The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is u...The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is usually sensitive to climate change.The water resource management in the monsoon margin should be better planned by understanding the composition of precipitation isotope and its influencing factors.In this study,the precipitation samples were collected at five sampling sites(Baiyin City,Kongtong District,Maqu County,Wudu District,and Yinchuan City)of the monsoon margin in the northwest of China in 2022 to analyze the characteristics of stable hydrogen(δD)and oxygen(δ18O)isotopes.We analyzed the impact of meteorological factors(temperature,precipitation,and relative humidity)on the composition of precipitation isotope at daily level by regression analysis,utilized the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)-based backward trajectory model to simulate the air mass trajectory of precipitation events,and adopted the potential source contribution function(PSCF)and concentration weighted trajectory(CWT)to analyze the water vapor sources.The results showed that compared with the global meteoric water line(GMWL),the slope of the local meteoric water line(LMWL;δD=7.34δ^(18)O-1.16)was lower,indicating the existence of strong regional evaporation in the study area.Temperature significantly contributed toδ18O value,while relative humidity had a significant negative effect onδ18O value.Through the backward trajectory analysis,we found eight primary locations that were responsible for the water vapor sources of precipitation in the study area,of which moisture from the Indian Ocean to South China Sea(ITSC)and the western continental(CW)had the greatest influence on precipitation in the study area.The hydrogen and oxygen isotopes in precipitation are significantly influenced by the sources and transportation paths of air mass.In addition,the results of PSCF and CWT analysis showed that the water vapor source areas were primarily distributed in the south and northwest direction of the study area.展开更多
To explain the presence and spatial distribution of NO_(3)^(−)and N-NH_(3)in the Aquifer of the Metropolitan Area of Mexico City(AMAMC),a hydrogeochemical and isotopic analysis using^(13)C DIC(as well as the stable is...To explain the presence and spatial distribution of NO_(3)^(−)and N-NH_(3)in the Aquifer of the Metropolitan Area of Mexico City(AMAMC),a hydrogeochemical and isotopic analysis using^(13)C DIC(as well as the stable isotopes^(18)O and^(2)H)in groundwater was conducted.This aquifer is located in an old closed lacustrine volcano-sedimentary basin;some wells hosted in the semi-confined zone contain high N-NH_(3)concentrations,while others present NO_(3)^(−)contents in the recharge zones(hosted in an oxidizing environment).In this study,a change in the isotopic signature(primarily in^(18)O and^(2)H)was observed from the recharge zones to the basin center in some of the wells with high NO_(3)^(−)concentrations,this behavior can be attributed to evaporation during the incorporation of recently infiltrated water.In addition,the results for^(13)C(along with ^(2) H)in wells with the highest N-NH_(3)concentrations exhibited an atypically broad range of values.Results indicated the occurrence of hydrogeochemical and/or biochemical processes in the aquifer(in an oxidizing or reducing environment),such as organic degradation,bacterial decomposition(primarily in the ancient Lake Texcoco and which acts as a natural sink for carbon,nitrogen,sulfur,and phosphorus),besides rock weathering and dissolution,which may be responsible for a very marked isotopic modification of the^(13)C(and,to a lesser extent,2 H).Methanotrophic bacterial activity and methanogenic activity may be related to N-NH_(3)removal processes by oxidation and residual water incorporation respectively,whereas the increase in the NO_(3)^(−)content in some wells is due to the recent contribution of poor-quality water due to contamination.展开更多
依据乌鲁木齐河流域山区3个站点实测次降水δ18O和δD数据以及气象观测资料,结合临近GNIP(Global Network of Isotopes in Precipitation)站点数据,对其降水δ18O和δD特征及水汽来源进行了分析。结果表明,大气降水中δ18O值波动范围大...依据乌鲁木齐河流域山区3个站点实测次降水δ18O和δD数据以及气象观测资料,结合临近GNIP(Global Network of Isotopes in Precipitation)站点数据,对其降水δ18O和δD特征及水汽来源进行了分析。结果表明,大气降水中δ18O值波动范围大,但呈现明显的季节性变化:冬季降水δ18O较低,夏季降水δ18O较高。受流域山区气候和地理条件影响,从上游到下游各站点大气降水线截距和斜率均呈现逐渐减小趋势。大气降水中δ18O和δD与日均气温存在密切正相关关系,且温度与δ18O之间的相关性优于δD。降水中d-excess值也表现出季节性变化,冬季降水d-excess值高于夏季降水。利用HYSPLIT 4.0气团轨迹模型,得出夏季水汽主要来源西风环流输送,冬季受西风环流和极地气团共同影响。展开更多
基于豫西老母洞LM2石笋8个高精度230Th年龄,449个氧碳同位素,建立了达十年际分辨率的8.2~10.9 ka B.P.亚洲季风变化的δ18O记录序列。老母洞石笋δ18O值最为偏负达-12.0‰,最偏正为-8.2‰,振幅达3.8‰。早全新世10.13~10.9 ka B.P.时段...基于豫西老母洞LM2石笋8个高精度230Th年龄,449个氧碳同位素,建立了达十年际分辨率的8.2~10.9 ka B.P.亚洲季风变化的δ18O记录序列。老母洞石笋δ18O值最为偏负达-12.0‰,最偏正为-8.2‰,振幅达3.8‰。早全新世10.13~10.9 ka B.P.时段内,河南西部老母洞石笋和东石崖石笋,陕西九仙洞C996-2石笋δ18O曲线揭示该时段内季风稳定,而中国南方的衙门洞石笋、三宝洞石笋和极地冰芯GRIP记录揭示该时段季风逐渐增强;同时季风达到顶峰的时期也不相同,进一步说明中国南北方早全新世10.13~10.9 ka B.P.时段季风演变过程的差异,可能与中国南北方气候的响应机制有关。从早全新世平均分辨率10年的LM2石笋记录中识别出8.2 ka,9.5 ka,10.2 ka和10.9 ka显著弱季风事件,尤其是8.2 ka和9.5 ka事件。对比分析老母洞与已发表的高分辨率石笋δ18O记录发现:石笋所揭示的某些冷事件发生时间在亚洲季风区存在差异,主要表现在事件内部变化特征及趋势上。LM2石笋δ18O曲线并没有明显记录9.3 ka弱季风事件,而是在9.3~9.6 ka B.P.左右记录了一个弱季风事件,与DSY09(2009)、Y1、HS-4记录相似,表明在该时段内存在季风的减弱事件,但是氧同位素传输的复杂性,使其在南北方表现不同。此外,在LM2石笋δ18O的8.2 ka B.P.开始时段,氧同位素曲线阶段性下降,且变幅达3‰,与Zhang等研究万象洞石笋提出的"中国8 200阶段"吻合,表明中国北方地区的8.2 ka事件是阶段性的事件,而南方的石笋氧同位素记录揭示的8.2 ka事件并未表现出阶段性特征,其原因有待于更多北方高精度石笋记录来进一步研究。LM2石笋氧同位素记录进行功率谱分析发现:在短尺度上季风变化与太阳活动密切相关,这与近年来对早全新世极端气候变化研究的驱动机制是一致的,早全新世亚洲季风的演化与太阳活动变化引起的太阳辐射能量的变化和北半球高纬气候的变化状况有关。展开更多
基金supported by the National Natural Science Foundation of China(42161007)the Scientific Research Program for Higher Education Institutions of Gansu Province(2021B-081)the Natural Science Foundation of Gansu Province(22JR5RA074).
文摘The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is usually sensitive to climate change.The water resource management in the monsoon margin should be better planned by understanding the composition of precipitation isotope and its influencing factors.In this study,the precipitation samples were collected at five sampling sites(Baiyin City,Kongtong District,Maqu County,Wudu District,and Yinchuan City)of the monsoon margin in the northwest of China in 2022 to analyze the characteristics of stable hydrogen(δD)and oxygen(δ18O)isotopes.We analyzed the impact of meteorological factors(temperature,precipitation,and relative humidity)on the composition of precipitation isotope at daily level by regression analysis,utilized the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)-based backward trajectory model to simulate the air mass trajectory of precipitation events,and adopted the potential source contribution function(PSCF)and concentration weighted trajectory(CWT)to analyze the water vapor sources.The results showed that compared with the global meteoric water line(GMWL),the slope of the local meteoric water line(LMWL;δD=7.34δ^(18)O-1.16)was lower,indicating the existence of strong regional evaporation in the study area.Temperature significantly contributed toδ18O value,while relative humidity had a significant negative effect onδ18O value.Through the backward trajectory analysis,we found eight primary locations that were responsible for the water vapor sources of precipitation in the study area,of which moisture from the Indian Ocean to South China Sea(ITSC)and the western continental(CW)had the greatest influence on precipitation in the study area.The hydrogen and oxygen isotopes in precipitation are significantly influenced by the sources and transportation paths of air mass.In addition,the results of PSCF and CWT analysis showed that the water vapor source areas were primarily distributed in the south and northwest direction of the study area.
基金support granted to carry out the research,and for the funding,Dr.Graciela Herrera Zamarron,responsible for the project with Contract number 0266-1O-ED-F-DGAT-UNAM-2-19-1928.
文摘To explain the presence and spatial distribution of NO_(3)^(−)and N-NH_(3)in the Aquifer of the Metropolitan Area of Mexico City(AMAMC),a hydrogeochemical and isotopic analysis using^(13)C DIC(as well as the stable isotopes^(18)O and^(2)H)in groundwater was conducted.This aquifer is located in an old closed lacustrine volcano-sedimentary basin;some wells hosted in the semi-confined zone contain high N-NH_(3)concentrations,while others present NO_(3)^(−)contents in the recharge zones(hosted in an oxidizing environment).In this study,a change in the isotopic signature(primarily in^(18)O and^(2)H)was observed from the recharge zones to the basin center in some of the wells with high NO_(3)^(−)concentrations,this behavior can be attributed to evaporation during the incorporation of recently infiltrated water.In addition,the results for^(13)C(along with ^(2) H)in wells with the highest N-NH_(3)concentrations exhibited an atypically broad range of values.Results indicated the occurrence of hydrogeochemical and/or biochemical processes in the aquifer(in an oxidizing or reducing environment),such as organic degradation,bacterial decomposition(primarily in the ancient Lake Texcoco and which acts as a natural sink for carbon,nitrogen,sulfur,and phosphorus),besides rock weathering and dissolution,which may be responsible for a very marked isotopic modification of the^(13)C(and,to a lesser extent,2 H).Methanotrophic bacterial activity and methanogenic activity may be related to N-NH_(3)removal processes by oxidation and residual water incorporation respectively,whereas the increase in the NO_(3)^(−)content in some wells is due to the recent contribution of poor-quality water due to contamination.
文摘依据乌鲁木齐河流域山区3个站点实测次降水δ18O和δD数据以及气象观测资料,结合临近GNIP(Global Network of Isotopes in Precipitation)站点数据,对其降水δ18O和δD特征及水汽来源进行了分析。结果表明,大气降水中δ18O值波动范围大,但呈现明显的季节性变化:冬季降水δ18O较低,夏季降水δ18O较高。受流域山区气候和地理条件影响,从上游到下游各站点大气降水线截距和斜率均呈现逐渐减小趋势。大气降水中δ18O和δD与日均气温存在密切正相关关系,且温度与δ18O之间的相关性优于δD。降水中d-excess值也表现出季节性变化,冬季降水d-excess值高于夏季降水。利用HYSPLIT 4.0气团轨迹模型,得出夏季水汽主要来源西风环流输送,冬季受西风环流和极地气团共同影响。
文摘基于豫西老母洞LM2石笋8个高精度230Th年龄,449个氧碳同位素,建立了达十年际分辨率的8.2~10.9 ka B.P.亚洲季风变化的δ18O记录序列。老母洞石笋δ18O值最为偏负达-12.0‰,最偏正为-8.2‰,振幅达3.8‰。早全新世10.13~10.9 ka B.P.时段内,河南西部老母洞石笋和东石崖石笋,陕西九仙洞C996-2石笋δ18O曲线揭示该时段内季风稳定,而中国南方的衙门洞石笋、三宝洞石笋和极地冰芯GRIP记录揭示该时段季风逐渐增强;同时季风达到顶峰的时期也不相同,进一步说明中国南北方早全新世10.13~10.9 ka B.P.时段季风演变过程的差异,可能与中国南北方气候的响应机制有关。从早全新世平均分辨率10年的LM2石笋记录中识别出8.2 ka,9.5 ka,10.2 ka和10.9 ka显著弱季风事件,尤其是8.2 ka和9.5 ka事件。对比分析老母洞与已发表的高分辨率石笋δ18O记录发现:石笋所揭示的某些冷事件发生时间在亚洲季风区存在差异,主要表现在事件内部变化特征及趋势上。LM2石笋δ18O曲线并没有明显记录9.3 ka弱季风事件,而是在9.3~9.6 ka B.P.左右记录了一个弱季风事件,与DSY09(2009)、Y1、HS-4记录相似,表明在该时段内存在季风的减弱事件,但是氧同位素传输的复杂性,使其在南北方表现不同。此外,在LM2石笋δ18O的8.2 ka B.P.开始时段,氧同位素曲线阶段性下降,且变幅达3‰,与Zhang等研究万象洞石笋提出的"中国8 200阶段"吻合,表明中国北方地区的8.2 ka事件是阶段性的事件,而南方的石笋氧同位素记录揭示的8.2 ka事件并未表现出阶段性特征,其原因有待于更多北方高精度石笋记录来进一步研究。LM2石笋氧同位素记录进行功率谱分析发现:在短尺度上季风变化与太阳活动密切相关,这与近年来对早全新世极端气候变化研究的驱动机制是一致的,早全新世亚洲季风的演化与太阳活动变化引起的太阳辐射能量的变化和北半球高纬气候的变化状况有关。
