Thermomechanical and Hydrous Effect of Heavy Fuel Oil in a Building Material Based on Silty Clayey Soil

This study focuses on the use of heavy fuel oil in construction in Burkina Faso.Mixed with silty and/or clay soil,it is used as a coating to reinforce the walls of raw soil constructions which are very sensitive to water.The interest of this paper is to shed light on the thermomechanical and above all water effects of heavy fuel oil on a sample of silty clayey soil.To achieve this,we used heavy fuel oil added in different proportions to silty clayey soil,to make sample of bricks on which tests were carried out.At the end of the experimental tests carried out on materials made(bricks)with our soil sample,it appears that heavy fuel oil moderately reduces the mechanical resistance of bricks and slightly increases thermal diffusion through them.On the contrary,we note a very good water resistance of the bricks thanks to the heavy fuel oil,in particular their water absorption by capillarity.This confirms that the mixture of heavy fuel oil and a silty-clayey soil used as a coating makes it possible to prevent the infiltration of water into the walls of raw soil constructions.However,its use as a construction material does not guarantee very good mechanical resistance,and slightly increases thermal diffusion.

Hexagonal boron nitride:A metal-free catalyst for deep oxidative desulfurization of fuel oils

Oxidative desulfurization(ODS)has been proved to be an efficient strategy for the production of clean fuel oil.Numerous metal-based materials have been employed as excellent ODS catalysts,but being hindered by their high-cost and potential secondary pollution.In this work,we employed graphene analogous hexagonal boron nitride(h-BN)as a metal-free catalyst for ODS with hydrogen peroxide(H2O2)as the oxidant.The h-BN catalyst was characterized and proved to be a few-layered structure with relatively high specific surface areas.The h-BN catalyst showed a 99.4%of sulfur removal in fuel oil under the optimized reaction conditions.Besides,the h-BN can be recycled for 8 times without significant decrease in the catalytic performance.Detailed mechanism analysis found that it is the boron radicals in h-BN activated H2O2 to generate·OH species,which can readily oxidize sulfides to corresponding sulfones for separation.This work would provide another choice in choosing metal-free catalysts for ODS.

An Empirical Analysis of the Price Discovery Function of Shanghai Fuel Oil Futures Market

This paper analyzes the role of price discovery of Shanghai fuel oil futures market by using methods, such as unit root test, co-integration test, error correction model, Granger causality test, impulse-response fimction and variance decomposition. The results showed that there exists a strong relationship between the spot price of Huangpu fuel oil spot market and the futures price of Shanghai fuel oil futures market. In addition, the Shanghai fuel oil futures market exhibits a highly effective price discovery function.

Comparison of toxicity effects of fuel oil treated by different dispersants on marine medaka(Oryzias melastigma) embryo

This study aims to evaluate the subacute toxic effects of oil under different treatments on marine organism by simulating natural contaminative processes. In this study, 120# （RMD15） fuel oil was selected as the pollutant and marine medaka （Oryzias melastigma） embryos as the experimental organism. The developmental toxicity of different volume concentrations （0.05%, 0.2%, 1% and 5%） of water-accommodated fractions, biologically-enhanced water-accommodated fractions, and chemically-enhanced water-accommodated fractions on the embryos in different exposure time （8, 15 and 22 d） were compared and the content of relevant polycyclic aromatic hydrocarbons （PAHs） was studied （in dispersion and in vivo）. The subacute toxic effects were assessed in terms of antioxidant activities of enzymes （superoxide dismutase, catalase and glutathione S-transferase） and the blue sac disease （BSD） indexes.The results showed that the BSD indexes of the treatment groups were significantly higher than the respective control groups and showed positive correlations with both concentration and exposure time. The experiments with three antioxidant enzymes indicated that enzymatic activities of the embryos changed dramatically under the oxidation stress of petroleum hydrocarbons, especially after adding the dispersants. With the increase of petroleum hydrocarbon concentration and exposure time, the three enzymes showed different degrees of induction and inhibition effects.

Numerical simulation of heavy fuel oil atomization using a pulsed pressure-swirl injector

It is known that increasing the injection pressure reduces the breakup length and the droplet size.Adding pulses,on the other hand,helps to atomize the liquid into finer droplets,similar to airassisted injectors but without altering the airtofuel concentration.To further reduce the droplet size and breakup length,a novel injector type,called''Pulsed PressureSwirl"(PPS),is introduced in this work,which is a combination of pressureswirl and ultrasonic pulsed injectors.A pressureswirl atomizer was designed and fabricated specifically for Mazut HFO(Heavy Fuel Oil).The droplet formation process and droplet size distribution have been studied experimentally(by shadowgraphy high speed imaging)and numerically(with the opensource VolumeofFluid code Gerris).Changing liquid injection pressure effect on the spray angle and film thickness has been quantified.These simulations have been used to study the primary breakup process and quantify the droplet size distributions,using different injection pulse frequencies and pressures.The numerical results have revealed that the new injector concept successfully produces finer droplets and results in a decrease in the breakup length,especially when applying high pulse frequencies,with no significant changes in the spray angle.

The Biomarker Changes of a Heavy Fuel Oil After Different Weathering Times

This paper presents the experimental results of composition changes of heavy fuel oil by stmulating weathering in static seawater under natural environmental conditions. The results indicate： n-C10 to n-C15 were lost gradually in 24 weeks and the relative abundance of alkanes with long chains （〉n-C19） increased markedly. The aromatic compounds with less than two tings （except C4N） were completely lost in 24 weeks and CnP and CnD became the main aromatics in the heavy fuel oil after 24 weeks. The ratios of n- C1/Pristane （Pr） and n-C18 Phytane （Ph） were suitable for identifying lightly weathered （3 weeks） heavy fuel oil. The ratios of n-ClT/n-C18 and Pr/Ph were suitable for identifying moderately weathered heavy fuel oil （12 weeks）; the ratios of C2D/C2P and C3D/C3P did not change significantly in 24 weeks and were more suitable for identifying moderately weathered heavy fuel oil （24 weeks）.

A STUDY ON' SYNCHRONOUS-HI GH-DERIVATIVE SPECTFLUOR—THE DI FFERENTI ATI ON OF CRUDE OIL AND FUEL OIL POLLUTION

A method of synchronous-high-derivative spectfluor for identification of crude oil and fuel oil pollution is studied. The best operation conditions for the 2nd and 4th deriv, are set. To differentiate oil-spill at river and sea, this method is rapid and simple, and the spectra have high resolution power as 'fingerprint'.

Microscopic and macroscopic atomization characteristics of a pressure-swirl atomizer, injecting a viscous fuel oil

Combustion of heavy fuels is one of the main sources of greenhouse gases, particulate emissions, ashes, NOxand SOx. Gasification is an advanced and environmentally friendly process that generates combustible and clean gas products such as hydrogen. Some entrained flow gasifiers operate with Heavy Fuel Oil(HFO) feedstock. In this application, HFO atomization is very important in determining the performance and efficiency of the gasifiers.The atomization characteristics of HFO(Mazut) discharging from a pressure-swirl atomizer(PSA) are studied for different pressures difference(Δp) and temperatures in the atmospheric ambient. The investigated parameters include atomizer mass flow rate( _m), discharge coefficient(CD), spray cone angle(θ), breakup length(Lb), the unstable wavelength of undulations on the liquid sheet(λs), global and local SMD(sauter mean diameter) and size distribution of droplets. The characteristics of Mazut sheet breakup are deduced from the shadowgraph technique. The experiments on Mazut film breakup were compared with the predictions obtained from the liquid film breakup model. Validity of the theory for predicting maximum unstable wavelength was investigated for HFO(as a highly viscous liquid). A modification on the formulation of maximum unstable wavelength was presented for HFO. SMD decreases by getting far from the atomizer. The measurement for SMD and θ were compared with the available correlations. The comparisons of the available correlations with the measurements of SMD andθ show a good agreement for Ballester and Varde correlations, respectively. The results show that the experimental sizing data could be presented by Rosin-Rammler distributions very well at different pressure difference and temperatures.

Biodiesel from Plant Resources—Sustainable Solution to Ever Increasing Fuel Oil Demands

The demand for fuel oil is ever increasing with the advance of the modern world, whereas worldwide reserves of fossil oils are diminishing at an alarming rate. However, there exist large stockpiles of vegetable oil feedstocks that could be exploited to produce fuel oil, called biodiesel with the aid of biotechnology. Initially, the biodiesel produced from vegetable oil did not attract much attention because of its high cost. However, the recent increase in petroleum prices and the uncertainties of petroleum availability led to the renewal of interest in biodiesel production from such sustainable resources (i.e., vegetable oil feedstocks). This research focuses on the production of biodiesel from plant resources, and further investigates the influences of key process parameters, such as the molar ratio of methanol to oil, catalyst concentration, reaction temperature, reaction period and stirring speed on the biodiesel yield. This investigation is to determine the optimum process parameters for maximum biodiesel yield. The biodiesel was produced from three vegetable oil feedstocks, namely palm, soybean and sunflower oil via a transesterification process. It was observed that all the process parameters significantly influenced the biodiesel yield. The maximum biodiesel yields for palm, sunflower and soybean oil feedstocks were found to be 87.5%, 83.6% and 80.2%, respectively at optimum condition. The results suggest that through proper optimization of the process parameters the biodiesel yields could be maximized. In conclusion, the production of biodiesel from plant resources would be regarded as a sustainable solution to the ever increasing demand of fuel oils.

Synthesis of nanofluids composed of deep eutectic solvents and metal-modified MCM-41 particles as multifunctional promoters for fuel oil desulfurization

Compared with traditional hydrodesulfurization,new nonhydrodesulfurization methods have the advantage of a high removal efficiency for thiophene compounds under mild conditions.However,independent nonhydrodesulfurization technologies are faced with their own shortcomings,such as limitations of the desulfurization performance and regeneration of materials.To overcome these limitations,four nanofluids were prepared by dispersing different metal-modified MCM-41 particles in deep eutectic solvent as multifunctional promoters to develop a comprehensive desulfurization method.Based on the excellent adsorbability and high catalytic activity of the dispersed particles and the outstanding extractability of deep eutectic solvent in nanofluids,a high sulfur removal of 99.33%was achieved for model oil under mild conditions in 15 min.The nanofluids also showed excellent reusability due to their high structural stability.In addition,NF@Cu/Al-MCM-41-2.5%exhibited the best desulfurization performance among the prepared nanofluids.This result was obtained because the introduction of Al ions increased the number of acid sites and defect sites to improve the catalytic activity and adsorbability,and the best affinity of Cu/Al-MCM-41 for the deep eutectic solvent favored the reaction mass transfer.This work opens the door to the development of a comprehensive nonhydrodesulfurization method based on the design of nanofluid materials.

Application of Non-Fuel Power Generation Technology in Steel Industry

Through continuous equipment technology transformation and full utilization of Ma Steel's abundant gas,the boiler no longer relies on fuel oil for stable combustion during boiler startup,sliding parameter shutdown,and RB,thus achieving safe and stable operation of the boiler under any abnormal working conditions,and achieving good economic and social benefits.

Chemical and Thermal Characterization of Cement Mortar Containing Ground Palm Oil Fuel Ash as a Partial Cement Replacement

This study investigates the influence of using ground palm oil fuel ash(G-POFA) from 10%-30% as cement replacement(by weight) on the cement mortar's pH under various curing conditions. These findings were supplemented by thermal gravimetric analysis(TGA). Moreover, the resistance of G-POFA blended cement mortars to water absorption and sorptivity was determined. Further, the k-value test was carried out to explain the pozzolanic and filler behavior of G-POFA and to support the results obtained from TGA. It was found that there was no significant impact of several curing conditions on the pH of mortars. The mortar with 10% G-POFA in replacement of cement(G-POFA-10) exhibited the best resistance against water absorption and sorptivity.

The Effect of Reaction Temperature, Catalyst Concentration and Alcohol Ratio in the Production of Biodiesel from Raw and Purified Castor Oil

In this study, a homogeneous alkaline catalyst was used in the production of biodiesel from raw and refined castor oil feedstock. The effect of potassium hydroxide (KOH) as a catalyst between the two feedstocks, raw and refined castor oil was compared. The transesterification technique was utilized in this study, aiming to investigate the effect of different parameters, which include the reaction temperature, methanol-to-oil mole ratio, and catalyst concentration at a constant period of 90 minutes. The result revealed the performance of the KOH catalyst on raw castor oil yielded 98.49% FAME, which was higher than the refined castor oil which yielded 97.9% FAME. The optimal conditions obtained from refined castor oil were applied to raw castor oil because of the same properties. The fuel quality of castor oil and produced biodiesel were tested for physicochemical properties.

Spectrum features of commercial derv fuel oils in the terahertz region

Characteristic spectra in the 0.5-2.5 terahertz (THz) range of three commercial derv fuel oils have been obtained using THz time-domain spectroscopy and calculated using density functional theory.The simulated results and experimental absorption curves suggest that the skeleton vibration is predominant in the THz region,and the absorption bumps of diesels are a superposition of various components.The investigation demonstrates that different diesels can be distinguished using THz time-domain spectroscopy and THz technology is a promising method to detect the composition and properties of diesels via chemical analysis.

Biodiesel from Palm Vegetable Oil

Energy obtained from a variety of non-renewable sources is considered unsustainable. Various fossil fuels, such as petroleum, coal, and natural gas, are among these sources. The combustion of fossil fuels resulted in the generation of greenhouse gases, which increased the amount of carbon dioxide in the atmosphere. Global warming and ozone layer degradation are the negative consequences. In a country like India, where consumable oils are still imported, it is sense to look at the possibility of using such unpalatable oils in CI engines that aren’t often utilized as cooking oil. Palm oil is a vegetable oil obtained from the monocarp of the oil palm’s crop. The main goal is to provide a low-cost, high-performance alternative to diesel. The possibility of palm oil as a realistic, modest, and effective hotspot for the generation of biodiesel is investigated in this research. The article is focused on the comparison of palm oil and diesel in terms of characteristics.

Numerical Heat Transfer Modelling for Rapid Impact Assessment of Limiting Thermostat Reliability on Fuel-Oil Burner Pre-Heaters： A Case Study

In this paper, the impact of limiting thermostat on the rupture event occuring in Fuel-Oil burner fuel pre-heaters＇ resistant （heat generating） wires is inspected numerically. Gaseous fuel content in the pipeline has also been issued as a possibility. Heater＇s inner temperature distributions have been simulated by an in-house MATrix LABoratory （MATLAB） script in order to understand the resistant wire exposure to high temperatures by numerous scenarios. It is concluded that the effect of fuel flowrate is not a major effect on the wires＇ fate because of the limiting thermostat co-working. The main difference between the calculations is the effect of thermostat cut off function. The numerical simulations enlightened the dominant effect of thermostat sensing delay, so the overheating event. Intolerable delay results with a quick drop in the thermal efficiency and an increased possibility on wire rupture due to overheating which means a burner malfunction. Referring to the first numerical simulation results, a distributed and reduced heat flux was implemented with the same fluid and thermodynamic properties on a revised pre-heater model with an increased heater plate. The increment, thus the reduction on the heat flux of the ribbon wires has been noted as the key for safe operation.

Microbial desulfurization of fuel oil

Culture conditions of desulfurization microbes were investigated with a bioreactor controlled by computer. Factors such as pH, choice of carbon source, optimal concentrations of carbon, nitrogen and sulfur sources were determined. The addition of carbon in a culture with a constant pH greatly improved the growth of Rhodococcus. Cells and cell debris from microbes rested using a sulfur-specific pathway were used to desulfurize diesel oil treated by hy-drodesulfurization (acquired from the Research Institute of Fushun Petroleum with total sulfur level at 205μg/mL). Strains lawq, IG, X7B, ZT, ZCR, and a mixture of No. 5 and No. 6, were used in the biodesulfurization process. The reduction of total sulfur was between 10.6% and 90.3%.

Strength and chloride resistance of blended Portland cement mortar containing palm oil fuel ash and fly ash

This paper presented a study on the strength and chloride resistance of mortars made with ternary blends of ordinary Portland cement （OPC）, ground palm oil fuel ash （POA）, and classified fly ash （FA）. The mortar mixtures were made with Portland cement type I containing 0-40wt% FA and POA. FA and POA with 1wt%-3wt% retained on a sieve No.325 were used. The compressive strength and rapid chloride penetration depth of mortars were determined. The results reveal that the use of ternary blended cements produces good strength mortars. The use of the blend of FA and POA also produces high strength mortars and excellent resistance to chloride penetration owing to the synergic effect of FA and POA. A mathematical analysis and two-parameter polynomial model were presented to predict the compressive strength. The mathematical model correlated well with the experimental results. The computer 3-D graphics of strength of the ternary blended mortars were also constructed and could be used to aid the understanding and the proportioning of the blended system.

Emission of intermediate volatility organic compounds from a ship main engine burning heavy fuel oil

Intermediate volatility organic compounds(IVOCs)are crucial precursors of secondary organic aerosol(SOA).In this study,gaseous IVOCs emitted from a ship main engine burning heavy fuel oil(HFO)were investigated on a test bench,which could simulate the real-world operations and emissions of ocean-going ships.The chemical compositions,emission factors(EFs)and volatility distributions of IVOC emissions were investigated.The results showed that the main engine burning HFO emitted a large amount of IVOCs,with average IVOC EFs of 20.2-201 mg/kg-fuel.The IVOCs were mainly comprised of unspeciated compounds.The chemical compositions of exhaust IVOCs were different from that of HFO fuel,especially for polycyclic aromatic compounds and alkylcyclohexanes.The volatility distributions of IVOCs were also different between HFO exhausts and HFO fuel.The distinctions in IVOC emission characteristics between HFO exhausts and HFO fuel should be considered when assessing the IVOC emission and related SOA formation potentials from ocean-going ships burning HFO,especially when using fuel-surrogate models.