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Sulfonation of 1,4-diaminoanthraquinone leuco by chlorosulfonic acid:Kinetics and process intensification
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作者 Bing Liu Yingjiao Li +5 位作者 Moses Arowo Guangwen Chu Yong Luo Liangliang Zhang Haikui Zou Baochang Sun 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第6期163-169,共7页
The work herein employed a rotating packed bed(RPB)to intensify the sulfonation process of 1,4-diaminoanthraquinone leuco(DL)in an attempt to improve the yield of the product 1,4-diaminoanthra quinone-2-sulfonic acid(... The work herein employed a rotating packed bed(RPB)to intensify the sulfonation process of 1,4-diaminoanthraquinone leuco(DL)in an attempt to improve the yield of the product 1,4-diaminoanthra quinone-2-sulfonic acid(DSA).First,the effects of operating conditions in a stirred tank reactor(STR),including stirring speed,chlorosulfonic acid/DL molar ratio(η),solvent/DL mass ratio(ζ),reaction temperature and dropping speed of chlorosulfonic acid,on the yield of DSA were investigated.The yield of DSA can reach 87.34%under the optimal operating conditions:stirring speed of 500 r·min^(-1),ηof 4.5,ζof 7,reaction temperature of 150℃,dropping speed of 0.61 ml·min^(-1).In addition,the kinetics of the sulfonation process via the shrinking core model revealed that the reaction is controlled by diffusion via a product layer under the reaction temperature of 140℃.Furthermore,the RPB was employed to intensify the mass transfer between liquid and solid phases during the sulfonation reaction process.The results showed that the DSA yield of 92.69%obtained by RPB was 5.35%higher than that by STR,indicating that RPB can significantly intensify the mass transfer in the liquid-solid phase sulfonation reaction process. 展开更多
关键词 sulfonation 1 4-Diaminoanthraquinone-2-sulfonic acid KINETICS Rotating packed bed(RPB) Chlorosulfonic acid
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Rheological property of low-damage,ideal packing,film-forming amphoteric/sulfonation polymer drilling fluids 被引量:2
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作者 张洪霞 鄢捷年 +1 位作者 舒勇 赵胜英 《Journal of Central South University》 SCIE EI CAS 2008年第S1期429-433,共5页
Low-permeability dense reservoirs,including micro-fractured reservoirs,are commonly characterized by high content of clay substances,high original water saturation,high sensitivity to invasive fluids,high capillary pr... Low-permeability dense reservoirs,including micro-fractured reservoirs,are commonly characterized by high content of clay substances,high original water saturation,high sensitivity to invasive fluids,high capillary pressure,complicated structure and anisotropic,high flow-resistance and micro pore throats etc,.Generally they also have lots of natural micro fractures,probably leading to stress sensibility.Main damaging factors in such reservoirs are water-sensibility and water-blocking caused by invasive fluids during drilling and production operations.Once damaged,formation permeability can rarely recovered.Numerous studies have shown that damaging extent of water-blocking ranges from 70% to 90%.Main damaging mechanisms and influencing factors of water-blocking were systematically analyzed.Also some feasible precaution or treating approaches of water-blocking were put forward.In a laboratory setting,a new multi-functional drilling fluid composed mainly of amphion polymer,sulfonation polymer,high effectively preventive water-blocking surfactants,ideal packing temporary bridging agents(TBA) and film-forming agents,etc.,were developed.New low-damage drilling fluids has many advantages,such as good rheological properties,excellent effectiveness of water-blocking prevention,good temporary plugging effect,low filtration and ultra-low permeability(API filtration≤5 mL,HTHP filtration≤10 mL,mud cake frictional coefficient≤0.14,permeability recovery>81%),can efficiently prevent or minimize damage,preserve natural formation and enhance comprehensive development-investment effect in TUHA Jurassic dense sandstone reservoir formation with low-permeability,the only one developing integrated condense gas field.Some references can be provided to similar reservoir formations. 展开更多
关键词 low-permeability dense gas condense reservoir AMPHION and sulfonation polymer drilling fluid DAMAGE controlling water-blocking ideal packing theory(IPT) film-forming agent rheological properties
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Implications from γ-globulin adsorption onto cation exchangers fabricated by sequential alginate grafting and sulfonation 被引量:1
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作者 Xianxiu Li Yan Sun Xiaoyan Dong 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第1期121-125,共5页
Our previous work proved that high adsorption capacity and uptake rate of lysozyme were achieved on alginate(Alg)-grafted re sin with an ionic capacity(IC) of 240 mmol·L^(-1)(Alg-FF-240).Moreover,the salt-toleran... Our previous work proved that high adsorption capacity and uptake rate of lysozyme were achieved on alginate(Alg)-grafted re sin with an ionic capacity(IC) of 240 mmol·L^(-1)(Alg-FF-240).Moreover,the salt-tolerant feature of Alg-FF-230 was improved by using sequential alginate grafting and sulfonation strategy.Inspired by the enhanced adsorption performance of lysozyme,we have herein proposed to investigate the static and dynamic adsorption behaviors of γ-globulin on a series of Alg-grafted resins with different grafting densities and sulfonation degrees.The adsorption ca pacity of γ-globulin decreased with increa sing alginate-grafting density(IC) from 160 to 230 mmol·L^(-1) at 0 mmol·L^(-1) NaCl because of the steric hindrance caused by the alginate-grafting layer.Effects of ionic strength(IS) indicated that the adsorption capacities of the resins with the IC value of 230-370 mmol·L^(-1) were much higher than CM Sepharose FF at 50-100 mmol·L^(-1) NaCl,and the uptake rate of Alg-FF-230 was about twice as much as that of CM Sepharose FF.This work demonstrated the important effects of alginate-grafting layer and IS in γ-globulin adsorption behavior,which would be helpful in the design of Alggrafted resins and the selection of proper IS condition for protein purification. 展开更多
关键词 ALGINATE sulfonation γ-Globulin Adsorption capacity Uptake rate
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Surface Sulfonation of Polyvinyl Chloride by Plasma for Antithrombogenicity 被引量:1
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作者 刘鹏 陈亚芍 《Plasma Science and Technology》 SCIE EI CAS CSCD 2004年第3期2328-2332,共5页
To enhance the blood compatibility of Polyvinyl Chloride (PVC) film, the film was modified by SO2/O2 gas plasma treatment. The effect of surface sulfonation of PVC treated by various SO2/O2 gas plasma depended on the ... To enhance the blood compatibility of Polyvinyl Chloride (PVC) film, the film was modified by SO2/O2 gas plasma treatment. The effect of surface sulfonation of PVC treated by various SO2/O2 gas plasma depended on the volume ratio O2/(SO2 +O2). When the volume ratio was 0.5, the effect of sulfonation was the best. Sulfonic acid groups were specifically and efficiently introduced onto the PVC surface, which was proved by X-ray photoelectron spectroscopy (XPS) and Attenuated Total Reflectance Fourier Transfer Infrared (ATR-FTIR) spectroscopy. The surface microstructure of modified PVC film was studied with scanning electron microscopy (SEM). The antithrombogenicity of the samples was determined by the activated partial thromboplastin time (APTT), prothrombin time (PT), thrombin time (TT) and plasma recalcification time (PRT) tests and platelet adhesion experiment. The results indicated that the antithrombogenicity of modified PVC was improved remarkably. 展开更多
关键词 polyvinyl chloride PLASMA surface sulfonation ANTITHROMBOGENICITY
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SULFONATION OF A NEW POLYETHERETHERKETONE PREPARED FROM PHENOLPHTHALEIN
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作者 陈天禄 袁雅桂 +2 位作者 张曼华 陈仲庆 徐纪平 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1990年第3期217-223,共7页
A novel polyetheretherketone (PEK-C) prepared from phenolphthalein has been synthesized. In order to improve some of its properties for application in high performance membrane, the PEK-C has been sulfonated with conc... A novel polyetheretherketone (PEK-C) prepared from phenolphthalein has been synthesized. In order to improve some of its properties for application in high performance membrane, the PEK-C has been sulfonated with concentrated sulfuric acid. Degree of sulfonation can be regulated by controlling the temmperature and time of sulfonation. The characterization of the sulfonated PEK-C in sodium salt form has been made by IR, ~1H NMR and ^(13)C NMR etc. It is shown that the sulfonation appears to take place exclusively in the ortho position to phenolic ether of phenolphthalein unit. The result is in agreement with theoretical deduction. Some properties of the sulfonated PEK-C, such as solubility, transition temperature, thermal degradation and hydrophilicity have also been discussed. 展开更多
关键词 POLYETHERETHERKETONE PHENOLPHTHALEIN sulfonation.
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EFFECT OF SOLVENT COMPOSITION ON THE SULFONATION DEGREE OF POLY(PHENYLENE OXIDE) (PPO)
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作者 徐铜文 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2002年第1期53-57,共5页
This paper investigates the possibility of attaining sulphonated poly(phenylene oxide) (SPPO) with a relativelyhigher sulfonation degree. To achieve this aim, the approach we adopt is to improve the solubility of the ... This paper investigates the possibility of attaining sulphonated poly(phenylene oxide) (SPPO) with a relativelyhigher sulfonation degree. To achieve this aim, the approach we adopt is to improve the solubility of the final product in themixed solvent so that the sulfonation may take place between the bulk solutions and PPO powders even at higher sulfonationdegree. It is shown that the addition of a proper amount of dimethyl formide (DMF) to the conventional PPO-chloroformsystem can actually enhance the sulfonation effect. The solvent composition is then correlated with the sulfonation degreebased on the solubility parameters. It is interesting to find that solubility parameters between the mixed solvent and theprecipitated products keep an approximately unchanged value at about 4.9, which is just equal to that when pure chloroformis used, though the solubility parameters of both solvents increase with the content of DMF in solution. This may be the mainreason why the addition of DMF can reduce the precipitation and improve the ion exchange capacity (IEC) of SPPOpolymer. 展开更多
关键词 Poly(phenylene oxide) sulfonation Solubility parameter
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CHEMISTRY OF 1,2,4—TRIAZINES XIX THE ANOMALOUS SUBSTITUTED BENZENE SULFONATION AND PROPERTIES OF NUCLEOPHILIC ATTACK ON 6-CARBON OF 3-METHYLTHIO-5-HYDROXY-1,2,4-TRIAZINE
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作者 Mei HAN Xu Ling SHI Zhen Jun YANG Meng Shen CAI Tie Ming CHENG School of Pharmaceutical Sciences,Beijing Medical University,Beijing 100083 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第9期771-774,共4页
3-Methylthio-5-hydroxy-1,2,4-triazine(1c)reacted with substituted benzenesulfonyl chloride to give 3-methylthio-5-oxy-1,2,4-triazin-6-yl pyridinium betaine(4)in anhydrous pyridine.But when NaOH/H_2O/CH_3COCH_3 or NaOH... 3-Methylthio-5-hydroxy-1,2,4-triazine(1c)reacted with substituted benzenesulfonyl chloride to give 3-methylthio-5-oxy-1,2,4-triazin-6-yl pyridinium betaine(4)in anhydrous pyridine.But when NaOH/H_2O/CH_3COCH_3 or NaOH/CH_3OH were used as reactant and solvent,3-methylthio-4-substituted benzenesulfonyl-5-oxo-6-hydroxy-1,4,5,6-tetrahydro-1,2,4-triazine(6)or 1-tosyl-3-methylthio-5-oxo-6-methyloxy-1,4,5,6-tetrahydro-1,2,4-triazine(7)was obtained respectively.The above reactions show anomalous properties of nucleophilic attack on 6-carbon in 1,2,4-triazine ring. 展开更多
关键词 NaOH CHEMISTRY OF 1 2 4 TRIAZINES XIX THE ANOMALOUS SUBSTITUTED BENZENE sulfonation AND PROPERTIES OF NUCLEOPHILIC ATTACK ON 6-CARBON OF 3-METHYLTHIO-5-HYDROXY-1 2 4-TRIAZINE
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Sulfonation of (1 →6)-β-D-Glucan (Lasiodiplodan) and Its Antioxidant and Antimicrobial Potential 被引量:1
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作者 Gabrielle C. Calegari Vidiany A. Q. Santos +3 位作者 Sirlei D. Teixeira Aneli M. Barbosa-Dekker Robert F. H. Dekker Mairio A. A. da Cunha 《Journal of Pharmacy and Pharmacology》 2017年第12期850-863,共14页
The objective of this study was to investigate the sulfonation of (1→6)-β-D-glucan (lasiodiplodan) as a potentiating mechanism for biological functionalities. Lasiodiplodan was sulfonated by the chlorosulfonic a... The objective of this study was to investigate the sulfonation of (1→6)-β-D-glucan (lasiodiplodan) as a potentiating mechanism for biological functionalities. Lasiodiplodan was sulfonated by the chlorosulfonic acid-pyridine method. The modified exopolysaccharide was characterized by FT-IR and 13C NMR spectroscopy, X-ray diffraction and SEM. Antioxidant activity was assessed by the methods of H2O2 and OH radical removal and reducing power. Antimicrobial potential was evaluated by the broth-microdilution method. Sulfonation resulted in a derivative with DS of 0.24. FT-IR analysis indicated the introduction of sulfonyl groups in the macromolecule structure through specific bands in the regions of 1,240 cm-1 and 810 cm-1. 13C NMR analysis suggested that sulfonation occurred at carbon 2 of the glucose residue. Sulfonation led to morphological changes in the structure of the biopolymer resulting in a heterogeneous structure with the presence of fibrils. Derivatization promoted an increase in the antioxidant ability of the macromolecule, with a high OH removal potential (74.32%). Bacteriostatic activity against E. coli (Escherichia coli) and S. enterica (Salmonella enterica) typhimurium and fungicidal activity against C. albicans (Candida albicans) and C. tropicalis (Candida tropicalis) were found in the sulfonated sample. Sulfonation potentiated the antioxidant and antimicrobial activities of the biomacromolecule, suggesting that it is a potentiating mechanism of biological functions. 展开更多
关键词 Chemical derivatization microbial polysaccharides bioactivity sulfonate groups.
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Conversion of carbonaceous materials into solid acids for tylosin mitigation:effect of preprocessing methods on the reactivity of sulfonation reaction
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作者 Chunmei Wang Qianqian Xie +2 位作者 Xiaomin Dou Lanxi Zhang Xiao Yang 《Biochar》 SCIE CAS CSCD 2023年第1期558-573,共16页
Carbon-based solid acids have been successfully employed as acidic catalysts for pollutant mitigation in wastewater.To fully tap the potentials of commercially viable carbons for the preparation of solid acids and enh... Carbon-based solid acids have been successfully employed as acidic catalysts for pollutant mitigation in wastewater.To fully tap the potentials of commercially viable carbons for the preparation of solid acids and enhance their catalytic performances is a challenging problem.In this work,three commercialized carbons including biochar,activated carbon and graphite were preprocessed(ball-milling,Hummer exfoliation,HNO3 soaking,and microwave heating in HNO_(3),etc.),sulfonated,and evaluated as solid-acid catalysts for tylosin mitigation.Graphite-originated solid acid performed the best through a balling-milling preprocess,while biochar-originated solid acids behaved well under all preprocessing treatments,in which 40 mg L^(−1) of tylosin was mitigated within 8 min by 1 g L^(−1) of biochar-originated solid acids.The biochar solid acid through the ball-milling preprocess presented high total acidity and large amounts of-SO_(3)H groups,due to dramatically increased surface area and the rise of activation groups(hydroxyl,alkyl and alkoxy groups,etc.)facilitating electrophilic reaction.In addition,decreased particle size and aromaticity and increased structural defects also contributed.Theoretical calculation of average local ionization energy(ALIE)of condensed aromatic model molecules with substituted activation groups confirmed the promoting effects on sulfonation from strong to weak were 8.40-9.06 eV.These findings have deepened the knowledge in tuning carbon surface chemistry for better sulfonation,thus strengthening catalytic degradation of tylosin.The value of this study is in pulling a clear thread for maneuvering solid-acid catalysts using carbons,which holds a novel promise for rationally functionalizing biochar-based catalysts for the remediation of macrolide antibiotics in polluted water. 展开更多
关键词 Biochar engineering sulfonation Heterogeneous catalysis Tylosin hydrolysis Antibiotic remediation
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Creating large EMS populations for functional genomics and breeding in wheat 被引量:1
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作者 Wenqiang Wang Xizhen Guan +10 位作者 Yong Gan Guojun Liu Chunhao Zou Weikang Wang Jifa Zhang Huifei Zhang Qunqun Hao Fei Ni Jiajie Wu Lynn Epstein Daolin Fu 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第2期484-493,共10页
Wheat germplasm is a fundamental resource for basic research,applied studies,and wheat breeding,which can be enriched normally by several paths,such as collecting natural lines,accumulating breeding lines,and introduc... Wheat germplasm is a fundamental resource for basic research,applied studies,and wheat breeding,which can be enriched normally by several paths,such as collecting natural lines,accumulating breeding lines,and introducing mutagenesis materials.Ethyl methane sulfonate(EMS)is an alkylating agent that can effectively introduce genetic variations in a wide variety of plant species.In this study,we created a million-scale EMS population(MEP)that started with the Chinese wheat cultivars‘Luyan 128’,‘Jimai 38’,‘Jimai 44’,and‘Shannong 30’.In the M1 generation,the MEP had numerous phenotypical variations,such as>3,000 chlorophyll-deficient mutants,2,519 compact spikes,and 1,692 male sterile spikes.There were also rare mutations,including 30 independent tillers each with double heads.Some M1 variations of chlorophyll-deficiency and compact spikes were inheritable,appearing in the M2 or M3 generations.To advance the entire MEP to higher generations,we adopted a single-seed descendent(SSD)approach.All other seed composites of M2 were used to screen other agronomically important traits,such as the tolerance to herbicide quizalofop-P-methyl.The MEP is available for collaborative projects,and provides a valuable toolbox for wheat genetics and breeding for sustainable agriculture. 展开更多
关键词 WHEAT GERMPLASM ethyl methane sulfonate genetics and breeding
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Gaseous sulfur trioxide induced controllable sulfonation promoting biomineralization and osseointegration of polyetheretherketone implants 被引量:7
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作者 Teng Wan Zixue Jiao +5 位作者 Min Guo Zongliang Wang Yizao Wan Kaili Lin Qinyi Liu Peibiao Zhang 《Bioactive Materials》 SCIE 2020年第4期1004-1017,共14页
Fabricating a desired porous structure on the surface of biomedical polyetheretherketone(PEEK)implants for enhancing biological functions is crucial and difficult due to its inherent chemical inertness.In this study,a... Fabricating a desired porous structure on the surface of biomedical polyetheretherketone(PEEK)implants for enhancing biological functions is crucial and difficult due to its inherent chemical inertness.In this study,a porous surface of PEEK implants was fabricated by controllable sulfonation using gaseous sulfur trioxide(SO3)for different time(5,15,30,60 and 90 min).Micro-topological structure was generated on the surface of sulfonated PEEK implants preserving original mechanical properties.The protein absorption capacity and apatite forming ability was thus improved by the morphological and elemental change with higher degree of sulfonation.In combination of the appropriate micromorphology and bioactive sulfonate components,the cell adhesion,migration,proliferation and extracellular matrix secretion were obviously enhanced by the SPEEK-15 samples which were sulfonated for 15 min.Finding from this study revealed that controllable sulfonation by gaseous SO3 would be an extraordinarily strategy for improving osseointegration of PEEK implants by adjusting the microstructure and chemical composition while maintaining excellent mechanical properties. 展开更多
关键词 POLYETHERETHERKETONE sulfonation Micro-topology Mechanical strength OSTEOINTEGRATION
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A deeper exploration of the relation between sulfonation degree and retanning performance of aromatic syntans 被引量:3
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作者 Qingyong Sun Yunhang Zeng +2 位作者 Ya‑nan Wang Yue Yu Bi Shi 《Journal of Leather Science and Engineering》 2021年第1期350-359,共10页
It is well‑known that the sulfonation degree(DS)of aromatic syntan is an important factor affecting its retanning performances.But the quantitative relation between DS and syntan property and the influencing mechanism... It is well‑known that the sulfonation degree(DS)of aromatic syntan is an important factor affecting its retanning performances.But the quantitative relation between DS and syntan property and the influencing mechanism of DS on syntan property are not clarified.In this work,five phenolic formaldehyde syntans(PFSs)with the same polym‑erization degree but varying DS were prepared to investigate the effect of DS on the properties of syntan and crust leather.It was found that the absolute value of zeta potential and the particle size of PFS decreased with increasing DS in aqueous solution.Molecular dynamic simulation results proved that the DS of PFS was a major contributor to electrostatic interaction and hydrogen bonding in the PFS–water system and greatly affected the aggregation and dispersion of PFS in aqueous solution.The PFS with a low DS was prone to aggregate to large particles in aqueous solution because of low intermolecular electrostatic repulsion and less hydrogen bonds and therefore can be used to increase the thickness and tightness of leather.The PFS with a high DS presented a small particle size with more anionic groups in aqueous solution,thereby sharply decreasing the positive charge of leather surface and facilitat‑ing the penetration of the post‑tanning agents into the leather.These results might be scientifically valid for rational molecular design of syntans and more productive use of syntans in leather making. 展开更多
关键词 sulfonation degree Aromatic syntan AGGREGATION PENETRATION Molecular dynamics simulation
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Effect of Sulfonation Degree on Performance of Proton Exchange Membranes for Direct Methanol Fuel Cells 被引量:1
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作者 XIANG Zheng ZHAO Xueping +3 位作者 GE Junjie MA Shuhua ZHANG Yuwei NA Hui 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2016年第2期291-295,共5页
A series of proton exchange membranes based on sulfonated polyarylene ether ketones(SPAEKs) was used to study the effect of sulfonation degree on proton conductivity, methanol permeation and performance of direct me... A series of proton exchange membranes based on sulfonated polyarylene ether ketones(SPAEKs) was used to study the effect of sulfonation degree on proton conductivity, methanol permeation and performance of direct methanol fuel cells(DMFCs). Dependences of physical characteristics of the membranes, i. e., proton conductivity, water uptake, swelling ratio, methanol permeability and ion exchange capacity(IEC) were systematically studied. Both methanol permeability and proton conductivity of the SPAEK membrane grow rapidly as the increase in sulfonation degree since methanol molecules and protons share the same transfer channel. However, the methanol permeability plays more important role comparing to proton conductivity. As a result, the SPAEK membrane with a medium sulfonation degree(60%) was found to yield the best performance in a DMFC due to the acquirement of balanced conductivity and methanol permeability. 展开更多
关键词 Fuel cell sulfonation degree Proton exchange membrane Methanol permeability
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Properties of Multiblock Sulfonated Poly(arylene ether sulfone)s Synthesized by Precise Controllable Post-sulfonation for Proton Exchange Membranes 被引量:1
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作者 Xing Chen Lei Xiao +1 位作者 Xin-Sheng Qiu Kang-Cheng Chen 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2022年第7期754-763,共10页
A series of multiblock sulfonated poly(arylene ether sulfone)s(SPAES)with various block lengths and predictable ion exchange capacity were synthesized from 4,4’-difluorodiphenyl sulfone,4,4’-dihydrodiphenyl sulfone ... A series of multiblock sulfonated poly(arylene ether sulfone)s(SPAES)with various block lengths and predictable ion exchange capacity were synthesized from 4,4’-difluorodiphenyl sulfone,4,4’-dihydrodiphenyl sulfone and 4,4’-biphenol by one-pot and two-pot polymerization.;H-NMR and FTIR spectra confirmed the structure that sulfonic acid groups were introduced precisely on the poly(arylene ether sulfone)s by post-sulfonation which resulted in controllable sulfonation degree.The proton exchange membranes(PEMs)-based SPAES displayed excellent dimensional,thermal,antioxidant stability,proton conductivity and mechanical properties(maximum tensile stress>35 MPa).Thermogravimetric analysis indicated the prepared SPAES began to degrade above 310℃.The effects of polymerization processes,those were,one-pot hydrophobic segment process,one-pot hydrophilic segment process and two-pot process,on the properties of polymers were investigated.The proton conductivity and microphase separation of SPAES PEMs increased in order of those prepared by one-pot hydrophobic segment process,two-pot process and one-pot hydrophilic segment process.The highest conductivities of SPAES synthesized by the above processes under 80℃ and 100%relative humidity were 213(MS4),297(MB3)and 360 mS·cm^(-1)(MQ2),respectively. 展开更多
关键词 Sulfonated poly(arylene ether sulfone)s(SPAES) Proton exchange membranes One-pot process Two-pot process Post-sulfonation
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Sulfonation of Hydroxymethylated Lignin and Its Application 被引量:1
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作者 Weijue GAOD John P.W.INWOODD Pedram FATEHI 《Journal of Bioresources and Bioproducts》 EI 2019年第2期80-88,共9页
To valorize kraft lignin,hydroxymethylation and sulfonation were applied on this under-utilized,but vastly available,material.The hydroxymethylation pretreatment was conducted as means to improve the reactivity of lig... To valorize kraft lignin,hydroxymethylation and sulfonation were applied on this under-utilized,but vastly available,material.The hydroxymethylation pretreatment was conducted as means to improve the reactivity of lignin.The sulfonation of hydroxymethylated kraft lignin was investigated by sulfuric acid and sodium sulfite treatments under various conditions.The modified lignin samples were characterized for their charge density,solubility,elemental components,and molecular weights.The results showed that the hydroxymethylation facilitated the sulfonation by sodium sulfite,yielding a product(SSH-lignin)with the charge density of-1.2 meq/g and water solubility of 10 g/L under the conditions of Ns_(2)SO_(3)/lignin molar ratio of 0.49 mol/mol,95℃and 3 h.On the other hand,hydroxymethylation hindered the sulfonation of lignin by sulfuric acid,yielding a product(SAH-lignin)with the charge density of–0.46 meq/g and solubility of 0.9 g/L under the conditions of H_(2)SO_(4)/lignin molar ratio of 14.8 mol/mol,80℃and 1 h.The SSH-lignin had a high adsorption on kaolinite(17 mg/g)at a lignin concentration of 40 g/L.The sulfonated lignins were also found to be effective coagulant for the cationic dye ethyl violet. 展开更多
关键词 kraft lignin HYDROXYMETHYLATION sulfonation ADSORPTION dye removal
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Removal of rubidium from brine by an integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide
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作者 Huanxi Xu Peihua Lin +6 位作者 Pei-Jun Liu Hai-Gang Liu Hui-Bin Guo Chao-Xiang Wu Ming Fang Xu Zhang Guan-Ping Jin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期112-121,共10页
A novel integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide(KCuFC/SPSG)was used for selectively extracting rubidium ion(Rb^(+))from brine.To form KCuFC/SPSG,the precursor film of sulfonate... A novel integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide(KCuFC/SPSG)was used for selectively extracting rubidium ion(Rb^(+))from brine.To form KCuFC/SPSG,the precursor film of sulfonated polysulfone/graphene(SPSG)was synthesized by phase conversion process,which was alternately immersed in 0.1 mol·L^(-1)CuSO_(4)/K_(4)[Fe(CN)_(6)]by in-situ adsorption coupled co-precipitation method.Various data such as nuclear magnetic resonance spectrometer,Fourier transform infrared spectroscope,X-ray photoelectron spectroscope,X-ray diffraction,scanning electron microscope,and energy dispersive spectroscopy all verified that abundant KCuFC were uniformly located on the film.The resulting KCuFC/SPSG was used in film separation system.As the solution was fed into the system,the Rb^(+)could be selectively adsorption by KCuFC/SPSG.After the saturation adsorption,0.5 mol·L^(-1)NH_(4)Cl/HCl was fed into the film cell,Rb^(+)could be quickly desorbed by ion-exchange between Rb^(+)and NH_(4)^(+)in the lattice of KCuFC.The purpose of separating and recovering Rb^(+)from the brine can be achieved after the repeated operation.The effects of pH,adsorption time,and interferential ions on the adsorption capacity of Rb^(+)were investigated by batch experiments.The adsorption behavior fits the pseudo-second order kinetic process,while KCuFC has a higher adsorption capacity(Langmuir maximum sorption 165.4 mg·g^(-1)).In addition,KCuFC/SPSG shows excellent selectivity for Rb^(+)even in complex brine systems.KCuFC/SPSG could maintain 93.5%extraction efficiency after five adsorption/desorption cycles. 展开更多
关键词 Rubidium extraction Potassium copper ferricyanide Sulfonated polysulfone Graphene oxide Adsorption
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High performance photodegradation resistant PVA@TiO_(2)/carboxyl-PES self-healing reactive ultrafiltration membrane
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作者 Yu Liang Yuanfang Fan +5 位作者 Zhongmin Su Mingxin Huo Xia Yang Hongliang Huo Chi Wang Zhi Geng 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期31-39,共9页
The occurrence of ultrafiltration(UF)membrane fouling frequently hampers the sustainable advancement of UF technology.Reactive self-cleaning UF membranes can effectively alleviate the problem of membrane fouling.Never... The occurrence of ultrafiltration(UF)membrane fouling frequently hampers the sustainable advancement of UF technology.Reactive self-cleaning UF membranes can effectively alleviate the problem of membrane fouling.Nevertheless,the self-cleaning process may accelerate membrane aging.Addressing these concerns,we present an innovative design concept for composite self-healing materials based on self-cleaning UF membranes.To begin,TiO_(2)nanoparticles were incorporated into the polymer molecular structure via molecular design,resulting in the synthesis of TiO_(2)/carboxyl-polyether sulfone(PES)hybrid materials.Subsequently,the nonsolvent-induced phase inversion technique was employed to prepare a novel of UF membrane.Lastly,a polyvinyl alcohol(PVA)hydrogel coating was applied to the hybrid UF membrane surface to create PVA@TiO_(2)/carboxyl-PES self-healing reactive UF membranes.By establishing a covalent bond,the TiO_(2)nanoparticles were effectively and uniformly dispersed within the UF membrane,leading to exceptional self-cleaning properties.Furthermore,the water-absorbing and swelling properties of PVA hydrogel,along with its capacity to form hydrogen bonds with water molecules,resulted in UF membranes with improved hydrophilicity and active self-healing abilities.The results demonstrated that the water contact angle of PVA@5%TiO_(2)/carboxyl-PES UF membrane was 43.1°.Following a 1-h exposure to simulated solar exposure,the water flux recovery ratio increased from 48.16%to 81.03%.Moreover,even after undergoing five cycles of 12-h simulated sunlight exposure,the UF membranes exhibited a consistent retention rate of over 97%,thus fully demonstrating their exceptional self-cleaning,antifouling,and selfhealing capabilities.We anticipate that the self-healing reactive UF membrane system will serve as a pioneering and comprehensive solution for the self-cleaning antifouling challenges encountered in UF membranes while also effectively mitigating the aging effects of reactive UF membranes. 展开更多
关键词 Ultrafiltration membrane SELF-CLEANING SELF-HEALING Poly(aryl ether sulfone)
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Regulating interfacial behavior of zinc metal anode via metal-organic framework functionalized separator
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作者 Ruotong Li Liang Pan +6 位作者 Ziyu Peng Ningning Zhao Zekun Zhang Jing Zhu Lei Dai Ling Wang Zhangxing He 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期213-220,I0006,共9页
Aqueous zinc ion batteries(AZIBs)are one of the promising energy storage devices.However,uncontrolled dendrite and side reactions have seriously hindered its further application.In this study,the metal-organic framewo... Aqueous zinc ion batteries(AZIBs)are one of the promising energy storage devices.However,uncontrolled dendrite and side reactions have seriously hindered its further application.In this study,the metal-organic framework(MOF)functionalized glass fiber separator(GF-PFC-31)was used to regulate interfacial behavior of zinc metal anode,enabling the development of high-performance AZIBs.In PFC-31,there areπ-πinteractions between two adjacent benzene rings with a spacing of 3.199 A.This spacing can block the passage of[Zn(H_(2)O)_6]^(2+)(8.6 A in diameter)through the GF-PFC-31 separator to a certain extent,which promotes the deposition process of Zn ions.In addition,the sulfonic acid group(-S03H)contained in GF-PFC-31 can form a hydrogen bonding network with H_(2)O,which can provide a desolvation effect and reduce the side reaction.Consequently,GF-PFC-31 separator achieves uniform deposition of Zn ions.The Zn‖GF-PFC-31‖Zn symmetric cell exhibits stable cycle life(3000 h at 1.2 mA cm^(-2),2000 h at 0.3 mA cm^(-2),and 2000 h at 5.0 mA cm^(-2)),and Zn‖GF-PFC-31‖MnO_(2) full cell with GF-PFC-31 separator can cycle for 1000 cycles at 1.2 A g^(-1)with capacity retention rate of 82.5%.This work provides a promising method to achieve high-performance AZIBs. 展开更多
关键词 Aqueous zinc ion batteries Interfacial behavior Metal-organic framework Sulfonic acid group SEPARATOR
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Probing the Efficiency of PPMG-Based Composite Electrolytes for Applications of Proton Exchange Membrane Fuel Cell
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作者 Shakeel Ahmed Faizah Altaf +6 位作者 Safyan Akram Khan Sumaira Manzoor Aziz Ahmad Muhammad Mansha Shahid Ali Ata-ur-Rehman Karl Jacob 《Transactions of Tianjin University》 EI CAS 2024年第3期262-283,共22页
PPMG-based composite electrolytes were fabricated via the solution method using the polyvinyl alcohol and polyvinylpyrrolidone blend reinforced with various contents of sulfonated inorganic filler.Sulfuric acid was em... PPMG-based composite electrolytes were fabricated via the solution method using the polyvinyl alcohol and polyvinylpyrrolidone blend reinforced with various contents of sulfonated inorganic filler.Sulfuric acid was employed as the sulfonating agent to functionalize the external surface of the inorganic filler,i.e.,graphene oxide.The proton conductivities of the newly prepared proton exchange membranes(PEMs)were increased by increasing the temperature and content of sulfonated graphene oxide(SGO),i.e.,ranging from 0.025 S/cm to 0.060 S/cm.The induction of the optimum level of SGO is determined to be an excellent route to enhance ionic conductivity.The single-cell performance test was conducted by sandwiching the newly prepared PEMs between an anode(0.2 mg/cm^(2) Pt/Ru)and a cathode(0.2 mg/cm^(2) Pt)to prepare membrane electrode assemblies,followed by hot pressing under a pressure of approximately 100 kg/cm^(2) at 60℃for 5–10 min.The highest power densities achieved with PPMG PEMs were 14.9 and 35.60 mW/cm^(2) at 25℃and 70℃,respectively,at ambient pressure with 100%relative humidity.Results showed that the newly prepared PEMs exhibit good electrochemical performance.The results indicated that the prepared composite membrane with 6 wt%filler can be used as an alternative membrane for applications of high-performance proton exchange membrane fuel cell. 展开更多
关键词 Proton exchange membrane fuel cell Sulfonated graphene oxide POLYVINYLPYRROLIDONE Solution casting Membrane electrode assembly Fuel cell performance
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Facile identification of fluorosurfactant category in aqueous film-forming foam concentrates via optimized^(19)F NMR
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作者 Peiyao Chen Shuang Zhuang +5 位作者 Weiguang Chen Zhijian Chen Rongzhen Li Fangyu Chen Tingting Jiang Xiaobin Fu 《Magnetic Resonance Letters》 2024年第3期42-51,共10页
Aqueous film-forming foams(AFFFs)are the primary source of toxic perfluoroalkyl and polyfluoroalkyl substances(PFAS)in wastewater.Thus,it is urgent to develop a facile and fast method for identifying fluorosurfactants... Aqueous film-forming foams(AFFFs)are the primary source of toxic perfluoroalkyl and polyfluoroalkyl substances(PFAS)in wastewater.Thus,it is urgent to develop a facile and fast method for identifying fluorosurfactants in commercially available AFFFs.In this work,fluorine nuclear magnetic resonance(^(19)F NMR)spectroscopy was optimized to measure AFFFs directly with the extra addition of 5%D_(2)O as the locking reagent,and high-quality spectra could be acquired within 4 min(0.1%fluorosurfactant content).Recovery experiments demonstrated that the use of different AFFFs had no marked influence on the quantitative analysis of fluorosurfactants.Such method works with low-field NMR spectroscopy(1.4 T)as well.Two-dimensional(2D)^(19)F COSY NMR was used to make signal assignments for different fluorosurfactant derivatives.The optimized ^(19)F NMR could quantify the commercially available fluorosurfactants in different AFFFs,identify them being in either the perfluorooctane sulfonate(PFOS)or fluorotelomer sulfonic acid(FTS)categories,and distinguish the head-group of PFOS and FTS derivatives,which exhibits great potentials in the developments of relevant commercial detections. 展开更多
关键词 Aqueous film-forming foams FLUOROSURFACTANTS 19F NMR Perfluorooctane sulfonate
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