The Mechanism of Cube Texture Formation in Ni-7 at%W Substrate

In order to obtain the sharp cube texture,a new process,the intermediate annealing rolling technique,has been introduced to prepare the Ni7W substrate.In this paper,a cubic texture content up to 98.5%within 10°of the standard cubic orientation is obtained in the final substrate and the influence of this improved rolling technique on the cube texture formation has been discussed.The results show that the increased cube texture in the Ni7W substrate is caused by the optimized deformation texture and the increased nucleated fraction of the cube grains.

Effect of trace yttrium on cube texture of high-purity aluminum foils

The effect of trace yttrium on cube texture of high purity aluminum foils has been investigated by means of orientation distribution functions (ODFs). The results show that a small addition of yttrium to high purity aluminum brings about a considerable increment of the cube texture, and it reduces the content of R texture. The rare earth yttrium may combine with the other impurities to form the metallic compounds, such as FeYAl 8, Fe 6YAl 6, Fe 4YAl 8 and Si 2YAl 2. When the precipitation of these particles in the matrix is nearly completed and the Fe concentration in the matrix becomes low, the cube texture can develop well and the R texture can be suppressed. [

Influence of Hot Rolling on Cube Texture of Ni Substrate for Coated Conductor

Pure Ni and Ni alloy tapes with sharp cube texture and low-angle grain boundaries prepared by thermomechanical process were extensively used as substrates for coated conductor. The thermomechanical process usually includes hot forging and cold rolling. In this study, a hot-rolling process between hot forging and cold rolling was induced. The influence of hot rolling on the cube texture of pure Ni was discussed. Sharp cube texture on pure Ni was obtained by suitable hot rolling, cold rolling, and recrystallization treatment. This deformation texture of tape was studied using orientation distribution function （ODF）. Orientation mapping, content of the cube texture, and grain boundary distribution were performed using an EBSD system mounted on LEO-1450 SEM. The results show that the substrates that are hot rolled have a sharp cube texture and low-angle grain boundaries.

Preparation of CeO_2 Buffer Layer on Cube Textured Nickel Substrate by Reactive Sputtering

The buffer layer CeO2 films were grown on cube textured metallic Ni substrates by using reactive magnetrun sputtering. Ar/H2 mixed atmosphere, which effectively inhibited the formation of NiO, was used as pre-depositing gas before CeO2 films were grown in Ar and 02. At 700 ℃ under the total pressure of 26 Pa,the pure c-axis orientation tilm was obtained. X-ray θ-2θscan, pole figure and φ-scan were used to observe the microstructure of the buffer layer. The resuits show that CeO2 film has strong cube texture and the FWHM is 9°. In addition, the CeO2 film is dense and crack-free.

Recrystallization Texture and Microstructure of Metal Substrate for Y123 Coated Superconductor

The cube textured pure Ni and non magnetic Cu Ni tapes were obtained by rolling and recrystallization, and these tapes are suitable as substrates of the second generation high temperature superconducting tape. The texture of tapes was studied using Orientation Distribution Function (ODF) and φ scans. The results indicate that sharp cube texture of Cu 0 70 Ni 0.30 and pure Ni was formed at 1000 ℃ and that of Cu 0 85 Ni 0.15 was formed at 900 ℃. The intensities of cube texture differ from each other. Uniform equiaxial crystallites are formed in all the tapes and the size of Cu 0.85 Ni 0.15 is larger than that of Cu 0.70 Ni 0.30 and pure Ni. Annealing twin is formed in Cu 0.85 Ni 0.15 and Cu 0.70 Ni 0.30 .

Highly c-axis Oriented YBCO Thin Films Deposited on Cold Rolling Ag Substrates and Textures of Cold-Rolling and Recrystallization in Ag

By selecting flexible polycrystalline Ag as the metallic substrates, highly c axis (001) textured YBCO thin films were fabricated by using a modified magnetron sputtering equipment which can accomplish dynamic deposition and in-situ anneal treatment. The textures of Ag substrates have important effects on forming YBCO films with high critical current densities. Research on the textures of cold rolling Ag at different deformation degrees and recrystallization textures of Ag at different temperatures shows that in plane alignment of YBCO films is difficult to be obtained directly on cold rolling Ag substrates, because of the texture change of Ag during deposition heating of substrates and the strong dependence of J c of YBCO films on grain boundary misorientation angle of substrates. The recrystallization textures with cube (001) and rotated cube (001) in Ag were obtained. Experiments offer a possible prospect for the further research of fabricating sharp biaxially texture in Ag and the following deposition of high J c YBCO films directly on it.

Regulating the recrystallized grain to induce strong cube texture in oriented silicon steel

Cube texture contains two easy magnetization directions<001>parallel to rolling and transverse direction,respectively,which is the most ideal magnetic texture suitable not only for transformers but also for rotating machines.In this study,a strong cube texture with ODF density of 50.73 mrd was successfully obtained by regulating the recrystallized grain orientation using cross-rolling and pulsed electric current,compared to conventional thermal annealing(the average cube texture intensity is~10 mrd in lots of latest studies).Cross cold rolling process intentionally"created"metastable deformed cube orientation in oriented silicon steel and the specific recrystallization texture rotation path was identified under pulsed electric current in 5 min:{114}<261>→{114}<151>→{114}<041>→{001}<150>→{001}<010>.The cube-oriented grains were induced by pulsed electric current(800℃)and rapid heating(51.9℃/s,750℃),while the cube grains were observed in the annealed samples at the high temperature(1060℃).Recrystallized grain size of pulsed samples is about twice that of the annealed sample.This phenomenon is considered that the concurrent effects of electron wind force and Joule heating affected the nucleation,growth and rotation of cube grains by reducing the nuclear barrier,producing higher grain boundary mobility and structural evolution towards a state with lower electrical resistance.This idea of current-controlled texture is worthy of popularization in more materials and the realization of an electromagnetic field to crystal orientation selection is an interesting topic.

Fabricating Buffer Layers for YBa_2Cu_3O_y Coated Conductor by Surface Oxidation Epitaxy

NiO buffer layers were formed on a tape of Ni for making YBCO coated conductor by surface-oxidation epitaxy （SOE） process. Different oxidizing conditions such as temperature and duration were studied for Ni tapes. It is found that the texture of NiO could be affected directly by the orientation and surface of substrate. X-ray diffraction （XRD） 2-2θ scan, φ-scan, and pole figure were employed to characterize the in-plane alignment and cube texture. X-ray φ-scan shows that NiO film is formed on Ni tape with high cube texture and a typical value at the full width at half maximum （FWHM） is ≤ 7.5°. Scanning electron microscopy was used to study the surface morphology of NiO films. No crack is found and the films appear dense. Such technique is simple and of low cost with perfect reproducibility, promising for developing long tapes.

Growth of CeO_2, Y_2O_3 Buffer Layers for YBCO Coated Conductor

The CeO2 and Y2O3 buffer layers were deposited on the cube textured metallic Ni substrates by using reactive magnetron sputtering. Ar/H2 mixed atmosphere, which is used as pre-depositing gas, can effectively inhibit the formation of NiO. In addition, the linear relationship between pre-depositing time and total depositing time is required to ensure the epitaxial growth of the films. The growth conditions of CeO2 and Y2O3 were comparatively studied, and it is found that the windows of substrate temperatures and pressures for CeO2 films are wider than that for Y2O3 films.

Cube texture formation of Ni9.3W alloy substrates:preparation by optimized deformation sequence and anneal process

The Ni9.3W alloy with no ferromagnetism and high yield strength is one of the most promising textured substrate materials for coated conductors, but its low stacking fault energy makes it difficult to obtain a strong cube texture by traditional rolling methods and recrystal- lization anneals. This paper introduces four-time static recoveries during the rolling process. Rolled tapes with 80 μm in thickness were obtained by applying various deformation sequences between static recoveries to study their effects on the cube texture formation in Ni9.3W alloy substrates. The results show that rising gradient deformation sequence is an advantageous way to obtain a higher amount of cube texture, its content increases by 29.2% compared to that of traditional deformation sequence. The effect of the new recrystallization annealing process on the cube texture formation was analyzed. It is shown that the cube texture content increases with anneal temperature increasing in one-step anneal, but decreases again at higher anneal temperature. Two-step anneal could effectively improve the cube texture content, which could be further enhanced by extending holding time during the first-step anneal. However, too long holding time leads to the decrease in cube texture content. Finally, Ni9.3W alloy substrates with a cube texture content of -90.0 vol% （〈15°） are obtained by optimized two-step anneal.