Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ig...Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ignition mechanism of EFIs directly igniting pyrotechnics.An oscilloscope,a photon Doppler velocimetry,and a plasma spectrum measurement system were employed to obtain information of electric characteristics,impact pressure,and plasma temperature.The results of the electric characteristics and the impact pressure were inconsistent with ignition results.The only thing that the ignition success tests had in common was that their plasma all had a relatively long period of high-temperature duration(HTD).It eventually concludes that the ignition mechanism in this research is the microconvection heat transfer rather than the shock initiation,which differs from that of exploding foil initiators detonating explosives.Furthermore,the methods for evaluating the ignition success of semiconductor bridge initiators are not entirely applicable to the tests mentioned in this paper.The HTD is the critical parameter for judging the ignition success,and it is influenced by two factors:the late time discharge and the energy of the electric explosion.The longer time of the late time discharge and the more energy of the electric explosion,the easier it is to expand the HTD,which improves the probability of the ignition success.展开更多
Purpose:This article aims to determine the percentage of"Sparking"articles among the work of this year’s Nobel Prize winners in medicine,physics,and chemistry.Design/methodology/approach:We focus on under-c...Purpose:This article aims to determine the percentage of"Sparking"articles among the work of this year’s Nobel Prize winners in medicine,physics,and chemistry.Design/methodology/approach:We focus on under-cited influential research among the key publications as mentioned by the Nobel Prize Committee for the 2020 Noble Prize laureates.Specifically,we extracted data from the Web of Science,and calculated the Sparking Indices using the formulas as proposed by Hu and Rousseau in 2016 and 2017.In addition,we identified another type of igniting articles based on the notion in 2017.Findings:In the fields of medicine and physics,the proportions of articles with sparking characteristics share 78.571%and 68.75%respectively,yet,in chemistry 90%articles characterized by"igniting".Moreover,the two types of articles share more than 93%in the work of the Nobel Prize included in this study.Research limitations:Our research did not cover the impact of topic,socio-political,and author’s reputation on the Sparking Indices.Practical implications:Our study shows that the Sparking Indices truly reflect influence of the best research work,so it can be used to detect under-cited influential articles,as well as identifying fundamental work.Originality/value:Our findings suggest that the Sparking Indices have good applicability for research evaluation.展开更多
How to directly fabricate metallic functional parts with selective laser sintering (SLS) process is a potential technique that scientists are researching. Existent problems during directly fabricating metal part by us...How to directly fabricate metallic functional parts with selective laser sintering (SLS) process is a potential technique that scientists are researching. Existent problems during directly fabricating metal part by use of SLS are analyzed. For the sake of solving the problems, a new idea of adding self-propagating high-temperature synthesis (SHS) material into metallic powder material to form new type of SLS metallic powder material is put forward. This powder material can release controllable amount of heat during its interaction with the laser beam energy to reduce the requirement to laser power during directly sintering metallic part, to prolong the time of metallic liquid phase existing, and to improve the intensity and accuracy of SLS part. For this reason, SHS material′s interaction with the CO2 laser beam energy is researched, which proves that CO2 laser beam energy may instantly ignite SHS reaction. On the basis of the above-mentioned researches, the effect of sintering the metal powder material mixing SHS material with CO2 laser is also researched, which shows: there is an optimal blending ratio of various material in the new metallic powder material. Under the optimal blending ratio and SLS process parameters, this new metallic powder material can indeed release amount of heat and SHS reaction may be controlled within the laser sintering. This research result makes it possible that the metallic part is directly sintered with small CO2 laser (less than 50W), which may greatly reduce the volume, cost and running expenditure of SLS machine, be propitious to application.展开更多
Ten million times more compact energy than from burning carbon can be obtained from nuclear fusion reactions corresponding to equilibrium temperature reactions in the range above 100 million degrees.Following the ener...Ten million times more compact energy than from burning carbon can be obtained from nuclear fusion reactions corresponding to equilibrium temperature reactions in the range above 100 million degrees.Following the energy gain in stars,one has to gain nuclear energy from slamming very light nuclei where however the extremely high temperatures above 100 million degrees are needed for the sufficient pressures at thermal equilibrium ignition.A radically new option works with non-thermal pressures of picosecond laser pulses at ultrahigh optical powers by nonlinear forces of ponderomotion.The nuclear fusion of hydrogen with the isotope 11 of boron produces primarily harmless helium and has no problems with dangerous radioactive waste and excludes any catastrophic melt-down as fission reactors,it has the potential to be of low costs and can supply the Earth for more than 10,000 years with electricity.展开更多
Hot molten metal droplets with high fire hazard can easily ignite combustibles. Molten metal kinetics on the surface of a combustible material directly affects the ignition likelihood. Existing research focuses on the...Hot molten metal droplets with high fire hazard can easily ignite combustibles. Molten metal kinetics on the surface of a combustible material directly affects the ignition likelihood. Existing research focuses on the behavior of droplets during collisions, rarely addressing the ignition of combustibles by hot metal droplets. Here, the mechanisms of aluminum and copper droplets impinging on and igniting extended polystyrene (EPS) foam boards at different velocities were investigated. The relationship between the critical ignition temperature and impact velocity of droplets with diameters of 6 and 8 mm was experimentally studied for aluminum droplets;the critical ignition temperature non-monotonically depended on the impact velocity. For copper droplets, the relationship between the ignition probability and the impact velocity of droplets with diameters in the 3.5–7 mm range was experimentally studied. The most obvious difference between the two droplet ignition types was that the impact of copper droplets was accompanied by intense splashing, and the fragmentation extent positively correlated with the impact velocity. It was challenging to ignite using completely broken copper droplets. Droplets with the diameter of 5 mm were the most dangerous under the experimental conditions of this study, because the foam could still be ignited at higher impact velocities. Numerical simulations suggested that the main factors explaining the critical ignition temperature of aluminum droplets were gas mixing and splat cooling. The main factor affecting the ignition of copper droplets was fragmentation, and experimental observations were explained using non-dimensional droplet fragmentation theories.展开更多
Boron has high mass and volume calorific values,but it is difficult to ignite and has low combustion efficiency.This literature review summarizes the strategies that are used to solve the above-mentioned problems,whic...Boron has high mass and volume calorific values,but it is difficult to ignite and has low combustion efficiency.This literature review summarizes the strategies that are used to solve the above-mentioned problems,which include coatings of boron by using fluoride compounds,energetic composites,metal fuels,and metal oxides.Coating techniques include recrystallization,dual-solvent,phase transfer,electrospinning,etc.As one of the effective coating agents,the fluorine compounds can react with the oxide shell of boron powder.In comparison,the energetic composites can effectively improve the flame temperature of boron powder and enhance the evaporation efficiency of oxide film as a condensed product.Metals and metal oxides would react with boron powder to form metal borides with a lower ignition point,which could reduce its ignition temperature.展开更多
The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of...The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of micro/nano satellite.However,charring polymers alone need a relatively high input voltage to achieve pyrolysis and ignition,which increases the burden and cost of the power system of micro/nano satellite in practical application.Adding conductive substance into charring polymers can effectively decrease the conducting voltage which can realize low voltage and low power consumption repeated ignition of arc ignition system.In this paper,a charring conductive polymer ignition grain with a cavity geometry in precombustion chamber,which is composed of PLA and multiwall carbon nanotubes(MWCNT)was proposed.The detailed ignition processes were analyzed and two different ignition mechanisms in the cavity of charring conductive polymers were revealed.The ignition characteristics of charring conductive polymers were also investigated at different input voltages,ignition grain structures,ignition locations and injection schemes in a visual ignition combustor.The results demonstrated that the ignition delay and external energy required for ignition were inversely correlated with the voltages applied to ignition grain.Moreover,the incremental depth of cavity shortened the ignition delay and external energy required for ignition while accelerated the propagation of flame.As the depth of cavity increased from 2 to 6 mm(at 50 V),the time of flame propagating out of ignition grain changed from 235.6 to 108 ms,and values of mean ignition delay time and mean external energy required for ignition decreased from 462.8 to 320 ms and 16.2 to 10.75 J,respectively.The rear side of the cavity was the ideal ignition position which had a shorter ignition delay and a faster flame propagation speed in comparison to other ignition positions.Compared to direct injection scheme,swirling injection provided a more favorable flow field environment in the cavity,which was beneficial to ignition and initial flame propagation,but the ignition position needed to be away from the outlet of swirling injector.At last,the repeated ignition characteristic of charring conductive polymers was also investigated.The ignition delay time and external energy required for ignition decreased with repeated ignition times but the variation was decreasing gradually.展开更多
The Mg-Y-Zn magnesium alloy system is commonly recognized for its remarkable combination of high strength and ductility,achieved even with minimal amounts of alloying elements.This exceptional performance is attribute...The Mg-Y-Zn magnesium alloy system is commonly recognized for its remarkable combination of high strength and ductility,achieved even with minimal amounts of alloying elements.This exceptional performance is attributed to its unique microstructure,which includes Long-Period Stacking Ordered(LPSO)phases or the distinctive microstructure derived from the LPSO phase,referred to as the Mille-Feuille structure(MFS).This study systematically compares the traditional ingot metallurgy method with the rapid solidification technique,coupled with diverse heat treatments and extrusion processes.Microscopic analyses reveal variations in the presence of LPSO phases,Mille-Feuille structure,and grain size,leading to divergent mechanical and corrosion properties.The rapid solidification approach stands out,ensuring superior mechanical properties alongside a reasonable corrosion rate.展开更多
During air injection into an oil reservoir,an oxidation reaction generates some heat to raise the reservoir temperature.When the reservoir temperature reaches an ignition temperature,spontaneous ignition occurs.There ...During air injection into an oil reservoir,an oxidation reaction generates some heat to raise the reservoir temperature.When the reservoir temperature reaches an ignition temperature,spontaneous ignition occurs.There is a time delay from the injection to ignition.There are mixed results regarding the feasibility of spontaneous ignition in real-field projects and in laboratory experiments.No analytical model is available in the literature to estimate the oxidation time required to reach spontaneous ignition with heat loss.This paper discusses the feasibility of spontaneous ignition from theoretical points and experimental and field project observations.An analytical model considering heat loss is proposed.Analytical models with and without heat loss investigate the factors that affect spontaneous ignition.Based on the discussion and investigations,we find that it is more difficult for spontaneous ignition to occur in laboratory experiments than in oil reservoirs;spontaneous ignition is strongly affected by the initial reservoir temperature,oil activity,and heat loss;spontaneous ignition is only possible when the initial reservoir temperature is high,the oil oxidation rate is high,and the heat loss is low.展开更多
Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement m...Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement mechanism of RMFs on semiconductor bridge(SCB)during the ignition process is crucial for the engineering and practical application of advanced initiator and pyrotechnics devices.In this study,a one-dimensional(1D)gas-solid two-phase flow ignition model was established to study the ignition process of ESCB to charge particles based on the reactivity of Al/MoO_(3) RMFs.In order to fully consider the coupled exothermic between the RMFs and the SCB plasma during the ignition process,the heat release of chemical reaction in RMFs was used as an internal heat source in this model.It is found that the exothermal reaction in RMFs improved the ignition performance of SCB.In the process of plasma rapid condensation with heat release,the product of RMFs enhanced the heat transfer process between the gas phase and the solid charge particle,which accelerated the expansion of hot plasma,and heated the solid charge particle as well as gas phase region with low temperature.In addition,it made up for pressure loss in the gas phase.During the plasma dissipation process,the exothermal chemical reaction in RMFs acted as the main heating source to heat the charge particle,making the surface temperature of the charge particle,gas pressure,and gas temperature rise continuously.This result may yield significant advantages in providing a universal ignition model for miniaturized ignition devices.展开更多
Incorporating aluminum metal-organic frameworks(Al-MOFs)as energetic additives for solid fuels presents a promising avenue for enhancing combustion performance.This study explores the potential benefits of Al-MOF(MIL-...Incorporating aluminum metal-organic frameworks(Al-MOFs)as energetic additives for solid fuels presents a promising avenue for enhancing combustion performance.This study explores the potential benefits of Al-MOF(MIL-53(Al))energetic additive on the combustion performance of hydroxyl-terminated polybutadiene(HTPB)fuel.The HTPB-MOF fuel samples were manufactured using the vacuum-casting technique,followed by a comprehensive evaluation of their ignition and combustion properties using an opposed flow burner(OFB)setup utilizing gaseous oxygen as an oxidizer.To gauge the effectiveness of Al-MOFs as fuel additives,their impact is compared with that of nano-aluminum(nAl),another traditional additive in HTPB fuel.The results indicate that the addition of 15%(mass fraction)nAl into HTPB resulted in the shortest ignition delay time(136 ms),demonstrating improved ignition performance compared to pure HTPB(273 ms).The incorporation of Al-MOF in HTPB also reduced ignition delay times to 227 ms and 189 ms,respectively.Moreover,under high oxidizer mass flux conditions(79—81 kg/(m^(2)s)),HTPB fuel with 15%nAl exhibited a substantial 83.2%increase in regression rate compared to the baseline HTPB fuel,highlighting the positive influence of nAl on combustion behavior.In contrast,HTPB-MOF with a 15%Al-MOF additive showed a 32.7%increase in regression rate compared to pure HTPB.These results suggest that HTPB-nAl outperforms HTPB-MOF in terms of regression rates,indicating a more vigorous and rapid burning behavior.展开更多
Booming low-power electric propulsion systems require 1–2 A hollow cathodes.Such cathodes are expected to go through more frequent ignitions in the low orbit,but the impact of cyclic ignitions on such 1–2 A barium t...Booming low-power electric propulsion systems require 1–2 A hollow cathodes.Such cathodes are expected to go through more frequent ignitions in the low orbit,but the impact of cyclic ignitions on such 1–2 A barium tungsten hollow cathodes with a heater was not clear.In this study,a 12,638-cyclic ignition test and a 6,000-hour-long life test on two identical cathodes were carried out.The discharge voltage of the cathode and the erosion of the orifice after cyclic ignition were all larger than that of the cathode after stable operation.This indicated that the impact of cycle ignition on the discharge performance of a low current BaO-W cathode with a heater was higher than that of stable operation.The results of the ion energy distribution function measured during the ignition period indicated that the main reason for the orifice expansion was ion bombardment.Therefore,it was necessary to pay attention to the number of ignitions for the lifetime of this kind of cathode.展开更多
Understanding the response of solid combustibles under high radiant fluxes is critical in predicting the thermal damage from extreme scenarios.Unlike the more moderate radiant fluxes in conventional hydrocarbon fires,...Understanding the response of solid combustibles under high radiant fluxes is critical in predicting the thermal damage from extreme scenarios.Unlike the more moderate radiant fluxes in conventional hydrocarbon fires,extreme events such as strong explosion,concentrated sunlight and directed energy can generate dynamic radiant fluxes at the MW/m^(2) level,creating a unique threat to materials.This study investigates the pyrolysis and spontaneous ignition behaviors of corrugated cardboard by using both experimental and numerical methods,under 10-cm dynamic high radiant fluxes ranging from 0.2 to 1.25 MW/m^(2) for 10 s.The spontaneous ignition process at dynamic high radiant fluxes was recorded and quantified.Two ignition modes were found at the critical radiant flux of 0.4 MW/m^(2),namely hot-gas spontaneous ignition and hot-residue piloted ignition.The latter is not the focus of this paper due to its extremely small probability of occurrence.The research reveals that the increase in flux intensity induces shorter delay times for both pyrolysis and ignition,lower ignition energy density,along with a corresponding rise in the critical mass flux and surface temperature at ignition moment.The simulation results are generally aligned with the experimental findings,despite some divergences may be attributed to model simplifications and parameter assumptions.The work contributes to a deeper insight into material behavior under extreme radiation,with valuable implications for fire safety and hazard assessment.展开更多
5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and ...5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and safety risks.In this study,we have developed a simple and safe synthetic route for CL-18.It was synthesized from 3,5-dihaloanisole in a four-step reaction with an overall yield exceeding 60%,surpassing all reported yields in the literature.Subsequently,recrystallization of CL-18 was successfully achieved by carefully selecting appropriate solvents and antisolvents to reduce its mechanical sensitivity.Ultimately,when DMF-ethanol was employed as the recrystallization solvent system,satisfactory product yield(>90%)and reduced mechanical sensitivity(IS=15 J;FS=216 N)were obtained.Additionally,CL-18 is derived from the rearrangement of oxygen atoms on i-CL-18 furoxan,and a comparative analysis of their physicochemical properties was conducted.The thermal stability of both compounds is similar,with onset decomposition temperatures recorded at 186 and 182℃respectively.Similarly,they exhibit 5 s breaking point temperatures of 236 and 237℃.Additionally,we present novel insights into the positional-isomerization-laser-ignition performance of CL-18 and its isomer i-CL-18 using laser irradiation for the first time.Remarkably,our findings demonstrate that i-CL-18 exhibits enhanced laser sensitivity,as it can be directly ignited by a 1064 nm wavelength laser,whereas CL-18 lacks this characteristic.展开更多
Copper-based azide(Cu(N_(3))2 or CuN_(3),CA)chips synthesized by in-situ azide reaction and utilized in miniaturized explosive systems has become a hot research topic in recent years.However,the advantages of in-situ ...Copper-based azide(Cu(N_(3))2 or CuN_(3),CA)chips synthesized by in-situ azide reaction and utilized in miniaturized explosive systems has become a hot research topic in recent years.However,the advantages of in-situ synthesis method,including small size and low dosage,bring about difficulties in quantitative analysis and differences in ignition capabilities of CA chips.The aim of present work is to develop a simplified quantitative analysis method for accurate and safe analysis of components in CA chips to evaluate and investigate the corresponding ignition ability.In this work,Cu(N_(3))2 and CuN_(3)components in CA chips were separated through dissolution and distillation by utilizing the difference in solubility and corresponding content was obtained by measuring N_(3)-concentration through spectrophotometry.The spectrophotometry method was optimized by studying influencing factors and the recovery rate of different separation methods was studied,ensuring the accuracy and reproducibility of test results.The optimized method is linear in range from 1.0-25.0 mg/L,with a correlation coefficient R^(2)=0.9998,which meets the requirements of CA chips with a milligram-level content test.Compared with the existing ICP method,component analysis results of CA chips obtained by spectrophotometry are closer to real component content in samples and have satisfactory accuracy.Moreover,as its application in miniaturized explosive systems,the ignition ability of CA chips with different component contents for direct ink writing CL-20 and the corresponding mechanism was studied.This study provided a basis and idea for the design and performance evaluation of CA chips in miniaturized explosive systems.展开更多
Investigating the ignition response of nitrate ester plasticized polyether(NEPE) propellant under dynamic extrusion loading is of great significant at least for two cases. Firstly, it helps to understand the mechanism...Investigating the ignition response of nitrate ester plasticized polyether(NEPE) propellant under dynamic extrusion loading is of great significant at least for two cases. Firstly, it helps to understand the mechanism and conditions of unwanted ignition inside charged propellant under accident stimulus.Secondly, evaluates the risk of a shell crevice in a solid rocket motor(SRM) under a falling or overturning scene. In the present study, an innovative visual crevice extrusion experiment is designed using a dropweight apparatus. The dynamic responses of NEPE propellant during extrusion loading, including compaction and compression, rapid shear flow into the crevice, stress concentration, and ignition reaction, have been firstly observed using a high-performance high-speed camera. The ignition reaction is observed in the triangular region of the NEPE propellant sample above the crevice when the drop weight velocity was 1.90 m/s. Based on the user material subroutine interface UMAT provided by finite element software LS-DYNA, a viscoelastic-plastic model and dual ignition criterion related to plastic shear dissipation are developed and applied to the local ignition response analysis under crevice extrusion conditions. The stress concentration occurs in the crevice location of the propellant sample, the shear stress is relatively large, the effective plastic work is relatively large, and the ignition reaction is easy to occur. When the sample thickness decreases from 5 mm to 2.5 mm, the shear stress increases from 22.3 MPa to 28.6 MPa, the critical value of effective plastic work required for ignition is shortened from 1280 μs to 730 μs, and the triangular area is easily triggering an ignition reaction. The propellant sample with a small thickness is more likely to stress concentration, resulting in large shear stress and effective work, triggering an ignition reaction.展开更多
This review article provides overall understanding of stainless,environment-friendly,and nonflammable Mg alloys(SEN alloys)recently developed at the Korea Institute of Materials Science.SEN alloys are produced by addi...This review article provides overall understanding of stainless,environment-friendly,and nonflammable Mg alloys(SEN alloys)recently developed at the Korea Institute of Materials Science.SEN alloys are produced by adding small amounts of Ca and Y(each<1 wt%)into commercial Mg–Al based alloys,resulting in exceptional ignition and corrosion resistances and impressive mechanical properties.Their main advantages of SEN alloys are as follows.(1)A dense multi-oxide layer of SEN alloys comprising MgO,CaO,and Y_(2)O_(3) impedes the outward dispersion of Mg vapor and the inward penetration of O_(2) during oxidation,thereby enhancing the oxidation and ignition resistances.(2)The presence of Ca-and Y-based second-phase particles in SEN alloys can enhance their corrosion resistance because Ca-containing particles prevent the spread of corrosion,and the replacement of Al-containing particles with less noble ones containing Y(e.g.,Al–Mn–Y or Al–Y particles)retards corrosion.(3)The addition of minor amounts of Ca and Y renders excellent mechanical properties due to improved strengthening effects.These enhanced properties are attributed to more pronounced dynamic recrystallization and grain refining behaviors caused by the second-phase particles during extrusion.(4)Despite the presence of various types of second-phase particles,the fatigue properties of SEN9 alloys are similar to those of commercial AZ91 alloys.(5)Simultaneous introduction of Ca and Y suppresses the formation of Mg17Al12 discontinuous precipitates during aging,leading to the enhanced elongation of aged SEN alloys.(6)Adding mischmetal into the SEN9 alloy leads to a six-fold enhancement in extrudability.Consequently,the studies conducted on SEN alloys demonstrate their excellent ignition and corrosion resistances and mechanical properties,which broaden the industrial applications of Mg alloys by addressing their inherent weaknesses.展开更多
To enhance the catalytic activity of copper ferrite(CuFe_(2)O_(4))nanoparticle and promote its application as combustion catalyst,a low-cost silicon dioxide(SiO_(2))carrier was employed to construct a novel CuFe_(2)O_...To enhance the catalytic activity of copper ferrite(CuFe_(2)O_(4))nanoparticle and promote its application as combustion catalyst,a low-cost silicon dioxide(SiO_(2))carrier was employed to construct a novel CuFe_(2)O_(4)/SiO_(2)binary composites via solvothermal method.The phase structure,morphology and catalytic activity of CuFe_(2)O_(4)/SiO_(2)composites were studied firstly,and thermal decomposition,combustion and safety performance of ammonium perchlorate(AP)and 1,3,5-trinitroperhydro-1,3,5-triazine(RDX)with it affecting were then systematically analyzed.The results show that CuFe_(2)O_(4)/SiO_(2)composite can remarkably either advance the decomposition peak temperature of AP and RDX,or reduce the apparent activation energy at their main decomposition zone.Moreover,the flame propagation rate of RDX was promoted by about 2.73 times with SiO_(2)content of 3 wt%,and safety property of energetic component was also improved greatly,in which depressing the electrostatic discharge sensitivity of pure RDX by about 1.89 times.In addition,the effective range of SiO_(2)carrier content in the binary catalyst is found to be 3 to 5 wt%.Therefore,SiO_(2)opens a new insight on the design of combustion catalyst carrier and will promote the application of CuFe_(2)O_(4)catalyst in solid propellant.展开更多
A model for fast electron-driven high-density plasma is proposed to describe the effect of injected fast electrons on the temperature and inner pressure of the plasma in the fast heating process of the double-cone ign...A model for fast electron-driven high-density plasma is proposed to describe the effect of injected fast electrons on the temperature and inner pressure of the plasma in the fast heating process of the double-cone ignition(DCI)scheme.Due to the collision of the two low-density plasmas,the density and volume of the high-density plasma vary.Therefore,the ignition temperature and energy requirement of the high-density plasma vary at different moments,and the required energy for hot electrons to heat the plasma also changes.In practical experiments,the energy input of hot electrons needs to be considered.To reduce the energy input of hot electrons,the optimal moment and the shortest time for injecting hot electrons with minimum energy are analyzed.In this paper,it is proposed to inject hot electrons for a short time to heat the high-density plasma to a relatively high temperature.Then,the alpha particles with the high heating rate and PdV work heat the plasma to the ignition temperature,further reducing the energy required to inject hot electrons.The study of the injection time of fast electrons can reduce the energy requirement of fast electrons for the high-density plasma and increase the probability of successful ignition of the high-density plasma.展开更多
In the double-cone ignition schemes(DCIS), the deuterium–tritium target shell is ablated and compressed by a highpower nanosecond laser in Au-cones to generate plasmas. Under the actions of spherically symmetric comp...In the double-cone ignition schemes(DCIS), the deuterium–tritium target shell is ablated and compressed by a highpower nanosecond laser in Au-cones to generate plasmas. Under the actions of spherically symmetric compression and acceleration along the Au cone, they will be ejected out of the cone mouth and collide with each other. The plasmas experience conversion from kinetic energy to internal energy at the vertex of the geometric center of two Au cones that are symmetric to each other, because of which high-density fusion plasmas are preheated. This key physical process has undergone experimental verification on the Shenguang-II upgraded facility in China. Apparently, the improvement and optimization of the velocity of plasmas in hypersonic jet flow at the cone mouth are crucial for the success of the DCIS. In the DCIR7 experiment of the Shenguang-II upgraded facility, a velocity yield of approximately 130–260 km/s was achieved for the plasmas at the cone mouth, with a result of nearly 300 km/s based on numerical simulation. In this paper, theoretical analysis is performed as regards the process, in which target shells are ablated and compressed by laser to generate highvelocity plasmas ejected through jet flow. Based on this analysis, the formula for the velocity of plasmas in supersonic jet flow at the cone mouth is proposed. This study also provides measures that are more effective for improving the kinetic energy of plasmas and optimizing energy conversion efficiency, which can serve as theoretical references for the adjustment and optimization of processes in subsequent experiments.展开更多
文摘Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ignition mechanism of EFIs directly igniting pyrotechnics.An oscilloscope,a photon Doppler velocimetry,and a plasma spectrum measurement system were employed to obtain information of electric characteristics,impact pressure,and plasma temperature.The results of the electric characteristics and the impact pressure were inconsistent with ignition results.The only thing that the ignition success tests had in common was that their plasma all had a relatively long period of high-temperature duration(HTD).It eventually concludes that the ignition mechanism in this research is the microconvection heat transfer rather than the shock initiation,which differs from that of exploding foil initiators detonating explosives.Furthermore,the methods for evaluating the ignition success of semiconductor bridge initiators are not entirely applicable to the tests mentioned in this paper.The HTD is the critical parameter for judging the ignition success,and it is influenced by two factors:the late time discharge and the energy of the electric explosion.The longer time of the late time discharge and the more energy of the electric explosion,the easier it is to expand the HTD,which improves the probability of the ignition success.
基金the National Natural Science Foundation of China Grant numbers:71974167 and 71573225。
文摘Purpose:This article aims to determine the percentage of"Sparking"articles among the work of this year’s Nobel Prize winners in medicine,physics,and chemistry.Design/methodology/approach:We focus on under-cited influential research among the key publications as mentioned by the Nobel Prize Committee for the 2020 Noble Prize laureates.Specifically,we extracted data from the Web of Science,and calculated the Sparking Indices using the formulas as proposed by Hu and Rousseau in 2016 and 2017.In addition,we identified another type of igniting articles based on the notion in 2017.Findings:In the fields of medicine and physics,the proportions of articles with sparking characteristics share 78.571%and 68.75%respectively,yet,in chemistry 90%articles characterized by"igniting".Moreover,the two types of articles share more than 93%in the work of the Nobel Prize included in this study.Research limitations:Our research did not cover the impact of topic,socio-political,and author’s reputation on the Sparking Indices.Practical implications:Our study shows that the Sparking Indices truly reflect influence of the best research work,so it can be used to detect under-cited influential articles,as well as identifying fundamental work.Originality/value:Our findings suggest that the Sparking Indices have good applicability for research evaluation.
文摘How to directly fabricate metallic functional parts with selective laser sintering (SLS) process is a potential technique that scientists are researching. Existent problems during directly fabricating metal part by use of SLS are analyzed. For the sake of solving the problems, a new idea of adding self-propagating high-temperature synthesis (SHS) material into metallic powder material to form new type of SLS metallic powder material is put forward. This powder material can release controllable amount of heat during its interaction with the laser beam energy to reduce the requirement to laser power during directly sintering metallic part, to prolong the time of metallic liquid phase existing, and to improve the intensity and accuracy of SLS part. For this reason, SHS material′s interaction with the CO2 laser beam energy is researched, which proves that CO2 laser beam energy may instantly ignite SHS reaction. On the basis of the above-mentioned researches, the effect of sintering the metal powder material mixing SHS material with CO2 laser is also researched, which shows: there is an optimal blending ratio of various material in the new metallic powder material. Under the optimal blending ratio and SLS process parameters, this new metallic powder material can indeed release amount of heat and SHS reaction may be controlled within the laser sintering. This research result makes it possible that the metallic part is directly sintered with small CO2 laser (less than 50W), which may greatly reduce the volume, cost and running expenditure of SLS machine, be propitious to application.
文摘Ten million times more compact energy than from burning carbon can be obtained from nuclear fusion reactions corresponding to equilibrium temperature reactions in the range above 100 million degrees.Following the energy gain in stars,one has to gain nuclear energy from slamming very light nuclei where however the extremely high temperatures above 100 million degrees are needed for the sufficient pressures at thermal equilibrium ignition.A radically new option works with non-thermal pressures of picosecond laser pulses at ultrahigh optical powers by nonlinear forces of ponderomotion.The nuclear fusion of hydrogen with the isotope 11 of boron produces primarily harmless helium and has no problems with dangerous radioactive waste and excludes any catastrophic melt-down as fission reactors,it has the potential to be of low costs and can supply the Earth for more than 10,000 years with electricity.
基金This research was supported by the National Natural Science Foundation of China(Grant No.:U2033206)China Postdoctoral Science Foundation(Grant No.2021M691705).
文摘Hot molten metal droplets with high fire hazard can easily ignite combustibles. Molten metal kinetics on the surface of a combustible material directly affects the ignition likelihood. Existing research focuses on the behavior of droplets during collisions, rarely addressing the ignition of combustibles by hot metal droplets. Here, the mechanisms of aluminum and copper droplets impinging on and igniting extended polystyrene (EPS) foam boards at different velocities were investigated. The relationship between the critical ignition temperature and impact velocity of droplets with diameters of 6 and 8 mm was experimentally studied for aluminum droplets;the critical ignition temperature non-monotonically depended on the impact velocity. For copper droplets, the relationship between the ignition probability and the impact velocity of droplets with diameters in the 3.5–7 mm range was experimentally studied. The most obvious difference between the two droplet ignition types was that the impact of copper droplets was accompanied by intense splashing, and the fragmentation extent positively correlated with the impact velocity. It was challenging to ignite using completely broken copper droplets. Droplets with the diameter of 5 mm were the most dangerous under the experimental conditions of this study, because the foam could still be ignited at higher impact velocities. Numerical simulations suggested that the main factors explaining the critical ignition temperature of aluminum droplets were gas mixing and splat cooling. The main factor affecting the ignition of copper droplets was fragmentation, and experimental observations were explained using non-dimensional droplet fragmentation theories.
基金funded by Shaanxi Provincial Key Research and Development Program of China(Grant No.2021ZDLGY11)partially supported by NSAF Project of China(Grant No.U2030202)。
文摘Boron has high mass and volume calorific values,but it is difficult to ignite and has low combustion efficiency.This literature review summarizes the strategies that are used to solve the above-mentioned problems,which include coatings of boron by using fluoride compounds,energetic composites,metal fuels,and metal oxides.Coating techniques include recrystallization,dual-solvent,phase transfer,electrospinning,etc.As one of the effective coating agents,the fluorine compounds can react with the oxide shell of boron powder.In comparison,the energetic composites can effectively improve the flame temperature of boron powder and enhance the evaporation efficiency of oxide film as a condensed product.Metals and metal oxides would react with boron powder to form metal borides with a lower ignition point,which could reduce its ignition temperature.
基金the Fundamental Research Funds for the Central Universities(Grant No.30920041102)National Natural Science Foundation of China(Grant No.11802134).
文摘The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of micro/nano satellite.However,charring polymers alone need a relatively high input voltage to achieve pyrolysis and ignition,which increases the burden and cost of the power system of micro/nano satellite in practical application.Adding conductive substance into charring polymers can effectively decrease the conducting voltage which can realize low voltage and low power consumption repeated ignition of arc ignition system.In this paper,a charring conductive polymer ignition grain with a cavity geometry in precombustion chamber,which is composed of PLA and multiwall carbon nanotubes(MWCNT)was proposed.The detailed ignition processes were analyzed and two different ignition mechanisms in the cavity of charring conductive polymers were revealed.The ignition characteristics of charring conductive polymers were also investigated at different input voltages,ignition grain structures,ignition locations and injection schemes in a visual ignition combustor.The results demonstrated that the ignition delay and external energy required for ignition were inversely correlated with the voltages applied to ignition grain.Moreover,the incremental depth of cavity shortened the ignition delay and external energy required for ignition while accelerated the propagation of flame.As the depth of cavity increased from 2 to 6 mm(at 50 V),the time of flame propagating out of ignition grain changed from 235.6 to 108 ms,and values of mean ignition delay time and mean external energy required for ignition decreased from 462.8 to 320 ms and 16.2 to 10.75 J,respectively.The rear side of the cavity was the ideal ignition position which had a shorter ignition delay and a faster flame propagation speed in comparison to other ignition positions.Compared to direct injection scheme,swirling injection provided a more favorable flow field environment in the cavity,which was beneficial to ignition and initial flame propagation,but the ignition position needed to be away from the outlet of swirling injector.At last,the repeated ignition characteristic of charring conductive polymers was also investigated.The ignition delay time and external energy required for ignition decreased with repeated ignition times but the variation was decreasing gradually.
基金supported by Japan Society for the Promotion of Science(KAKENHI Grant-in-Aid for Scientific Research18H05475,18H05476 and JP20H00312)+2 种基金MRC International Collaborative Research Grant.The authors would like to thank the Czech Science Foundation(Project No.22-22248S)specific university research(A1_FCHT_2024_007)for financial supportthe assistance provided by the Ferroic Multifunctionalities project,supported by the Ministry of Education,Youth,and Sports of the Czech Republic.Project No.CZ.02.01.01/00/22_008/0004591,co-funded by the European Union.CzechNanoLab project LM2023051 funded by MEYS CR is gratefully acknowledged for the financial support of the measurements/sample fabrication at LNSM Research Infrastructure.
文摘The Mg-Y-Zn magnesium alloy system is commonly recognized for its remarkable combination of high strength and ductility,achieved even with minimal amounts of alloying elements.This exceptional performance is attributed to its unique microstructure,which includes Long-Period Stacking Ordered(LPSO)phases or the distinctive microstructure derived from the LPSO phase,referred to as the Mille-Feuille structure(MFS).This study systematically compares the traditional ingot metallurgy method with the rapid solidification technique,coupled with diverse heat treatments and extrusion processes.Microscopic analyses reveal variations in the presence of LPSO phases,Mille-Feuille structure,and grain size,leading to divergent mechanical and corrosion properties.The rapid solidification approach stands out,ensuring superior mechanical properties alongside a reasonable corrosion rate.
基金supported by the National Natural Science Foundation of China (No.51974334)Hainan Province Science and Technology Special Fund (ZDYF2022SHFZ107)local efficient reform and development funds for personnel training projects supported by the central government,Heilongjiang Postdoctoral Scientific Research Fund (LBH-Q21012)。
文摘During air injection into an oil reservoir,an oxidation reaction generates some heat to raise the reservoir temperature.When the reservoir temperature reaches an ignition temperature,spontaneous ignition occurs.There is a time delay from the injection to ignition.There are mixed results regarding the feasibility of spontaneous ignition in real-field projects and in laboratory experiments.No analytical model is available in the literature to estimate the oxidation time required to reach spontaneous ignition with heat loss.This paper discusses the feasibility of spontaneous ignition from theoretical points and experimental and field project observations.An analytical model considering heat loss is proposed.Analytical models with and without heat loss investigate the factors that affect spontaneous ignition.Based on the discussion and investigations,we find that it is more difficult for spontaneous ignition to occur in laboratory experiments than in oil reservoirs;spontaneous ignition is strongly affected by the initial reservoir temperature,oil activity,and heat loss;spontaneous ignition is only possible when the initial reservoir temperature is high,the oil oxidation rate is high,and the heat loss is low.
基金supported by the National Natural Science Foundation of China(Grant Nos.22275092,52102107 and 52372084)the Fundamental Research Funds for the Central Universities(Grant No.30923010920)。
文摘Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement mechanism of RMFs on semiconductor bridge(SCB)during the ignition process is crucial for the engineering and practical application of advanced initiator and pyrotechnics devices.In this study,a one-dimensional(1D)gas-solid two-phase flow ignition model was established to study the ignition process of ESCB to charge particles based on the reactivity of Al/MoO_(3) RMFs.In order to fully consider the coupled exothermic between the RMFs and the SCB plasma during the ignition process,the heat release of chemical reaction in RMFs was used as an internal heat source in this model.It is found that the exothermal reaction in RMFs improved the ignition performance of SCB.In the process of plasma rapid condensation with heat release,the product of RMFs enhanced the heat transfer process between the gas phase and the solid charge particle,which accelerated the expansion of hot plasma,and heated the solid charge particle as well as gas phase region with low temperature.In addition,it made up for pressure loss in the gas phase.During the plasma dissipation process,the exothermal chemical reaction in RMFs acted as the main heating source to heat the charge particle,making the surface temperature of the charge particle,gas pressure,and gas temperature rise continuously.This result may yield significant advantages in providing a universal ignition model for miniaturized ignition devices.
文摘Incorporating aluminum metal-organic frameworks(Al-MOFs)as energetic additives for solid fuels presents a promising avenue for enhancing combustion performance.This study explores the potential benefits of Al-MOF(MIL-53(Al))energetic additive on the combustion performance of hydroxyl-terminated polybutadiene(HTPB)fuel.The HTPB-MOF fuel samples were manufactured using the vacuum-casting technique,followed by a comprehensive evaluation of their ignition and combustion properties using an opposed flow burner(OFB)setup utilizing gaseous oxygen as an oxidizer.To gauge the effectiveness of Al-MOFs as fuel additives,their impact is compared with that of nano-aluminum(nAl),another traditional additive in HTPB fuel.The results indicate that the addition of 15%(mass fraction)nAl into HTPB resulted in the shortest ignition delay time(136 ms),demonstrating improved ignition performance compared to pure HTPB(273 ms).The incorporation of Al-MOF in HTPB also reduced ignition delay times to 227 ms and 189 ms,respectively.Moreover,under high oxidizer mass flux conditions(79—81 kg/(m^(2)s)),HTPB fuel with 15%nAl exhibited a substantial 83.2%increase in regression rate compared to the baseline HTPB fuel,highlighting the positive influence of nAl on combustion behavior.In contrast,HTPB-MOF with a 15%Al-MOF additive showed a 32.7%increase in regression rate compared to pure HTPB.These results suggest that HTPB-nAl outperforms HTPB-MOF in terms of regression rates,indicating a more vigorous and rapid burning behavior.
基金supported by the Key Projects of Schoolenterprise Joint Fund(No.U22B20120)the National Science Fund for Distinguished Young Scholars(No.52107141)。
文摘Booming low-power electric propulsion systems require 1–2 A hollow cathodes.Such cathodes are expected to go through more frequent ignitions in the low orbit,but the impact of cyclic ignitions on such 1–2 A barium tungsten hollow cathodes with a heater was not clear.In this study,a 12,638-cyclic ignition test and a 6,000-hour-long life test on two identical cathodes were carried out.The discharge voltage of the cathode and the erosion of the orifice after cyclic ignition were all larger than that of the cathode after stable operation.This indicated that the impact of cycle ignition on the discharge performance of a low current BaO-W cathode with a heater was higher than that of stable operation.The results of the ion energy distribution function measured during the ignition period indicated that the main reason for the orifice expansion was ion bombardment.Therefore,it was necessary to pay attention to the number of ignitions for the lifetime of this kind of cathode.
基金the Presidential Foundation of CAEP(Grant No.YZJJZQ2023008)the National Natural Science Foundation of China(Grant No.NSFC 12372342)for financial support of this work.
文摘Understanding the response of solid combustibles under high radiant fluxes is critical in predicting the thermal damage from extreme scenarios.Unlike the more moderate radiant fluxes in conventional hydrocarbon fires,extreme events such as strong explosion,concentrated sunlight and directed energy can generate dynamic radiant fluxes at the MW/m^(2) level,creating a unique threat to materials.This study investigates the pyrolysis and spontaneous ignition behaviors of corrugated cardboard by using both experimental and numerical methods,under 10-cm dynamic high radiant fluxes ranging from 0.2 to 1.25 MW/m^(2) for 10 s.The spontaneous ignition process at dynamic high radiant fluxes was recorded and quantified.Two ignition modes were found at the critical radiant flux of 0.4 MW/m^(2),namely hot-gas spontaneous ignition and hot-residue piloted ignition.The latter is not the focus of this paper due to its extremely small probability of occurrence.The research reveals that the increase in flux intensity induces shorter delay times for both pyrolysis and ignition,lower ignition energy density,along with a corresponding rise in the critical mass flux and surface temperature at ignition moment.The simulation results are generally aligned with the experimental findings,despite some divergences may be attributed to model simplifications and parameter assumptions.The work contributes to a deeper insight into material behavior under extreme radiation,with valuable implications for fire safety and hazard assessment.
基金support from the National Natural Science Foundation of China(Grant No.22175160)the Science Challenge Project(Grant No.TZ2018004)。
文摘5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and safety risks.In this study,we have developed a simple and safe synthetic route for CL-18.It was synthesized from 3,5-dihaloanisole in a four-step reaction with an overall yield exceeding 60%,surpassing all reported yields in the literature.Subsequently,recrystallization of CL-18 was successfully achieved by carefully selecting appropriate solvents and antisolvents to reduce its mechanical sensitivity.Ultimately,when DMF-ethanol was employed as the recrystallization solvent system,satisfactory product yield(>90%)and reduced mechanical sensitivity(IS=15 J;FS=216 N)were obtained.Additionally,CL-18 is derived from the rearrangement of oxygen atoms on i-CL-18 furoxan,and a comparative analysis of their physicochemical properties was conducted.The thermal stability of both compounds is similar,with onset decomposition temperatures recorded at 186 and 182℃respectively.Similarly,they exhibit 5 s breaking point temperatures of 236 and 237℃.Additionally,we present novel insights into the positional-isomerization-laser-ignition performance of CL-18 and its isomer i-CL-18 using laser irradiation for the first time.Remarkably,our findings demonstrate that i-CL-18 exhibits enhanced laser sensitivity,as it can be directly ignited by a 1064 nm wavelength laser,whereas CL-18 lacks this characteristic.
基金the financial support provided by the National Natural Science Foundation of China(Grant No.11872013).
文摘Copper-based azide(Cu(N_(3))2 or CuN_(3),CA)chips synthesized by in-situ azide reaction and utilized in miniaturized explosive systems has become a hot research topic in recent years.However,the advantages of in-situ synthesis method,including small size and low dosage,bring about difficulties in quantitative analysis and differences in ignition capabilities of CA chips.The aim of present work is to develop a simplified quantitative analysis method for accurate and safe analysis of components in CA chips to evaluate and investigate the corresponding ignition ability.In this work,Cu(N_(3))2 and CuN_(3)components in CA chips were separated through dissolution and distillation by utilizing the difference in solubility and corresponding content was obtained by measuring N_(3)-concentration through spectrophotometry.The spectrophotometry method was optimized by studying influencing factors and the recovery rate of different separation methods was studied,ensuring the accuracy and reproducibility of test results.The optimized method is linear in range from 1.0-25.0 mg/L,with a correlation coefficient R^(2)=0.9998,which meets the requirements of CA chips with a milligram-level content test.Compared with the existing ICP method,component analysis results of CA chips obtained by spectrophotometry are closer to real component content in samples and have satisfactory accuracy.Moreover,as its application in miniaturized explosive systems,the ignition ability of CA chips with different component contents for direct ink writing CL-20 and the corresponding mechanism was studied.This study provided a basis and idea for the design and performance evaluation of CA chips in miniaturized explosive systems.
基金National Natural Science Foundation of China(U22B20131)State Key Laboratory of Explosion Science and Technology(QNKT23-10)for supporting this project.
文摘Investigating the ignition response of nitrate ester plasticized polyether(NEPE) propellant under dynamic extrusion loading is of great significant at least for two cases. Firstly, it helps to understand the mechanism and conditions of unwanted ignition inside charged propellant under accident stimulus.Secondly, evaluates the risk of a shell crevice in a solid rocket motor(SRM) under a falling or overturning scene. In the present study, an innovative visual crevice extrusion experiment is designed using a dropweight apparatus. The dynamic responses of NEPE propellant during extrusion loading, including compaction and compression, rapid shear flow into the crevice, stress concentration, and ignition reaction, have been firstly observed using a high-performance high-speed camera. The ignition reaction is observed in the triangular region of the NEPE propellant sample above the crevice when the drop weight velocity was 1.90 m/s. Based on the user material subroutine interface UMAT provided by finite element software LS-DYNA, a viscoelastic-plastic model and dual ignition criterion related to plastic shear dissipation are developed and applied to the local ignition response analysis under crevice extrusion conditions. The stress concentration occurs in the crevice location of the propellant sample, the shear stress is relatively large, the effective plastic work is relatively large, and the ignition reaction is easy to occur. When the sample thickness decreases from 5 mm to 2.5 mm, the shear stress increases from 22.3 MPa to 28.6 MPa, the critical value of effective plastic work required for ignition is shortened from 1280 μs to 730 μs, and the triangular area is easily triggering an ignition reaction. The propellant sample with a small thickness is more likely to stress concentration, resulting in large shear stress and effective work, triggering an ignition reaction.
基金supported by the Materials and Components Technology Development Program(No.20024843)funded by the Ministry of Trade,Industry&Energy(MOTIE,South Korea)by the National Research Council of Science&Technology(NST)grant(No.CRC23011-000)funded by the Korea government(MSIT).
文摘This review article provides overall understanding of stainless,environment-friendly,and nonflammable Mg alloys(SEN alloys)recently developed at the Korea Institute of Materials Science.SEN alloys are produced by adding small amounts of Ca and Y(each<1 wt%)into commercial Mg–Al based alloys,resulting in exceptional ignition and corrosion resistances and impressive mechanical properties.Their main advantages of SEN alloys are as follows.(1)A dense multi-oxide layer of SEN alloys comprising MgO,CaO,and Y_(2)O_(3) impedes the outward dispersion of Mg vapor and the inward penetration of O_(2) during oxidation,thereby enhancing the oxidation and ignition resistances.(2)The presence of Ca-and Y-based second-phase particles in SEN alloys can enhance their corrosion resistance because Ca-containing particles prevent the spread of corrosion,and the replacement of Al-containing particles with less noble ones containing Y(e.g.,Al–Mn–Y or Al–Y particles)retards corrosion.(3)The addition of minor amounts of Ca and Y renders excellent mechanical properties due to improved strengthening effects.These enhanced properties are attributed to more pronounced dynamic recrystallization and grain refining behaviors caused by the second-phase particles during extrusion.(4)Despite the presence of various types of second-phase particles,the fatigue properties of SEN9 alloys are similar to those of commercial AZ91 alloys.(5)Simultaneous introduction of Ca and Y suppresses the formation of Mg17Al12 discontinuous precipitates during aging,leading to the enhanced elongation of aged SEN alloys.(6)Adding mischmetal into the SEN9 alloy leads to a six-fold enhancement in extrudability.Consequently,the studies conducted on SEN alloys demonstrate their excellent ignition and corrosion resistances and mechanical properties,which broaden the industrial applications of Mg alloys by addressing their inherent weaknesses.
基金the National Nature Science Foundation of China(Grant Nos.21673178,22105160)the Natural Science Foundation of Shaanxi Province(Grant No.2023-JC-ZD-07)+1 种基金the Foundation of Key Laboratory of Defense Science and technology(Grant No.6142603032213)the Key Science and Technology Innovation Team of Shaanxi Province(Grant No.2022TD-33).
文摘To enhance the catalytic activity of copper ferrite(CuFe_(2)O_(4))nanoparticle and promote its application as combustion catalyst,a low-cost silicon dioxide(SiO_(2))carrier was employed to construct a novel CuFe_(2)O_(4)/SiO_(2)binary composites via solvothermal method.The phase structure,morphology and catalytic activity of CuFe_(2)O_(4)/SiO_(2)composites were studied firstly,and thermal decomposition,combustion and safety performance of ammonium perchlorate(AP)and 1,3,5-trinitroperhydro-1,3,5-triazine(RDX)with it affecting were then systematically analyzed.The results show that CuFe_(2)O_(4)/SiO_(2)composite can remarkably either advance the decomposition peak temperature of AP and RDX,or reduce the apparent activation energy at their main decomposition zone.Moreover,the flame propagation rate of RDX was promoted by about 2.73 times with SiO_(2)content of 3 wt%,and safety property of energetic component was also improved greatly,in which depressing the electrostatic discharge sensitivity of pure RDX by about 1.89 times.In addition,the effective range of SiO_(2)carrier content in the binary catalyst is found to be 3 to 5 wt%.Therefore,SiO_(2)opens a new insight on the design of combustion catalyst carrier and will promote the application of CuFe_(2)O_(4)catalyst in solid propellant.
基金Project supported by the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDA_(2)5051000)the National Key R&D Program of China(Grant No.2023YFA1608400)+1 种基金the National Natural Science Foundation of China(Grant No.12005008)the Natural Science Foundation of Top Talent of SZTU(Grant No.GDRC202209).
文摘A model for fast electron-driven high-density plasma is proposed to describe the effect of injected fast electrons on the temperature and inner pressure of the plasma in the fast heating process of the double-cone ignition(DCI)scheme.Due to the collision of the two low-density plasmas,the density and volume of the high-density plasma vary.Therefore,the ignition temperature and energy requirement of the high-density plasma vary at different moments,and the required energy for hot electrons to heat the plasma also changes.In practical experiments,the energy input of hot electrons needs to be considered.To reduce the energy input of hot electrons,the optimal moment and the shortest time for injecting hot electrons with minimum energy are analyzed.In this paper,it is proposed to inject hot electrons for a short time to heat the high-density plasma to a relatively high temperature.Then,the alpha particles with the high heating rate and PdV work heat the plasma to the ignition temperature,further reducing the energy required to inject hot electrons.The study of the injection time of fast electrons can reduce the energy requirement of fast electrons for the high-density plasma and increase the probability of successful ignition of the high-density plasma.
基金Project supported by the Strategic Priority Research Program of Chinese Academy of Sciences (Grant Nos. XDA25051000 and XDA 25010100)。
文摘In the double-cone ignition schemes(DCIS), the deuterium–tritium target shell is ablated and compressed by a highpower nanosecond laser in Au-cones to generate plasmas. Under the actions of spherically symmetric compression and acceleration along the Au cone, they will be ejected out of the cone mouth and collide with each other. The plasmas experience conversion from kinetic energy to internal energy at the vertex of the geometric center of two Au cones that are symmetric to each other, because of which high-density fusion plasmas are preheated. This key physical process has undergone experimental verification on the Shenguang-II upgraded facility in China. Apparently, the improvement and optimization of the velocity of plasmas in hypersonic jet flow at the cone mouth are crucial for the success of the DCIS. In the DCIR7 experiment of the Shenguang-II upgraded facility, a velocity yield of approximately 130–260 km/s was achieved for the plasmas at the cone mouth, with a result of nearly 300 km/s based on numerical simulation. In this paper, theoretical analysis is performed as regards the process, in which target shells are ablated and compressed by laser to generate highvelocity plasmas ejected through jet flow. Based on this analysis, the formula for the velocity of plasmas in supersonic jet flow at the cone mouth is proposed. This study also provides measures that are more effective for improving the kinetic energy of plasmas and optimizing energy conversion efficiency, which can serve as theoretical references for the adjustment and optimization of processes in subsequent experiments.