Data Analysis of Chang'E-1 Gamma-Ray Spectrometer and Global Distribution of U,K,and Th Elemental Abundances

Gamma-ray spectrometer （GRS） is one of the main payloads on the Chang＇E-1 （CE-1） lunar probe, mainly aimed to detect the elemental abundances and distributions on the lunar surface. At 03：58 on 28 November 2007, it performed the first observation of the lunar gamma rays. As of 24 October 2008, 2105 h of effective gamma rays spectra had been acquired by CE-1 GRS, which covers the whole surface of the moon. This paper mainly describes the data processing procedures and methods of deriving the elemental abundances by using the CE-1 GRS time series corrected spectra： first, to bin data into pixels for mapping; then, to perform a background deduction of the cumulative spectra and obtain a peak area of the elements; and finally, to use the elemental abundances inversion model to produce the elemental abundances. Based on these processing methods, the global abundance maps of U, K, and Th at a 5°×5° equal-area pixel are acquired by CE-1 GRS data. The paper gives a preliminary analysis of the uncertainties of the elemental abundances.

Chemical abundances of three new Ba stars from the Keck/HIRES spectra

Based on high resolution,high signal-to-noise(S/N)ratio spectra from Keck/HIRES,we have determined abundances of 20 elements for 18 Ba candidates.The parameter space of these stars is in the range of 4880≤Teff≤6050 K,2.56≤log g≤4.53 dex and-0.27≤[Fe/H]≤0.09 dex.It is found that four of them can be identified as Ba stars with[s/Fe]>0.25 dex(s:Sr,Y,Zr,Ba,La,Ce and Nd),and three of them are newly discovered,which include two Ba giants(HD 16178 and HD 22233)and one Ba subgiant(HD 2946).Our results show that the abundances ofα,odd and iron-peak elements(O,Na,Mg,Al,Si,Ca,Sc,Ti,Mn,Ni and Cu)for our program stars are similar to those of the thin disk,while the distribution of[hs/ls](hs:Ba,La,Ce and Nd,ls:Sr,Y and Zr)ratios of our Ba stars is similar to those of the known Ba objects.None of the four Ba stars show clear enhancement in carbon including the known CH subgiant HD 4395.It is found that three of the Ba stars present clear evidence of hosting stellar or sub-stellar companions from the radial velocity data.

Influence of Thermal Radiation on Hot Cluster Decay Rates and Abundances

The influence of radiative cooling on the unimolecular decay rates of free, hot clusters and molecules with unspecified excitation energies is quantified. Two different regimes, dedined by the magnitude of the energy of the photons emitted, are identified and the boundary between them is given. The boundary is determined in terms of the photon emission rate constants and thermal properties of the particles. Also the abundance spectra are calculated for the continuous cooling case, corresponding to small photon energies. The two regimes correspond to continuous cooling and single photon quenching of the unimolecular decay. The radiative effect can be parametrized by a redefinition of the time each individual cluster has available to undergo evaporation, expressed by an effective radiative time constant.

Influence of the convective mixing-length parameterαon the chemical abundances in the case of metal-poor giant HD 122563

One-dimensional(1 D)model atmospheres are still the most commonly used tool for the determination of stellar chemical composition.Convection in the model is usually treated by mixing-length theory(MLT).The mixing-length parameterαis generally calibrated from the Sun and applied to all other stars.The metal-poor giant,HD 122563,is an important benchmark star to test stellar atmosphere and interior physics.We investigate the influence of the convection mixing-length parameterαon the determination of chemical abundances of Na,Mg,Al,Si,Ca,Sc,Ti,Cr,Mn,Co,Ni,Sr,Y,Zr and Ba in the case of HD 122563,taking advantage of a high resolution and high signal-to-noise ratio HARPS spectrum.The abundance discrepanciesΔ[X/H]that occur due toαvariation rarely exceed 0.05 dex and most are less than 0.03 dex.We calculate the discrepancyΔ[X/H]using a line-by-line differential analysis.The abundance discrepancies do not have direct relation with either line strength or the excitation potential.For 1 D stellar atmospheric analysis of HD 122563,the accuracy of abundance determination does not strongly depend on the choice of mixing-length parameterα(causing average discrepancies of<0.03 dex),while the uncertainties in the effective temperature and surface gravity play a more important role.

Estimation of ages and masses via carbon and nitrogen abundances for 556 007 giants from LAMOST

Estimating ages for a large number of giants is of great importance for studying Galactic evolution.In this work,we determine stellar ages and masses for 556007 giants from LAMOST Data Release 5(DR5)with empirical relations estimated from chemical[C/N]abundance ratios.Our sample reveals the two wellknown sequences in the age-[α/M]relation.The high-αsequence is composed of stars older than 8 Gyr and low-αsequence is composed of stars with age ranging from 0 Gyr to 13.8 Gyr.Our sample also shows a flat age-[M/H]relation up until 12 Gyr.We compare these distributions with Galactic Chemical Evolution models for reference.When looking at the spatial distribution of stars in 2 Gyr age bins,we find that young stars are concentrated towards the Galactic plane and older stars extend to higher height above and below the disk.We find a smooth transition of median Galactic height for different age bins,which suggests a strong age-dependence on Galactic scale height.

p-capture reaction cycles in rotating massive stars and their impact on elemental abundances in globular cluster stars: A case study of O, Na and Al

Elemental abundance patterns of globular cluster stars can provide important clues for understanding cluster formation and early chemical evolution.The origin of the abundance patterns,however,still remains poorly understood.We have studied the impact of p-capture reaction cycles on the abundances of oxygen,sodium and aluminium considering nuclear reaction cycles of carbon-nitrogenoxygen-fluorine,neon-sodium and magnesium-aluminium in massive stars in stellar conditions of temperature range 2×107to 10×107K and typical density of 102gm cc-1.We have estimated abundances of oxygen,sodium and aluminium with respect to Fe,which are then assumed to be ejected from those stars because of rotation reaching a critical limit.These ejected abundances of elements are then compared with their counterparts that have been observed in some metal-poor evolved stars,mainly giants and red giants,of globular clusters M3,M4,M13 and NGC 6752.We observe an excellent agreement with[O/Fe]between the estimated and observed abundance values for globular clusters M3 and M4 with a correlation coefficient above 0.9 and a strong linear correlation for the remaining two clusters with a correlation coefficient above 0.7.The estimated[Na/Fe]is found to have a correlation coefficient above 0.7,thus implying a strong correlation for all four globular clusters.As far as[Al/Fe]is concerned,it also shows a strong correlation between the estimated abundance and the observed abundance for globular clusters M13 and NGC 6752,since here also the correlation coefficient is above 0.7 whereas for globular cluster M4 there is a moderate correlation found with a correlation coefficient above 0.6.Possible sources of these discrepancies are discussed.

Sodium Abundances in Very Metal-poor Stars

Chemical composition of very metal-poor(VMP)stars can provide observational constraints on current models of nucleosynthesis and the chemical evolution of the Galaxy.It has been found that the scatter of[Na/Fe]versus[Fe/H]in VMP stars is very large in contrast with most other elements.Moreover,a negative slope in[Na/Fe]versus[Fe/H]was found for giants,which is very unlikely according to the theory of nucleosynthesis.For the sample of93 VMP stars in the metallicity range-4.25<[Fe/H]<-1.64 we obtained NLTE sodium abundances using the line profile fitting method by employing accurate atmospheric parameters determined when taking into account NLTE line formation for both FeⅠand FeⅡ.Originally selected from the LAMOST low-resolution spectral database,the spectra of stars were obtained with the High Dispersion Spectrograph of the Subaru Telescope.For 57turn-off stars in metallicity domain-3.04<[Fe/H]<-1.64,we obtained mean[Na/Fe]=-0.29±0.14 and positive slope 0.09±0.06.For 21 giants distributed over metallicity-3.59<[Fe/H]<-2.19,we found mean[Na/Fe]=-0.35±0.1 and positive slope 0.07±0.07.Our[Na/Fe]trend is lower by~0.2 dex,compared to the modern GCE model.We believe the GCE model should be adjusted,by considering the associated scatter.Twelve stars in our sample are found to be outliers,with too low or too high Na abundances.

Temperature Fluctuations in Photoionized Nebulae in Case of Oxygen and Nitrogen Abundances

We present the dependence of electron temperature fluctuations of O++ and H+ by the chemical abundances of oxygen and nitrogen. Models assume that hydrogen density is uniform in one case and non uniform in the second case, which vary with the distance from the central star. The abundances of oxygen and nitrogen change by scale factor 5 and 1/5. Our analysis suggests that temperature fluctuations are consistent with photoionization. Using the cloudy photoionization code, we found a reasonable close agreement of the computed value with the one that was done before this work. Our simulation also shows that how change of abundances affects temperature fluctuations and its value is less than 0.01.

Abundances of 23 field RR Lyrae stars

We present stellar parameters and abundances of 15 elements （Na, Mg, A1, Si, Ca, Sc, Ti, V, Cr, Mn, Fe, Ni, Cu, Y and Ba） for 23 field RR Lyrae variables based on high-resolution （R ~ 60 000） and high signal-to-noise （S/N~ 200） spectra obtained using the High Dispersion Spectrograph on the Subaru Telescope. Six stars in the sample have more than one spectrum observed at different pulsation phases. The derived abundance ratios of [X/Fe] for 14 elements （except for Ba） do not vary during the pulsation cycle. An interesting curve of [Ba/Fe] versus phase is detected for the first time and it shows decreasing [Ba/Fe] with increasing temperature at a given metallicity. Combining with data in the literature, abundances of most RR Lyrae stars as a function of [Fe/H] follow the same trends as those of dwarf stars, but [Sc/Fe] and [Y/Fe] ratios of RR Lyrae stars at solar metallicity are lower than those of dwarf stars. The kinematics of RR Lyrae stars indicate that three comparatively metal-rich RR Lyrae stars might originate from the thick disk and they show higher [a/Fe] ratios than RR Lyrae stars with thin disk kinematics. Among 23 RR Lyrae stars, two special objects are found with abnormal abundances; TV Lib has high [a/Fe], [Sc/Fe], [Y/Fe] and [Ba/Fe] ratios while TW Her has solar [a/Fe] but significantly lower [Sc/Fe], [Y/Fe] and [Ba/Fe] ratios as compared with other RR Lyrae stars.

REGIONAL ELEMENT ABUNDANCES OFCONTINENTAL CRUSTOBODIES IN CHINA

The continental crustobody of China is composed of three regional crustobodies, i. e., the Cathaysian crustobody, the West China crustobody and the South Tibet crustobody. This paper gives their mass models and element abundance values and discusses their regional abundance characteristics from metallogenic elernents, heat source elements and lanthanide elements. The conclusion is that their geochemical backgrounds are quite different from each other.

Mineral abundances and different levels of alteration around Mawrth Vallis,Mars

Spectral indices from OMEGA hyperspectral data show that there are two main phyllosilicates exposed in and around Mawrth Vallis:Al phyllosilicates and Fe/Mg phyllosilicates.Detailed analysis of CRISM spectra shows that Al phyllosilicates such as montmorillonite,hydrated silica,kaolinite;Fe/Mg phyllosilicates such as nontronite,saponite,serpentine are widespread on the light-toned outcrops.Though similar stratigraphical sequences,morphologies and textures are observed on both sides of Mawrth Vallis from HiRISE images,suggesting that the geological processes that formed these units must have operated at a regional scale;the multiple endmember spectral mixture analysis(MESMA) derived mineral abundance indicates that there is a higher level of alteration in the western side relative to the eastern side.We suggest that the observed phyllosilicates,stratigraphical sequences and different levels of alteration might have been caused by sedimentary deposition processes in which the composition of the external source sediment or the local solution was different,or by a pedogenic process closely related to the leaching of abundant liquid water with different chemical properties.

High-level theoretical study of the evolution of abundances and interconversion of glycine conformers

The relative conformer energies of glycine are evaluated by using a focal point analysis expressed as（HF→MP2→MP3→CCSD→CCSD（T））.The conformer abundances at various temperatures（298–500 K） are calculated based on the relative energies and Boltzmann statistical thermostatistical analysis with and without considering internal hindered rotations.A comparison between the available Raman spectrum and the electron momentum spectrum confirms that the influence of rigid-rotor hindered rotation on the conformational proportions of glycine is considerable,especially for the IIIp structure.The conformational interconversions are discussed.It is found that with increasing temperature,the mole fraction of IIn keeps constant and Ip structure can convert into IVn and IIIp,leading to the decrease in the weight of Ip and the increase in the weights of IVn and IIIp conformers,which is in accordance with experimental observations.

Differentiation of Four Pairs of Isomers by Comparing Their Relative Abundances of Fragment Ions

Based on the LC-ESI/MSn technique, the four pairs of isomers of psoralen and isopsoralen, imperatorin and isoimperatorin, neohesperidin and hesperidin, naringin and narirutin were distinguished mainly by comparison of the relative abundances of their major fragment ions. Because of the effect of the hydrogen on the C8 of psoralen, the intensity of the fragment ion formed by the loss of CO2 was relatively increased. By comparing the abundance of the product ions formed by the loss of CO and 2CO, the isomers of psoralen and isopsoralen could be distinguished. This method can also be used to distinguish the isomers of imperatorin and isoimperatorin. Because of the different con- nected position between glucose and rhamnose, in the mass spectrum of neohesperidin, the relative abundances of ions at m/z 489 and 343 generated by the ring-cross cleavage of glycan were more than 10%, while in the mass spec- trum of hesperidin, they were all less than 1%. This approach can also be used to distinguish the isomers ofnaringin and narirutin. Although the fragmentation pathways were similar, according to the tiny difference of structure, the change of relative intensity of main fragment ions could be observed and it could be used to distinguish some isomers more accurately and quickly.

Origin of the Dashuigou Independent Tellurium Deposit at the Southeastern Qinghai-Tibet Plateau:Based on the Abundances of Trace Elements in the Country Rocks

Through a detailed study of the abundances and spatial-temporal distribution patterns of Te,Bi,As,Se,Cu,Pb,Zn,Au,and Ag in the rock types of different geological epochs in the Dashuigou independent tellurium deposit,and in combination with other research findings of previous researchers in this area,the authors conclude as follows:Abundances of the main ore-forming elements Te,Bi,As,Se,Au,and Ag are not high in the regional geological background,generally lower or close to their respective crustal Clark values,but almost all altered country rocks contain high levels of ore-forming elements.This indicates that the deposit’s ore-forming elements do not come from the country rocks.This also indicates that the geological thermal events that cause alteration and mineralization originate from depths and may be related to mantle plumes.Considering the distribution pattern of these ore-forming elements in the ore bodies’hanging wall and footwall,the metallogenic mechanism may be as follows:Mineralization is not achieved through lateral secretion in the horizontal or near horizontal direction,but rather through the upward movement and emplacement of deep ore-forming elements driven by geological processes such as mantle plumes.In addition,the migration of deep ore-forming elements is not achieved through dispersed infiltration between overlying rock particles,but through non widespread concentrated penetrating channels.This type of channel is likely to be the expansion structures where faults from different directions intersect,or where linear faults intersect with circular structures.

Stable isotope labelled mass spectrometry for quantification of the relative abundances for expressed proteins induced by PeaT1

The protein elicitor from the mycelium of Alternaria tenuissima has been isolated.The elicitor triggered resistance to the tobacco mosaic virus in tobacco by inducing relative oxygen species,but without causing hypersensitive necrosis.The elicitor is reported to impart resistance against Verticillium dahliae and to increase yield in cotton,but its mechanism is not yet clear.In this study,the stable isotope labelled mass spectrometry method was used to quantify the relative abundances of protein expression induced by PeaT1 in Arabidopsis.A significant difference in the relative abundances for the expression of different proteins related to metabolism,modification,regulatory,defense,stress and antioxidation was found in Arabidopsis.

Neuropeptide cholecystokinin:a key neuromodulator for hippocampal functions

Spatial memory is crucial for survival within external surroundings and wild environments.The hippocampus,a critical hub for spatial learning and memory formation,has received extensive investigations on how neuromodulators shape its functions(Teixeira et al.,2018;Zhang et al.,2024).However,the landscape of neuromodulations in the hippocampal system remains poorly understood because most studies focus on classical monoamine neuromodulators,such as acetylcholine,serotonin,dopamine,and noradrenaline.The neuropeptides,comprising the most abundant neuromodulators in the central nervous system,play a pivotal role in neural information processing in the hippocampal system.Cholecystokinin(CCK),one of the most abundant neuropeptides,has been implicated in regulating various physiological and neurobiological statuses(Chen et al.,2019).CCK-A receptor(CCK-AR)and CCK-B receptors(CCK-BR)are two key receptors mediating the biological functions of CCK,both of which belong to class-A sevenfold transmembrane G protein-coupled receptors(Nishimura et al.,2015).CCK-AR preferentially reacts to sulfated CCK,whereas CCK-BR binds both CCK and gastrin with similar affinities(Ding et al.,2022).The expression patterns of CCK-AR and CCK-BR are distinct,implying that CCK has various functions in target regions.For instance,CCK-AR is widely expressed in the GI and brain subregions and is hence implicated in the control of digestive function and satiety regulation.Conversely,CCK-BR is abundantly and widely distributed in the central nervous system,which majorly regulates anxiety,learning,and memory(Ding et al.,2022).However,the roles of endogenous CCK and CCK receptors in regulating hippocampal function at electrophysiological and behavioral levels have received less attention.

Noble gas abundances and isotopic compositions in mantle-derived xenoliths,NE China

Following the researches of helium isotopic compositions in mantle-derived xenoliths in eastern China, this study reported noble gas abundances and isotopic compositions of mantle-derived xenoliths from Kuandian of Liaoning Province, Huinan of Jilin Province and Hannuoba of Hebei Province. Compared with the middle ocean ridge basalt (MORB) and other continental areas, mantle-derived xenoliths in NE China are characterized by slightly low noble gas abundances, 3He/4He equivalent to or lower than that of MORB, 40Ar/36Ar lower than that of MORB, 38Ar/36Ar and Ne-Kr-Xe isotopic ratios equivalent to those of atmosphere. These results indicate the heterogeneity of subcontinental lithospheric mantle beneath northeastern China, that is, a MORB reservoir-like mantle beneath Kuandian and an enriched/metasomatized mantle beneath Huinan. Low 40Ar/ 36Ar ratios in the three studied areas may imply that a subducted atmospheric component has been preserved in the subcontinental lithospheric mantle.

Molecular Oxygen Abundance in Galactic Massive Star Formation Regions Based on SWAS Observations

Molecular oxygen abundance is a key parameter in understanding the chemical network of the interstellar medium.We estimate the molecular oxygen column density and abundance for a sample of Galactic massive star formation regions based on observations from the Submillimiter Wave Astronomy Satellite(SWAS)survey.We obtained an averaged O_(2)spectrum based on this sample using the(SWAS)survey data(O_(2),487.249 GHz,N=3-1,J=3-2).No emission or absorption feature is seen around the supposed central velocity with a total integration time of t_(total)=8.67×10^(3)hr and an rms noise per channel of 1.45 m K.Assuming a kinetic temperature T_(kin)=30 K,we derive the 3σupper limit of the O_(2)column density to be 3.3×10^(15)cm^(-2),close to the lowest values reported in Galactic massive star formation regions in previous studies.The corresponding O_(2)abundance upper limit is6.7×10^(-8),lower than all previous results based on SWAS observations and is close to the lowest reported value in massive star formation regions.On a galactic scale,our statistical results confirm a generally low O_(2)abundance for Galactic massive star formation regions.This abundance is also lower than results reported in extragalactic sources.

ARE THE ABUNDANCES OF ELEMENTS IN THE SOLAR SYSTEM ABNORMAL?

In recent two years, it has been discovered by sattilite ISEE-3 that the abundances of chemical elements in cosmic rays are remarkablydifferent from that in the solar system. In cosmic rays the contents of some neutron-rich

Abundances of heavy elements in ultra-metal-poor star CS 22892-052

Based on the heavy element nucleosynthesis theory, with the solar heavy-nuclide abundances and the observed abundances of three elements which are the representatives of the individul neutron-capture processes, a method to determine the relative contributions from the individul neutron-capture processes to the abundances of heavy elements in metal-poor stars is applied. With this method, the abundances of heavy elements in ultra-metal-poor star CS 22892-052 are calculated. It is found that the observed abundances of heavy elements in this star are well matched by our calculations in error limits, except for thorium.