The V 2O 5 sol was fabricated by ultra fast quenching.The vanadium with low valence (V 4+ ) was found in V 2O 5 xerogel films by XPS analysis.The technology of oxygen top blown was applied to analyze the XPS...The V 2O 5 sol was fabricated by ultra fast quenching.The vanadium with low valence (V 4+ ) was found in V 2O 5 xerogel films by XPS analysis.The technology of oxygen top blown was applied to analyze the XPS spectrum difference of V 2O 5 xerogel when the powder of V 2O 5 was melting in air or in oxygen atmosphere.The results show that the different melting atmosphere has certain influences on the chemical valence of V 2O 5 xerogel.展开更多
The nanocomposite films were prepared by poly(ethylene oxide), PEO, intercalation in V2O5 xero-gel in sol-gel. The synthesis and state of the films are investigated by the XRD, IR, SEM, etc. The results show that V2O5...The nanocomposite films were prepared by poly(ethylene oxide), PEO, intercalation in V2O5 xero-gel in sol-gel. The synthesis and state of the films are investigated by the XRD, IR, SEM, etc. The results show that V2O5, xerogel is a layered structure which arranges in c-direction. The mterlayer distance of V2O5 xerogel increases remarkably when PEO is intercalated in V2O5 xero-gel interlayer. PEO has strong interaction with V2O5 host. The surface of the films is homogeneous without holes and cracks.展开更多
文摘The V 2O 5 sol was fabricated by ultra fast quenching.The vanadium with low valence (V 4+ ) was found in V 2O 5 xerogel films by XPS analysis.The technology of oxygen top blown was applied to analyze the XPS spectrum difference of V 2O 5 xerogel when the powder of V 2O 5 was melting in air or in oxygen atmosphere.The results show that the different melting atmosphere has certain influences on the chemical valence of V 2O 5 xerogel.
基金This project was supported by National Natural Science Foundation of China (Grant No.59802009 ) and Hubei Province Natural Science Foundation(Grant No. 99J053).
文摘The nanocomposite films were prepared by poly(ethylene oxide), PEO, intercalation in V2O5 xero-gel in sol-gel. The synthesis and state of the films are investigated by the XRD, IR, SEM, etc. The results show that V2O5, xerogel is a layered structure which arranges in c-direction. The mterlayer distance of V2O5 xerogel increases remarkably when PEO is intercalated in V2O5 xero-gel interlayer. PEO has strong interaction with V2O5 host. The surface of the films is homogeneous without holes and cracks.
