The polarization orientation effect and porosity effect on the piezoelectric properties and related parameters are studied in 2-2-type composites based on domain-engineered relaxor-ferroelectric[011]-poled single crys...The polarization orientation effect and porosity effect on the piezoelectric properties and related parameters are studied in 2-2-type composites based on domain-engineered relaxor-ferroelectric[011]-poled single crystals.The parameters,which are of great interest,are an anisotropy of the piezoelectric coefficients d_(3j)^(*),an anisotropy of the energy-harvesting figures of merit d_(3j)^(*)g_(3j)^(*) and the hydrostatic piezoelectric coefficient d_(h)^(*).An orientation of the main crystallographic axes in each polydomain single-crystal layer is described by anglesβandγ.Diagrams built for the first time show the(β,γ)regions,where a large anisotropy of d_(3j)^(*)(or d_(3j)^(*)g_(3j)^(*))is achieved,and where inequality d_(h)^(*)>1000 pC/N holds.A large local max d_(h)^(*)=1930 pC/N is achieved in a 2-2-0 PZN-0.065PT-based composite at the longitudinal piezoelectric coefficient d33*=2290 pC/N and figure of merit d*33g*33=1.02.10−9 Pa−1.The aforementioned large parameters are to be of value in piezoelectric sensing,energy harvesting and hydroacoustics.展开更多
基金supported by the Southern Federal University(research topic“Development and Materials-Science Substantiation of the Creation of Materials and Products Based on Piezoelectric Ceramics Using Additive Technologies”,stage 2022,contract No.176/22-D,July 11th,2022).
文摘The polarization orientation effect and porosity effect on the piezoelectric properties and related parameters are studied in 2-2-type composites based on domain-engineered relaxor-ferroelectric[011]-poled single crystals.The parameters,which are of great interest,are an anisotropy of the piezoelectric coefficients d_(3j)^(*),an anisotropy of the energy-harvesting figures of merit d_(3j)^(*)g_(3j)^(*) and the hydrostatic piezoelectric coefficient d_(h)^(*).An orientation of the main crystallographic axes in each polydomain single-crystal layer is described by anglesβandγ.Diagrams built for the first time show the(β,γ)regions,where a large anisotropy of d_(3j)^(*)(or d_(3j)^(*)g_(3j)^(*))is achieved,and where inequality d_(h)^(*)>1000 pC/N holds.A large local max d_(h)^(*)=1930 pC/N is achieved in a 2-2-0 PZN-0.065PT-based composite at the longitudinal piezoelectric coefficient d33*=2290 pC/N and figure of merit d*33g*33=1.02.10−9 Pa−1.The aforementioned large parameters are to be of value in piezoelectric sensing,energy harvesting and hydroacoustics.
