Investigation of hydroxyl-terminated polybutadiene propellant breaking characteristics and mechanism impacted by submerged cavitation water jet

A submerged cavitation water jet(SCWJ)is an effective method to recycle solid propellant from obsolete solid engines by the breaking method.Solid propellant's breaking modes and mechanical process under SCWJ impact are unclear.This study aims to understand those impact breaking mechanisms.The hydroxyl-terminated polybutadiene(HTPB)propellant was chosen as the research material,and a self-designed test system was used to conduct impact tests at four different working pressures.The high-speed camera characterized crack propagation,and the DIC method calculated strain change during the impact process.Besides,micro and macro fracture morphologies were characterized by scanning electron microscope(SEM)and computed tomography(CT)scanning.The results reveal that the compressive strain concentration region locates right below the nozzle,and the shear strain region distributes symmetrically with the jet axis,which increases to 4% at first 16th ms,the compressive strain rises to 2% and 6% in the axial and transverse direction,respectively.The two tensile cracks formed first at the compression strain concentrate region,and there generate many shear cracks around the tensile cracks,and those shear cracks that develop and aggregate cause the cracks to become wider and cut through the tensile cracks,forming the tensile-shear cracks and the impact parts eventually fail.The HTPB propellant forms a breaking hole shaped conical after impact 10 s.The mass loss increases by 17 times at maximum,with the working pressure increasing by three times.Meanwhile,the damage value of the breaking hole remaining on the surface increases by 7.8 times while 2.9 times in the depth of the breaking hole.The breaking efficiency is closely affected by working pressures.The failure modes of HTPB impacted by SCWJ are classified as tensile crack-dominated and tensile-shear crack-dominated damage mechanisms.

Observation of Zero-Energy Modes with Possible Time-Reversal Symmetry Breaking on Step Edge of CaKFe_(4)As_(4)

Topologically nontrivial Fe-based superconductors attract extensive attentions due to their ability of hosting Majorana zero modes(MZMs)which could be used for topological quantum computation.Topological defects such as vortex lines are required to generate MZMs.Here,we observe the robust edge states along the surface steps of CaKFe_(4)As_(4).Remarkably,the tunneling spectra show a sharp zero-bias peak(ZBP)with multiple integerquantized states at the step edge under zero magnetic field.We propose that the increasing hole doping around step edges may drive the local superconductivity into a state with possible spontaneous time-reversal symmetry breaking.Consequently,the ZBP can be interpreted as an MZM in an effective vortex in the superconducting topological surface state by proximity to the center of a tri-junction with different superconducting order parameters.Our results provide new insights into the interplay between topology and unconventional superconductivity,and pave a new path to generate MZMs without magnetic field.

Across two phylogeographic breaks: Quaternary evolutionary history of a mountain aspen (Populus rotundifolia) in the Hengduan Mountains

Biogeographical barriers to gene flow are central to plant phylogeography.In East Asia,plant distribution is greatly influenced by two phylogeographic breaks,the Mekong-Salween Divide and Tanaka-Kaiyong Line,however,few studies have investigated how these barriers affect the genetic diversity of species that are distributed across both.Here we used 14 microsatellite loci and four chloroplast DNA fragments to examine genetic diversity and distribution patterns of 49 populations of Populus rotundifolia,a species that spans both the Mekong-Salween Divide and the Tanaka-Kaiyong Line in southwestern China.Demographic and migration hypotheses were tested using coalescent-based approaches.Limited historical gene flow was observed between the western and eastern groups of P.rotundifolia,but substantial flow occurred across both the Mekong-Salween Divide and Tanaka-Kaiyong Line,manifesting in clear admixture and high genetic diversity in the central group.Wind-borne pollen and seeds may have facilitated the dispersal of P.rotundifolia following prevalent northwest winds in the spring.We also found that the Hengduan Mountains,where multiple genetic barriers were detected,acted on the whole as a barrier between the western and eastern groups of P.rotundifolia.Ecological niche modeling suggested that P.rotundifolia has undergone range expansion since the last glacial maximum,and demographic reconstruction indicated an earlier population expansion around 600 Ka.The phylogeographic pattern of P.rotundifolia reflects the interplay of biological traits,wind patterns,barriers,niche differentiation,and Quaternary climate history.This study emphasizes the need for multiple lines of evidence in understanding the Quaternary evolution of plants in topographically complex areas.

Generating highly active oxide-phosphide heterostructure through interfacial engineering to break the energy scaling relation toward urea-assisted natural seawater electrolysis

Urea-assisted natural seawater electrolysis is an emerging technology that is effective for grid-scale carbon-neutral hydrogen mass production yet challenging.Circumventing scaling relations is an effective strategy to break through the bottleneck of natural seawater splitting.Herein,by DFT calculation,we demonstrated that the interface boundaries between Ni_(2)P and MoO_(2) play an essential role in the selfrelaxation of the Ni-O interfacial bond,effectively modulating a coordination number of intermediates to control independently their adsorption-free energy,thus circumventing the adsorption-energy scaling relation.Following this conceptual model,a well-defined 3D F-doped Ni_(2)P-MoO_(2) heterostructure microrod array was rationally designed via an interfacial engineering strategy toward urea-assisted natural seawater electrolysis.As a result,the F-Ni_(2)P-MoO_(2) exhibits eminently active and durable bifunctional catalysts for both HER and OER in acid,alkaline,and alkaline sea water-based electrolytes.By in-situ analysis,we found that a thin amorphous layer of NiOOH,which is evolved from the Ni_(2)P during anodic reaction,is real catalytic active sites for the OER and UOR processes.Remarkable,such electrode-assembled urea-assisted natural seawater electrolyzer requires low voltages of 1.29 and 1.75 V to drive 10 and600 mA cm^(-2)and demonstrates superior durability by operating continuously for 100 h at 100 mA cm^(-2),beyond commercial Pt/C||RuO_(2) and most previous reports.

Team China’s Groundbreaking Success at Paris Olympics

China’s Olympic delegation at the Paris 2024,with 404 athletes competing in 232 events across 30 sports,clinched 40 gold,27 silver,and 24 bronze medals,marking their best performance at an Olympics held abroad.The success of these athletes across various disciplines demonstrates the country’s efforts to expand its athletic prowess while also marks a new chapter for Chinese sportsmanship on the international stage.

Enhancing textile production:Smartex exhibits groundbreaking solutions

Smartex,a trailblazing leader in textile industry innovation,was proud to announce its return to ITM 2024,showcasing unparalleled advancements in quality control and production efficiency.Building on the success of previous exhibitions at ITM 2022 and ITMA Milan 2023,Smartex emerges stronger than ever,presenting its complete Smartex System tailored to transform textile manufacturing.

Numerical Simulation of Dam-Break Flows Using Radial Basis Functions: Application to Urban Flood Inundation

Dam-break flows pose significant threats to urban areas due to their potential for causing rapid and extensive flooding. Traditional numerical methods for simulating these events struggle with complex urban landscapes. This paper presents an alternative approach using Radial Basis Functions to simulate dam-break flows and their impact on urban flood inundation. The proposed method adapts a new strategy based on Particle Swarm Optimization for variable shape parameter selection on meshfree formulation to enhance the numerical stability and convergence of the simulation. The method’s accuracy and efficiency are demonstrated through numerical experiments, including well-known partial and circular dam-break problems and an idealized city with a single building, highlighting its potential as a valuable tool for urban flood risk management.

Impacts of monsoon break events in the western North Pacific on the cross-equatorial flows over the Maritime Continent

本文利用ERA5逐日再分析资料,探讨了1979-2020年间西北太平洋季风中断事件对海洋性大陆越赤道气流的影响.合成结果表明,西北太平洋季风中断事件会造成高,低空越赤道气流减弱,即高层南风异常,低层北风异常,与此相关的环流异常表现为西北太平洋高层气旋,低层反气旋的斜压结构。特别的是,西北太平洋季风中断对高空越赤道气流的影响更为显著,92%的季风中断事件都导致高空越赤道气流减弱,而只有70%的事件造成低空越赤道气流减弱,这是由于低空越赤道气流同时还受到赤道中东太平洋海温异常的调控.

Comprehensive evaluation of chemical breakers for multistage network ultra-high strength gel

Polymer gels have been accepted as a useful tool to address many sealing operations such as drilling and completion,well stimulation,wellbore integrity,water and gas shutoff,etc.Previously,we developed an ultra-high strength gel(USGel)for medium to ultra-low temperature reservoirs.However,the removal of USGel is a difficult problem for most temporary plugging operations.This paper first provides new insights into the mechanism of USGel,where multistage network structure and physical entanglement are the main reasons for USGel possessing ultra-high strength.Then the effects of acid breakers,encapsulated breakers,and oxidation breakers(including H_(2)O_(2),Na_(2)S_(2)O_(8),Ca(ClO)_(2),H_(2)O_(2)+NaOH,Na_(2)S_(2)O_(8)+NaOH,and Ca(ClO)_(2)+NaOH)were evaluated.The effects of component concentration and temperature on the breaking solution were studied,and the corrosion performance,physical simulation and formation damage tests of the breaking solution were carried out.The final formulation of 2%-4%NaOH+4.5%-6%H_(2)O_(2) breaking solution was determined,which can make USGel completely turn into water at 35e105C.The combinations of“acid t breaking solution”,“acid+encapsulated breaker”and“encapsulated breaker+breaking solution”were evaluated for breaking effect.The acid gradually reduced the volume of USGel,which increased the contact area between breaking solution and USGel,and the effect of“4%acid+breaking solution”was 23 times higher than that of breaking solution alone at 35C.However,the acid significantly reduced the strength of USGel.This paper provides new insights into the breaking of high-strength gels with complex network structures.

A record-breaking high efficiency facilitated by hierarchical morphology in all polymer solar cells

Organic solar cells(OSCs) especially non-fullerene OSCs(NF-OSCs) are promising to become the next-generation of commercial applications and have received great attention from many researchers due to their typical advantages of low cost,light weight,and flexibility [1,2].

Experimental research and energy analysis of a new type of dry ice powder pneumatic rock breaking technology

When the traditional drill and blast method is applied to rock crushing projects,it has strong vibration,loud noise and dust pollution,so it cannot be used in densely populated areas such as urban public works.We developed a supercritical CO_(2)true triaxial pneumatic rock-breaking experimental system,and conducted laboratory and field tests of dry ice powder pneumatic rock-breaking.The characteristics of the blast-induced vibration velocity waveform and the evolution of the vibration velocity and frequency with the focal distance were analyzed and discussed.The fracturing mechanism of dry ice powder pneumatic rock breaking is studied.The research results show that:(1)The vibration velocity induced by dry ice powder pneumatic rock breaking decays as a power function with the increase of the focal distance;(2)The vibration frequency caused by dry ice powder pneumatic rock breaking is mainly distributed in 1–120 Hz.Due to the dispersion effect,the dominant frequency of 10–30 Hz appears abnormally attenuated;(3)The traditional CO_(2)phase change fracturing energy calculation formula is also applicable to dry ice pneumatic rock breaking technology,and the trinitrotoluene(TNT)equivalent of fracturing energy is applicable to the Sadovsky formula;(4)Dry ice powder pneumatic rock breaking is shock wave and highenergy gas acting together to fracture rock,which can be divided into three stages,among which the gas wedge action of high-energy gas plays a dominant role in rock mass damage.

Monsoon Break over the South China Sea during Summer: Statistical Features and Associated Atmospheric Anomalies

This study identifies break events of the South China Sea(SCS)summer monsoon(SCSSM)based on 42 years of data from 1979 to 2020,and investigates their statistical characteristics and associated atmospheric anomalies.A total of 214 break events are identified by examining the convection evolution during each monsoon season.It is found that most events occur between June and September and show a roughly even distribution.Short-lived events(3–7 days)are more frequent,accounting for about two thirds of total events,with the residual one third for long-lived events(8–24 days).The SCSSM break is featured by drastic variations in various atmospheric variables.Particularly,the convection and precipitation change from anomalous enhancement in adjoining periods to a substantial suppression during the break,with the differences being more than 60 W m−2 for outgoing longwave radiation(OLR)and 10 mm d−1 for precipitation.This convection/precipitation suppression is accompanied by an anomalous anticyclone in the lower troposphere,corresponding to a remarkable westward retreat of the monsoon trough from the Philippine Sea to the Indochina Peninsula,which reduces the transportation of water vapor into the SCS.Besides,the pseudo-equivalent potential temperature()declines sharply,mainly attributable to the local specific humidity reduction caused by downward dry advection.Furthermore,it is found that the suppressed convection and anomalous anticyclone responsible for the monsoon break form near the equatorial western Pacific and then propagate northwestward to the SCS.

Comparative Study of the Rock-breaking Mechanism of a Disc Cutter and Wedge Tooth Cutter by Discrete Element Modelling

The operation of a shield tunnel boring machine(TBM)in a high-strength hard rock stratum results in significant cutter damage,adversely affecting the thrust and torque of the cutter head.Therefore,it is very important to carry out the research on the stress characteristics and optimize the cutter parameters of cutters break high-strength hard rock.In this paper,the rock-breaking performance of cutters in an andesite stratum in the tunnel of Qingdao Metro Line No.8 was investigated using the discrete element method and theoretical analysis.The rock-breaking processes of a disc cutter and wedge tooth cutter were simulated by software particle flow code PFC^(3D),and the rock-breaking degree,stress of the cutter,and rock-breaking specific energy were analyzed.The rock damage caused by the cutter in a specific section was divided into three stages:the advanced influence,crushing,and stabilizing stages.The rock-breaking degree and the tangential and normal forces of the wedge tooth cutter are larger than that of the disc cutter under the same conditions.The disc cutter(wedge tooth cutter)has the highest rock-breaking efficiency at a cutter spacing of 100 mm(110 mm)and a penetration depth of 8 mm(10 mm),and the rock-breaking specific energy is 11.48 MJ/m^(3)(12.05 MJ/m^(3)).Therefore,two types of cutters with different penetration depths or cutter spacing should be considered.The number of teeth of wedge tooth cutters can be increased in hard strata to improve the rock-breaking efficiency of the shield.The research results provide a reference for shield cutterhead selection and cutter layout in similar projects.

Rock breaking performance of the newly proposed unsubmerged cavitating abrasive waterjet

To improve the rock breaking ability, cavitating waterjet and abrasive waterjet are combined by using a coaxial low-speed waterjet generated around the periphery of a high-speed abrasive waterjet, and a new type of waterjet called unsubmerged cavitating abrasive waterjet(UCAWJ) is thus produced. The rock breaking performance of UCAWJ was compared with submerged cavitating abrasive waterjet(SCAWJ)and unsubmerged abrasive waterjet(UAWJ) by impinging sandstone specimens. Moreover, the effects of jet pressure, standoff distance, abrasive flow rate and concentration were studied by evaluating the specific energy consumption, and the area, depth, and mass loss of the eroded specimen. The results show that the artificially generated submerged environment in UCAWJ is able to enhance the rock breaking performance under the same operating parameters. Furthermore, the rock breaking performance of UCAWJ is much better at higher jet pressures and smaller standoff distances when compared with UAWJ. The greatest rock breaking ability of UCAWJ appears at jet pressure of 50 MPa and standoff distance of 32 mm, with the mass loss of sandstone increased by 370.6% and the energy dissipation decreased by 75.8%. In addition, under the experimental conditions the optimal abrasive flow rate and concentration are 76.5 m L/min and 3%, respectively.

Volatility spillovers,structural breaks and uncertainty in technology sector markets

This study uses the dynamic conditional correlation to investigate how technology subsector stocks interact with financial assets in the face of economic and financial uncertainty.Our results suggest that structural breaks have diverse effects on financial asset connectedness and that the level of bond linkage increases when the trend breaks.We see a growing co-movement between the technology sector and major financial assets when uncertainty is considered.Overall,our findings indicate that the connectedness response varies depending on the type of uncertainty shock.

China’s import expo yields record-breaking deals, boosts global economy

The sixth China International Import Expo(CIIE),the world’s first national-level import-themed expo,saw a total of 78.41 billion U.S.dollars’worth of tentative deals reached for one-year purchases of goods and services,setting a record high.

Hello World Thai teen movies break out by looking out,refine by looking back in

In the 21st Century,the native culture of Thailand has become a major inspiration for production of Thai movies,which have boomed,especially in four distinct genres:Thai epics,Muay Thai,horror,and teen movies.The first three genres are introspective and focus on the local characteristics of the nation by telling stories of Thai history,elaborating on the techniques of Muay Thai,and highlighting local spiritual beliefs.However,Thai teen movies are different because the genre tends to deploy internationalized narratives as part of the country’s efforts to build a Thai cultural identity that permeates global screens.

Factor analysis and numerical simulation of rock breaking efficiency of TBM deep rock mass based on orthogonal design

This study investigates the factors affecting the rock-breaking efficiency of the TBM disc cutter in deep rock excavation,including confining pressure,penetration,cutter spacing,and revolution speed.The finite element method is employed to formulate a rock-breaking model of the rotary disc cutters and a numerical simulation is also implemented.The rock breaking effect,rock breaking volume,and rock breaking specific energy consumption under different combinations of the factors are investigated.An orthogonal test of four factors at four levels was constructed.Based on the test results and range analysis in the process of deep rock mass breaking,the order of sensitivity of each influencing factor with respect to the rock breaking specific energy for the disc cutter is cutter spacing>revolution speed>penetration>confining pressure.By constructing a numerical simulation comparison scheme,the orthogonal test results are analyzed and corroborated,and the rock breaking law and rock breaking efficiency under different influencing factors are derived.Finally,the sensitivity of different influencing factors on the rock-breaking efficiency is verified.

Study on the Mathematical Model of Dielectric Recovery Characteristics in High Voltage SF6 Circuit Breaker

According to the stream theory, this paper proposes a mathematical model of the dielectric recovery characteristic based on the two-temperature ionization equilibrium equation. Taking the dynamic variation of charged particle＇s ionization and attachment into account, this model can be used in collaboration with the Coulomb collision model, which gives the relationship of the heavy particle temperature and electron temperature to calculate the electron density and temperature under different pressure and electric field conditions, so as to deliver the breakdown electric field strength under different pressure conditions. Meanwhile an experiment loop of the circuit breaker has been built to measure the breakdown voltage. It is shown that calculated results are in conformity with experiment results on the whole while results based on the stream criterion are larger than experiment results. This indicates that the mathematical model proposed here is more accurate for calculating the dielectric recovery characteristic, it is derived from the stream model with some improvement and refinement and has great significance for increasing the simulation accuracy of circuit breaker＇s interruption characteristic.

Intermittency of Wind Wave Group Breaking

Knowledge on intermittency of wave breaking is so far limited to a few summary statistics, while the probability distribution of time interval between breaking events can provide a full view of intermittency. Based on a series of experiments on wind wave breaking, such probability distributions are investigated. Breaking waves within a wave group were taken as a single breaking event according to recent studies. Interval between successive wave groups with breaker is the focus of this paper. For intervals in our experiments with different fetch and wind conditions, their distributions are all skewed and weighted on small intervals. Results of Kolmogorov-Smirnov tests on time series of these intervals indicate that they all follow gamma distribution, and some are even exponential type. Average breaking-group-interval decreases with friction velocity and significant steepness until the wind is strong enough;most of them are more than 10 times the dominant wave period. Group breaking probability proposed by Babanin recently and the average number of breaking waves in wave groups are also discussed, and they are seemingly more reasonable and sensitive than traditional breaking probability defined in terms of single wave.