Nano-SrB2O4 powder was prepared by solid-state reaction at room temperature followed by a subsequent calcination process. The highly productive method which can be operated easily confirms to the Green-chemistry princ...Nano-SrB2O4 powder was prepared by solid-state reaction at room temperature followed by a subsequent calcination process. The highly productive method which can be operated easily confirms to the Green-chemistry principles. The XRD patters demonstrate that the component of the as-obtained sample is SrB2O4 after calcination at 600℃. Differential thermal analysis and thermogravimetriy (DTA/TG) curves suggest the process of dehydration and crystal transition from Sr[B(OH)4]2 to SrB2O4·2H2O. SEM image of SrB2O4 shows that the particles are uniform and spherical with average size of 80 nm in diameter. Furthermore, the mechanism of reaction was discussed. The chemical reaction of the process is assumed to be acid-base neutralization reaction. The water generated from the acid-base neutralization reaction and the release of crystal water from Sr(OH)2·8H2O plays an essential role in the reaction system.展开更多
A novel and simple one-step, solid state reaction of multicomponent systems has been developed to synthesize cyclopentadienyl-containing organolanthanide complexes, in which the effects of the coordinated solvent mole...A novel and simple one-step, solid state reaction of multicomponent systems has been developed to synthesize cyclopentadienyl-containing organolanthanide complexes, in which the effects of the coordinated solvent molecules and the nature of the reactants were also studied. We also studied the solid state decomposition reaction of Cp2YbPz(HPz), and the formation of [CpYb(Pz)2]2 may indicate that the constrained environment in solid state can lead to a novel chemical transformation, with product selectivity possibly different from that in the liquid phase.展开更多
文摘Nano-SrB2O4 powder was prepared by solid-state reaction at room temperature followed by a subsequent calcination process. The highly productive method which can be operated easily confirms to the Green-chemistry principles. The XRD patters demonstrate that the component of the as-obtained sample is SrB2O4 after calcination at 600℃. Differential thermal analysis and thermogravimetriy (DTA/TG) curves suggest the process of dehydration and crystal transition from Sr[B(OH)4]2 to SrB2O4·2H2O. SEM image of SrB2O4 shows that the particles are uniform and spherical with average size of 80 nm in diameter. Furthermore, the mechanism of reaction was discussed. The chemical reaction of the process is assumed to be acid-base neutralization reaction. The water generated from the acid-base neutralization reaction and the release of crystal water from Sr(OH)2·8H2O plays an essential role in the reaction system.
基金This work was supported by the National Natural Science Foundation of China(Grunt No.20172013)the Rescarch Funds of Excellent Young Teacher and the New Century Distinguished Scientist of the Ministry of Education of China.
文摘A novel and simple one-step, solid state reaction of multicomponent systems has been developed to synthesize cyclopentadienyl-containing organolanthanide complexes, in which the effects of the coordinated solvent molecules and the nature of the reactants were also studied. We also studied the solid state decomposition reaction of Cp2YbPz(HPz), and the formation of [CpYb(Pz)2]2 may indicate that the constrained environment in solid state can lead to a novel chemical transformation, with product selectivity possibly different from that in the liquid phase.
