Effects of air-sea coupling on the eastward propagating boreal winter intraseasonal oscillation over the tropical Indian Ocean

The effects of air-sea coupling over the tropical Indian Ocean（TIO） on the eastward propagating boreal winter intraseasonal oscillation（MJO） are investigated by comparing a fully coupled and a partially decoupled Indian Ocean experiment using the SINTEX-F coupled model.Air-sea coupling over the TIO significantly enhances the intensity of the eastward propagations of the MJO along the5°-10°S zonal areas.The zonal asymmetry of the SST anomaly（SSTA） is responsible for the enhanced eastward propagation.A positive SSTA appears to the east of the MJO convection,which results in the boundary layer moisture convergence and positively feeds back to the MJO convection.In addition,the air-sea interaction effect on the eastward propagation of the MJO is related to the interannual variations of the TIO.Air-sea coupling enhances（reduces） the eastward-propagating spectrum during the negative Indian Ocean dipole mode and positive Indian Ocean basin mode.Such phase dependence is attributed to the role of the background mean westerly in affecting the wind-evaporation-SST feedback.Air-sea coupling（decoupling） enhances（reduces） the zonal asymmetry of the low-level specific humidity,and thus the eastward propagation spectrum of the MJO.

Importance of Air-Sea Coupling in Simulating Tropical Cyclone Intensity at Landfall

An atmosphere-only model system for making seasonal prediction and projecting future intensities of landfalling tropical cyclones(TCs)along the South China coast is upgraded by including ocean and wave models.A total of 642 TCs have been re-simulated using the new system to produce a climatology of TC intensity in the South China Sea.Detailed comparisons of the simulations from the atmosphere-only and the fully coupled systems reveal that the inclusion of the additional ocean and wave models enable differential sea surface temperature responses to various TC characteristics such as translational speed and size.In particular,interaction with the ocean does not necessarily imply a weakening of the TC,with the coastal bathymetry possibly playing a role in causing a near-shore intensification of the TC.These results suggest that to simulate the evolution of TC structure more accurately,it is essential to use an air-sea coupled model instead of an atmosphere-only model.

The influences of environmental factors on the air-sea coupling coefficient

The response relationship between equivalent neutral wind speed anomaly(ENWSA)and sea-air temperature difference anomaly(SATDA)has been analyzed over four typical sea regions,i.e.,the Kuroshio Extension,the Gulf Stream,the Brazil-Malvinas Confluence and the Agulhas Return Current.The results show that ENWSA is more sensitive to SATDA than sea surface temperature anomaly(SSTA),which implies that SATDA seems to be a more suitable parameter than SSTA to analyze the mesoscale air-sea interactions.Here,the slope of the linear relation between ENWSA and SATDA is defined as the air-sea coupling coefficient.It is found that the values of the coupling coefficient over the four typical sea areas have obvious seasonal variations and geographical differences.In order to reveal the reason of the seasonal variation and geographical difference of the coupling coefficient,the influences of some environmental background factors,such as the spatially averaged sea surface temperature(SST),the spatially averaged air temperature,the spatially averaged sea-air temperature difference and the spatially averaged equivalent neutral wind speed,on the coupling coefficient are discussed in detail.The results reveal that the background sea-air temperature difference is an important environmental factor which directly affects the magnitude of the coupling coefficients,meanwhile,the seasonal and geographical variations of the coupling coefficient.

A study on dynamical features of air-sea coupling waves in the tropics

The dynamical features of air-sea coupling waves and their stabilities in a simple coupled air-sea model in the tropics have been studied with respect to interaction occurring among different types of the free waves in the o-cean and in the atmosphere. It is pointed out that there exist a stable and an unstable air-sea interaction modes in the tropical coupled system , respectively. The propagation of the unstable mode relies greatly on the zonal space scale, i. e. only for wave length ranging from 5 000 km to 10 000 km can the disturbance unstably move slowly eastward. The waves that slowly propagate unstably eastward agree well with the observational facts. Finally,it is also proposed that the interaction between Kelvin wave in one medium and Rossby wave in another medium is a necessary condition for the occurrence of destabilization of the coupled air-sea system in the tropics.

AIR-SEA COUPLING MODES OF TROPICAL PACIFIC SSTA AND WIND STRESS FIELDS

The EOF thechnique is employed to investigate the characteristic modes of spatial distribution and features of temporal variation in the context of 1970-1989 wind stress and SSTA datasets over the tropical Pacific. Results show similar variation in the time coefficients of the first eigenvectors for the wind stress and SSTA fields, revealing air-sea interaction and coupling at the multiple space/time scales,which are in fairly good correspondence to the E1 Nino cycle.

Defects‑Rich Heterostructures Trigger Strong Polarization Coupling in Sulfides/Carbon Composites with Robust Electromagnetic Wave Absorption

Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.

Response of IAP/LASG GOALS Model to the Coupling of Air-Sea Fresh Water Exchange

The process of air—sea fresh water exchange is included successfully in the Global— Ocean—Atmosphere Land—System model developed at the State Key Laboratory of Atmospheric Sciences and Geophysical Fluid Dynamics (LASG). The results of the coupled integration show that the climate drift has been controlled successfully. Analyses on the responses of ocean circulation to the changes of surface fresh water or salinity forcing show that the ocean spin-up stage under flux condition for salinity is the key to the implementation of air-sea fresh water flux coupling. This study also demonstrates that the Modified—Monthly—Flux—Anomaly coupling scheme (MMFA) brought forward by Yu and Zhang (1998) is suitable not only for daily air—sea heat flux coupling but also for daily fresh water flux coupling. Key words Fresh water flux - Air-sea coupling - Thermohaline circulation This work was co-supported by the National Key Project (Grant No.96-908-02-03), the Excellent National Key Laboratory Research Project (Grant No.49823002) and Chinese Academy of Sciences (CAS) under grant “ Bai Ren Ji Hua? for “Validation of Coupled Climate Models”.

Impacts of boundary layer parameterization schemes and air-sea coupling on WRF simulation of the East Asian summer monsoon

The planetary boundary layer （PBL） scheme in the regional climate model （RCM） has a significant impact on the interactions and exchanges of moisture, momentum, and energy between land, ocean, and atmosphere; however, its uncertainty will cause large systematic biases of RCM. Based on the four different PBL schemes （YSU, ACM2, Boulac, and MYJ） in Weather Research and Forecasting （WRF） model, the impacts of these schemes on the simulation of circulation and precipitation during the East Asian summer monsoon （EASM） are investigated. The simulated results of the two local turbulent kinetic energy （TKE） schemes, Boulac and MYJ, are more consistent with the observations than those in the two nonlocal closure schemes, YSU and ACM2. The former simulate more reasonable low-level southwesterly flow over East China and west pacific subtropical high （WPSH） than the latter. As to the modeling of summer monsoon precipitation, both the spatial distributions and temporal evolutions from Boulac and MTT are also better than those in YSU and ACM2 schemes. In addition, through the comparison between YSU and Boulac experiments, the differences from the results of EASM simulation are more obvious over the oceanic area. In the experiments with the nonlocal schemes YSU and ACM2, the boundary layer mixing processes are much stronger, which lead to produce more sea surface latent heat flux and enhanced convection, and finally induce the overestimated precipitation and corresponding deviation of monsoon circulation. With the further study, it is found that the absence of air-sea interaction in WRF may amplify the biases caused by PBL scheme over the ocean. Consequently, there is a reduced latent heat flux over the sea surface and even more reasonable EASM simulation, if an ocean model coupled into WRF.

Time-Dependent Solutions to the Fokker-Planck Equation of Maximum Reduced Air-Sea Coupling Climate Model

The time-dependent solution of reduced air-sea coupling stochastic-dynamicmodel is accurately obtained by using the Fokker-Planck equation and the quantum mechanical method.The analysis of the time-dependent solution suggests that when the climate system is in the groundstate, the behavior of the system appears to be a Brownian movement, thus reasoning the foothold ofHasselmann's stochastic climatic model; when the system is in the first excitation state, the motionof the system exhibits a form of time-decaying, or under certain condition a periodic oscillationwith the main period being 2.3 yr. At last, the results are used to discuss the impact of thedoubling of carbon dioxide on climate.

AIR-SEA COUPLING FEATURES FROM THE WARM PHASE TO THE COLD PHASE OF ENSO CYCLES IN THE SEVENTIES TO THE EIGHTIES

Using the sea surface temperature and wind anomalies(SSTA and SSWA for short)of the tropical Pacific from January 1970 to December 1989,main spatial patterns of tropical Pacific SSTA and SSWA coupling features in the transform course from the warm phase to the cold phase of El Nino-southern Oscillation(ENSO)cycles are discussed. The main conclusions are as follows:(1)air-sea coupling patterns at the mature stage of El Nino(La Nina)are main spatial ones of tropical Pacific SSWA and SSTA coupling:(2)at the mature stage of El Nino,the interaction of the anticyclonic anomaly wind,generated by the forcing of distinct meridional SSTA gradient in the Northern Hemisphere tropical central Pacific.with the California cold current and SSTA is mainly responsible for weakening of El Nino;(3)the second sea temperature increase along the South American coast in the decaying course of El Nino results from the eastward movement of the weakened positive SSTA in the tropical central-eastern Pacific forced by anomalous west wind stress:(4)La Nina results from the joint effect of Walker circulation,Ekman drift and negative SSTA in the tropical central-eastern Pacific.

Structurally Flexible 2D Spacer for Suppressing the Electron-Phonon Coupling Induced Non-Radiative Decay in Perovskite Solar Cells

This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker electron-phonon coupling in perovskite has been achieved by introducing the structurally soft cyclohexane methylamine(CMA^(+))cation,which could serve as a damper to alleviate the mechanical stress caused by lattice oscillations,compared to the rigid phenethyl methylamine(PEA^(+))analog.It demonstrates a significantly lower non-radiative recombination rate,even though the two types of bulky cations have similar chemical passivation effects on perovskite,which might be explained by the suppressed carrier capture process and improved lattice geometry relaxation.The resulting PSCs achieve an exceptional power conversion efficiency(PCE)of 25.5%with a record-high opencircuit voltage(V_(OC))of 1.20 V for narrow bandgap perovskite(FAPbI_(3)).The established correlations between electron-phonon coupling and non-radiative decay provide design and screening criteria for more effective passivators for highly efficient PSCs approaching the Shockley-Queisser limit.

Influence of water coupling coefficient on the blasting effect of red sandstone specimens

This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation in wall pressure of the blasting holes.Using DDNP explosive as the explosive load,blasting tests were conducted on red sandstone specimens with four different water coupling coefficients:1.20,1.33,1.50,and 2.00.The study examines the morphologies of the rock specimens after blasting under these different water coupling coefficients.Additionally,the fractal dimensions of the surface cracks resulting from the blasting were calculated to provide a quantitative evaluation of the extent of rock damage.CT scanning and 3D reconstruction were performed on the post-blasting specimens to visually depict the extent of damage and fractures within the rock.Additionally,the volume fractal dimension and damage degree of the post-blasting specimens are calculated.The findings are then combined with numerical simulation to facilitate auxiliary analysis.The results demonstrate that an increase in the water coupling coefficient leads to a reduction in the peak pressure on the hole wall and the crushing zone,enabling more of the explosion energy to be utilized for crack propagation following the explosion.The specimens exhibited distinct failure patterns,resulting in corresponding changes in fractal dimensions.The simulated pore wall pressure–time curve validated the derived theoretical results,whereas the stress cloud map and explosion energy-time curve demonstrated the buffering effect of the water medium.As the water coupling coefficient increases,the buffering effect of the water medium becomes increasingly prominent.

Strong coupling and catenary field enhancement in the hybrid plasmonic metamaterial cavity and TMDC monolayers

Strong coupling between resonantly matched surface plasmons of metals and excitons of quantum emitters results in the formation of new plasmon-exciton hybridized energy states.In plasmon-exciton strong coupling,plasmonic nanocavities play a significant role due to their ability to confine light in an ultrasmall volume.Additionally,two-dimensional transition metal dichalcogenides(TMDCs) have a significant exciton binding energy and remain stable at ambient conditions,making them an excellent alternative for investigating light-matter interactions.As a result,strong plasmon-exciton coupling has been reported by introducing a single metallic cavity.However,single nanoparticles have lower spatial confinement of electromagnetic fields and limited tunability to match the excitonic resonance.Here,we introduce the concept of catenary-shaped optical fields induced by plasmonic metamaterial cavities to scale the strength of plasmon-exciton coupling.The demonstrated plasmon modes of metallic metamaterial cavities offer high confinement and tunability and can match with the excitons of TMDCs to exhibit a strong coupling regime by tuning either the size of the cavity gap or thickness.The calculated Rabi splitting of Au-MoSe_2 and Au-WSe_2 heterostructures strongly depends on the catenary-like field enhancement induced by the Au cavity,resulting in room-temperature Rabi splitting ranging between 77.86 and 320 me V.These plasmonic metamaterial cavities can pave the way for manipulating excitons in TMDCs and operating active nanophotonic devices at ambient temperature.

Icariin accelerates bone regeneration by inducing osteogenesisangiogenesis coupling in rats with type 1 diabetes mellitus

BACKGROUND Icariin(ICA),a natural flavonoid compound monomer,has multiple pharmacological activities.However,its effect on bone defect in the context of type 1 diabetes mellitus(T1DM)has not yet been examined.AIM To explore the role and potential mechanism of ICA on bone defect in the context of T1DM.METHODS The effects of ICA on osteogenesis and angiogenesis were evaluated by alkaline phosphatase staining,alizarin red S staining,quantitative real-time polymerase chain reaction,Western blot,and immunofluorescence.Angiogenesis-related assays were conducted to investigate the relationship between osteogenesis and angiogenesis.A bone defect model was established in T1DM rats.The model rats were then treated with ICA or placebo and micron-scale computed tomography,histomorphometry,histology,and sequential fluorescent labeling were used to evaluate the effect of ICA on bone formation in the defect area.RESULTS ICA promoted bone marrow mesenchymal stem cell(BMSC)proliferation and osteogenic differentiation.The ICA treated-BMSCs showed higher expression levels of osteogenesis-related markers(alkaline phosphatase and osteocalcin)and angiogenesis-related markers(vascular endothelial growth factor A and platelet endothelial cell adhesion molecule 1)compared to the untreated group.ICA was also found to induce osteogenesis-angiogenesis coupling of BMSCs.In the bone defect model T1DM rats,ICA facilitated bone formation and CD31hiEMCNhi type H-positive capillary formation.Lastly,ICA effectively accelerated the rate of bone formation in the defect area.CONCLUSION ICA was able to accelerate bone regeneration in a T1DM rat model by inducing osteogenesis-angiogenesis coupling of BMSCs.

Rheological properties and concentration evolution of thickened tailings under the coupling effect of compression and shear

Cemented paste backfill(CPB)is a key technology for green mining in metal mines,in which tailings thickening comprises the primary link of CPB technology.However,difficult flocculation and substandard concentrations of thickened tailings often occur.The rheological properties and concentration evolution in the thickened tailings remain unclear.Moreover,traditional indoor thickening experiments have yet to quantitatively characterize their rheological properties.An experiment of flocculation condition optimization based on the Box-Behnken design(BBD)was performed in the study,and the two response values were investigated:concentration and the mean weighted chord length(MWCL)of flocs.Thus,optimal flocculation conditions were obtained.In addition,the rheological properties and concentration evolution of different flocculant dosages and ultrafine tailing contents under shear,compression,and compression-shear coupling experimental conditions were tested and compared.The results show that the shear yield stress under compression and compression-shear coupling increases with the growth of compressive yield stress,while the shear yield stress increases slightly under shear.The order of shear yield stress from low to high under different thickening conditions is shear,compression,and compression-shear coupling.Under compression and compression-shear coupling,the concentration first rapidly increases with the growth of compressive yield stress and then slowly increases,while concentration increases slightly under shear.The order of concentration from low to high under different thickening conditions is shear,compression,and compression-shear coupling.Finally,the evolution mechanism of the flocs and drainage channels during the thickening of the thickened tailings under different experimental conditions was revealed.

Metal–Organic Gel Leading to Customized Magnetic‑Coupling Engineering in Carbon Aerogels for Excellent Radar Stealth and Thermal Insulation Performances

Metal–organic gel(MOG)derived composites are promising multi-functional materials due to their alterable composition,identifiable chemical homogeneity,tunable shape,and porous structure.Herein,stable metal–organic hydrogels are prepared by regulating the complexation effect,solution polarity and curing speed.Meanwhile,collagen peptide is used to facilitate the fabrication of a porous aerogel with excellent physical properties as well as the homogeneous dispersion of magnetic particles during calcination.Subsequently,two kinds of heterometallic magnetic coupling systems are obtained through the application of Kirkendall effect.FeCo/nitrogen-doped carbon(NC)aerogel demonstrates an ultra-strong microwave absorption of−85 dB at an ultra-low loading of 5%.After reducing the time taken by atom shifting,a FeCo/Fe3O4/NC aerogel containing virus-shaped particles is obtained,which achieves an ultra-broad absorption of 7.44 GHz at an ultra-thin thickness of 1.59 mm due to the coupling effect offered by dual-soft-magnetic particles.Furthermore,both aerogels show excellent thermal insulation property,and their outstanding radar stealth performances in J-20 aircraft are confirmed by computer simulation technology.The formation mechanism of MOG is also discussed along with the thermal insulation and electromagnetic wave absorption mechanism of the aerogels,which will enable the development and application of novel and lightweight stealth coatings.

Algorithm Selection Method Based on Coupling Strength for Partitioned Analysis of Structure-Piezoelectric-Circuit Coupling

In this study, we propose an algorithm selection method based on coupling strength for the partitioned analysis ofstructure-piezoelectric-circuit coupling, which includes two types of coupling or inverse and direct piezoelectriccoupling and direct piezoelectric and circuit coupling. In the proposed method, implicit and explicit formulationsare used for strong and weak coupling, respectively. Three feasible partitioned algorithms are generated, namely(1) a strongly coupled algorithm that uses a fully implicit formulation for both types of coupling, (2) a weaklycoupled algorithm that uses a fully explicit formulation for both types of coupling, and (3) a partially stronglycoupled and partially weakly coupled algorithm that uses an implicit formulation and an explicit formulation forthe two types of coupling, respectively.Numerical examples using a piezoelectric energy harvester,which is a typicalstructure-piezoelectric-circuit coupling problem, demonstrate that the proposed method selects the most costeffectivealgorithm.

Plasma induced dynamic coupling of microscopic factors to collaboratively promote EM losses coupling of transition metal dichalcogenide absorbers

Plasma as the fourth state of matter has attracted great attention for material surface modification,which could induce changes in material microscopic factors,such as defects,phase transitions,crystallinity,and so on.However,the interactions among those microscopic factors and regulation mechanism of macroscopic properties have rarely been investigated.Two-dimensional(2D)transition metal dichalcogenide with tunable structure and phase is one of the most promising electromagnetic wave(EMW)absorbers,which provides a favorable platform for systematically studying the dynamic coupling of its microscopic factors.Herein,we constructed a NaBH_(4) solution-assisted Ar plasma method to modify the 2H-MoS_(2)and 1T-WS_(2)for exploring the regulation mechanism of microscopic factors.For MoS_(2)and WS_(2),NaBH_(4) solution-assisted Ar plasma treatment behaves with different effects on dielectric responses,realizing dynamic coupling of material microscopic factors to collaboratively promote EM losses coupling.Consequently,the MS-D3-0.5(MoS_(2),3 kV voltage,0.5 mol L^(-1)NaBH_(4) solution)displays an optimum effective absorption bandwidth of 8.01 GHz,which is 319.4%more than that of MS-raw sample.This study not only reveals the novel mechanism of plasma induced dynamic coupling of microscopic factors for EMW dissipation,but also presents a new method of plasma-dominated surface modification to optimize the EMW absorption performance.

A review on electrocatalytic CO_(2) conversion via C-C and C-N coupling

Electrochemical C-C and C-N coupling reactions with the conversion of abundant and inexpensive small molecules,such as CO_(2) and nitrogencontaining species,are considered a promising route for increasing the value of CO_(2) reduction products.The development of high-performance catalysts is the key to the both electrocatalytic reactions.In this review,we present a systematic summary of the reaction systems for electrocatalytic CO_(2) reduction,along with the coupling mechanisms of C-C and C-N bonds over outstanding electrocatalytic materials recently developed.The key intermediate species and reaction pathways related to the coupling as well as the catalyst-structure relationship will be also discussed,aiming to provide insights and guidance for designing efficient CO_(2) reduction systems.

Analysis of Strong Coupling Constant with Machine Learning and Its Application

We investigate the nature of the strong coupling constant and related physics.Through the analysis of accumulated experimental data around the world,we employ the ability of machine learning to unravel its physical laws.The result of our efforts is a formula that captures the expansive panorama of the distribution of the strong coupling constant across the entire energy range.