Graphitic carbon nitride(g-C_(3)N_(4))has been extensively doped with alkali metals to enlarge photocatalytic output,in which cesium(Cs)doping is predicted to be the most efficient.Nevertheless,the sluggish diffusion ...Graphitic carbon nitride(g-C_(3)N_(4))has been extensively doped with alkali metals to enlarge photocatalytic output,in which cesium(Cs)doping is predicted to be the most efficient.Nevertheless,the sluggish diffusion and doping kinetics of precursors with high melting points,along with imprecise regulation,have raised the debate on whether Cs doping could make sense.For this matter,we attempt to confirm the positive effects of Cs doping on multifunctional photocatalysis by first using cesium acetate with the character of easy manipulation.The optimized Csdoped g-C_(3)N_(4)(CCN)shows a 41.6-fold increase in visible-light-driven hydrogen evolution reaction(HER)compared to pure g-C_(3)N_(4) and impressive degradation capability,especially with 77%refractory tetracycline and almost 100%rhodamine B degradedwithin an hour.The penetration ofCs+is demonstrated to be a mode of interlayer doping,and Cs–N bonds(especially with sp^(2) pyridine N in C═N–C),along with robust chemical interaction and electron exchange,are fabricated.This atomic configuration triggers the broadened spectral response,the improved charge migration,and the activated photocatalytic capacity.Furthermore,we evaluate the CCN/cadmium sulfide hybrid as a Z-scheme configuration,promoting the visible HER yield to 9.02 mmol g^(−1) h^(−1),which is the highest ever reported among all CCN systems.This work adds to the rapidly expanding field of manipulation strategies and supports further development of mediating served for photocatalysis.展开更多
针对传统自然资源地籍调查依赖大量现场工作和后期数据处理导致的调查周期长、成本高等问题,提出了一种基于Cesium for Unreal的自然资源远程协同调查方法。该方法以倾斜摄影获取的实景三维模型为基础,叠加权属、土地利用等业务数据构...针对传统自然资源地籍调查依赖大量现场工作和后期数据处理导致的调查周期长、成本高等问题,提出了一种基于Cesium for Unreal的自然资源远程协同调查方法。该方法以倾斜摄影获取的实景三维模型为基础,叠加权属、土地利用等业务数据构建调查场景,并通过优化实景三维模型的渲染效果和性能,使自然资源信息以更加直观、真实的方式呈现。在此基础上,自然资源所在地相关政府部门可直接在系统中查看界址、权属等信息,并与实景进行对比核实,然后在线反馈和记录问题;调查单位根据反馈在系统中直接修改数据,完成后即可与政府部门进行线上确认和签字。肇庆某湿地公园的试点应用结果表明,该方法能显著提高自然资源地籍调查效率,压缩工期,具有较好的应用前景。展开更多
基金supported primarily by the National Natural Science Foundation of China(Contract No.21975245,51972300,62274155,and U20A20206)the National Key Research and Development Program of China(Grant No.2018YFE0204000)+2 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB43000000)the National Natural Science Foundation of China under Grant No.62175231.Prof.Kong Liu appreciates the support from the Youth Innovation Promotion Association,the Chinese Academy of Sciences(No.2020114)the Beijing Nova Program(No.2020117).
文摘Graphitic carbon nitride(g-C_(3)N_(4))has been extensively doped with alkali metals to enlarge photocatalytic output,in which cesium(Cs)doping is predicted to be the most efficient.Nevertheless,the sluggish diffusion and doping kinetics of precursors with high melting points,along with imprecise regulation,have raised the debate on whether Cs doping could make sense.For this matter,we attempt to confirm the positive effects of Cs doping on multifunctional photocatalysis by first using cesium acetate with the character of easy manipulation.The optimized Csdoped g-C_(3)N_(4)(CCN)shows a 41.6-fold increase in visible-light-driven hydrogen evolution reaction(HER)compared to pure g-C_(3)N_(4) and impressive degradation capability,especially with 77%refractory tetracycline and almost 100%rhodamine B degradedwithin an hour.The penetration ofCs+is demonstrated to be a mode of interlayer doping,and Cs–N bonds(especially with sp^(2) pyridine N in C═N–C),along with robust chemical interaction and electron exchange,are fabricated.This atomic configuration triggers the broadened spectral response,the improved charge migration,and the activated photocatalytic capacity.Furthermore,we evaluate the CCN/cadmium sulfide hybrid as a Z-scheme configuration,promoting the visible HER yield to 9.02 mmol g^(−1) h^(−1),which is the highest ever reported among all CCN systems.This work adds to the rapidly expanding field of manipulation strategies and supports further development of mediating served for photocatalysis.
文摘针对传统自然资源地籍调查依赖大量现场工作和后期数据处理导致的调查周期长、成本高等问题,提出了一种基于Cesium for Unreal的自然资源远程协同调查方法。该方法以倾斜摄影获取的实景三维模型为基础,叠加权属、土地利用等业务数据构建调查场景,并通过优化实景三维模型的渲染效果和性能,使自然资源信息以更加直观、真实的方式呈现。在此基础上,自然资源所在地相关政府部门可直接在系统中查看界址、权属等信息,并与实景进行对比核实,然后在线反馈和记录问题;调查单位根据反馈在系统中直接修改数据,完成后即可与政府部门进行线上确认和签字。肇庆某湿地公园的试点应用结果表明,该方法能显著提高自然资源地籍调查效率,压缩工期,具有较好的应用前景。
