The nanometer particles of TiO_2 and TiO_2/SiO_2 oxides wereprepared by sol-gel supercritical fluid drying method. The propertiesof TiO_2 and TiO_2/SiO_2 were characterized by means of BET(Brunner-Emmett- Teller metho...The nanometer particles of TiO_2 and TiO_2/SiO_2 oxides wereprepared by sol-gel supercritical fluid drying method. The propertiesof TiO_2 and TiO_2/SiO_2 were characterized by means of BET(Brunner-Emmett- Teller method), TEM (transmission electronmicroscopy), SEM (scanning electron microscopy), XRD (X-ray diffrac-tion) and FTIR (Fourier transform-infrared) techniques. The effectsof different preparation route, prehydrolysis and non-prehydrolysis,on the properties of TiO_2/SiO_2 oxide were also examined.展开更多
Two critical parameters:Glossiness and chromaticity space of pearlescent pigments were evaluated based on crystallinity and grain size.Both the roughness and the vertical distance evolution along the surface of deposi...Two critical parameters:Glossiness and chromaticity space of pearlescent pigments were evaluated based on crystallinity and grain size.Both the roughness and the vertical distance evolution along the surface of deposited TiO_(2)film are affected by the crystallinity.The optimal crystallinity of TiO_(2)was deposited at the temperature of 350℃.The TiCl4 concentration effectively changed the grain size.However,the high flow rate of fluidizing gas and optimal gas–solid ratio(<0.11 m^(3)/(kg h))restricted the change of TiCl_(4)concentrations in fluidized bed reactor.In this case,the grain size of the deposited TiO_(2)film was about 55 nm.Depending on the grain size,the color of pearlescent pigments was adjusted by controlling the film thickness based on TiO_(2)concentration.Finally,the silver pearlescent pigment with high glossiness was prepared by chemical vapor deposition method in a fluidized bed reactor.展开更多
基金Supported by PetroChina Company Limited (990801-21-2).
文摘The nanometer particles of TiO_2 and TiO_2/SiO_2 oxides wereprepared by sol-gel supercritical fluid drying method. The propertiesof TiO_2 and TiO_2/SiO_2 were characterized by means of BET(Brunner-Emmett- Teller method), TEM (transmission electronmicroscopy), SEM (scanning electron microscopy), XRD (X-ray diffrac-tion) and FTIR (Fourier transform-infrared) techniques. The effectsof different preparation route, prehydrolysis and non-prehydrolysis,on the properties of TiO_2/SiO_2 oxide were also examined.
基金support from National Natural Science Foundation of China(grant Nos.22208355,21978300 and 22178363).
文摘Two critical parameters:Glossiness and chromaticity space of pearlescent pigments were evaluated based on crystallinity and grain size.Both the roughness and the vertical distance evolution along the surface of deposited TiO_(2)film are affected by the crystallinity.The optimal crystallinity of TiO_(2)was deposited at the temperature of 350℃.The TiCl4 concentration effectively changed the grain size.However,the high flow rate of fluidizing gas and optimal gas–solid ratio(<0.11 m^(3)/(kg h))restricted the change of TiCl_(4)concentrations in fluidized bed reactor.In this case,the grain size of the deposited TiO_(2)film was about 55 nm.Depending on the grain size,the color of pearlescent pigments was adjusted by controlling the film thickness based on TiO_(2)concentration.Finally,the silver pearlescent pigment with high glossiness was prepared by chemical vapor deposition method in a fluidized bed reactor.
