system during tensile testing using an electromagnetic acoustic transducer (EMAT) with an SH0-plate wave and S0-Lamb wave. The EMAT can measure the propagation time in which the ultrasonic wave travels between a receiver and a transmitter without a coupling medium during the tensile testing and can move easily. The interval between the transmitter and the receiver is 10mm and can be moved along the parallel direction or the vertical direction of the tensile load. The transit time was measured by a cross-correlation method and converted into the stress on the test specimen using the acoustoelastic method. We confirmed that the stress measurement using an SH0-plate wave was superior to that with an S0-Lamb wave.
基金Supported by the NSFC (No. 40076020) National Basic Research Priority Program (973) (No.2001CB409700) and the research fund for the doctoral program for higher education.
文摘In this paper, the application of a homemade Nafion and Co(Salen) modified platinum microelec-trode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nafion and Co(Salen) modified platinum microelectrode.
文摘仪器正确定向是保证仪器观测质量的一个重要环节。由于地磁场的长期变化,仪器需要定期重新定向。本文应用全国44个地磁台站2008—2012年观测数据,研究了各台站D分量的长期变化特征。结果表明,仪器定向位置和被测磁场位置产生较大偏离时,必须重新定向。同时首次提出影响定向精度的零场漂移S0,并根据理论计算在红山地磁台实地开展测量,测量结果表明,零场漂移S0数值达到50.3 n T,超出D分量定向输出范围(磁静日时日变缓慢时间段为-50n T—+50n T)。
