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Photochemical effect driven fluid behavior control in microscale pores and channels 被引量:2
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作者 Shuli Wang Ruimin Zhou +2 位作者 Yaqi Hou Miao Wang Xu Hou 《Chinese Chemical Letters》 SCIE CAS CSCD 2022年第8期3650-3656,共7页
Manipulating the fluid transport in the microscale pores and channels is playing a paramount role in the realization of the versatile functions of microfluidics.In recent years,using light to control the fluid behavio... Manipulating the fluid transport in the microscale pores and channels is playing a paramount role in the realization of the versatile functions of microfluidics.In recent years,using light to control the fluid behavior in the microchannels/pores has attracted many researchers'attention due to the advantages of light such as non-contact stimulation,tunable excitation,high spatial and temporal resolution.With efforts,great achievements and progresses have been achieved for photochemical effect driven microscale flow control,including fluid pumping,flow rate control,and fluid mixing,etc.In this review,we discuss the responsive mechanisms of photochemical effect driven fluid behavior control at the microscale.We also give a comprehensive review on the latest research progresses in photochemical effect controlled microfluid behaviors.Besides,prospective opportunities for the future development of light control of microscale flow are provided to attract scientific interest for the fast development and applications of various microchannel/pore systems. 展开更多
关键词 Photochemical effect fluid behavior Microscale pore MICROCHANNEL MICROfluidICS
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稠油开采中多元热复合流体相态的研究进展 被引量:1
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作者 李洪毅 黄致新 +3 位作者 唐亮 魏超平 吴光焕 尹小梅 《油气地质与采收率》 CAS CSCD 北大核心 2024年第1期87-102,共16页
稠油的储量远超常规石油的储量,但因稠油黏度大和密度大的特点而难以开采,高效经济开发稠油已成为石油领域的研究重点。热复合开采技术是目前高效开发稠油油藏的关键技术,其中多元热复合流体的相态特征是稠油油藏开采流程设计与评价的... 稠油的储量远超常规石油的储量,但因稠油黏度大和密度大的特点而难以开采,高效经济开发稠油已成为石油领域的研究重点。热复合开采技术是目前高效开发稠油油藏的关键技术,其中多元热复合流体的相态特征是稠油油藏开采流程设计与评价的关键。为此,从热复合开采技术中的混合气体系和稠油-气体系2个方面,系统地阐述了多元热复合流体相态的实验和理论研究现状。对于混合气体系相态,多采用静态法进行实验测试,使用状态方程结合混合规则进行理论预测,CO_(2),N_(2),H_(2)O和CH_(4)等常见气体分子组成的二元体系的相态测试趋于成熟,但缺少多元体系的测试数据与预测模型;对于稠油-气体系相态,总结了一般性实验流程与近年实验结果,提出一种加速油气相平衡的新型实验装置构想,指出目前理论预测在气体种类、注气量、气体扩散模型、二元相互作用系数等方面的不足。进而对多元热复合流体相态研究提出展望,以期促进热复合开采技术进一步的机理研究与参数优化。 展开更多
关键词 热复合开采 混合流体 稠油开采 相态特征 热力学性质
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非常规储层微纳米孔隙介质中流体相态研究进展
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作者 汪周华 范琨鹏 +4 位作者 赵建飞 余曹 匡红先 郭平 涂汉敏 《世界石油工业》 2024年第3期68-77,共10页
非常规油气储层具有岩石骨架颗粒小、比表面积大、微纳米孔隙发育的特点,流体与孔隙介质间存在着诸多复杂的界面效应问题,影响微纳米孔隙介质中流体的相态变化规律。对于受限域流体,经典油气相态理论方法忽略分子间相互作用及界面效应... 非常规油气储层具有岩石骨架颗粒小、比表面积大、微纳米孔隙发育的特点,流体与孔隙介质间存在着诸多复杂的界面效应问题,影响微纳米孔隙介质中流体的相态变化规律。对于受限域流体,经典油气相态理论方法忽略分子间相互作用及界面效应的影响,预测微纳米孔隙介质中流体相变特征存在偏差。为了更全面地揭示油气在受限空间中的相态特征及其微观作用机理,总结当前微纳米孔隙介质中流体相态研究技术现状,详细阐述微观实验测试、相态理论模型和分子模拟3种主流技术方法,指出3种技术各自的优缺点,并对未来流体相态研究技术提出展望。分析认为:微观实验测试方法可通过研究流体热力学参数的变化来确定流体相变点,由于实验误差、人为误差等原因,需与理论计算相结合;相态理论模型方法可通过改进临界参数场、考虑流体与孔壁界面作用、考虑相间毛管压力修正相平衡判据方程等方法建立纳米孔隙空间相态理论模型,但是由于没有综合考虑界面效应带来的影响且缺乏有力的实验数据支撑,难以推广应用;分子模拟方法能在分子尺度上揭示流体分子的相行为,但现有研究主要围绕小分子展开,并且与流体发生相变时的临界参数结合得较少。后续研究应以多界面效应耦合影响的微纳米孔隙介质中油气流体相变特征为研究对象,以微观实验、理论模型和分子模拟为技术手段,为描述微纳米孔隙介质中流体相态提供合理的实验测试手段和可靠的理论计算模型。 展开更多
关键词 流体相态 微观实验测试 相态理论模型 分子模拟 油气藏开发
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可降解医用Zn-3Al-1Mg合金的体外腐蚀行为和力学性能
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作者 刘晓倩 刘翠 +1 位作者 乔爱科 穆永亮 《材料与冶金学报》 CAS 北大核心 2024年第2期181-189,196,共10页
采用热挤压方法制备了管状Zn-3Al-1Mg合金,利用扫描电子显微镜(SEM)及拉伸、压缩测试等方法研究了铸态和挤压态管状Zn-3Al-1Mg合金的微观组织与力学性能同时,利用浸泡试验、电化学测试、X射线光电子能谱分析(XPS)研究了挤压态管状Zn-3Al... 采用热挤压方法制备了管状Zn-3Al-1Mg合金,利用扫描电子显微镜(SEM)及拉伸、压缩测试等方法研究了铸态和挤压态管状Zn-3Al-1Mg合金的微观组织与力学性能同时,利用浸泡试验、电化学测试、X射线光电子能谱分析(XPS)研究了挤压态管状Zn-3Al-1Mg合金在模拟体液(SBF)溶液中的腐蚀行为结果表明:铸态及挤压态合金均由η-Zn,α-Al及Mg2Zn11三相组成,挤压态合金的微观组织明显细化,且力学性能明显优于铸态合金的力学性能挤压态合金在模拟体液中的腐蚀速率为015~028 mm/a腐蚀形貌分析结果揭示了不同物相间的微电偶腐蚀机制,腐蚀产物包括Zn/Al/Mg的氧化物、氢氧化物,以及Ca,P和Zn/Al/Mg相结合产生的磷酸盐、碳酸盐结合电化学测试结果,对挤压态合金的腐蚀过程和腐蚀机理进行了分析. 展开更多
关键词 ZN合金 生物材料 力学性能 模拟体液 降解行为
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激光熔化沉积TiC/TC4复合材料热-流行为及陶瓷颗粒分布状态
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作者 蔡绪康 王磊磊 +1 位作者 杨兴运 占小红 《焊接学报》 EI CAS CSCD 北大核心 2024年第5期74-83,共10页
颗粒增强钛基复合材料在航空航天等领域具有广阔的应用前景,采用仿真与试验相结合的方法,对激光熔化沉积TiC/TC4复合材料过程中的热-流行为和沉积层中陶瓷颗粒的分布状态进行了研究.结果表明,工艺参数对熔池的热-流行为及沉积层形貌具... 颗粒增强钛基复合材料在航空航天等领域具有广阔的应用前景,采用仿真与试验相结合的方法,对激光熔化沉积TiC/TC4复合材料过程中的热-流行为和沉积层中陶瓷颗粒的分布状态进行了研究.结果表明,工艺参数对熔池的热-流行为及沉积层形貌具有显著的影响,熔池表面的流体流动呈波纹状,熔融金属从熔池中心向四周流动;熔池底部等温面上熔融金属从四周流向熔池底部,并出现漩涡现象.在激光熔化沉积过程中,TiC颗粒穿透熔池表面的Marangoni对流区,在熔池中与流体交互作用,最终在沉积层中出现沉积层中上方部位团聚、沉积层中下方部位团聚、沉积层中均匀分布等分布状态. 展开更多
关键词 激光熔化沉积 TC4钛合金 复合材料 热-流行为 颗粒分布
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注多元热流体环境下流速对N80钢腐蚀行为的影响研究
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作者 陈宇凡 林学强 +4 位作者 孙建波 孙冲 徐学旭 逄波 陈慧 《表面技术》 EI CAS CSCD 北大核心 2024年第10期124-133,共10页
目的研究不同流速条件下N80钢在注多元热流体环境中的腐蚀特征,探究流速变化对N80钢腐蚀行为的影响规律及机理。方法利用自制高温高压多相流冲刷腐蚀环路装置模拟不同流速(0、0.5、1.0、2.0m/s)的注多元热流体环境,采用失重法计算不同... 目的研究不同流速条件下N80钢在注多元热流体环境中的腐蚀特征,探究流速变化对N80钢腐蚀行为的影响规律及机理。方法利用自制高温高压多相流冲刷腐蚀环路装置模拟不同流速(0、0.5、1.0、2.0m/s)的注多元热流体环境,采用失重法计算不同流速下N80钢的平均腐蚀速率,并同时进行原位电化学测试。采用扫描电子显微镜(SEM)和X射线衍射仪(XRD)对不同流速条件下N80钢腐蚀后的腐蚀产物物相组成和表面微观形貌进行分析。结果N80钢在注多元热流体环境中的平均腐蚀速率随着流速增加而增大。流速增加影响O_(2)的扩散传质过程、近表面离子分布和壁面剪切力的大小,使腐蚀产物膜特征发生变化。0m/s时,腐蚀产物主要由FeCO_(3)和少量Fe_(2)O_(3)组成,为单层膜结构,腐蚀形态为均匀腐蚀。0.5~2.0m/s范围内,腐蚀产物种类增加,主要由FeCO_(3)、Fe_(2)O_(3)和少量FeO(OH)组成,呈双层膜结构,同时N80钢表面腐蚀产物膜出现鼓泡,且随流速增加鼓泡数量增加,去除腐蚀产物膜后发现鼓泡下方存在局部腐蚀。原位电化学测试结果表明:随着流速增加,塔菲尔极化曲线的阳极斜率增大,阴极斜率减小。电化学阻抗谱测试结果表明,N80钢表面外层腐蚀产物膜电阻Rf1、电荷转移电阻Rct和扩散电阻W随流速增加而减小。结论流速增大加快了O_(2)的扩散传质过程,使得腐蚀电化学控制步骤由阴极氧扩散过程转变为阳极溶解过程,且试样表面保护性FeCO_(3)膜厚度减小,导致产物膜保护性降低。另外,Fe^(2+)更容易被氧化形成Fe^(3+),局部FeCO_(3)被氧化成为Fe_(2)O_(3),破坏了内层膜的完整性,导致局部腐蚀发生。 展开更多
关键词 N80钢 流体流速 CO_(2)-O_(2)共存 多元热流体 原位电化学测试 腐蚀行为
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耐盐性PAM-AMPS/Fe_(3)O_(4)纳米减阻剂流变性 被引量:1
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作者 秦文龙 李璐 +2 位作者 李国庆 李晗晰 秦国伟 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2024年第1期137-145,共9页
采用丙烯酰胺/2-丙烯酰胺基-2-甲基丙磺酸(AM/AMPS)共聚物接枝纳米Fe_(3)O_(4)合成了一种PAM-AMPS/Fe_(3)O_(4)纳米减阻剂,并利用动态流变仪研究了PAM-AMPS/Fe_(3)O_(4)减阻剂的剪切稀释性,分析了纳米Fe_(3)O_(4)、盐含量及剪切作用对... 采用丙烯酰胺/2-丙烯酰胺基-2-甲基丙磺酸(AM/AMPS)共聚物接枝纳米Fe_(3)O_(4)合成了一种PAM-AMPS/Fe_(3)O_(4)纳米减阻剂,并利用动态流变仪研究了PAM-AMPS/Fe_(3)O_(4)减阻剂的剪切稀释性,分析了纳米Fe_(3)O_(4)、盐含量及剪切作用对其流变行为的影响规律。结果表明:PAM-AMPS/Fe_(3)O_(4)纳米减阻剂的粒径为100~500 nm、黏均分子质量为4.99×10^(6)g/mol;在30℃下,剪切速率大于0.3 s^(-1)时PAM-AMPS/Fe_(3)O_(4)减阻剂表现出显著的剪切稀释特征,该减阻剂具有更复杂的微观结构,其超临界质量分数为0.035%,相比空白聚合物表现出更优良的增黏性能和黏弹性;由于AMPS含有耐温耐盐基团,在NaCl和CaCl2质量分数分别为10%和5%的条件下,PAM-AMPS/Fe_(3)O_(4)减阻剂黏度保留率分别为69%和53%,表现出了较强的耐盐性;同时,该减阻剂在剪切速率1000 s^(-1)条件下剪切3600、7200 s后的黏度回复率分别为100%和94%,表现出良好的耐剪切性。 展开更多
关键词 减阻剂 聚丙烯酰胺 纳米Fe_(3)O_(4) 黏弹性流体 耐盐性 耐剪切性 流变行为
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污酸水As(Ⅲ)在射流反应器中氧化的流体行为研究
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作者 王振威 李瑞冰 《辽宁化工》 CAS 2024年第4期493-496,共4页
铅锌冶炼污酸水中的砷主要以3价砷形态存在,处理污酸水中的砷需要将3价砷氧化为5价砷。为了提高氧化效率,采用一种新型的射流反应器,对该反应器中的气液两相流动进行数值模拟研究,得到了压力场分布、气液速度场分布、气泡尺寸、气含率... 铅锌冶炼污酸水中的砷主要以3价砷形态存在,处理污酸水中的砷需要将3价砷氧化为5价砷。为了提高氧化效率,采用一种新型的射流反应器,对该反应器中的气液两相流动进行数值模拟研究,得到了压力场分布、气液速度场分布、气泡尺寸、气含率、宏观混合效果等参数,对后续的氧化工艺设计具有重要的指导意义。 展开更多
关键词 射流反应器 数值模拟 流体行为 宏观混合效果
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强封堵防塌型水基钻井液体系室内制备及其应用
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作者 王国辉 苏乐 赵燕博 《当代化工》 CAS 2024年第5期1162-1165,1169,共5页
选取目标区块进行了储层水化行为特性分析,提出了一种强封堵防塌型高性能水基钻井液体系。优选了封堵剂、降滤失剂、抑制剂与润滑剂为关键处理剂,对其流变性、封堵性、抑制性、润滑性、抗温性以及井壁稳定性进行了实验评价,并进行了现... 选取目标区块进行了储层水化行为特性分析,提出了一种强封堵防塌型高性能水基钻井液体系。优选了封堵剂、降滤失剂、抑制剂与润滑剂为关键处理剂,对其流变性、封堵性、抑制性、润滑性、抗温性以及井壁稳定性进行了实验评价,并进行了现场应用测试。结果显示:基浆、3.0%磺化沥青及5%碳酸钙三者组合可实现体系滤失量最低,3%SAP+6%PAH+0.5%HB降滤失效果最佳,6%PEG和5%FH6为抑制剂与润滑剂。配制的水基钻井液体系滤失量几乎为0,页岩滚动回收率为96.99%,可以很好地起到井壁防塌稳定的效用,综合性能与油基钻井液体系相差不大。现场应用测试过程中高温高压失水量低至3.9 mL,钻井固相质量分数仅为5.29%,极压润滑系数显著低于非测试井,验证了该水基钻井液体系的实用性。 展开更多
关键词 水化行为 水基压裂液 强封堵 性能评价 流动 分散 混合
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Review of Rare Earths and Fluid-Rock Interaction 被引量:4
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作者 凌其聪 刘丛强 《Journal of Rare Earths》 SCIE EI CAS CSCD 2002年第6期570-578,共9页
As demonstrated by a great amount of geologic and experimental evidences, RE of rock systems may be mobilized during fluid-rock interaction when solutions are rich in F -, Cl -, CO 3 2-, HCO 3 -, CO 2, HPO 4... As demonstrated by a great amount of geologic and experimental evidences, RE of rock systems may be mobilized during fluid-rock interaction when solutions are rich in F -, Cl -, CO 3 2-, HCO 3 -, CO 2, HPO 4 2-, HS -, S 2-, SO 4 2-, though little has been known about the mobilizing mechanism of these anions or ligands. The fractionation of RE resulted from hydrothermal alterations, i. e., fluid-rock interactions, are distinctive. One set of field data implies the preferential mobility of the LRE, while another set of field observations demonstrates the dominant mobilization of the HRE, and some theoretical prediction is not consistent with the field evidence. The Eu anomalies caused by fluid-rock interaction are complex and compelling explanation is not available due to inadequate experimental approaches. To know the exact behavior of RE during fluid-rock interaction and to solve the contradiction between some theoretical predictions and field observations, the following works remain to be done: (1) experimental investigations of RE mobility and fractionation as a function of fluid chemistry, e.g., the activity of F -, Cl -, CO 3 2-, HCO 3 -, CO 2, HPO 4 2-, HS -, S 2-, SO 4 2-, etc.; (2) experimental determination of RE mobility and fractionation as a function of T, P, pH, E h and water/rock ratios; (3) investigation of the mechanism and the controlling factors of RE partitioning between hydrothermal minerals and fluids. It was demonstrated that RE mobility is a potentially useful method for exploration. 展开更多
关键词 rare earths REE behavior fluid-rock interaction GEOCHEMISTRY
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High temperature and high pressure rheological properties of high-density water-based drilling fluids for deep wells 被引量:9
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作者 Wang Fuhua Tan Xuechao +3 位作者 Wang Ruihe Sun Mingbo Wang Li Liu Jianghua 《Petroleum Science》 SCIE CAS CSCD 2012年第3期354-362,共9页
To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines... To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines temperature effects on the rheological properties of two types of high-density water-based drilling fluids (fresh water-based and brine-based) under high temperature and high pressure (HTHP) with a Fann 50SL rheometer. On the basis of the water-based drilling fluid systems formulated in laboratory, this paper mainly describes the influences of different types and concentration of clay, the content of a colloid stabilizer named GHJ-1 and fluid density on the rheological parameters such as viscosity and shear stress. In addition, the effects of aging temperature and aging time of the drilling fluid on these parameters were also examined. Clay content and proportions for different densities of brine-based fluids were recommended to effectively regulate the rheological properties. Four theological models, the Bingham, power law, Casson and H-B models, were employed to fit the rheological parameters. It turns out that the H-B model was the best one to describe the rheological properties of the high-density drilling fluid under HTHP conditions and power law model produced the worst fit. In addition, a new mathematical model that describes the apparent viscosity as a function of temperature and pressure was established and has been applied on site. 展开更多
关键词 High-density water-based drilling fluid rheological behavior CLAY high temperature high pressure linear fitting rheological model mathematical model
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Unsteady Flow and Structural Behaviors of Centrifugal Pump under Cavitation Conditions 被引量:4
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作者 Denghao Wu Yun Ren +2 位作者 Jiegang Mou Yunqing Gu Lanfang Jiang 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2019年第1期127-141,共15页
Cavitation has a significant e ect on the flow fields and structural behaviors of a centrifugal pump. In this study, the unsteady flow and structural behaviors of a centrifugal pump are investigated numerically under ... Cavitation has a significant e ect on the flow fields and structural behaviors of a centrifugal pump. In this study, the unsteady flow and structural behaviors of a centrifugal pump are investigated numerically under di erent cavitation conditions. A strong two-way coupling fluid-structure interaction simulation is applied to obtain interior views of the e ects of cavitating bubbles on the flow and structural dynamics of a pump. The renormalization-group k-ε turbulence model and the Zwart–Gerbe–Belamri cavitation model are solved for the fluid side, while a transient structural dynamic analysis is employed for the structure side. The di erent cavitation states are mapped in the head-net positive suction head(H-NPSH) curves and flow field features inside the impeller are fully revealed. Results indicate that cavitating bubbles grow and expand rapidly with decreasing NPSH. In addition, the pressure fluctuations, both in the impeller and volute, are quantitatively analyzed and associated with the cavitation states. It is shown that influence of the cavitation on the flow field is critical, specifically in the super-cavitation state. The e ect of cavitation on the unsteady radial force and blade loads is also discussed. The results indicate that the averaged radial force increased from 8.5 N to 54.4 N in the transition progress from an onset cavitation state to a super-cavitation state. Furthermore, the structural behaviors, including blade deformation, stress, and natural frequencies, corresponding to the cavitation states are discussed. A large volume of cavitating bubbles weakens the fluid forces on the blade and decreases the natural frequencies of the rotor system. This study could enhance the understanding of the e ects of cavitation on pump flow and structural behaviors. 展开更多
关键词 CENTRIFUGAL PUMP CAVITATION UNSTEADY flow Structural behaviorS fluid-structure interaction
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岩石组构、地应力与流体黏度对鄂尔多斯盆地长73陆相页岩水力裂缝扩展的影响规律
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作者 郭鹏 李晓 +3 位作者 李守定 赫建明 毛天桥 郑博 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第5期1646-1658,共13页
页岩油是原油增储上产的重要领域。由于储层结构致密、超低渗透,页岩油工业开发需要对储层进行大规模压裂改造。与海相页岩储层相比,鄂尔多斯盆地长7_(3)陆相页岩油储层矿物成分与岩石组构差异较大,力学非均质性较强。陆相页岩油靶层选... 页岩油是原油增储上产的重要领域。由于储层结构致密、超低渗透,页岩油工业开发需要对储层进行大规模压裂改造。与海相页岩储层相比,鄂尔多斯盆地长7_(3)陆相页岩油储层矿物成分与岩石组构差异较大,力学非均质性较强。陆相页岩油靶层选取和高效压裂改造需要明确页岩力学行为和水力裂缝扩展规律。对长7_(3)陆相页岩进行了原位X-ray CT力学试验和三轴水力压裂试验。分析了岩石组构、地应力差和流体黏度对水力裂缝垂向扩展的影响规律。结果表明,岩石组构对陆相页岩的力学行为和破坏过程有显著影响。陆相页岩水力裂缝的垂向扩展受垂向应力差和流体黏度的共同控制。当垂向应力差较小时,黑色页岩中原生弱面显著抑制了水力裂缝的垂向扩展。随着垂向应力差的增大,黑色页岩裂缝体积呈线性增加趋势,而纹层型页岩裂缝体积呈先增大后减小趋势。增大压裂液黏度可减弱层面的阻碍作用,促进水力裂缝垂向扩展。 展开更多
关键词 陆相页岩 力学行为 水力裂缝 岩石组构 地应力 流体黏度
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Rheological behaviors of coal slime produced by filter-pressing 被引量:7
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作者 Dai Zhaohui Shi Lele +1 位作者 Wang Lijun Guo Chuwen 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2018年第2期347-351,共5页
It is an effective way to use coal slime as fuel for circulating fluidized bed boilers, which will not only solve its pollution to the environment, but also turn waste to treasure. In order to provide basic technical ... It is an effective way to use coal slime as fuel for circulating fluidized bed boilers, which will not only solve its pollution to the environment, but also turn waste to treasure. In order to provide basic technical information for transportation of coal slime from the coal preparation plant to the boiler, this paper experimentally studied the rheological behaviors of coal slime produced by filter-pressing. By using a rotational viscometer, the influences of water content, temperature, and shear time on the rheological behaviors of coal slime were investigated. Experimental results show that the coal slime will behave like Bingham plastics with low water content and like Bingham pseudo-plastics with 37.5% water content,while like pseudo-plastics with 40% water content. This indicates that the water content of coal slime must be controlled in consideration of both transportation resistance and combustion efficiency. Study results also show that, the apparent viscosity of coal slime at 5℃ is about 1.5–1.7 times of that at 40℃ for water contents 32%–37.5%, while the influence of temperature can be neglected when the water content is 40%. With increasing of water content, the influences of shear time on the apparent viscosity of coal slime becomes less. When the water content is more than 30%, the effect of shear time is negligible. It indicates that water content has the most important influence on the rheological behaviors of coal slime. There must be an optimal water content in considering conveying resistance and combustion efficiency. The environmental temperature must also be considered in coal slime transportation. 展开更多
关键词 COAL SLIME RHEOLOGICAL behavior Non-Newtonian fluid APPARENT VISCOSITY
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Electrochemical behavior of SUS316L stainless steelafter surface modification 被引量:1
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作者 梁成浩 郭亮 +1 位作者 陈婉 刘敬肖 《中国有色金属学会会刊:英文版》 CSCD 2003年第2期398-401,共4页
The surface modification for SUS316L stainless steel was carried out by electroplating Rh, ion beam assisted deposition Ta 2O 5 and sol gel derived TiO 2. In Tyrodes stimulated body fluid, the surface modified sampl... The surface modification for SUS316L stainless steel was carried out by electroplating Rh, ion beam assisted deposition Ta 2O 5 and sol gel derived TiO 2. In Tyrodes stimulated body fluid, the surface modified samples were investigated with electrochemical techniques. The results indicate that the electrochemical stability and dissolution are improved significantly after surface modification. Moreover, as to ion beam assisted deposition Ta 2O 5 and sol gel derived TiO 2 film, the metals d orbit electron holes filled up by the oxygen electrons make against the adsorption of hydrogen. Thus the cathode process, which is controlled by the hydrogen reduction, is held back. X ray diffraction analysis of SUS316L stainless steel after surface modification reveal that each method forms the uniform and compact film on SUS316L stainless steel. These films prevent the dissolving of elements and improve passivation property of the SUS316L stainless steel. 展开更多
关键词 不锈钢 表面处理 电化学行为 电镀
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EFFECT OF GRAVITY FIELD ON SOLIDIFICATION BEHAVIOR OF STEEL INGOT
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作者 CHEN Weide ZHENG Xianshu JIN Junze(Dalian University of Technology,Dalian,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1995年第2期110-114,共5页
By means of numerical simulation. the in fluence of gravity on fluid flow,patterns has been simulated.The result shows that with the increase of inclined angle,the velocity of fluid flow decreases and the isotherms be... By means of numerical simulation. the in fluence of gravity on fluid flow,patterns has been simulated.The result shows that with the increase of inclined angle,the velocity of fluid flow decreases and the isotherms become flatter,which suppresses the evolution of channel segregation. 展开更多
关键词 gravity field fluid flow.solidification behavior channel segregation
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Shear-thinning behavior of the CaO–SiO2–CaF2–Si3N4 system mold flux and its practical application 被引量:1
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作者 Ying Xu Zhi-peng Yuan +2 位作者 Li-guang Zhu Yi-hua Han Xing-juan Wang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2017年第10期1096-1103,共8页
Satisfying the mold-flux performance requirements for high-speed continuous casting necessitates the development of a new non-Newtonian-fluid mold flux with shear-thinning behavior, i.e., a mold flux whose viscosity i... Satisfying the mold-flux performance requirements for high-speed continuous casting necessitates the development of a new non-Newtonian-fluid mold flux with shear-thinning behavior, i.e., a mold flux whose viscosity is relatively high under lower shear rates and relatively low under higher shear rates. In this work, a mold flux that exhibits shear-thinning behavior was developed by adding different amounts of Si_3N_4 to the CaO–SiO_2–CaF_2 mold flux. The shear-thinning behavior was investigated using a rotational viscometer. In addition, the microstructure of the newly prepared slags was studied by high-temperature Raman spectroscopy and X-ray photoelectron spectroscopy. The results showed that the mechanism of shear-thinning was attributable to a temporary viscosity loss caused by the one-way shear stress, whereas the corresponding magnitude of shear-thinning was closely related to the degree of polymerization(DP). Finally, the non-Newtonian fluid mold flux was used for laboratory casting tests, which revealed that the mold flux could reduce slag entrapment and positively affect the continuous casting optimization. 展开更多
关键词 MOLD flux viscosity SHEAR-THINNING behavior non-Newtonian fluid degree of POLYMERIZATION
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非饱和矿堆溶液渗流迟滞与毛细扩散行为表征 被引量:1
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作者 王雷鸣 李希雯 +4 位作者 尹升华 周根茂 李辉 刘培正 邓博纳 《工程科学学报》 EI CSCD 北大核心 2023年第3期359-368,共10页
为深入理解非饱和矿堆内溶浸液毛细渗流扩散以及渗流迟滞行为,本文构建适于非饱和矿堆的毛细渗流模型,利用COMSOL multiphysics有限元数值平台开展毛细渗流可视化模拟研究,并利用时域反射器(Time domain reflector,TDR)实时探测了非饱... 为深入理解非饱和矿堆内溶浸液毛细渗流扩散以及渗流迟滞行为,本文构建适于非饱和矿堆的毛细渗流模型,利用COMSOL multiphysics有限元数值平台开展毛细渗流可视化模拟研究,并利用时域反射器(Time domain reflector,TDR)实时探测了非饱和堆内持液率变化,探索了基于Design Expert的毛细渗流过程多因素响应规律,讨论了非饱和矿堆持液率、毛细吸力、孔隙率与喷淋强度间的潜在关联机制.研究结果表明:孔隙率对矿堆持液率的影响高于喷淋强度,矿堆持液率随喷淋时间的增长收敛性增加,且孔隙率小的矿堆需要更长的时间才能达到稳态持液;不考虑溶液喷淋强度影响时,矿堆持液率与孔隙比、水力传导系数呈正相关;特别是在喷淋初期(0~20 s),喷淋强度、水力传导系数和孔隙比对矿堆持液率的影响更为显著;初步构建了考虑气液两相运移的非饱和矿堆溶液毛细渗流模型;毛细吸力的变化对孔隙率较小的矿堆更敏感;喷淋强度较大、孔隙比越小时,矿堆底部的毛细吸力越大,更易达到稳态持液状态. 展开更多
关键词 非饱和矿堆 流体流动行为 渗流迟滞 毛细吸力 持液率 COMSOL multiphysics
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Heavy-organic particle deposition from petroleum fluid flow in oil wells and pipelines
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作者 Joel Escobedo G.Ali Mansoori 《Petroleum Science》 SCIE CAS CSCD 2010年第4期502-508,共7页
Suspended asphaltenic heavy organic particles in petroleum fluids may stick to the inner walls of oil wells and pipelines. This is the major reason for fouling and arterial blockage in the petroleum industry. This rep... Suspended asphaltenic heavy organic particles in petroleum fluids may stick to the inner walls of oil wells and pipelines. This is the major reason for fouling and arterial blockage in the petroleum industry. This report is devoted the study of the mechanism of migration of suspended heavy organic particles towards the walls in oil-producing wells and pipelines. In this report we present a detailed analytical model for the heavy organics suspended particle deposition coefficient corresponding to petroleum fluids flow production conditions in oil wells. We predict the rate of particle deposition during various turbulent flow regimes. The turbulent boundary layer theory and the concepts of mass transfer are utilized to model and calculate the particle deposition rates on the walls of flowing conduits. The developed model accounts for the eddy diffusivity, and Brownian diffusivity as well as for inertial effects. The analysis presented in this paper shows that rates of particle deposition (during petroleum fluid production) on the walls of the flowing channel due solely to diffusion effects are small. It is also shown that deposition rates decrease with increasing particle size. However, when the process is momentum controlled (large particle sizes) higher deposition rates are expected. 展开更多
关键词 ASPHALTENE Brownian deposition coefficient diffusivity DIAMONDOIDS heavy organic particles paraffin/wax particle deposition petroleum fluid prefouling behavior production operation suspended particles turbulent flow
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Nonplanar post-buckling analysis of simply supported pipes conveying fluid with an axially sliding downstream end 被引量:5
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作者 Tianli JIANG Huliang DAI +1 位作者 Kun ZHOU Lin WANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2020年第1期15-32,共18页
In this study,the nonplanar post-buckling behavior of a simply supported fluid-conveying pipe with an axially sliding downstream end is investigated within the framework of a three-dimensional(3 D)theoretical model.Th... In this study,the nonplanar post-buckling behavior of a simply supported fluid-conveying pipe with an axially sliding downstream end is investigated within the framework of a three-dimensional(3 D)theoretical model.The complete nonlinear governing equations are discretized via Galerkin’s method and then numerically solved by the use of a fourth-order Runge-Kutta integration algorithm.Different initial conditions are chosen for calculations to show the nonplanar buckling characteristics of the pipe in two perpendicular lateral directions.A detailed parametric analysis is performed in order to study the influence of several key system parameters such as the mass ratio,the flow velocity,and the gravity parameter on the post-buckling behavior of the pipe.Typical results are presented in the form of bifurcation diagrams when the flow velocity is selected as the variable parameter.It is found that the pipe will stay at its original straight equilibrium position until the critical flow velocity is reached.Just beyond the critical flow velocity,the pipe would lose stability by static divergence via a pitchfork bifurcation,and two possible nonzero equilibrium positions are generated.It is shown that the buckling and post-buckling behaviors of the pipe cannot be influenced by the mass ratio parameter.Unlike a pipe with two immovable ends,however,the pinned-pinned pipe with an axially sliding downstream end shows some different features regarding post-buckling behaviors.The most important feature is that the buckling amplitude of the pipe with an axially sliding downstream end would increase first and then decrease with the increase in the flow velocity.In addition,the buckled shapes of the pipe varying with the flow velocity are displayed in order to further show the new post-buckling features of the pipe with an axially sliding downstream end. 展开更多
关键词 fluid-conveying pipe axially sliding downstream end NONPLANAR postbuckling behavior
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