Influence of particle composition on thorium scavenging in the marginal China seas

Thorium-234 and particle composition （organic matter, biogenic silica, carbonate and lithogenic component） were examined in the East China Sea （ECS） and the northern South China Sea （NSCS） in order to constrain the particle types scavenging thorium isotopes. Good positive correlations between particulate organic matter （POM） or carbonate and thorium-234 in suspended particulate matter （SPM） indicates that POM and carbonate are efficient to scavenge thorium-234. No relationship between biogenic silica and thorium-234 suggests that geochemical behavior of thorium-234 may be not influenced by biogenic silica. A simple model was used to evaluate the affinity of thorium-234 to different particle components. The results show that POM is the most efficient scavenger for thorium-234 in the ECS and the NSCS, followed by carbonate. The authors＇ results lend support to the utility of thorium-234 as a proxy of POC and carbonate in the upper layer. However, the strong dependence of thorium scavenging on particle composition challenges thorium-230 as a constant flux proxy.

Service composition based on discrete particle swarm optimization in military organization cloud cooperation

This paper addresses the problem of service composition in military organization cloud cooperation（MOCC）. Military service providers（MSP） cooperate together to provide military resources for military service users（MSU）. A group of atom services, each of which has its level of quality of service（QoS）, can be combined together into a certain structure to form a composite service. Since there are a large number of atom services having the same function, the atom service is selected to participate in the composite service so as to fulfill users＇ will. In this paper a method based on discrete particle swarm optimization（DPSO） is proposed to tackle this problem. The method aims at selecting atom services from service repositories to constitute the composite service, satisfying the MSU＇s requirement on QoS. Since the QoS criteria include location-aware criteria and location-independent criteria, this method aims to get the composite service with the highest location-aware criteria and the best-match location-independent criteria. Simulations show that the DPSO has a better performance compared with the standard particle swarm optimization（PSO） and genetic algorithm（GA）.

Theoretical analysis of the double-differential cross-sections of neutron,proton,deuteron,^(3)He,andαfor the p+^(6) Li reaction

Based on the unified Hauser–Feshbach and exciton model,which can describe the particle emission processes between discrete energy levels with energy,angular momentum,and parity conservations,a statistical theory of light nucleus reaction(STLN)is developed to calculate the double-differential cross-sections of the outgoing neutron and light charged particles for the proton-induced^(6) Li reaction.A significant difference is observed between the p+^(6) Li and p+^(7) Li reactions owing to the discrepancies in the energy-level structures of the targets.The reaction channels,including sequential and simultaneous emission processes,are analyzed in detail.Taking the double-differential cross-sections of the outgoing proton as an example,the influence of contaminations(such as^(1) H,^(7)Li,^(12)C,and^(16)O)on the target is identified in terms of the kinetic energy of the first emitted particles.The optical potential parameters of the proton are obtained by fitting the elastic scattering differential cross-sections.The calculated total double-differential cross-sections of the outgoing proton and deuteron at E_(p)=14 MeV agree well with the experimental data for different outgoing angles.Simultaneously,the mixed double differential cross-sections of^(3) He andαare in good agreement with the measurements.The agreement between the measured data and calculated results indicates that the two-body and three-body breakup reactions need to be considered,and the pre-equilibrium reaction mechanism dominates the reaction processes.Based on the STLN model,a PLUNF code for the p+^(6) Li reaction is developed to obtain an ENDF-6-formatted file of the double-differential cross-sections of the nucleon and light composite charged particles.

Preparation of Clay/Biochar Composite Adsorption Particle and Performance for Ammonia Nitrogen Removal from Aqueous Solution

This study aimed to present a novel clay/biochar composite adsorption particle, which made from abandoned reed straw and clay to remove ammonia nitrogen(NH4^+-N) from micro-contaminated water. The removal performance of NH4^+-N by composite adsorption particle was monitored under different raw material proportions and initial NH4^+-N concentration. Besides, adsorption kinetics and adsorption isotherms were investigated to reveal the adsorption mechanisms. The results showed that NH4^+-N was effectively removed under optimal proportion of biochar, foaming agent and crosslinker with 20%, 3%, and 3%, respectively. The optimal contact time was 150 min and the best removal efficiency was 88.6% at initial NH4^+-N concentration of 20 mg L^-1. The adsorption performance was well described by the second order kinetic model and Freundlich model. The novel clay/biochar composite adsorption particle in this study demonstrated a high potential for NH4^+-N removal from surface water.

Characterization of Calcined Kaolin/TiO_2 Composite Particle Material Prepared by Mechano-Chemical Method

Calcined kaolin/TiO2 composite particle material （CK/TCPM） was prepared with TiO2 coating on the surfaces of calcined kaolin particles by the mechano-chemical method. X-ray diffraction （XRD） and scanning electron microscope （SEM） were used to investigate the microstructures and morphologies, respectively. The mechanism of the mechano-chemical reaction between calcined kaolin and TiO2 was studied by infrared spectra （IR）. The results show that TiO2 coats evenly on the surfaces of calcined kaolin particles by Si-O-Ti and Al-O-Ti bonds on their interfaces. The hiding power and whiteness of CK/TCPM are 17.12 g/m^2 and 95.7%, respectively, presenting its similarity to TiO2 in pigment properties.

Synthesis of nano-CaCO_3 composite particles and their application

Nano-calcium carbonate composite particles were synthesized by the soapless emulsion polymerization technique of double monomers. The composite particles formation mechanism was investigated. The effects of composite particles on the mechanical properties of nano-CaCO3-ABS （acrylonitrile-butadiene-styrene copolymer） composite material were studied. It was validated that the composite particles are made up of the nano-calcium carbonate cores and the shells of alternating copolymers of butyl acrylate （BA） and styrene （St）. The shells are chemically grafted and physically wrapped on the surface of nano-calcium carbonate particles. When the composite particles were filled in ABS matrix, the CaCO3 particles are homogeneously dispersed in the composite material as nanoscales. The impact strength of the composite material is obviously enhanced after filling appropriate amounts of composite particles. It can be concluded that the soapless emulsion polymerization of double monomers is an effective method for nano-CaCO3 surface treatment. 2008 University of Science and Technology Beijing. All rights reserved.

Effective Elastic Properties of 3-Phase Particle Reinforced Composites with Randomly Dispersed Elastic Spherical Particles of Different Sizes Dedicated to Professor Karl Stark Pister for his 95th birthday

Higher-order multiscale structures are proposed to predict the effective elastic properties of 3-phase particle reinforced composites by considering the probabilistic spherical particles spatial distribution,the particle interactions,and utilizing homogenization with ensemble volume average approach.The matrix material,spherical particles with radius a1,and spherical particles with radius a2,are denoted as the 0th phase,the 1st phase,and the 2nd phase,respectively.Particularly,the two inhomogeneity phases are different particle sizes and the same elastic material properties.Improved higher-order(in ratio of spherical particle sizes to the distance between the centers of spherical particles)bounds on effective elastic properties of 3-phase particle reinforced proposed Formulation II and Formulation I derive composites.As a special case,i.e.,particle size of the 1st phase is the same as that of the 2nd phase,the proposed formulations reduce to 2-phase formulas.Our theoretical predictions demonstrate excellent agreement with selected experimental data.In addition,several numerical examples are presented to demonstrate the competence of the proposed frameworks.

Sol-Gel Preparation of Graphite/TiO_2 Composite Particles and Their Electrorheological Effect

Graphite/TiO2 composite particles were obtained by sol-gel technique in this paper. The structure and characteristic of the composite particles are analyzed by XRD, SEM and TG-DTA. The electrorheological properties of the ER fluid containing the particles were measured by a Couette-type rheometer under shear rates of 1-136 s-1 and AC electric fields of 0-3 kV/mm. The experimental results show that the leaking current density of the ER fluid is higher than that of pure titanium dioxide particles dispersed in damping oil. The shear yield stress of the ER fluid increases with increasing electric field and exhibits a typical Bingham flow behavior. The suspension demonstrates an excellent ER performance (τ/τo=1200) compared with conventional ER fluids (τ/τ0 ≤500). The sedimentation of the ER fluid is improved obviously due to the coating effect of the particles.

Analysis of Equivalent Oxygen DifFusivity of Particle Dispersed Composites

This paper presents a new method to determine the equivalent oxygen diffusivities of particle dispersed composites. This method can be used to design FGM thermal barrier systems with the function of oxygen barrier. A qualitative explanation of the oxidation of nickel with the increment of zirconia contents in the composite samples can be accepted by this method. The values of equivalent oxygen diffusivities obtained with this method are in excellent agreement with those from the EMT method for the composites with ZrO2 particle dispersed phase when the volume fractions of dispersed phase are lower than 25%.

A CFD-DEM-Wear Coupling Method for Stone Chip Resistance of Automotive Coatings with a Rigid Connection ParticleMethod for Non-Spherical Particles

The stone chip resistance performance of automotive coatings has attracted increasing attention in academic and industrial communities.Even though traditional gravelometer tests can be used to evaluate stone chip resistance of automotive coatings,such experiment-based methods suffer from poor repeatability and high cost.The main purpose of this work is to develop a CFD-DEM-wear coupling method to accurately and efficiently simulate stone chipbehaviorof automotive coatings inagravelometer test.Toachieve this end,an approach coupling an unresolved computational fluid dynamics(CFD)method and a discrete element method(DEM)are employed to account for interactions between fluids and large particles.In order to accurately describe large particles,a rigid connection particle method is proposed.In doing so,each actual non-spherical particle can be approximately described by rigidly connecting a group of non-overlapping spheres,and particle-fluid interactions are simulated based on each component sphere.An erosion wear model is used to calculate the impact damage of coatings based on particlecoating interactions.Single spherical particle tests are performed to demonstrate the feasibility of the proposed rigid connection particle method under various air pressure conditions.Then,the developed CFD-DEM-wear model is applied to reproduce the stone chip behavior of two standard tests,i.e.,DIN 55996-1 and SAE-J400-2002 tests.Numerical results are found to be in good agreement with experimental data,which demonstrates the capacity of our developed method in stone chip resistance evaluation.Finally,parametric studies are conducted to numerically investigate the influences of initial velocity and test panel orientation on impact damage of automotive coatings.

HYBRID AND CHARACTERISTIC OF POLYANILINEBARIUM TITANATE NANOCOMPOSITE PARTICLES

Polyaniline-barium titanate (PAn-Ba-TiO3) ultrafine composite particles were prepared by the oxidative polymerization of aniline with H2O2 while barium titanate nanoparticles were synthesized with a sol-gel method. The infrared spectrogram shows that the polymerization of PAn in the hybrid process of PAn-BaTiO3 is similar with the polymeric process of pure aniline, and there is interaction of PAn and BaTiO3 in the PAn-Ba-TiO3. SEM and TEM results show that the average diameter of the composite particles is 1.50μm and the diameters of BaTiO3 nanoparticles are 5 - 15 nm in the composite particle. The electrical conductivity of the ultrafine com-posite particles is transformable from 10°to 10-11S/cm by equilibrium doping or dedoping method using various concentration of HCl or NaOH solutions.

Facile Preparation of PVA-AA/TiO2 Composite Gel Particles and Their Tunable Photo-catalytic Property for the Degradation of Methyl Orange

In the presence of titanium dioxide powder, cross-linking reaction between commercial polyvinyl alcohol(PVA)-based macromonomer and acrylic acid(AA) was initiated with potassium persulfate in an emulsifying system. As a result, PVA-AA/TiO2 composite gel particles were obtained. The morphology and composition of the particles were analyzed with scanning electron microscopy(SEM), energy scattering x-ray spectroscopy(EDS), Fourier infrared spectroscopy(FTIR), and thermogravimetric analysis(TGA). The analysis results confirmed that the particles were the expected ones. TiO2 was dispersed homogeneously within the spheroidal particles. Compared to the control gel, the composite gel particles not only contained Ti element but also showed higher thermal stability. In addition, the photo-catalytic behavior of the particles for the degradation of methyl orange contained in aqueous solution was examined. The particles exhibited photocatalytic characteristic for the degradation of the model dye, which could be modulated by simply varying the amount of cross-linking agent or TiO2. The photo-catalytic degradation percentage of methyl orange maintained at 91%-96% after using the particles three times, which indicated that TiO2 could played its role repeatedly via being fixated within polyvinyl alcohol-based gel.

Study on Diffusion Welding Parameters of Particle reinforced Aluminium Matrix Composite Al_2O_(3p) /6061Al

Effects of diffusion welding process parameters on strength of welded joint based on particle reinforced aluminium matrix composite Al 2O 3p /6061Al have been studied through comparing with aluminium matrix alloy. The mechanism for loss of joint strength has been analyzed. It should be pointed out that key processing parameters affecting the strength of joint was welding temperature. The high quality joint can be successfully obtained with appropriate diffusion welding parameters.

<i>H</i>, <i>W</i>, <i>Z</i>Bosons, Dark Matter: Composite Particles?

The present article develops a model initially published in ref. [1]. It is a quasi-classical quantum model of composite particles with ultra-relativistic (UR) constituents (leptons and quarks). The model is used to calculate the mass energy of three composite particles: a UR tauonium, a UR bottomonium and a UR leptoquarkonium. The result is that these three hypothetic particles have masses close to 125 GeV: the Higgs boson mass energy. These results are recalled in the present article. Then the model is extended to calculate the mass energy of pi-mesons, W and Z bosons. Finally, the model provides a hypothesis on dark matter.

Characterization of Fe-containing particles in Chengdu,southwest China,using single-particle aerosol mass spectrometry

Single-particle aerosol mass spectrometry was used to study the characteristics of Fecontaining particles during winter in Chengdu,southwest China.The mass concentrations of PM_(2.5)and PM_(10)during the study period were 64±38 and 89±49μg/m~3,respectively,and NO_(2)and particulate matter were high compared with most other regions of China.The Fecontaining particles were divided into seven categories with different mass spectra,sources and aging characteristics.The highest contribution was from Fe mixed with carbonaceous components(Fe-C,23.1%)particles.Fe was more mixed with sulfate than nitrate and therefore the contribution of Fe mixed with sulfate(Fe-S,20.7%)particles was higher than that of Fe mixed with nitrate(Fe-N,12.5%)particles.The contributions from Fe-containing particles related to primary combustion were high in the small particle size range,whereas aged Fecontaining particles and dust-related particles were mostly found in the coarse particle size range.The air masses mainly originated from the west and east of Chengdu,and the corresponding PM_(2.5)concentrations were 79±36 and 55±36μg/m~3,respectively.The west and east air masses showed stronger contributions of Fe-containing particles related to biomass burning(Fe-B)and fossil fuel combustion(Fe-C and Fe-S)particles,respectively.The southwest area contributed the most Fe-containing particles.Future assessments of the effects of Fe-containing particles during heavy pollution period should pay more attention to Fe-C and Fe-S particles.Emission-reduction of Fe-containing particles should consider both local emissions and short-distance transmission from the surrounding areas.

A New Interpretation of the Higgs Vacuum Potential Energy Based on a Planckion Composite Model for the Higgs

We present a new interpretation of the Higgs field as a composite particle made up of a positive, with, a negative mass Planck particle. According to the Winterberg hypothesis, space, i.e., the vacuum, consists of both positive and negative physical massive particles, which he called planckions, interacting through strong superfluid forces. In our composite model for the Higgs boson, there is an intrinsic length scale associated with the vacuum, different from the one introduced by Winterberg, where, when the vacuum is in a perfectly balanced state, the number density of positive Planck particles equals the number density of negative Planck particles. Due to the mass compensating effect, the vacuum thus appears massless, chargeless, without pressure, energy density, or entropy. However, a situation can arise where there is an effective mass density imbalance due to the two species of Planck particle not matching in terms of populations, within their respective excited energy states. This does not require the physical addition or removal of either positive or negative Planck particles, within a given region of space, as originally thought. Ordinary matter, dark matter, and dark energy can thus be given a new interpretation as residual vacuum energies within the context of a greater vacuum, where the populations of the positive and negative energy states exactly balance. In the present epoch, it is estimated that the dark energy number density imbalance amounts to, , per cubic meter, when cosmic distance scales in excess of, 100 Mpc, are considered. Compared to a strictly balanced vacuum, where we estimate that the positive, and the negative Planck number density, is of the order, 7.85E54 particles per cubic meter, the above is a very small perturbation. This slight imbalance, we argue, would dramatically alleviate, if not altogether eliminate, the long standing cosmological constant problem.

On the Cosmic Evolution of the Quantum Vacuum Using Two Variable G Models and Winterberg’s Thesis

We work within a Winterberg framework where space, i.e., the vacuum, consists of a two component superfluid/super-solid made up of a vast assembly (sea) of positive and negative mass Planck particles, called planckions. These material particles interact indirectly, and have very strong restoring forces keeping them a finite distance apart from each other within their respective species. Because of their mass compensating effect, the vacuum appears massless, charge-less, without pressure, net energy density or entropy. In addition, we consider two varying G models, where G, is Newton’s constant, and G-1, increases with an increase in cosmological time. We argue that there are at least two competing models for the quantum vacuum within such a framework. The first follows a strict extension of Winterberg’s model. This leads to nonsensible results, if G increases, going back in cosmological time, as the length scale inherent in such a model will not scale properly. The second model introduces a different length scale, which does scale properly, but keeps the mass of the Planck particle as, ± the Planck mass. Moreover we establish a connection between ordinary matter, dark matter, and dark energy, where all three mass densities within the Friedman equation must be interpreted as residual vacuum energies, which only surface, once aggregate matter has formed, at relatively low CMB temperatures. The symmetry of the vacuum will be shown to be broken, because of the different scaling laws, beginning with the formation of elementary particles. Much like waves on an ocean where positive and negative planckion mass densities effectively cancel each other out and form a zero vacuum energy density/zero vacuum pressure surface, these positive mass densities are very small perturbations (anomalies) about the mean. This greatly alleviates, i.e., minimizes the cosmological constant problem, a long standing problem associated with the vacuum.

The sound velocity and bulk properties of sediments in the Bohai Sea and the Yellow Sea of China

In order to investigate the correlation between a sound velocity and sediment bulk properties and explore the influence of frequency dependence of the sound velocity on the prediction of the sediment properties by the sound velocity, a compressional wave velocity is measured at frequencies of 25-250 kHz on marine sediment samples collected from the Bohai Sea and the Yellow Sea in laboratory, together with the geotechnical parameters of sediments. The results indicate that the sound velocity ranges from 1.232 to 1.721 km/s for the collected sediment samples with a significant dispersion within the series measuring frequency. Poorly sorted sediments are highly dispersive nearly with a positive linear relationship. The porosity shows a better negative logarithmic correlation with the sound velocity compared with other geotechnical parameters. Generally, the sound velocity increases with the increasing of the average particle size, sand content, wet and dry bulk densities, and decreasing of the clay content, and water content. An important point should be demonstrated that the higher correlation can be obtained when the measuring frequency is low within the frequency ranges from 25 to 250 kHz since the inhomogeneity of sediment properties has a more remarkably influence on the laboratory sound velocity measurement at the high frequency.

Soil Physical Properties of Different Land Use Types in Loess Hilly Region

[Objectives]To explore the impact of land use changes on physical properties of soil in loess hilly region.[Methods]The methods of field sampling and indoor analysis were adopted.Farmland in a small watershed in the middle of the Loess Plateau,grassland that had been abandoned for 7 years,grassland that had been abandoned for 30 years,jujube orchard and ditch were sampled,and the particle composition(clay,silt and sand)and moisture changes of the soil in the top 0-100 cm were studied.[Results]In the small watershed,the top 0-100 cm of the soil was composed of 14%clay,70%silt and 16%sand.The contents of clay,silt and sand in the grassland that had been abandoned for 30 years varied greatly,while varied little in the land of other use types.The soil moisture content of grassland that had been abandoned for 30 years,jujube orchard,grassland that had been abandoned for 7 years,farmland and ditch increased with the increase of depth,with means of 10.29%,11.66%,10.08%,11.43%and 11.34%,respectively.[Conclusions]This study provides a theoretical basis for the growth of crops of different land use types in the loess hilly region.

Effect of sintering parameters on the microstructure and thermal conductivity of diamond/Cu composites prepared by high pressure and high temperature infiltration

Pure Cu composites reinforced with diamond particles were fabricated by a high pressure and high temperature （HPHT） infiltration technique. Their microstructural evolution and thermal conductivity were presented as a function of sintering parameters （temperature, pressure, and time）. The improvement in interfacial bonding strength and the maximum thermM conductivity of 750 W/（m.K） were achieved at the optimal sintering parameters of 1200℃, 6 GPa and 10 min. It is found that the thermal conductivity of the composites depends strongly on sintering pressure. When the sintering pressure is above 6 GPa, the diamond skeleton is detected, which greatly contributes to the excellent thermal conductivity.