The Cenozoic Himalayan leucogranite-pegmatite belt has been a hotspot for rare metal exploration in recent years.To determine the genesis of the pegmatite in the Himalayan region and its relationship with the Greater ...The Cenozoic Himalayan leucogranite-pegmatite belt has been a hotspot for rare metal exploration in recent years.To determine the genesis of the pegmatite in the Himalayan region and its relationship with the Greater Himalayan Crystalline Complex(GHC),the Gyirong pegmatite in southern Tibet was chosen for geochronological and geochemical studies.The dating analyses indicate that the U-Th-Pb ages of zircon,monazite,and xenotime exhibit large variations(38.6‒16.1 Ma),with the weighted average value of the four youngest points is 16.5±0.3 Ma,which indicates that the final stage of crystallization of the melt occurred in the Miocene.The age of the muscovite Ar-Ar inverse isochron is 15.2±0.4 Ma,which is slightly later than the intrusion age,showing that a cooling process associated with rapid denudation occurred at 16‒15 Ma.TheεHf(t)values of the Cenozoic anatectic zircons cluster between−12 and−9 with an average of−11.4.The Gyirong pegmatite shows high contents of Si,Al,and K,a high Al saturation index,and low contents of Na,Ca,Fe,Mn,P,Mg,and Ti.Overall,the Gyirong pegmatite is enriched in Rb,Cs,U,K,Th and Pb and depleted in Nb,Ta,Zr,Ti,Eu,Sr,and Ba.The samples show a high 87Sr/86Sr(16 Ma)ratio of ca.0.762 and a lowεNd(16 Ma)value of−16.0.The calculated average initial values of 208Pb/204Pb(16 Ma),207Pb/204Pb(16 Ma)and 206Pb/204Pb(16 Ma)of the whole rock are 39.72,15.79 and 19.56,respectively.The Sr-Nd-Pb-Hf isotopic characteristics of the Gyirong pegmatite are consistent with those of the GHC.This study concludes that the Gyirong pegmatite represents a typical crustal‒derived anatectic pegmatite with low metallogenic potential for rare metals.The Gyirong pegmatite records the long‒term metamorphism and partial melting process of the GHC,and reflects the crustal thickening caused by thrust compression at 39‒29 Ma and the crustal thinning induced by extensional decompression during 28‒15 Ma.展开更多
Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the C...Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the Cenozoic extrusive and intrusive rocks in the Yao’an area,western Yunnan Province,SW China,are geochemically shoshonitic,collectively termed here the Yao’an Shoshonitic Complex(YSC).The YSC is located in the(south)easternmost part of the ENE-WSW-trending,~550 km-long and~250 km-wide Cenozoic magmatic zone;the latter separates the orthogonal and oblique collision belts of the India-Eurasia collision orogen.Previously published geochronological and thermochronological data revealed that the rocks of the YSC were emplaced over a short timespan of 34-32 Ma.This and our new data suggest that the primary magma of the YSC likely was formed by partial melting of ancient continental lithospheric mantle beneath the Yangtze Block.This part of the continental lithospheric mantle had likely not been modified by any oceanic subduction.Fractionation crystallization of an Mg-and Ca-bearing mineral and TiFe oxides during the magmatic evolution probably account for the variable lithologies of the YSC.展开更多
In order to constrain the crustal wave velocity structure in the southernTibetan crust and provide insight into the contribution of crustal composition, geothermal gradientand partial melting to the velocity structure...In order to constrain the crustal wave velocity structure in the southernTibetan crust and provide insight into the contribution of crustal composition, geothermal gradientand partial melting to the velocity structure, which is characterized by low average crustalvelocities and widespread presence of low-velocity zone(s), the authors model the crustal velocityand density as functions of depth corresponding to various heat flow values in light of velocitymeasurements at high temperature and high pressure. The modeled velocity and density are regarded ascomparison standards. The comparison of the standards with seismic observations in southern Tibetimplies that the predominantly felsic composition at high heat flow cannot explain the observedvelocity structure there. Hence, the authors are in favor of attributing low average crustalvelocities and low-velocity zone(s) observed in southern Tibet mainly to partial melting. Modelingbased on the experimental results suggests that a melting percentage of 7-12 could account for thelow-velocity zone(s).展开更多
Study practice has proved that the ultrahigh pressure metamorphic rocks iu Dabieshan must have exPerienced botk the retrograde metumorphism and partial melting under decompression and amphibolite-facies conditions dur...Study practice has proved that the ultrahigh pressure metamorphic rocks iu Dabieshan must have exPerienced botk the retrograde metumorphism and partial melting under decompression and amphibolite-facies conditions during their exhumation from mantel depth to lower-middle crust.The retrometamorphism and partial melting of the ultrahigh pressure rocks in association with thermal state changing in the middle-lower crust, under amphibolite-facies conditions, are important physical and chemical processes. It would result in a great detrease in the integrated yield strength, and the enhancement of the de formabilitY or the rocks, promoting the transition from contractional (collision) to extensional defoemational regime. The statement of tbe retrometamorphism and partial melting of the ultrahigh pressure rocks has proved the in-site model for the ultrahigh pressure rocks in Dabieshan. It not only clarifies the evolutiou from the UHP eclogite to the surrounding gneissic rock (so called UHP gueiss) and to the garnet-beariug roliated granites (non-UHP country rocks), but also provides scientific arguments for the establiskment of the dynamic model of the exhumation of UHP metamorphic rocks in Dabiesban. In general, Purely conductive heat transfer from the crust itself is probably insurficient to produce temperature conditions for partial melting, and additional heat sources must have been present during partial melting. We infer that the partial melting and extensional flow are probably driveu by delamination and magmatic underplating of thickeued lithospkeric mantle following the continental oblique collision.展开更多
Ultrahigh-pressure(UHP) metamorphic rocks are distinctive products of crustal deep subduction,and are mainly exposed in continental subduction-collision terranes. UHP slices of continental crust are usually involved...Ultrahigh-pressure(UHP) metamorphic rocks are distinctive products of crustal deep subduction,and are mainly exposed in continental subduction-collision terranes. UHP slices of continental crust are usually involved in multistage exhumation and partial melting, which has obvious influence on the rheological features of the rocks, and thus significantly affect the dynamic behavior of subducted slices. Moreover,partial melting of UHP rocks have significant influence on element mobility and related isotope behavior within continental subduction zones, which is in turn crucial to chemical differentiation of the continental crust and to crust-mantle interaction.Partial melting can occur before, during or after the peak metamorphism of UHP rocks. Post-peak decompression melting has been better constrained by remelting experiments; however, because of multiple stages of decompression, retrogression and deformation, evidence of former melts in UHP rocks is often erased. Field evidence is among the most reliable criteria to infer partial melting. Glass and nanogranitoid inclusions are generally considered conclusive petrographic evidence. The residual assemblages after melt extraction are also significant to indicate partial melting in some cases. Besides field and petrographic evidence, bulk-rock and zircon trace-element geochemical features are also effective tools for recognizing partial melting of UHP rocks. Phase equilibrium modeling is an important petrological tool that is becoming more and more popular in P-T estimation of the evolution of metamorphic rocks; by taking into account the activity model of silicate melt, it can predict when partial melting occurred if the P-T path of a given rock is provided.UHP silicate melt is commonly leucogranitic and peraluminous in composition with high SiO_2,low MgO, FeO, MnO, TiO_2 and CaO, and variable K_2 O and Na_2 O contents. Mineralogy of nanogranites found in UHP rocks mainly consists of plagioclase + K-feldspar + quartz, plagioclase being commonly albite-rich.Trace element pattern of the melt is characterized by significant enrichment of large ion lithophile elements(LILE), depletion of heavy rare earth elements(HREE) and high field strength elements(HFSE),indicating garnet and rutile stability in the residual assemblage. In eclogites, significant Mg-isotope fractionation occurs between garnet and phengite; therefore, Mg isotopes may become an effective indicator for partial melting of eclogites.展开更多
Objective Previous studies on adakitic rocks with high Sr/Y and La/Yb ratios have established that such rocks may form in a variety of tectonic settings through different petrogenetic processes including: (1) parti...Objective Previous studies on adakitic rocks with high Sr/Y and La/Yb ratios have established that such rocks may form in a variety of tectonic settings through different petrogenetic processes including: (1) partial melting of subducted young (〈25 Ma), hot and hydrated oceanic slab; (2) partial melting of thickened lower crust; (3) assimilation and fractional crystallization processes involving basaltic magma; (4) partial melting of delaminated lower crust; and (5) partial melting of hydrous garnet peridotite. The various origins for adakites provide important constraints on crustal growth and evolution throughout the Earth's history.展开更多
Phase equilibria modelling coupled with U–Pb zircon and monazite ages of garnet–cordierite gneiss from Vallikodu Kottayam in the Kerala Khondalite Belt,southern India are presented here.The results suggest that the ...Phase equilibria modelling coupled with U–Pb zircon and monazite ages of garnet–cordierite gneiss from Vallikodu Kottayam in the Kerala Khondalite Belt,southern India are presented here.The results suggest that the area attained peak P–T conditions of^900C at 7.5–8 kbar,followed by decompression to 3.5–5 kbar and cooling to 450–480C,preserving signatures of the partial melting event in the field of high to ultra-high temperature metamorphism.Melt reintegration models suggest that up to 35%granitic melt could have been produced during metamorphism at^950C.The U–Pb age data from zircons(~1.0–~0.7 Ga)and chemical ages from monazites(~540 Ma and^941 Ma)reflect a complex tectonometamorphic evolution of the terrain.The^941 Ma age reported from these monazites indicate a Tonian ultra-high temperature event,linked to juvenile magmatism/deformation episodes reported from the Southern Granulite Terrane and associated fragments in Rodinia,which were subsequently overprinted by the Cambrian(~540 Ma)tectonothermal episode.展开更多
Studies of the mantle-derived iherzolites from Nushan show that in addition to CO2,there were present H2O and small amounts of CO, CH4, SO2,Cl and F in the initial mantlc fluids derived fron the asthenospheric mantlc ...Studies of the mantle-derived iherzolites from Nushan show that in addition to CO2,there were present H2O and small amounts of CO, CH4, SO2,Cl and F in the initial mantlc fluids derived fron the asthenospheric mantlc plumc .The imitial fluids accumulated in some regions of the mantle, resulting in lowering of the mantle solidus (and liquidus) and partial melting of the upper mantle. Melts formed from low-degree of fluid-involved partial melting of the upper mantle would be highly enriched in incompatible elements.Fluies and melts are allthe metasomatic agents for mantle metasomatism, and the interaction between them and the depleted mantle could result in the substan-tial local enrichment of LREE and incompatible elements in the latter.In case that the concentration of H2O in the fluids (and melts) is lower ,only cryptic metasomatism would occur, in case that the concentration of H2O is higher,the degree of partial melting would be higher and hydrous metasomatic phases(e.g. amphiboles )would nucleate. Under such circumstances, there would occur model metasomatism.展开更多
Experiments on partial melting of mantle lherzolite have been realized at 0.6 and 1.0 GPa and the chemical compositional variations of melts during different melting stages have been first discussed. The results show ...Experiments on partial melting of mantle lherzolite have been realized at 0.6 and 1.0 GPa and the chemical compositional variations of melts during different melting stages have been first discussed. The results show that the trends of variations in SiO2, CaO, Al2O3, Na2O and TiO2 are different at different melting stages. The melts produced at lower pressure are richer in SiO2 than those at higher pressure. The mantle-derived silica-rich fluids (silicate melts) are polygenetic, but the basic and intermediate-acid silicate melts in mantle peridotite xenoliths from the same host rocks, which have equivalent contents of volatile and alkali components and different contents of other components, should result from in-situ (low-degree) partial melting of mantle peridotite under different conditions (e.g. at different depths, with introduction of C-O-H fluids or in the presence of metasomatic minerals). The intermediate-acid melts may be the result of partial melting (at lower pressure) Opx + Sp + K-Na-rich fluid ±(Am-phi) ± (Phlog) = OI + melt. But the intermediate-acid magmas cannot be produced from the partial melting of normal mantle peridotite unless the crustal materials are introduced to some extent.展开更多
Ultramafic rocks of Tibet and Xinjiang are the products of partial melting of the upper mantle. The evolution of their mineral composition is marked by two parallel evolutionary series: one is the progressive increase...Ultramafic rocks of Tibet and Xinjiang are the products of partial melting of the upper mantle. The evolution of their mineral composition is marked by two parallel evolutionary series: one is the progressive increase of the 100 Mg/(Mg+Fe^(2+) ratio of silicate minerals in order of lherzolite→harzburgite→dunite, i.e. the increase in magnesium; the other is the increase of the 100 Cr/(Cr+Al) ratio of accessory chrome spinel in the same order, i. e. the increase in Chromium. The above-mentioned evolutionary trends are contrary to that of magmatic differentiation. The evolution of fabrics of ultramafic rocks is characterized by progressive variation in order of protogranular texture→melted residual texture, symplectic texture and clastophyritic texture→equigranular mosaic texture and tabular mosaic texture. Experiments of partial melting of lherzolite have convincingly shown that the evolution of Alpine ultramafic rocks resulted from the partial melting of pyrolite. Various subtypes of them represent different degrees of partial melting. The vertical zoning marked by more basic rocks in the upper part and more acid rocks in the lower actually belongs to the fusion zoning of pyrolite.展开更多
The peridotite xenoliths are widely distributed in the Cenozoic basalts, Eastern China. However, their petrogenesis is hotly controversial. The peridotite xenoliths of Nanjing are found embedded in Cenozoic alkali bas...The peridotite xenoliths are widely distributed in the Cenozoic basalts, Eastern China. However, their petrogenesis is hotly controversial. The peridotite xenoliths of Nanjing are found embedded in Cenozoic alkali basalt. Most of the xenoliths are rounded and small to moderate in size(typically 5~10 cm in diameter), though larger ones have been found. Nearly all small xenoliths are harzburgite and dunite. However, the big ones have zoned structure: lherzolite core and harzburgite or dunite rim with new growth clinopyroxene(Cpx) as eyeliner along their margins. Petrology, mineralogy, and Major and trace element compositions of the Nanjing peridotite xenoliths in the Cenozoic basalts are measured to provide an insight into the nature of their mantle sources and processes. Our works suggest that they were suffered from a partial melting process and subsequently underwent a process of melt-peridotite interaction. The evidences of partial melting are as follows. Firstly, the lherzolite core is mostly composed of olivine(Ol) + orthopyroxene(Opx) + Cpx with minor spinel(Spl), however, the harzburgite or dunite rim is mostly complosed of Ol + Opx with minor Cpx. Secondly, from the lherzolite core to the harzburgite or dunite rim, Ol and Opx contents are gradually increased, inversely, Cpx contents are decreased, and the Spl disappears. Thirdly, Mg# values of Ol are increased from the core(~89.5) to the rim(>92) of the peridotite xenolith, but FeO contents(from 11.0 to 8.1) in Ol are opposite.Forthly, Mg#(from 90 to 93) and Cr#(from 4 to 17) values of the Opx are increased, but its Al2O3 contents(from 5.0 to 2.0) are decreased from the core to the rim. The evidences of meltperidotite interaction are mostly from clinopyroxenes. The clinopyroxenes can roughly divided into two groups: original clinopyroxenes of the peridotite and new growth clinopyroxenes generated by melt-peridotite interaction. The original clinopyroxenes are generally in the inner of peridotite xenoliths such as lherzolite. They are mostly coarse-grained, euhedral and bottle-green. However, the new growth clinopyroxenes generally occur as eyeliner along the margin of the peridotite xenoliths. They are generally fine-grained, irregular and light green. Compared with the original clinopyroxenes, the new growth ones have low Na2O and Al2O3 and high CaO contents. The Nanjing peridotite xenoliths in the Cenozoic alkali basalts suggest that the SCLM beneath eastern China might be a fertile mantle which has had a complex history, and is now a mixture of refractory and fertile mantle domains modified by a number of events.展开更多
A relatively high predetermined crystallization temperature (135℃) was chosen to grow well developed iPP spherulites, then the partial melting was carried out at a temperature of 165℃, where the preformed spheruli...A relatively high predetermined crystallization temperature (135℃) was chosen to grow well developed iPP spherulites, then the partial melting was carried out at a temperature of 165℃, where the preformed spherulites were seen to only decrease their size but not completely melted. The crystallization behavior of partially melted isotactic polypropylene (iPP) has been carefully examined by different scanning calorimetry (DSC) and polarized light microscopy (PLM). The experimental results show that at a special annealing temperature (165℃) the melting behavior of iPP includes two parts with different mechanism, one part is the melting of iPP spherulite outside, another is the partial lamellae perfection during longer annealing time in the unmelted spherulite. The conformational orders of the iPP melt decrease with the increase of the annealing temperature.展开更多
The ultrahigh-pressure(UHP) eclogite and gneiss from the Dabie(大别)-Sulu(苏鲁) oro-gen experienced variable degrees of partial melting during exhumation.We report here dehydration partial melting experiments of...The ultrahigh-pressure(UHP) eclogite and gneiss from the Dabie(大别)-Sulu(苏鲁) oro-gen experienced variable degrees of partial melting during exhumation.We report here dehydration partial melting experiments of biotite gneiss and phengite-bearing eclogite at 2 GPa and 800-950 ℃.Our results show that the partial melting of gneiss is associated with the breakdown of biotite into almandine-rich garnet starting at 900 ℃.About 10% granitic melt can be produced at 950 ℃.In con-trast,the partial melting of phengite-bearing eclogite exists at slightly lower temperatures(800-850 ℃).The melt fraction is in general more in biotite gneiss than in phengite-bearing eclogite under similar pressure and temperature conditions.Both melts are rich in silica and alkali,but poor in FeO,MgO and CaO.These results suggest that low-degree partial melting of gneiss and eclogite is often associated with dehydration of hydrous mineral,such as micas.The dehydration temperature and melt composi-tion can place important constraints on the partial melting phenomena(granitic leucosome and multi-phase mineral inclusions) recorded in UHP rocks.展开更多
In order to constrain temperature during subduction and subsequent exhumation of fel- sic continental crust, we carried out a Ti-in-zircon thermometer coupled with zircon internal structure and U-Pb age on migmatitic ...In order to constrain temperature during subduction and subsequent exhumation of fel- sic continental crust, we carried out a Ti-in-zircon thermometer coupled with zircon internal structure and U-Pb age on migmatitic gneisses from the Weihai region in the Sulu ultra-high pres- sure (UHP) metamorphic terrane, eastern China. The Weihai migmatitic gneisses are composed of in- tercalated compositional layers of melanosome and plagioclase (Pl)-rich lencosome and K-feldspar (Kfs)-rich pegmatite veins. Four stages of zircon growth were recognized in the Weihai migmatitic gneisses. They successively recorded informations of protolith, prograde metamorphism, decompres- sional partial melting during early stage exhumation and subsequent fractional crystallization of pri- mary melt during later stage cooling exhumation. The inherited cores in zircon from the melanosome and the Pl-rich leucosome suggest that the pro- tolith of the migmatitic gneiss is Mid- Neoproterozoic (-780 Ma) magmatic rock. Metamorphic zircons with concordant ages ranging from 243 to 256 Ma occur as over- growth mantles on the protolith magmatic zir- con cores. The estimated growth temperatures (625-717 "C) of the metamorphic zircons have a negative correlation with their ages, indicating a progressive metamorphism in HP eciogite-facies condition during subduction. Zircon recrystal- lized rims (228-2 Ma) in the PI-rich ieucosome layers provide the lower limit of the decompress-sional partial melting time during exhumation. The ages from 228^-2 to 219~2 Ma recorded in the Pl-rich leucosome and the Kfs-rich pegmatite vein, respectively, suggest the duration of the fractional crystallization of primary melt during exhumation. The calculated growth temperatures of the zircon rims from the Pl-rich leucosome range from 858 to 739 , and the temperatures of new growth zircon grains (219±2 Ma) in Kfs-rich vein are between 769 and 529 . The estimated temperatures have a positive correlation with ages from the Pl-rich leucosome to the Kfs-rich pegmatite vein, strongly indi- cating that a process of fractional crystallization of the partial melt during exhumation.展开更多
Water plays a crucial role in the melting of Earth's mantle. Mantle magmatisms mostly occur at plate boundaries(including subduction zones and mid-ocean ridges) and in some intraplate regions with thermal anomaly....Water plays a crucial role in the melting of Earth's mantle. Mantle magmatisms mostly occur at plate boundaries(including subduction zones and mid-ocean ridges) and in some intraplate regions with thermal anomaly. At oceanic subduction zones, water released by the subducted slab may induce melting of the overlying mantle wedge or even the slab itself, giving rise to arc magmatism, or may evolve into a supercritical fluid. The physicochemical conditions for the formation of slab melt and supercritical fluid are still under debate. At mid-ocean ridges and intraplate hot zones, water and CO_2 cause melting of the upwelling mantle to occur at greater depths and in greater extents. Low degree melting of the mantle may occur at boundaries between Earth's internal spheres, including the lithosphere-asthenosphere boundary(LAB), the upper mantletransition zone boundary, and the transition zone-lower mantle boundary, usually attributed to contrasting water storage capacity across the boundary. The origin for the stimulating effect of water on melting lies in that water as an incompatible component has a strong tendency to be enriched in the melt(i.e., with a mineral-melt partition coefficient much smaller than unity), thereby lowering the Gibbs free energy of the melt. The partitioning of water between melt and mantle minerals such as olivine, pyroxenes and garnet has been investigated extensively, but the effects of hydration on the density and transport properties of silicate melts require further assessments by experimental and computational approaches.展开更多
It is proposed in the subduction channel model that the plate interface interaction is a basic mechanism for the mass and energy exchange between Earth’s surface and interior.The significant difference in composition...It is proposed in the subduction channel model that the plate interface interaction is a basic mechanism for the mass and energy exchange between Earth’s surface and interior.The significant difference in composition and nature between continental lithosphere and oceanic lithosphere inevitably leads to variations in deep physical and chemical processes as well as crust-mantle interaction products in these two settings.Many studies of experimental petrology have provided constraints on the potential partial melting and crust-mantle interaction in oceanic subduction channels for silicate and carbonate rocks.The partial melts of mafic and felsic compositions are adakitic or non-adakitic granitic melts depending on melting pressure or depth.A trivial amount of CO2 can lower significantly the melting temperature of peridotites and lead to pronounced enrichment of incompatible elements in carbonate melt.The silica saturated or unsaturated melts can react with mantle-wedge peridotites in subduction channels to generate complex products.However,the existing experiments are mostly dedicated to island arc settings above oceanic subduction zones rather than dehydration melting above continental subduction zones.It is crucial to conduct high pressure and high temperature experiments to investigate all possible reactions between peridotites and crustal materials and their derivatives under the conditions responsible for the slab-mantle interface in continental subduction channels.Experimental results,combined with natural observations,are possible to elucidate the processes of metamorphic dehydration,partial melting and mantle metasomatism in continental subduction channels.展开更多
High-temperature(HT, >850℃) metamorphism in continental collision orogens, particularly for those ultrahigh-pressure(UHP) metamorphic rocks, has become one of the remarkable topics in Earth science. It has bearing...High-temperature(HT, >850℃) metamorphism in continental collision orogens, particularly for those ultrahigh-pressure(UHP) metamorphic rocks, has become one of the remarkable topics in Earth science. It has bearing on the element and isotope behaviors of UHP rocks, their partial melting and related geodynamic effects during exhumation. In this paper, five representative continental collision orogens with typical HT/UHP rocks, including the Dabie orogen in China, the Kokchetav in Kazakhstan, the Caledonides in Greenland, the Rhodope in Greece, and the Erzgebirge in Germany are introduced, and their HT/UHP metamorphism and evolution processes are summarized. In addition, metamorphic P-T-t paths, multistage exhumation processes, and partial melting and preservation and retrogression of UHP index minerals during exhumation and their possible mechanisms are discussed. On this basis, the forthcoming key fields and scientific subjects of HT/UHP rocks within continental subduction channel are proposed.展开更多
Partial melting experiments were carried on KLB-1 peridotite, a xenolith sample from the Earth's upper mantle, at 1.5 GPa and temperatures from 1 300 to 1 600 ℃, with heating time varies from 1 to 30 min. We quantif...Partial melting experiments were carried on KLB-1 peridotite, a xenolith sample from the Earth's upper mantle, at 1.5 GPa and temperatures from 1 300 to 1 600 ℃, with heating time varies from 1 to 30 min. We quantify the axial temperature gradient in the deformation-DIA appa- ratus (D-DIA) and constrain the time scale of partial melting by comparing experimental observa- tions with calculated result from pMELTS program. The compositions of the liquid phase and the coexisting solid phases (clinopyroxene, orthopyroxene, and olivine) agree well with those calculated from pMELTS program, suggesting that local chemical equilibrium achieves during partial melting, although longer heating time is required to homogenize the bulk sample. The Mg# (=Mg/(Mg+Fe) moi.%) of olivines from the 1-minute heating experiment changed continuously along the axial of the graphite capsule. A thermal gradient of 50 ℃/mm was calculated by comparing the Mg# of oli- vine grains with the output of pMELTS program. Olivine grains at the hot end of the graphite cap- sule from the three experiments heated at 1 400 ℃ but with different annealing time show consis- tence on Mg#, indicating that partitioning of Fe2+ between the olivine grains and the silicate melt happened fast, and partial melting occurs in seconds.展开更多
Crustal anatexis in continental subduction zones has great bearing on chemical differentiation of the continental crust at convergent plate boundaries.This was experimentally investigated for ultrahigh-pressure(UHP)me...Crustal anatexis in continental subduction zones has great bearing on chemical differentiation of the continental crust at convergent plate boundaries.This was experimentally investigated for ultrahigh-pressure(UHP)metafelsic rocks at 0.5-3.0 GPa and 650-900℃.The results show that partial melting begins at about 750℃ when pressure drops from 3.0 to 2.0 GPa,corresponding to decompressional exhumation of the deeply subducted continental crust.As the pressure further decreases to 1.0 GPa,the partial melting degree reaches the maximum of~25%at 900℃.Partial melts produced in these experiments are rich in silica and alkali,and poor in iron,manganese and magnesium.As the degree of partial melting increases,the composition of partial melts gradually converges toward homogeneous one.In the absence of free water,the partial melting of metafelsic rocks were triggered by the breakdown of hydrous minerals.At low temperatures of~750℃at 1.0-2.0 GPa,phengite dehydration melting occurs at first,giving rise to small amounts of felsic melts and peritectic K-feldspar.As the temperature rises up to 850-900℃,biotite begins to break down and gives rise to large amounts of felsic melts and peritectic minerals such as garnet,K-feldspar and orthopyroxene.It is noted that peritectic garnet is much different from anatectic garnet crystallized from anatectic melts and metamorphic garnet formed through metamorphic dehydration reaction under subsolidus conditions.The peritectic garnet is characterized not only by anhedral shapes with many multiphase crystal inclusions but also by compositions poor in spessartine and grossular but rich in almandine and pyrope.On the other hand,the anatectic garnets are characterized not only by euhedral shapes with few inclusions but also by compositions rich in grossular and spessartine but poor in almandine and pyrope.These observations provide experimental constraints on the origin of garnets in UHP metamorphic rocks,which have great bearing on understanding of anatectic metamorphism in collisional orogens.展开更多
Two types of melt pockets, closed melt pocket (CMP) and open melt pocket (OMP), are recognized from the peridotite xenoliths entrained in the Cenozoic kamafugites in western Qinling (秦岭), Central China. The Ha...Two types of melt pockets, closed melt pocket (CMP) and open melt pocket (OMP), are recognized from the peridotite xenoliths entrained in the Cenozoic kamafugites in western Qinling (秦岭), Central China. The Haoti (好梯) CMPs have a mineral assemblage of olivine+ clinopyroxene+amphibole+K- feldspar, whereas the Baiguan (白关) CMPs are composed of olivine+clinopyroxene+Umenite+carbonate. The components of the OMPs are more complicated. In the Haoti OMPs, there are olivine, ciinopyroxene, glass, low modal abundances of amphibole, K-feldspar (Kfs), Umenite, sulfide, chlorite, perovskite, chromite and phlogopite. The Baiguan OMPs contain olivine, clinopyroxene, glass, chlorite and chromite. Compositionally, ofivines in the CMPs and OMPs are both apparently depleted in Ni, and those in the OMPs are also depleted in Fe and Mg, and enriched in Ca compared to the primary ones. Ciinopyroxenes display large and systematical compositional variations between the CMPs and OMPs, particularly in Al, Cr, Na, Ca and Ti. Glasses are generally depleted in Si compared to the worldwide glasses in melt pockets, although they still have large variations. Amphiboles and K-feldspars have relatively restricted compositional variations. The petrographical observations and mineral chemistry suggest that the Haoti and Baiguan CMPs were generated by the in-sitn decompression melting of orthopyroxenes, olivines and clinopyroxenes, and by the addition of minor external K-rich and Ca-rich melt/fluids. The OMPs formed during the latest metasomatic event in the lithospheric mantle beneath the western Qinling.展开更多
基金sponsored by the National Key R&D Programme of China(2021YFC2901803)National Natural Science Foundation of China(92055314 and 41802095)+2 种基金the China Geological Survey(DD20230049 and DD20220983)is a contribution to the International Geoscience Programme(IGCP-741)Academician Bao-jun Liu Foundation of Southwest Geological Science and Technology Innovation Center.
文摘The Cenozoic Himalayan leucogranite-pegmatite belt has been a hotspot for rare metal exploration in recent years.To determine the genesis of the pegmatite in the Himalayan region and its relationship with the Greater Himalayan Crystalline Complex(GHC),the Gyirong pegmatite in southern Tibet was chosen for geochronological and geochemical studies.The dating analyses indicate that the U-Th-Pb ages of zircon,monazite,and xenotime exhibit large variations(38.6‒16.1 Ma),with the weighted average value of the four youngest points is 16.5±0.3 Ma,which indicates that the final stage of crystallization of the melt occurred in the Miocene.The age of the muscovite Ar-Ar inverse isochron is 15.2±0.4 Ma,which is slightly later than the intrusion age,showing that a cooling process associated with rapid denudation occurred at 16‒15 Ma.TheεHf(t)values of the Cenozoic anatectic zircons cluster between−12 and−9 with an average of−11.4.The Gyirong pegmatite shows high contents of Si,Al,and K,a high Al saturation index,and low contents of Na,Ca,Fe,Mn,P,Mg,and Ti.Overall,the Gyirong pegmatite is enriched in Rb,Cs,U,K,Th and Pb and depleted in Nb,Ta,Zr,Ti,Eu,Sr,and Ba.The samples show a high 87Sr/86Sr(16 Ma)ratio of ca.0.762 and a lowεNd(16 Ma)value of−16.0.The calculated average initial values of 208Pb/204Pb(16 Ma),207Pb/204Pb(16 Ma)and 206Pb/204Pb(16 Ma)of the whole rock are 39.72,15.79 and 19.56,respectively.The Sr-Nd-Pb-Hf isotopic characteristics of the Gyirong pegmatite are consistent with those of the GHC.This study concludes that the Gyirong pegmatite represents a typical crustal‒derived anatectic pegmatite with low metallogenic potential for rare metals.The Gyirong pegmatite records the long‒term metamorphism and partial melting process of the GHC,and reflects the crustal thickening caused by thrust compression at 39‒29 Ma and the crustal thinning induced by extensional decompression during 28‒15 Ma.
基金financially supported by the Ministry of Sciences and Technology of China(Grant No.2022YFF0800901)the Natural Science Foundation of China(Grant Nos.92055206 and 42163007)。
文摘Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the Cenozoic extrusive and intrusive rocks in the Yao’an area,western Yunnan Province,SW China,are geochemically shoshonitic,collectively termed here the Yao’an Shoshonitic Complex(YSC).The YSC is located in the(south)easternmost part of the ENE-WSW-trending,~550 km-long and~250 km-wide Cenozoic magmatic zone;the latter separates the orthogonal and oblique collision belts of the India-Eurasia collision orogen.Previously published geochronological and thermochronological data revealed that the rocks of the YSC were emplaced over a short timespan of 34-32 Ma.This and our new data suggest that the primary magma of the YSC likely was formed by partial melting of ancient continental lithospheric mantle beneath the Yangtze Block.This part of the continental lithospheric mantle had likely not been modified by any oceanic subduction.Fractionation crystallization of an Mg-and Ca-bearing mineral and TiFe oxides during the magmatic evolution probably account for the variable lithologies of the YSC.
基金supported by the Key Basic Research and Development Program of China(G19980407000)the National Natural Science Foundation of China(40072062)+1 种基金the Foundation of the Open Laboratory of Tectonophysics,China Seismological Bureauthe Post-Doctoral Grant of Ministry of Education,China.
文摘In order to constrain the crustal wave velocity structure in the southernTibetan crust and provide insight into the contribution of crustal composition, geothermal gradientand partial melting to the velocity structure, which is characterized by low average crustalvelocities and widespread presence of low-velocity zone(s), the authors model the crustal velocityand density as functions of depth corresponding to various heat flow values in light of velocitymeasurements at high temperature and high pressure. The modeled velocity and density are regarded ascomparison standards. The comparison of the standards with seismic observations in southern Tibetimplies that the predominantly felsic composition at high heat flow cannot explain the observedvelocity structure there. Hence, the authors are in favor of attributing low average crustalvelocities and low-velocity zone(s) observed in southern Tibet mainly to partial melting. Modelingbased on the experimental results suggests that a melting percentage of 7-12 could account for thelow-velocity zone(s).
文摘Study practice has proved that the ultrahigh pressure metamorphic rocks iu Dabieshan must have exPerienced botk the retrograde metumorphism and partial melting under decompression and amphibolite-facies conditions during their exhumation from mantel depth to lower-middle crust.The retrometamorphism and partial melting of the ultrahigh pressure rocks in association with thermal state changing in the middle-lower crust, under amphibolite-facies conditions, are important physical and chemical processes. It would result in a great detrease in the integrated yield strength, and the enhancement of the de formabilitY or the rocks, promoting the transition from contractional (collision) to extensional defoemational regime. The statement of tbe retrometamorphism and partial melting of the ultrahigh pressure rocks has proved the in-site model for the ultrahigh pressure rocks in Dabieshan. It not only clarifies the evolutiou from the UHP eclogite to the surrounding gneissic rock (so called UHP gueiss) and to the garnet-beariug roliated granites (non-UHP country rocks), but also provides scientific arguments for the establiskment of the dynamic model of the exhumation of UHP metamorphic rocks in Dabiesban. In general, Purely conductive heat transfer from the crust itself is probably insurficient to produce temperature conditions for partial melting, and additional heat sources must have been present during partial melting. We infer that the partial melting and extensional flow are probably driveu by delamination and magmatic underplating of thickeued lithospkeric mantle following the continental oblique collision.
基金financially supported by the National Basic Research Program of China (Grant No. 2015CB856104)the National Natural Science Foundation of China (Grant No. 41273036)
文摘Ultrahigh-pressure(UHP) metamorphic rocks are distinctive products of crustal deep subduction,and are mainly exposed in continental subduction-collision terranes. UHP slices of continental crust are usually involved in multistage exhumation and partial melting, which has obvious influence on the rheological features of the rocks, and thus significantly affect the dynamic behavior of subducted slices. Moreover,partial melting of UHP rocks have significant influence on element mobility and related isotope behavior within continental subduction zones, which is in turn crucial to chemical differentiation of the continental crust and to crust-mantle interaction.Partial melting can occur before, during or after the peak metamorphism of UHP rocks. Post-peak decompression melting has been better constrained by remelting experiments; however, because of multiple stages of decompression, retrogression and deformation, evidence of former melts in UHP rocks is often erased. Field evidence is among the most reliable criteria to infer partial melting. Glass and nanogranitoid inclusions are generally considered conclusive petrographic evidence. The residual assemblages after melt extraction are also significant to indicate partial melting in some cases. Besides field and petrographic evidence, bulk-rock and zircon trace-element geochemical features are also effective tools for recognizing partial melting of UHP rocks. Phase equilibrium modeling is an important petrological tool that is becoming more and more popular in P-T estimation of the evolution of metamorphic rocks; by taking into account the activity model of silicate melt, it can predict when partial melting occurred if the P-T path of a given rock is provided.UHP silicate melt is commonly leucogranitic and peraluminous in composition with high SiO_2,low MgO, FeO, MnO, TiO_2 and CaO, and variable K_2 O and Na_2 O contents. Mineralogy of nanogranites found in UHP rocks mainly consists of plagioclase + K-feldspar + quartz, plagioclase being commonly albite-rich.Trace element pattern of the melt is characterized by significant enrichment of large ion lithophile elements(LILE), depletion of heavy rare earth elements(HREE) and high field strength elements(HFSE),indicating garnet and rutile stability in the residual assemblage. In eclogites, significant Mg-isotope fractionation occurs between garnet and phengite; therefore, Mg isotopes may become an effective indicator for partial melting of eclogites.
基金financially supported by the National Nature Science Foundation of China(grant No. 41202037)
文摘Objective Previous studies on adakitic rocks with high Sr/Y and La/Yb ratios have established that such rocks may form in a variety of tectonic settings through different petrogenetic processes including: (1) partial melting of subducted young (〈25 Ma), hot and hydrated oceanic slab; (2) partial melting of thickened lower crust; (3) assimilation and fractional crystallization processes involving basaltic magma; (4) partial melting of delaminated lower crust; and (5) partial melting of hydrous garnet peridotite. The various origins for adakites provide important constraints on crustal growth and evolution throughout the Earth's history.
基金funding from the Department of Science and Technology, Government of India(India) under the DST INSPIRE Faculty Scheme (Grant:DST/INSPIRE/04/2014/000221)
文摘Phase equilibria modelling coupled with U–Pb zircon and monazite ages of garnet–cordierite gneiss from Vallikodu Kottayam in the Kerala Khondalite Belt,southern India are presented here.The results suggest that the area attained peak P–T conditions of^900C at 7.5–8 kbar,followed by decompression to 3.5–5 kbar and cooling to 450–480C,preserving signatures of the partial melting event in the field of high to ultra-high temperature metamorphism.Melt reintegration models suggest that up to 35%granitic melt could have been produced during metamorphism at^950C.The U–Pb age data from zircons(~1.0–~0.7 Ga)and chemical ages from monazites(~540 Ma and^941 Ma)reflect a complex tectonometamorphic evolution of the terrain.The^941 Ma age reported from these monazites indicate a Tonian ultra-high temperature event,linked to juvenile magmatism/deformation episodes reported from the Southern Granulite Terrane and associated fragments in Rodinia,which were subsequently overprinted by the Cambrian(~540 Ma)tectonothermal episode.
文摘Studies of the mantle-derived iherzolites from Nushan show that in addition to CO2,there were present H2O and small amounts of CO, CH4, SO2,Cl and F in the initial mantlc fluids derived fron the asthenospheric mantlc plumc .The imitial fluids accumulated in some regions of the mantle, resulting in lowering of the mantle solidus (and liquidus) and partial melting of the upper mantle. Melts formed from low-degree of fluid-involved partial melting of the upper mantle would be highly enriched in incompatible elements.Fluies and melts are allthe metasomatic agents for mantle metasomatism, and the interaction between them and the depleted mantle could result in the substan-tial local enrichment of LREE and incompatible elements in the latter.In case that the concentration of H2O in the fluids (and melts) is lower ,only cryptic metasomatism would occur, in case that the concentration of H2O is higher,the degree of partial melting would be higher and hydrous metasomatic phases(e.g. amphiboles )would nucleate. Under such circumstances, there would occur model metasomatism.
文摘Experiments on partial melting of mantle lherzolite have been realized at 0.6 and 1.0 GPa and the chemical compositional variations of melts during different melting stages have been first discussed. The results show that the trends of variations in SiO2, CaO, Al2O3, Na2O and TiO2 are different at different melting stages. The melts produced at lower pressure are richer in SiO2 than those at higher pressure. The mantle-derived silica-rich fluids (silicate melts) are polygenetic, but the basic and intermediate-acid silicate melts in mantle peridotite xenoliths from the same host rocks, which have equivalent contents of volatile and alkali components and different contents of other components, should result from in-situ (low-degree) partial melting of mantle peridotite under different conditions (e.g. at different depths, with introduction of C-O-H fluids or in the presence of metasomatic minerals). The intermediate-acid melts may be the result of partial melting (at lower pressure) Opx + Sp + K-Na-rich fluid ±(Am-phi) ± (Phlog) = OI + melt. But the intermediate-acid magmas cannot be produced from the partial melting of normal mantle peridotite unless the crustal materials are introduced to some extent.
基金This research was supported by National Natural Science Foundation of China (Project 4870117).
文摘Ultramafic rocks of Tibet and Xinjiang are the products of partial melting of the upper mantle. The evolution of their mineral composition is marked by two parallel evolutionary series: one is the progressive increase of the 100 Mg/(Mg+Fe^(2+) ratio of silicate minerals in order of lherzolite→harzburgite→dunite, i.e. the increase in magnesium; the other is the increase of the 100 Cr/(Cr+Al) ratio of accessory chrome spinel in the same order, i. e. the increase in Chromium. The above-mentioned evolutionary trends are contrary to that of magmatic differentiation. The evolution of fabrics of ultramafic rocks is characterized by progressive variation in order of protogranular texture→melted residual texture, symplectic texture and clastophyritic texture→equigranular mosaic texture and tabular mosaic texture. Experiments of partial melting of lherzolite have convincingly shown that the evolution of Alpine ultramafic rocks resulted from the partial melting of pyrolite. Various subtypes of them represent different degrees of partial melting. The vertical zoning marked by more basic rocks in the upper part and more acid rocks in the lower actually belongs to the fusion zoning of pyrolite.
基金granted by the National Natural Science Foundation of China(Nos.41772054 and 41572039)
文摘The peridotite xenoliths are widely distributed in the Cenozoic basalts, Eastern China. However, their petrogenesis is hotly controversial. The peridotite xenoliths of Nanjing are found embedded in Cenozoic alkali basalt. Most of the xenoliths are rounded and small to moderate in size(typically 5~10 cm in diameter), though larger ones have been found. Nearly all small xenoliths are harzburgite and dunite. However, the big ones have zoned structure: lherzolite core and harzburgite or dunite rim with new growth clinopyroxene(Cpx) as eyeliner along their margins. Petrology, mineralogy, and Major and trace element compositions of the Nanjing peridotite xenoliths in the Cenozoic basalts are measured to provide an insight into the nature of their mantle sources and processes. Our works suggest that they were suffered from a partial melting process and subsequently underwent a process of melt-peridotite interaction. The evidences of partial melting are as follows. Firstly, the lherzolite core is mostly composed of olivine(Ol) + orthopyroxene(Opx) + Cpx with minor spinel(Spl), however, the harzburgite or dunite rim is mostly complosed of Ol + Opx with minor Cpx. Secondly, from the lherzolite core to the harzburgite or dunite rim, Ol and Opx contents are gradually increased, inversely, Cpx contents are decreased, and the Spl disappears. Thirdly, Mg# values of Ol are increased from the core(~89.5) to the rim(>92) of the peridotite xenolith, but FeO contents(from 11.0 to 8.1) in Ol are opposite.Forthly, Mg#(from 90 to 93) and Cr#(from 4 to 17) values of the Opx are increased, but its Al2O3 contents(from 5.0 to 2.0) are decreased from the core to the rim. The evidences of meltperidotite interaction are mostly from clinopyroxenes. The clinopyroxenes can roughly divided into two groups: original clinopyroxenes of the peridotite and new growth clinopyroxenes generated by melt-peridotite interaction. The original clinopyroxenes are generally in the inner of peridotite xenoliths such as lherzolite. They are mostly coarse-grained, euhedral and bottle-green. However, the new growth clinopyroxenes generally occur as eyeliner along the margin of the peridotite xenoliths. They are generally fine-grained, irregular and light green. Compared with the original clinopyroxenes, the new growth ones have low Na2O and Al2O3 and high CaO contents. The Nanjing peridotite xenoliths in the Cenozoic alkali basalts suggest that the SCLM beneath eastern China might be a fertile mantle which has had a complex history, and is now a mixture of refractory and fertile mantle domains modified by a number of events.
基金supported by the National Natural Science Foundation of China(Nos.50533050 and 20634050)
文摘A relatively high predetermined crystallization temperature (135℃) was chosen to grow well developed iPP spherulites, then the partial melting was carried out at a temperature of 165℃, where the preformed spherulites were seen to only decrease their size but not completely melted. The crystallization behavior of partially melted isotactic polypropylene (iPP) has been carefully examined by different scanning calorimetry (DSC) and polarized light microscopy (PLM). The experimental results show that at a special annealing temperature (165℃) the melting behavior of iPP includes two parts with different mechanism, one part is the melting of iPP spherulite outside, another is the partial lamellae perfection during longer annealing time in the unmelted spherulite. The conformational orders of the iPP melt decrease with the increase of the annealing temperature.
基金supported by the National Natural Science Foundation of China (Nos. 40802046 and 90714005)the National Key Basic Research Program from MOST (No. 2009CB825003)
文摘The ultrahigh-pressure(UHP) eclogite and gneiss from the Dabie(大别)-Sulu(苏鲁) oro-gen experienced variable degrees of partial melting during exhumation.We report here dehydration partial melting experiments of biotite gneiss and phengite-bearing eclogite at 2 GPa and 800-950 ℃.Our results show that the partial melting of gneiss is associated with the breakdown of biotite into almandine-rich garnet starting at 900 ℃.About 10% granitic melt can be produced at 950 ℃.In con-trast,the partial melting of phengite-bearing eclogite exists at slightly lower temperatures(800-850 ℃).The melt fraction is in general more in biotite gneiss than in phengite-bearing eclogite under similar pressure and temperature conditions.Both melts are rich in silica and alkali,but poor in FeO,MgO and CaO.These results suggest that low-degree partial melting of gneiss and eclogite is often associated with dehydration of hydrous mineral,such as micas.The dehydration temperature and melt composi-tion can place important constraints on the partial melting phenomena(granitic leucosome and multi-phase mineral inclusions) recorded in UHP rocks.
基金supported by the National Key Basic Research Program of China (No.2009CB825001)the National Natural Science Foundation of China (Nos.40603002,41072046,and 41090371)the Fundamental Research Funds for the Central Universities,China University of Geosciences,Wuhan (No.CUG120121)
文摘In order to constrain temperature during subduction and subsequent exhumation of fel- sic continental crust, we carried out a Ti-in-zircon thermometer coupled with zircon internal structure and U-Pb age on migmatitic gneisses from the Weihai region in the Sulu ultra-high pres- sure (UHP) metamorphic terrane, eastern China. The Weihai migmatitic gneisses are composed of in- tercalated compositional layers of melanosome and plagioclase (Pl)-rich lencosome and K-feldspar (Kfs)-rich pegmatite veins. Four stages of zircon growth were recognized in the Weihai migmatitic gneisses. They successively recorded informations of protolith, prograde metamorphism, decompres- sional partial melting during early stage exhumation and subsequent fractional crystallization of pri- mary melt during later stage cooling exhumation. The inherited cores in zircon from the melanosome and the Pl-rich leucosome suggest that the pro- tolith of the migmatitic gneiss is Mid- Neoproterozoic (-780 Ma) magmatic rock. Metamorphic zircons with concordant ages ranging from 243 to 256 Ma occur as over- growth mantles on the protolith magmatic zir- con cores. The estimated growth temperatures (625-717 "C) of the metamorphic zircons have a negative correlation with their ages, indicating a progressive metamorphism in HP eciogite-facies condition during subduction. Zircon recrystal- lized rims (228-2 Ma) in the PI-rich ieucosome layers provide the lower limit of the decompress-sional partial melting time during exhumation. The ages from 228^-2 to 219~2 Ma recorded in the Pl-rich leucosome and the Kfs-rich pegmatite vein, respectively, suggest the duration of the fractional crystallization of primary melt during exhumation. The calculated growth temperatures of the zircon rims from the Pl-rich leucosome range from 858 to 739 , and the temperatures of new growth zircon grains (219±2 Ma) in Kfs-rich vein are between 769 and 529 . The estimated temperatures have a positive correlation with ages from the Pl-rich leucosome to the Kfs-rich pegmatite vein, strongly indi- cating that a process of fractional crystallization of the partial melt during exhumation.
基金supported by the National Natural Science Foundation of China(Grant Nos.41590622&41473058)the 111 Project of Ministry of Education,China+1 种基金the Fundamental Research Funds for the Central Universities of Chinathe Recruitment Program of Global Experts(Thousand Talents),China
文摘Water plays a crucial role in the melting of Earth's mantle. Mantle magmatisms mostly occur at plate boundaries(including subduction zones and mid-ocean ridges) and in some intraplate regions with thermal anomaly. At oceanic subduction zones, water released by the subducted slab may induce melting of the overlying mantle wedge or even the slab itself, giving rise to arc magmatism, or may evolve into a supercritical fluid. The physicochemical conditions for the formation of slab melt and supercritical fluid are still under debate. At mid-ocean ridges and intraplate hot zones, water and CO_2 cause melting of the upwelling mantle to occur at greater depths and in greater extents. Low degree melting of the mantle may occur at boundaries between Earth's internal spheres, including the lithosphere-asthenosphere boundary(LAB), the upper mantletransition zone boundary, and the transition zone-lower mantle boundary, usually attributed to contrasting water storage capacity across the boundary. The origin for the stimulating effect of water on melting lies in that water as an incompatible component has a strong tendency to be enriched in the melt(i.e., with a mineral-melt partition coefficient much smaller than unity), thereby lowering the Gibbs free energy of the melt. The partitioning of water between melt and mantle minerals such as olivine, pyroxenes and garnet has been investigated extensively, but the effects of hydration on the density and transport properties of silicate melts require further assessments by experimental and computational approaches.
基金supported by the National Basic Research Program of China(Grant No.2015CB856101)the National Natural Science Foundation of China(Grant Nos.41172070,41425012)the Ministry of Education of China and the State Administration of Foreign Expert Affairs of China(Grant No.B07039)
文摘It is proposed in the subduction channel model that the plate interface interaction is a basic mechanism for the mass and energy exchange between Earth’s surface and interior.The significant difference in composition and nature between continental lithosphere and oceanic lithosphere inevitably leads to variations in deep physical and chemical processes as well as crust-mantle interaction products in these two settings.Many studies of experimental petrology have provided constraints on the potential partial melting and crust-mantle interaction in oceanic subduction channels for silicate and carbonate rocks.The partial melts of mafic and felsic compositions are adakitic or non-adakitic granitic melts depending on melting pressure or depth.A trivial amount of CO2 can lower significantly the melting temperature of peridotites and lead to pronounced enrichment of incompatible elements in carbonate melt.The silica saturated or unsaturated melts can react with mantle-wedge peridotites in subduction channels to generate complex products.However,the existing experiments are mostly dedicated to island arc settings above oceanic subduction zones rather than dehydration melting above continental subduction zones.It is crucial to conduct high pressure and high temperature experiments to investigate all possible reactions between peridotites and crustal materials and their derivatives under the conditions responsible for the slab-mantle interface in continental subduction channels.Experimental results,combined with natural observations,are possible to elucidate the processes of metamorphic dehydration,partial melting and mantle metasomatism in continental subduction channels.
基金supported by the National Basic Research Program of China(Grant No.2015CB856104)the National Natural Science Foundation of China(Grant No.41273036)
文摘High-temperature(HT, >850℃) metamorphism in continental collision orogens, particularly for those ultrahigh-pressure(UHP) metamorphic rocks, has become one of the remarkable topics in Earth science. It has bearing on the element and isotope behaviors of UHP rocks, their partial melting and related geodynamic effects during exhumation. In this paper, five representative continental collision orogens with typical HT/UHP rocks, including the Dabie orogen in China, the Kokchetav in Kazakhstan, the Caledonides in Greenland, the Rhodope in Greece, and the Erzgebirge in Germany are introduced, and their HT/UHP metamorphism and evolution processes are summarized. In addition, metamorphic P-T-t paths, multistage exhumation processes, and partial melting and preservation and retrogression of UHP index minerals during exhumation and their possible mechanisms are discussed. On this basis, the forthcoming key fields and scientific subjects of HT/UHP rocks within continental subduction channel are proposed.
基金support by the National Natural Science Foundation of China (No. 41773052)the National Science Foundation of USA (Nos. EAR 1141895, EAR 1045629, and EAR 0968823)
文摘Partial melting experiments were carried on KLB-1 peridotite, a xenolith sample from the Earth's upper mantle, at 1.5 GPa and temperatures from 1 300 to 1 600 ℃, with heating time varies from 1 to 30 min. We quantify the axial temperature gradient in the deformation-DIA appa- ratus (D-DIA) and constrain the time scale of partial melting by comparing experimental observa- tions with calculated result from pMELTS program. The compositions of the liquid phase and the coexisting solid phases (clinopyroxene, orthopyroxene, and olivine) agree well with those calculated from pMELTS program, suggesting that local chemical equilibrium achieves during partial melting, although longer heating time is required to homogenize the bulk sample. The Mg# (=Mg/(Mg+Fe) moi.%) of olivines from the 1-minute heating experiment changed continuously along the axial of the graphite capsule. A thermal gradient of 50 ℃/mm was calculated by comparing the Mg# of oli- vine grains with the output of pMELTS program. Olivine grains at the hot end of the graphite cap- sule from the three experiments heated at 1 400 ℃ but with different annealing time show consis- tence on Mg#, indicating that partitioning of Fe2+ between the olivine grains and the silicate melt happened fast, and partial melting occurs in seconds.
基金supported by the National Natural Science Foundation of China (Nos.41822201 and 41772048)the BType Strategic Priority Program of the Chinese Academy of Sciences (No.XDB41000000)the Fundamental Research Funds for the Central Universities of China
文摘Crustal anatexis in continental subduction zones has great bearing on chemical differentiation of the continental crust at convergent plate boundaries.This was experimentally investigated for ultrahigh-pressure(UHP)metafelsic rocks at 0.5-3.0 GPa and 650-900℃.The results show that partial melting begins at about 750℃ when pressure drops from 3.0 to 2.0 GPa,corresponding to decompressional exhumation of the deeply subducted continental crust.As the pressure further decreases to 1.0 GPa,the partial melting degree reaches the maximum of~25%at 900℃.Partial melts produced in these experiments are rich in silica and alkali,and poor in iron,manganese and magnesium.As the degree of partial melting increases,the composition of partial melts gradually converges toward homogeneous one.In the absence of free water,the partial melting of metafelsic rocks were triggered by the breakdown of hydrous minerals.At low temperatures of~750℃at 1.0-2.0 GPa,phengite dehydration melting occurs at first,giving rise to small amounts of felsic melts and peritectic K-feldspar.As the temperature rises up to 850-900℃,biotite begins to break down and gives rise to large amounts of felsic melts and peritectic minerals such as garnet,K-feldspar and orthopyroxene.It is noted that peritectic garnet is much different from anatectic garnet crystallized from anatectic melts and metamorphic garnet formed through metamorphic dehydration reaction under subsolidus conditions.The peritectic garnet is characterized not only by anhedral shapes with many multiphase crystal inclusions but also by compositions poor in spessartine and grossular but rich in almandine and pyrope.On the other hand,the anatectic garnets are characterized not only by euhedral shapes with few inclusions but also by compositions rich in grossular and spessartine but poor in almandine and pyrope.These observations provide experimental constraints on the origin of garnets in UHP metamorphic rocks,which have great bearing on understanding of anatectic metamorphism in collisional orogens.
基金supported by the Special Research Project of the State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences (No. 1008)the National Natural Science Foundation of China (No. 90714008)
文摘Two types of melt pockets, closed melt pocket (CMP) and open melt pocket (OMP), are recognized from the peridotite xenoliths entrained in the Cenozoic kamafugites in western Qinling (秦岭), Central China. The Haoti (好梯) CMPs have a mineral assemblage of olivine+ clinopyroxene+amphibole+K- feldspar, whereas the Baiguan (白关) CMPs are composed of olivine+clinopyroxene+Umenite+carbonate. The components of the OMPs are more complicated. In the Haoti OMPs, there are olivine, ciinopyroxene, glass, low modal abundances of amphibole, K-feldspar (Kfs), Umenite, sulfide, chlorite, perovskite, chromite and phlogopite. The Baiguan OMPs contain olivine, clinopyroxene, glass, chlorite and chromite. Compositionally, ofivines in the CMPs and OMPs are both apparently depleted in Ni, and those in the OMPs are also depleted in Fe and Mg, and enriched in Ca compared to the primary ones. Ciinopyroxenes display large and systematical compositional variations between the CMPs and OMPs, particularly in Al, Cr, Na, Ca and Ti. Glasses are generally depleted in Si compared to the worldwide glasses in melt pockets, although they still have large variations. Amphiboles and K-feldspars have relatively restricted compositional variations. The petrographical observations and mineral chemistry suggest that the Haoti and Baiguan CMPs were generated by the in-sitn decompression melting of orthopyroxenes, olivines and clinopyroxenes, and by the addition of minor external K-rich and Ca-rich melt/fluids. The OMPs formed during the latest metasomatic event in the lithospheric mantle beneath the western Qinling.