High-density triple-phase contact points for enhanced photocatalytic CO_(2) reduction to methanol

The efficiency of photocatalytic CO_(2) reduction reaction(PCRR)is restricted by the low solubility and mobility of CO_(2) in water,poor CO_(2) adsorption capacity of catalyst,and competition with hydrogen evolution reaction(HER).Recently,hydrophobic modification of the catalyst surface has been proposed as a potential solution to induce the formation of triple-phase contact points(TPCPs)of CO_(2)(gas phase),H_(2) O(liquid phase),and catalysts(solid phase)near the surface of the catalyst,enabling direct delivery of highly concentrated CO_(2) molecules to the active reaction sites,resulting in higher CO_(2) and lower H+surface concentrations.The TPCPs thus act as the ideal reaction points with enhanced PCRR and suppressed HER.However,the initial synthesis of triple-phase photocatalysts tends to possess a lower bulk density of TPCPs due to the simple structure leading to limited active points and CO_(2) adsorption sites.Here,based on constructing a hydrophobic hierarchical porous TiO_(2)(o-HPT)with interconnected macropores and mesopores structure,we have significantly increased the density of TPCPs in a unit volume of the photocatalyst.Compared with hydrophobic macroporous TiO_(2)(o-MacPT)or mesoporous TiO_(2)(o-MesPT),the o-HPT with increased TPCP density leads to enhanced photoactivity,enabling a high methanol production rate with 1111.5μmol g^(−1) h^(−1) from PCRR.These results emphasize the significance of high-density TPCPs design and propose a potential path for developing efficient PCRR systems.

Multi-point Contact of the High-speed Vehicle-turnout System Dynamics

The wheel-rail contact problems, such as the number, location and the track of contact patches, are very important for optimizing the spatial structure of the rails and lowering the vehicle-turnout system dynamics. However, the above problems are not well solved currently because of having the difficulties in how to determine the multi-contact, to preciously present the changeable profiles of the rails and to establish an accurate spatial turnout system dynamics model. Based on a high-speed vehicle-turnout coupled model in which the track is modeled as flexible with rails and sleepers represented by beams, the line tracing extreme point method is introduced to investigate the wheel-rail multiple contact conditions and the key sections of the blade rail, longer nose rail, shorter rail in the switch and nose rail area are discretized to represent the varying profiles of rails in the turnout. The dynamic interaction between the vehicle and turnout is simulated for cases of the vehicle divergently passing the turnout and the multi-point contact is obtained. The tracks of the contact patches on the top of the rails are presented and the wheel-rail impact forces are offered in comparison with the contact patches transference on the rails. The numerical simulation results indicate that the length of two-point contact occurrence of a worn wheel profile and rails is longer than that of the new wheel profile and rails; The two-point contact definitely occurs in the switch and crossing area. Generally, three-point contact doesn’t occur for the new rail profile, which is testified by the wheel-rails interpolation distance and the first order derivative function of the tracing line extreme points. The presented research is not only helpful to optimize the structure of the turnout, but also useful to lower the dynamics of the high speed vehicle-turnout system.

A grasp planning algorithm under uneven contact point distribution scenario for space non-cooperative target capture

The contact point configuration should be carefully chosen to ensure a stable capture,especially for the non-cooperative target capture mission using multi-armed spacecraft.In this work scenario,the contact points on the base and on the arms are distributed on the opposite side of the target.Otherwise,large forces will be needed.To cope with this problem,an uneven-oriented distribution union criterion is proposed.The union criterion contains a virtual symmetrical criterion and a geometry criterion.The virtual symmetrical contact point criterion is derived from the proof of the force closure principle using computational geometry to ensure a stable grasp,and the geometry criterion is calculated by the volume of the minimum polyhedron formed by the contact points to get a wide-range distribution.To further accelerate the optimization rate and enhance the global search ability,a line array modeling method and a continuous-discrete global search algorithm are proposed.The line array modeling method reduces the workload of calculating the descent direction and the gradient available,while the continuous-discrete global search algorithm reducing the optimization dimension.Then a highly efficient grasping is achieved and the corresponding contact point is calculated.Finally,an exhaustive verification is conducted to numerically analyze the disturbance resistance ability,and simulation results demonstrate the effectiveness of the proposed algorithms.

Research on the influence of flexible wheelset rotation effect on wheel rail contact force

Purpose-Under the high-speed operating conditions,the effects of wheelset elastic deformation on the wheel rail dynamic forces will become more notable compared to the low-speed condition.In order to meet different analysis requirements and selecting appropriate models to analyzing the wheel rail interaction,it is crucial to understand the influence of wheelset flexibility on the wheel-rail dynamics under different speeds and track excitations condition.Design/methodology/approach-The wheel rail contact points solving method and vehicle dynamics equations considering wheelset flexibility in the trajectory body coordinate system were investigated in this paper.As for the wheel-rail contact forces,which is a particular force element in vehicle multibody system,a method for calculating the Jacobian matrix of the wheel-rail contact force is proposed to better couple the wheel-rail contact force calculation with the vehicle dynamics response calculation.Based on the flexible wheelset modeling approach in this paper,two vehicle dynamic models considering the wheelset as both elastic and rigid bodies are established,two kinds of track excitations,namely normal measured track irregularities and short-wave irregularities are used,wheel-rail geometric contact characteristic and wheel-rail contact forces in both time and frequency domains are compared with the two models in order to study the influence of flexible wheelset rotation effect on wheel rail contact force.Findings-Under normal track irregularity excitations,the amplitudes of vertical,longitudinal and lateral forces computed by the flexible wheelset model are smaller than those of the rigid wheelset model,and the virtual penetration and equivalent contact patch are also slightly smaller.For the flexible wheelset model,the wheel rail longitudinal and lateral creepages will also decrease.The higher the vehicle speed,the larger the differences in wheel-rail forces computed by the flexible and rigid wheelset model.Under track short-wave irregularity excitations,the vertical force amplitude computed by the flexible wheelset is also smaller than that of the rigid wheelset.However,unlike the excitation case of measured track irregularity,under short-wave excitations,for the speed within the range of 200 to 350 km/h,the difference in the amplitude of the vertical force between the flexible and rigid wheelset models gradually decreases as the speed increase.This is partly due to the contribution of wheelset's elastic vibration under short-wave excitations.For low-frequency wheel-rail force analysis problems at speeds of 350 km/h and above,as well as high-frequency wheel-rail interaction analysis problems under various speed conditions,the flexible wheelset model will give results agrees better with the reality.Originality/value-This study provides reference for the modeling method of the flexible wheelset and the coupling method of wheel-rail contact force to the vehicle multibody dynamics system.Furthermore,by comparative research,the influence of wheelset flexibility and rotation on wheel-rail dynamic behavior are obtained,which is useful to the application scope of rigid and flexible wheelset models.

Transition from tunneling regime to local point contact realized on Ba0.6K0.4Fe2As2 surface

Using scanning tunneling spectroscopy, we studied the transition from tunneling regime to local point contact on the iron-based superconductor Ba0.6K0.4Fe2As2. By gradually reducing the junction resistance, a series of spectra were obtained with the characteristics evolving from single-particle tunneling into Andreev reflection. The spectra can be well fitted to the modified Blonder–Tinkham–Klapwijk（BTK） model and exhibit significant changes of both spectral broadening and orbital selection due to the formation of point contact. The spatial resolution of the point contact was estimated to be several nanometers, providing a unique way to study the inhomogeneity of unconventional superconductors on such a scale.

Contact Force Distribution and Static Load-carrying Capacity of Large Size Double Row Four-point Contact Ball Bearing

Clearance not only affects the startup torque,rotation precision and stiffness of bearing,but also affects the load distribution,load-carrying capacity and life of bearing.A computational model in which the clearance of bearing is first included is presented for determining the contact force distribution and static load-carrying capacity of a double row four-point contact ball bearing which is subjected to the combined radial,axial and overturning moment loadings.The relation between the negative axial clearance and the contact force distribution is analyzed.The static load-carrying capacity curves are established,and the effects of the changes in negative axial clearance,curvature radius coefficient of raceway groove and initial contact angle on the static load-carrying capacity are analyzed.The results show that,with the increase in the absolute value of negative clearance,the maximum contact load decreases first and then increases.The clearance values in the range of 0.2 mme0 mm have little effect on the static load-carrying capacity of bearing.With the increase in the curvature radius coefficient of raceway groove and the decrease in the initial contact angle,the static load capacity of bearing decreases.

Magnetic vortex gyration mediated by point-contact position

Micromagnetic simulation is employed to study the gyration motion of magnetic vortices in distinct permalloy nanodisks driven by a spin-polarized current. The critical current density for magnetic vortex gyration, eigenfrequency, trajectory, velocity and the time for a magnetic vortex to obtain the steady gyration are analyzed. Simulation results reveal that the magnetic vortices in larger and thinner nanodisks can achieve a lower-frequency gyration at a lower current density in a shorter time. However, the magnetic vortices in thicker nanodisks need a higher current density and longer time to attain steady gyration but with a higher eigenfrequency. We also find that the point-contact position exerts different influences on these parameters in different nanodisks, which contributes to the control of the magnetic vortex gyration. The conclusions of this paper can serve as a theoretical basis for designing nano-oscillators and microwave frequency modulators.

Distinction between critical current effects and intrinsic anomalies in the point-contact Andreev reflection spectra of unconventional superconductors

In this work,we discuss the origin of several anomalies present in the point-contact Andreev reflection spectra of（Li1-xFex）OHFeSe,LiTi2O4,and La2-xCexCuO4.While these features are similar to those stemming from intrinsic superconducting properties,such as Andreev reflection,electron-boson coupling,multigap superconductivity,d-wave and p-wave pairing symmetry,they cannot be accounted for by the modified Blonder–Tinkham–Klapwijk（BTK） model,but require to consider critical current effects arising from the junction geometry.Our results point to the importance of tracking the evolution of the dips and peaks in the differential conductance as a function of the bias voltage,in order to correctly deduce the properties of the superconducting state.

Effect of Surface Texturing on Lubricating Condition under Point Contact Using Numerical Analysis

The contact fatigue life of machine elements is affected by pitting, wear and so on, under heavier loading conditions. Increasing the fatigue life requires mainly the improvements of lubricating condition, operating condition and materials. In order to improve the lubricating condition, it is necessary to investigate the relation of the microscopic surface texturing and the contact modes of machine elements. In this paper, thus, the pressure and oil film thickness of the contact between sphere and the plate with 5 kinds surface texturing were calculated using a commercial software based on Reynolds equation. There was sufficient evidence to suggest that the dimple shape was the optimum texturing to increase the lubricating condition.

A solution to the hydrodynamic lubrication of a circular point contact sliding over a flat surface with cavitation

This letter presents an analytical solution to the hydrodynamic lubrication of a circular point contact sliding over a flat surface with cavitation.The solution is found by solving the Reynolds equation with Reynolds boundary condition for cavitation.The cavitation boundary is shown to be straight lines directed 108.4°against the sliding direction.The result is experimentally verified in the limit of large values of viscosity,sliding velocity and radius of a spherical ball.The solution raises questions about the coupling between cavitation and film rupture and can be used as an independent check on the validity of numerical solutions.

Shot Noise Suppression in a Quantum Point Contact with Short Channel Length

An experimental study on the current shot noise of a quantum point contact with short channel length is reported. The experimentally measured maximum energy level spacing between the ground and the first excited state of the device reached up to 7.5meV, probably due to the hard wall confinement by using shallow electron gas and sharp point contact geometry. The two-dimensionM non-equilibrium shot noise contour map shows noise suppression characteristics in a wide range of bias voltage. Fano factor analysis indicates spin-polarized transport through a short quantum point contact.

The 0.7-Anomaly in Quantum Point Contact;Many-Body or Single-Electron Effect?

Apart from usual quantization steps on the ballistic conductance of quasi-one-dimensional conductor, an additional plateau-like feature appears at a fraction of about 0.7 below the first conductance step in GaAs-based quantum point contacts (QPCs). Despite a tremendous amount of research on this anomalous feature, its origin remains still unclear. Here, a unique model of this anomaly is proposed relying on fundamental principles of quantum mechanics. It is noticed that just after opening a quasi-1D conducting channel in the QPC a single electron travels the channel at a time, and such electron can be—in principle—observed. The act of observation destroys superposition of spin states, in which the electron otherwise exists, and this suppresses their quantum interference. It is shown that then the QPC-conductance is reduced by a factor of 0.74. “Visibility” of electron is enhanced if the electron spends some time in the channel due to resonant transmission. Electron’s resonance can also explain an unusual temperature behavior of the anomaly as well as its recently discovered feature: oscillatory modulation as a function of the channel length and electrostatic potential. A recipe for experimental verification of the model is given.

沟曲率半径(密合度)对四点接触球轴承疲劳寿命影响研究

采用Romax Designer工程分析软件,应用ISO/TS 16281—2008寿命计算方法,根据经典的滚动轴承理论,对某电机轴四点接触球轴承内部载荷分布、接触应力、套圈滚道等效动态滚动元件载荷和ISO/TS16281—2008寿命等进行了大量的计算,重点研究滚道沟曲率半径对轴承内部载荷分布、接触应力、套圈滚道等效动态滚动元件载荷和ISO/TS16281—2008疲劳寿命的影响。研究结果表明,轴承型号和制造质量、载荷条件、润滑条件和可靠度等其他条件确定时,存在一个相对最优的滚道沟曲率半径(密合度);当载荷条件不同时,相应最优的滚道沟曲率半径(密合度)不同。在所研究的具体条件下,由于轴系中的2个轴承所承受的载荷不同,因而,2个轴承的最优滚道沟曲率半径(密合度)不同。研究结果可为四点接触球轴承的设计方案提供参考。

基于双车接触点响应残差的桥梁模态参数识别方法研究

针对“车辆扫描法”在桥梁模态参数识别过程中存在对路面粗糙度和车辆速度过于敏感等问题,提出一种新的基于接触点响应的车辆扫描法识别桥梁模态参数(频率和振型)。在考虑相位差的前提下对两车的接触点响应作差,利用该残差识别结构各阶模态频率以及对应的模态振型;给出了基于双车接触点响应残差进行桥梁模态参数识别的流程,通过数值算例验证了其可行性,并系统讨论了车辆速度、质量以及路面粗糙度等因素对识别结果的影响。数值结果表明:该文所提出的方法简单有效,能够在有效剔除路面粗糙度影响的前提下准确识别桥梁结构的模态参数。

A Novel Method of Nanocontact Fabrication for Andreev Reflection Measurement

A new method of nanocontact fabrication for Adreev reflection measurement based on the nanopore method using a SiN membrane with focused ion beam technique is presented. With this method, controllable, clean,tensionless nano-contacts for spin polarization probing can be obtained. Measurements of the fabricated samples show complicated spectral structures with a zero bias anomaly and dip structures from quasipartical interactions. A control sample of Co40Fe40B20 is measured with Nb tip method. None of the measured spectra can be explained satisfactorily by present theory. Further analysis of the contact interface and a more complete theory are needed to extract a reliable spin polarization message with the point contact Andreev reflection method.

ANALYSIS OF THE SINGULARITY FOR THE VERTICAL CONTACT PROBLEM OF LINE CRACK-INCLUSION

Taking the short-fiber composite materials as engineering back-ground, utilizing the existing basic solutions of single inclusion and single crack, the plane problem of vertical contact interactions between line crack and rigid line inclusion in infinite plane (matrix) from the viewpoint of crack fracture mechanics is studied. According to boundary conditions, a set of standard Cauchy-type singular integral equations of the problem is obtainable. Besides, singular indexes, stresses and stress intensity factors around the contact point are expressed. Numerical examples are given to provide references to engineering.

机油压力报警开关漏油分析及解决方案

机油压力报警开关广泛应用于多个领域,作为机油压力报警系统重要原件检测机油压力并发出报警信号。某发动机用机油压力报警开关在台架耐久试验中漏油频发,成立公关小组调查。从设计、制造、安装、运行过程排查,用故障树FTA分析原因,确认要因为压紧垫片弯折面无倒角和膜片冲型面有裂纹。针对要因制定对策,重新设计压紧垫片结构,更换膜片结构及材质,优化膜片制作工艺。效果检查表明改进后耐压合格,台架耐久试验及市场量装跟踪无泄漏,漏油问题解决,为其他部件优化提供思路。

Enhancement of surface wettability via micro-and nanostructures by single point diamond turning

Studies on surface wettability have received tremendous interest due to their potential applications in research and industrial processes. One of the strategies to tune surface wettability is modifying surface topography at micro-and nanoscales. In this research, periodic micro-and nanostructures were patterned on several polymer surfaces by ultra-precision single point diamond turning to investigate the relationships between surface topographies at the micro-and nanoscales and their surface wettability. This research revealed that single-point diamond turning could be used to enhance the wettability of a variety of polymers, including polyvinyl chloride(PVC), polyethylene 1000(PE1000), polypropylene copolymer(PP) and polytetrafluoroethylene(PFTE), which cannot be processed by conventional semiconductor-based manufacturing processes. Materials exhibiting common wettability properties(θ≈ 90°) changed to exhibit "superhydrophobic" behavior(θ > 150°). Compared with the size of the structures, the aspect ratio of the void space between micro-and nanostructures has a strong impact on surface wettability.

FRICTIONAL CONTACT MULTIPOLE-BEM AND 3-D ANALYSIS OF SCREWPAIRS

The 3-D traction field in the pressure screw-pair of a 3 500 heavy and mediumplate mill press down system is successfully calculated by applying the 3-D frictional contactmultipole-BEM and the corresponding program that has been developed. The computing results show themedium diameter orientation is unreliable, especially under the interference of an outer forcecouple. Under such working conditions, the circumferential traction distribution on the screw teethis extremely uneven, which is the main reason for the destruction and short life time ofscrew-pairs. When utilizing the same precision (the relative tolerance is 10X10^(-5)), themultipole-BEM uses almost the same CPU time as used by the FEM, but the needed computer memory sizeis only one eightieth of that needed by the FEM (10 MB vs. 800 MB). The multipole-BEM is well suitedfor computing large-scale engineering problems.

考虑电磁-热-结构耦合的并沟线夹温升特性分析及验证

为更准确地研究并沟线夹的温升特性,分析了导线与并沟线夹之间接触点的实际分布特征,建立了并沟线夹的三维电磁、热、结构多物理场耦合模型。基于结构场分析线夹与导线安装和发生热膨胀后导线的接触压力,并计算接触电阻,通过电磁-热耦合得到线夹的电流密度及温度分布规律,探明最高温度的具体位置。分析了不同载流量与螺栓松脱程度对线夹最高温度的影响。研究结果表明:当电流流经并沟线夹系统时,导线与线夹本体接触点界面外侧的电流密度最大,造成的发热最严重;载流量越小,螺栓松脱对线夹的最高温度影响越小,反之,螺栓松脱对线夹的最高温度影响越大;相对误差在3%内,模型具有较高的准确性。