Artificial nest boxes are placed to attract birds to nest and breed in a specific location,and they are widely used in avian ecology research and in the attraction of insectivorous birds.There is evidence that artific...Artificial nest boxes are placed to attract birds to nest and breed in a specific location,and they are widely used in avian ecology research and in the attraction of insectivorous birds.There is evidence that artificial nest boxes can adversely affect breeding fitness but no great focus has been placed on this issue by researchers.Therefore,we retrieved 321 research papers regarding artificial nest boxes published from 2003 to 2022 and used the'Biblioshiny'program to extract and integrate keywords;we then summarized the adverse effects of artificial nest boxes on avian breeding success.The studies highlighted many drawbacks and misuses in the designing and placement of nest boxes;furthermore,bird attraction was decreased by their inappropriate selection,thus reducing breeding success.Regarding nest box production,there were shortcomings in the construction material,color,smell,and structural design of the boxes used.Nest boxes were also placed at inappropriate densities,locations,orientations,heights,and managed incorrectly.Finally,we propose suggestions for more efficient and safer artificial nest boxes for future use in avian ecology research and bird conservation.展开更多
This paper attempts to investigate the negative effects of the spread of COVID-19 on low-income families in Egypt.Coronavirus spread is measured by"Coronavirus cases"and"Coronavirus deaths"on a dai...This paper attempts to investigate the negative effects of the spread of COVID-19 on low-income families in Egypt.Coronavirus spread is measured by"Coronavirus cases"and"Coronavirus deaths"on a daily basis.Besides,it is measured by both"new Coronavirus cases"and"new deaths from Coronavirus",in relation to the population of Egypt.The Egyptian government is taking some measures to reduce the negative effects of COVID-19,including increasing personal exemptions by amending some provisions of the Egyptian Income Tax Law promulgated by Law No.91 of 2005 to protect low-income families.Of the negative effects of COVID-19,it is one of the most important tax policies to achieve social justice in distributing the tax burden,according to income levels,in a manner that achieves justice and equality.We find that Personal exemptions did not succeed in achieving tax justice by easing the tax burden on the low-income people in society.展开更多
With the development of computer and network technologies, computer--assisted language teaching and learning have been changing from the presentation of single text materials and response model to the integration of o...With the development of computer and network technologies, computer--assisted language teaching and learning have been changing from the presentation of single text materials and response model to the integration of outside classroom education media combining text, graphics, images, sound, animation and network communication (CMC) technology. As an auxiliary tool of foreign language teaching, the computer plays its huge potential and promotes the completion of all kinds of language learning tasks. However, high cost and lack of technical support bringing the negative effects to the foreign language teaching is also cannot be ignored. Therefore, in the study of the historical evolvement of the CALL, to fully understand the positive and negative effects from the foreign language teaching will help make the positive effect of foreign language teaching maximized, and avoid misuse and abuse of the CALL.展开更多
In such an information age, multimedia teaching has changed into one of the most important educational ways in middle and primary schools. In contrast to traditional education, multimedia teaching owns numerous advant...In such an information age, multimedia teaching has changed into one of the most important educational ways in middle and primary schools. In contrast to traditional education, multimedia teaching owns numerous advantages. However, there are also a great number of shortcomings in it. In this paper, considering the current situation of education in middle and primary schools, the author carries out an analysis on the negative effects of multimedia teaching on education in middle and primary schools, and also proposes some personal suggestions, hopefully providing a reference for teaching personnel in middle and primary schools.展开更多
This paper summarizes the negative effects on geological environment caused by groundwater exploitation and its distribution. There are seven main types of the geological environment negative effects, which are genera...This paper summarizes the negative effects on geological environment caused by groundwater exploitation and its distribution. There are seven main types of the geological environment negative effects, which are generally as follows:(1) Constant decrease of groundwater level is mainly distributed in China(East Asia), India(South Asia), Tajikistan(Central Asia) and Saudi Arabia(West Asia);(2) land subsidence occurs mainly in eastern plains of East Asia and west Siberian Plain of North Asia;(3) seawater intrusion occurs mainly in China, Japan and South Korea in East Asia, Philippines and Indonesia in Southeast Asia, the Indian coastal areas in South Asia;(4) groundwater level decline caused by groundwater exploitation in oil fields;(5) mining collapse is mainly in 50° to 70° north latitude band;(6) the total area of karst collapse in China of East Asia is as much as 197.05 km^2; and(7) ground fracture is mainly distributed in the North China Plain, Fenwei Plain and the Yangtze River Delta. Asia can be divided into 6 zones in terms of the geological environment negative effect caused by groundwater exploitation. According to analysis, with the increasing intensity of human activities, geological environment issues become more and more serious, therefore it is vital to control the human activities within the scope of 5× 10~5 people/km^2 to 9.9× 10~5 people/km^2 for the effective control of the size of the affected area by geological environment problems.展开更多
deployment of the THAAD system in South Korea imposed by the United States is superficially and nominally to target at the DPRK's nuclear and missile threats,but essentially to respond to the rising China and Russ...deployment of the THAAD system in South Korea imposed by the United States is superficially and nominally to target at the DPRK's nuclear and missile threats,but essentially to respond to the rising China and Russia,is further tied South Korea to the U.S.war chariot and is a dose of poison undermining the Northeast Asian environment for the mutual benefit,mutual trust and win-win cooperation as well as development and stability.展开更多
Soil structure and nutrient ingredient before and after shattering and returning sugarcane leaf as well as its technologies and methods were comparatively analyzed in this study to discuss the main reasons primarily,w...Soil structure and nutrient ingredient before and after shattering and returning sugarcane leaf as well as its technologies and methods were comparatively analyzed in this study to discuss the main reasons primarily,while the controlling technologies were proposed by combining cultivation,management and technical measures.展开更多
Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial stre...Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial strengths, the specimens were placed in 40, 60, or 80 t water tanks foraccelerated curing. The Coulomb values of the specimens weemeasured with ASTM C1202 experiment at 28, 100, 200, ad300 d. Partial specimens were also selected for rapid chlorideion migration coefficient and mercury intrusion porosimetryexperiments. The experimental results show that theaccelerated curing for ordinary concrete linealy deterioratesthe chloride penetration resistance, whereas the incorporationof mineral admixtures improves the concrete microscopic pore-structures and negative effects. An upper temperature limit of60 t of the accelerated curing is suitable for obtainingsuperior chloride penetration resistance for the mineraladmixture concrete. Pre-curing at a normal temperature of 20t is beneficial for improving the negative effect, which isalso aieviated with increasing testing age as a result of thesuccessive hydration of binder materials in concrete.展开更多
The electronic and transport characteristics of protonated derivatives of naphthalocyanine(Nc)were investigated using density functional theory and non-equilibrium Green's functions.The results indicate that the p...The electronic and transport characteristics of protonated derivatives of naphthalocyanine(Nc)were investigated using density functional theory and non-equilibrium Green's functions.The results indicate that the protonation of external meso-N atoms of Nc preserves its planar structure and is energetically more favorable than the protonation of internal isoindole-N atoms.The protonation shifts the energy levels of system's frontier molecular orbitals closer to the Fermi level,thus creating channels for electron transport.In contrast with the semiconductor transport properties of H2Nc,its protonation products respond more sensitively to bias and exhibit negative differential resistance phenomena at specific bias.展开更多
As one of the most distinguished features of Chinese Culture,collective oriented culture is the deep structure of Chinese cultural psychology which has shaped Chinese character and influenced their behavior.As a resul...As one of the most distinguished features of Chinese Culture,collective oriented culture is the deep structure of Chinese cultural psychology which has shaped Chinese character and influenced their behavior.As a result of it,Chinese students suffer this negative effect from collective orientated culture when acquiring English,especially in oral English acquisition.TEFL teachers should be aware of cultural psychology and try their best to minimize its negative effect instead of neglecting or even enlarging it during oral English teaching.展开更多
Efficient photogenerated carrier migration/separation plays a critical role in increasing the photocatalytic performance of g-C_(3)N_(4).Herein,sulfonic acid group-functionalized g-C_(3)N_(4)(SACN)was synthesized and ...Efficient photogenerated carrier migration/separation plays a critical role in increasing the photocatalytic performance of g-C_(3)N_(4).Herein,sulfonic acid group-functionalized g-C_(3)N_(4)(SACN)was synthesized and then synchronously strengthened by a facile-solid-state thermal reaction of g-C_(3)N_(4)and sulfamic acid.As a solid strong acid,sulfamic acid can be used to achieve acid etching on the surface of g-C_(3)N_(4)with the assistance of thermal treatment,leading to an enlarged specific surface area and increased surface catalytic reaction sites.More importantly,our experiments and density functional theory calculations indicate that the driving force generated by the negative inductive effect of sulfonic acid groups significantly improves the charge transfer dynamics and effectively inhibits their recombination.Moreover,the negative inductive effect can induce charge redistribution,which reduces the conduction band potential of g-C_(3)N_(4)to enhance the reduction ability of photo-induced electrons.As a result,the SACN-400 sample showed excellent photocatalytic performance in H2 generation with an apparent quantum efficiency of 11.03%at 420±15 nm,as well as an efficient photodegradation rate for organic pollutants.展开更多
The anti-resonant phenomenon of effective electromagnetic parameters of metamaterials has aroused controversy due to negative imaginary permittivity or permeability. It is experimentally found that the negative imagin...The anti-resonant phenomenon of effective electromagnetic parameters of metamaterials has aroused controversy due to negative imaginary permittivity or permeability. It is experimentally found that the negative imaginary permittivity can occur for the natural passive materials near the Fabry Perot resonances. We reveal the nature of negative imaginary permittivity, which is correlated with the magnetoelectric coupling. The anti-resonance of permittivity is a non-inherent feature for passive materials, while it can be inherent for devices or metamaterials. Our finding validates that the negative imaginary part of effective permittivity does not contradict the second law of thermodynamics for metamaterials owing to the magnetoelectric coupling.展开更多
The present paper discusses three major sources of negative effect of classroom instruction on L2 learners' pragmatic development: inadequate or inappropriate metapragmatic input, non-authentic classroom discourse a...The present paper discusses three major sources of negative effect of classroom instruction on L2 learners' pragmatic development: inadequate or inappropriate metapragmatic input, non-authentic classroom discourse and grammar-oriented pedagogy, then proposes some pedagogical suggestions on developing pragmatic competence.展开更多
Y^3+-doped (Bi 1/2 Na 1/2) TiO 3-CaTiO 3-BaTiO 3 (BNCBT) positive temperature coefficient of resistivity (PTCR) ceramics sintered in air atmosphere were investigated in this study. (Bi 1/2 Na 1/2) TiO 3 (BNT...Y^3+-doped (Bi 1/2 Na 1/2) TiO 3-CaTiO 3-BaTiO 3 (BNCBT) positive temperature coefficient of resistivity (PTCR) ceramics sintered in air atmosphere were investigated in this study. (Bi 1/2 Na 1/2) TiO 3 (BNT) component can remarkably increase the onset temperature T c of PTCR ceramics with the expense of the resistivity R 25 increase. CaTiO 3 (9–27 mol%) component can decrease the resistivity, and adjust the effects of BNT phase on the T c point. For the sample containing 3 mol% CaTiO 3 , T c raises from 122 ℃ to 153 ℃ when only 0.6 mol% BNT added, while for the ones with higher CaTiO 3 content (9–27 mol%), T c is only increased by a rate of 8–9℃/1.0 mol% BNT. The effects of BNT and CaTiO 3 components on R25/Rmin (negative temperature coefficient effect) are also discussed.展开更多
To clarify the anodic dissolution mechanism of Mg,the hydrogen evolution from pure Mg in acidic solutions under galvanostatic conditions were systematically measured.With increasing anodic current density,the cathodic...To clarify the anodic dissolution mechanism of Mg,the hydrogen evolution from pure Mg in acidic solutions under galvanostatic conditions were systematically measured.With increasing anodic current density,the cathodic hydrogen evolution rate decreased,and the anodic hydrogen evolution became faster while some surface area on the Mg was becoming dark under anodic polarization.Based on the surface analysis results and the generally accepted basic electrochemical equations,the evolution kinetics of hydrogen from Mg was deduced,and the most possible surface intermediate active species that could facilitate the anodic Mg dissolution and anodic hydrogen evolution were proposed.This paper further develops the model of incomplete film Mg^(+) dissolution,explains many reported experimental phenomena,and clarifies misunderstandings of current mechanism.展开更多
San-Huang chicken is a high-quality breed in China with yellow feather, claw and break. However, the abnormal phenomenon of the yellow shank turning into green shank of San-Huang chicken has been a concern, as it seri...San-Huang chicken is a high-quality breed in China with yellow feather, claw and break. However, the abnormal phenomenon of the yellow shank turning into green shank of San-Huang chicken has been a concern, as it seriously reduces the carcass quality and economic benefit of yellow-feathered broilers. In this study, the cause of this abnormal green skin in shank was systematically investigated. Physiological anatomy revealed that the abnormal skin in shank was primarily due to the deposition of melanin under the dermis. After analyzing multiple potential causes such as heredity(pedigree and genetic markers), environment(water quality monitoring) and feed composition(mycotoxin detection), excessive aflatoxin B1(AFB1) in feed was screened, accompanied with a higher L-dihydroxy-phenylalanine(L-DOPA)(P<0.05) and melanin content(P<0.01). So it was speculated that excessive AFB1 might be the main cause of abnormal green skin in shank. Subsequently, the further results showed that a high concentration of AFB1(>170 μg kg–1)indeed induced the abnormal green skin in shank compared to the normal AFB1 content(<10 μg kg–1), and the mRNA levels of TYR, TYRP1, MITE, MC1R and EDN3 genes related to melanin deposition would significantly up-regulate(P<0.01) and the content and activity of tyrosinase(TyR) significantly increased(P<0.05). At the same time, the content of L-DOPA and melanin deposition also increased significantly(P<0.01), which also confirmed the effect of excessive AFB1 on melanin deposition in skin of shank. Results of additional experiments revealed that the AFB1's negative effect on melanin deposition in skin of shank could last for a longer time. Taken together, the results of this study explained the occurrence and possible mechanisms of the abnormal AFB1-related green skin in shank of chickens. Excessive AFB1 in diets increased the L-DOPA content and melanin abnormal deposition in the chicken shank possibly via promoting TyR content and activity, and the expression of melanin synthesis-related genes. Furthermore, our findings once again raised the alarm of the danger of AFB1 in the broiler production.展开更多
Mechanistic understanding of the active intermediates of 2,6-diaminopyridine(DAP) dinitration in the concentrated nitric-sulfuric acid system is of crucial importance for the selectivity control of target product, i.e...Mechanistic understanding of the active intermediates of 2,6-diaminopyridine(DAP) dinitration in the concentrated nitric-sulfuric acid system is of crucial importance for the selectivity control of target product, i.e., 2,6-diamino-3,5-dinitropyridine(DADNP). The active intermediates determining the product selectivity are theoretically studied. The HSO_(4)^(-)-NO_(2)^(+) complex is proposed as the dominant active nitrating intermediate for the first time, which shows low energy barrier(i.e., 10.19 kcal·mol^(-1),1 kcal = 4.186 k J) for direct dinitration of DAP to DADNP. The formed water during the reaction results in not only the formation of less active SO_(4)^(2-)-NO_(2)^(+) complex, but also the occurance of DAP sulfonation(DAP-SO_(3)H intermediate)to facilitate the formation of mononitration byproduct. Meanwhile, the accompanied thermal effects cause the generation of undesirable pyridine-NHNO_(2) intermediate, which is difficult to be rearranged to yield DADNP, inhibiting the reaction and thus giving low DAP conversion. The insights reported here elucidates the importance of thermal effects elimination and water content control, confirmed experimentally in the batch-and micro-reaction systems.展开更多
Nodal-line semimetals have become a research hot-spot due to their novel properties and great potential application in spin electronics. It is more challenging to find 2D nodal-line semimetals that can resist the spin...Nodal-line semimetals have become a research hot-spot due to their novel properties and great potential application in spin electronics. It is more challenging to find 2D nodal-line semimetals that can resist the spin–orbit coupling(SOC)effect. Here, we predict that 2D tetragonal Zn B is a nodal-line semimetal with great transport properties. There are two crossing bands centered on the S point at the Fermi surface without SOC, which are mainly composed of the pxy orbitals of Zn and B atoms and the pz orbitals of the B atom. Therefore, the system presents a nodal line centered on the S point in its Brillouin zone(BZ). And the nodal line is protected by the horizontal mirror symmetry M_(z). We further examine the robustness of a nodal line under biaxial strain by applying up to-4% in-plane compressive strain and 5% tensile strain on the Zn B monolayer, respectively. The transmission along the a direction is significantly stronger than that along the b direction in the conductive channel. The current in the a direction is as high as 26.63 μA at 0.8 V, and that in the b direction reaches 8.68 μA at 0.8 V. It is interesting that the transport characteristics of Zn B show the negative differential resistance(NDR) effect after 0.8 V along the a(b) direction. The results provide an ideal platform for research of fundamental physics of 2D nodal-line fermions and nanoscale spintronics, as well as the design of new quantum devices.展开更多
A negative capacitance(NC)effect has been proposed as a critical pathway to overcome the‘Boltzmann tyranny’of electrons,achieve the steep slope operation of transistors and reduce the power dissipation of current se...A negative capacitance(NC)effect has been proposed as a critical pathway to overcome the‘Boltzmann tyranny’of electrons,achieve the steep slope operation of transistors and reduce the power dissipation of current semiconductor devices.In particular,the ferroic property in hafnium-based films with fluorite structure provides an opportunity for the application of the NC effect in electronic devices.However,to date,only a transient NC effect has been confirmed in hafnium-based ferroic materials,which is usually accompanied by hysteresis and is detrimental to low-power transistor operations.The stabilized NC effect enables hysteresis-free and low-power transistors but is difficult to observe and demonstrate in hafnium-based films.This difficulty is closely related to the polycrystalline and multi-phase structure of hafnium-based films fabricated by atomic layer deposition or chemical solution deposition.Here,we prepare epitaxial ferroelectric Hf_(0.5)Zr_(0.5)O_(2) and antiferroelectric ZrO_(2) films with single-phase structure and observe the capacitance enhancement effect of Hf_(0.5)Zr_(0.5)O_(2)/Al_(2)O_(3) and ZrO_(2)/Al_(2)O_(3) capacitors compared to that of the isolated Al_(2)O_(3) capacitor,verifying the stabilized NC effect.The capacitance of Hf_(0.5)Zr_(0.5)O_(2) and ZrO_(2) is evaluated as−17.41 and−27.64 pF,respectively.The observation of the stabilized NC effect in hafnium-based films sheds light on NC studies and paves the way for low-power transistors.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.32170485,31501867)the Fundamental Research Funds for the Central Universities(Grant No.2572022BE02)。
文摘Artificial nest boxes are placed to attract birds to nest and breed in a specific location,and they are widely used in avian ecology research and in the attraction of insectivorous birds.There is evidence that artificial nest boxes can adversely affect breeding fitness but no great focus has been placed on this issue by researchers.Therefore,we retrieved 321 research papers regarding artificial nest boxes published from 2003 to 2022 and used the'Biblioshiny'program to extract and integrate keywords;we then summarized the adverse effects of artificial nest boxes on avian breeding success.The studies highlighted many drawbacks and misuses in the designing and placement of nest boxes;furthermore,bird attraction was decreased by their inappropriate selection,thus reducing breeding success.Regarding nest box production,there were shortcomings in the construction material,color,smell,and structural design of the boxes used.Nest boxes were also placed at inappropriate densities,locations,orientations,heights,and managed incorrectly.Finally,we propose suggestions for more efficient and safer artificial nest boxes for future use in avian ecology research and bird conservation.
文摘This paper attempts to investigate the negative effects of the spread of COVID-19 on low-income families in Egypt.Coronavirus spread is measured by"Coronavirus cases"and"Coronavirus deaths"on a daily basis.Besides,it is measured by both"new Coronavirus cases"and"new deaths from Coronavirus",in relation to the population of Egypt.The Egyptian government is taking some measures to reduce the negative effects of COVID-19,including increasing personal exemptions by amending some provisions of the Egyptian Income Tax Law promulgated by Law No.91 of 2005 to protect low-income families.Of the negative effects of COVID-19,it is one of the most important tax policies to achieve social justice in distributing the tax burden,according to income levels,in a manner that achieves justice and equality.We find that Personal exemptions did not succeed in achieving tax justice by easing the tax burden on the low-income people in society.
文摘With the development of computer and network technologies, computer--assisted language teaching and learning have been changing from the presentation of single text materials and response model to the integration of outside classroom education media combining text, graphics, images, sound, animation and network communication (CMC) technology. As an auxiliary tool of foreign language teaching, the computer plays its huge potential and promotes the completion of all kinds of language learning tasks. However, high cost and lack of technical support bringing the negative effects to the foreign language teaching is also cannot be ignored. Therefore, in the study of the historical evolvement of the CALL, to fully understand the positive and negative effects from the foreign language teaching will help make the positive effect of foreign language teaching maximized, and avoid misuse and abuse of the CALL.
文摘In such an information age, multimedia teaching has changed into one of the most important educational ways in middle and primary schools. In contrast to traditional education, multimedia teaching owns numerous advantages. However, there are also a great number of shortcomings in it. In this paper, considering the current situation of education in middle and primary schools, the author carries out an analysis on the negative effects of multimedia teaching on education in middle and primary schools, and also proposes some personal suggestions, hopefully providing a reference for teaching personnel in middle and primary schools.
基金supported by Geological Map of Groundwater Resources and Environment of China and Surrounding Areas(12120113014200)Series Maps of Karst Environment Geology of China and South East Asia(12120114006401,12120114006301)
文摘This paper summarizes the negative effects on geological environment caused by groundwater exploitation and its distribution. There are seven main types of the geological environment negative effects, which are generally as follows:(1) Constant decrease of groundwater level is mainly distributed in China(East Asia), India(South Asia), Tajikistan(Central Asia) and Saudi Arabia(West Asia);(2) land subsidence occurs mainly in eastern plains of East Asia and west Siberian Plain of North Asia;(3) seawater intrusion occurs mainly in China, Japan and South Korea in East Asia, Philippines and Indonesia in Southeast Asia, the Indian coastal areas in South Asia;(4) groundwater level decline caused by groundwater exploitation in oil fields;(5) mining collapse is mainly in 50° to 70° north latitude band;(6) the total area of karst collapse in China of East Asia is as much as 197.05 km^2; and(7) ground fracture is mainly distributed in the North China Plain, Fenwei Plain and the Yangtze River Delta. Asia can be divided into 6 zones in terms of the geological environment negative effect caused by groundwater exploitation. According to analysis, with the increasing intensity of human activities, geological environment issues become more and more serious, therefore it is vital to control the human activities within the scope of 5× 10~5 people/km^2 to 9.9× 10~5 people/km^2 for the effective control of the size of the affected area by geological environment problems.
文摘deployment of the THAAD system in South Korea imposed by the United States is superficially and nominally to target at the DPRK's nuclear and missile threats,but essentially to respond to the rising China and Russia,is further tied South Korea to the U.S.war chariot and is a dose of poison undermining the Northeast Asian environment for the mutual benefit,mutual trust and win-win cooperation as well as development and stability.
基金Supported by Agricultural Science and Technology Stride Plan(2009-16)Natural Science Fund in Hainan(808202)Scienceand Technology Project from Chinese Academy of Tropical Agricultural Sciences(Rky09)~~
文摘Soil structure and nutrient ingredient before and after shattering and returning sugarcane leaf as well as its technologies and methods were comparatively analyzed in this study to discuss the main reasons primarily,while the controlling technologies were proposed by combining cultivation,management and technical measures.
基金The National Natural Science Foundation of China(No.51178455)the Transformation Program of Science and Technology Achievements of Jiangsu Province(No.BA2015133)
文摘Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial strengths, the specimens were placed in 40, 60, or 80 t water tanks foraccelerated curing. The Coulomb values of the specimens weemeasured with ASTM C1202 experiment at 28, 100, 200, ad300 d. Partial specimens were also selected for rapid chlorideion migration coefficient and mercury intrusion porosimetryexperiments. The experimental results show that theaccelerated curing for ordinary concrete linealy deterioratesthe chloride penetration resistance, whereas the incorporationof mineral admixtures improves the concrete microscopic pore-structures and negative effects. An upper temperature limit of60 t of the accelerated curing is suitable for obtainingsuperior chloride penetration resistance for the mineraladmixture concrete. Pre-curing at a normal temperature of 20t is beneficial for improving the negative effect, which isalso aieviated with increasing testing age as a result of thesuccessive hydration of binder materials in concrete.
基金supported by the Postgraduate Inovation Programme of Changchun Wormal University(YJSCX202424)the Science and Technology Project of Jilin Provincial Education Department(JJKH20220828KJ)the Natural Science Foundation of Changchun Normal University(2020-005).
文摘The electronic and transport characteristics of protonated derivatives of naphthalocyanine(Nc)were investigated using density functional theory and non-equilibrium Green's functions.The results indicate that the protonation of external meso-N atoms of Nc preserves its planar structure and is energetically more favorable than the protonation of internal isoindole-N atoms.The protonation shifts the energy levels of system's frontier molecular orbitals closer to the Fermi level,thus creating channels for electron transport.In contrast with the semiconductor transport properties of H2Nc,its protonation products respond more sensitively to bias and exhibit negative differential resistance phenomena at specific bias.
文摘As one of the most distinguished features of Chinese Culture,collective oriented culture is the deep structure of Chinese cultural psychology which has shaped Chinese character and influenced their behavior.As a result of it,Chinese students suffer this negative effect from collective orientated culture when acquiring English,especially in oral English acquisition.TEFL teachers should be aware of cultural psychology and try their best to minimize its negative effect instead of neglecting or even enlarging it during oral English teaching.
文摘Efficient photogenerated carrier migration/separation plays a critical role in increasing the photocatalytic performance of g-C_(3)N_(4).Herein,sulfonic acid group-functionalized g-C_(3)N_(4)(SACN)was synthesized and then synchronously strengthened by a facile-solid-state thermal reaction of g-C_(3)N_(4)and sulfamic acid.As a solid strong acid,sulfamic acid can be used to achieve acid etching on the surface of g-C_(3)N_(4)with the assistance of thermal treatment,leading to an enlarged specific surface area and increased surface catalytic reaction sites.More importantly,our experiments and density functional theory calculations indicate that the driving force generated by the negative inductive effect of sulfonic acid groups significantly improves the charge transfer dynamics and effectively inhibits their recombination.Moreover,the negative inductive effect can induce charge redistribution,which reduces the conduction band potential of g-C_(3)N_(4)to enhance the reduction ability of photo-induced electrons.As a result,the SACN-400 sample showed excellent photocatalytic performance in H2 generation with an apparent quantum efficiency of 11.03%at 420±15 nm,as well as an efficient photodegradation rate for organic pollutants.
基金Supported by the National Natural Science Foundation of China under Grant No 51102007the Fund for Discipline Construction of Beijing University of Chemical Technology under Grant No XK1702
文摘The anti-resonant phenomenon of effective electromagnetic parameters of metamaterials has aroused controversy due to negative imaginary permittivity or permeability. It is experimentally found that the negative imaginary permittivity can occur for the natural passive materials near the Fabry Perot resonances. We reveal the nature of negative imaginary permittivity, which is correlated with the magnetoelectric coupling. The anti-resonance of permittivity is a non-inherent feature for passive materials, while it can be inherent for devices or metamaterials. Our finding validates that the negative imaginary part of effective permittivity does not contradict the second law of thermodynamics for metamaterials owing to the magnetoelectric coupling.
文摘The present paper discusses three major sources of negative effect of classroom instruction on L2 learners' pragmatic development: inadequate or inappropriate metapragmatic input, non-authentic classroom discourse and grammar-oriented pedagogy, then proposes some pedagogical suggestions on developing pragmatic competence.
基金Project supported by the SPAT of Shanghai Committee of Chinese People's Political Consultative Conference and Shanghai Education Development Foundation (Grant No.2008012)
文摘Y^3+-doped (Bi 1/2 Na 1/2) TiO 3-CaTiO 3-BaTiO 3 (BNCBT) positive temperature coefficient of resistivity (PTCR) ceramics sintered in air atmosphere were investigated in this study. (Bi 1/2 Na 1/2) TiO 3 (BNT) component can remarkably increase the onset temperature T c of PTCR ceramics with the expense of the resistivity R 25 increase. CaTiO 3 (9–27 mol%) component can decrease the resistivity, and adjust the effects of BNT phase on the T c point. For the sample containing 3 mol% CaTiO 3 , T c raises from 122 ℃ to 153 ℃ when only 0.6 mol% BNT added, while for the ones with higher CaTiO 3 content (9–27 mol%), T c is only increased by a rate of 8–9℃/1.0 mol% BNT. The effects of BNT and CaTiO 3 components on R25/Rmin (negative temperature coefficient effect) are also discussed.
基金supported by the National Science Foundation of China(key project grant No.51731008 and general project grant No.51671163).
文摘To clarify the anodic dissolution mechanism of Mg,the hydrogen evolution from pure Mg in acidic solutions under galvanostatic conditions were systematically measured.With increasing anodic current density,the cathodic hydrogen evolution rate decreased,and the anodic hydrogen evolution became faster while some surface area on the Mg was becoming dark under anodic polarization.Based on the surface analysis results and the generally accepted basic electrochemical equations,the evolution kinetics of hydrogen from Mg was deduced,and the most possible surface intermediate active species that could facilitate the anodic Mg dissolution and anodic hydrogen evolution were proposed.This paper further develops the model of incomplete film Mg^(+) dissolution,explains many reported experimental phenomena,and clarifies misunderstandings of current mechanism.
基金funded by the grants from the China Agriculture Research System of MOF and MARA (CARS-41)the Agricultural Science and Technology Innovation Program, China (ASTIP-IAS04)。
文摘San-Huang chicken is a high-quality breed in China with yellow feather, claw and break. However, the abnormal phenomenon of the yellow shank turning into green shank of San-Huang chicken has been a concern, as it seriously reduces the carcass quality and economic benefit of yellow-feathered broilers. In this study, the cause of this abnormal green skin in shank was systematically investigated. Physiological anatomy revealed that the abnormal skin in shank was primarily due to the deposition of melanin under the dermis. After analyzing multiple potential causes such as heredity(pedigree and genetic markers), environment(water quality monitoring) and feed composition(mycotoxin detection), excessive aflatoxin B1(AFB1) in feed was screened, accompanied with a higher L-dihydroxy-phenylalanine(L-DOPA)(P<0.05) and melanin content(P<0.01). So it was speculated that excessive AFB1 might be the main cause of abnormal green skin in shank. Subsequently, the further results showed that a high concentration of AFB1(>170 μg kg–1)indeed induced the abnormal green skin in shank compared to the normal AFB1 content(<10 μg kg–1), and the mRNA levels of TYR, TYRP1, MITE, MC1R and EDN3 genes related to melanin deposition would significantly up-regulate(P<0.01) and the content and activity of tyrosinase(TyR) significantly increased(P<0.05). At the same time, the content of L-DOPA and melanin deposition also increased significantly(P<0.01), which also confirmed the effect of excessive AFB1 on melanin deposition in skin of shank. Results of additional experiments revealed that the AFB1's negative effect on melanin deposition in skin of shank could last for a longer time. Taken together, the results of this study explained the occurrence and possible mechanisms of the abnormal AFB1-related green skin in shank of chickens. Excessive AFB1 in diets increased the L-DOPA content and melanin abnormal deposition in the chicken shank possibly via promoting TyR content and activity, and the expression of melanin synthesis-related genes. Furthermore, our findings once again raised the alarm of the danger of AFB1 in the broiler production.
基金financially supported by the National Natural Science Foundation of China, China (21922803, 22122807, and 22008072)the Innovation Program of Shanghai Municipal Education Commission, China+1 种基金the Program of Shanghai Academic/Technology Research Leader, China (21XD1421000)the China Postdoctoral Science Foundation, China (2020M671025 and 2019TQ0093)。
文摘Mechanistic understanding of the active intermediates of 2,6-diaminopyridine(DAP) dinitration in the concentrated nitric-sulfuric acid system is of crucial importance for the selectivity control of target product, i.e., 2,6-diamino-3,5-dinitropyridine(DADNP). The active intermediates determining the product selectivity are theoretically studied. The HSO_(4)^(-)-NO_(2)^(+) complex is proposed as the dominant active nitrating intermediate for the first time, which shows low energy barrier(i.e., 10.19 kcal·mol^(-1),1 kcal = 4.186 k J) for direct dinitration of DAP to DADNP. The formed water during the reaction results in not only the formation of less active SO_(4)^(2-)-NO_(2)^(+) complex, but also the occurance of DAP sulfonation(DAP-SO_(3)H intermediate)to facilitate the formation of mononitration byproduct. Meanwhile, the accompanied thermal effects cause the generation of undesirable pyridine-NHNO_(2) intermediate, which is difficult to be rearranged to yield DADNP, inhibiting the reaction and thus giving low DAP conversion. The insights reported here elucidates the importance of thermal effects elimination and water content control, confirmed experimentally in the batch-and micro-reaction systems.
基金Project supported by the Natural Science Foundation of Shandong Province, China (Grant No. ZR2019MA041)Taishan Scholar Project of Shandong Province, China (Grant No. ts20190939)the National Natural Science Foundation of China (Grant No. 62071200)。
文摘Nodal-line semimetals have become a research hot-spot due to their novel properties and great potential application in spin electronics. It is more challenging to find 2D nodal-line semimetals that can resist the spin–orbit coupling(SOC)effect. Here, we predict that 2D tetragonal Zn B is a nodal-line semimetal with great transport properties. There are two crossing bands centered on the S point at the Fermi surface without SOC, which are mainly composed of the pxy orbitals of Zn and B atoms and the pz orbitals of the B atom. Therefore, the system presents a nodal line centered on the S point in its Brillouin zone(BZ). And the nodal line is protected by the horizontal mirror symmetry M_(z). We further examine the robustness of a nodal line under biaxial strain by applying up to-4% in-plane compressive strain and 5% tensile strain on the Zn B monolayer, respectively. The transmission along the a direction is significantly stronger than that along the b direction in the conductive channel. The current in the a direction is as high as 26.63 μA at 0.8 V, and that in the b direction reaches 8.68 μA at 0.8 V. It is interesting that the transport characteristics of Zn B show the negative differential resistance(NDR) effect after 0.8 V along the a(b) direction. The results provide an ideal platform for research of fundamental physics of 2D nodal-line fermions and nanoscale spintronics, as well as the design of new quantum devices.
基金The National Key R&D Program of China(Grant No.2021YFB3601301)the National Natural Science Foundation of China(Grant No.52225106 and 12241404)the Natural Science Foundation of Beijing,China(Grant No.JQ20010).
文摘A negative capacitance(NC)effect has been proposed as a critical pathway to overcome the‘Boltzmann tyranny’of electrons,achieve the steep slope operation of transistors and reduce the power dissipation of current semiconductor devices.In particular,the ferroic property in hafnium-based films with fluorite structure provides an opportunity for the application of the NC effect in electronic devices.However,to date,only a transient NC effect has been confirmed in hafnium-based ferroic materials,which is usually accompanied by hysteresis and is detrimental to low-power transistor operations.The stabilized NC effect enables hysteresis-free and low-power transistors but is difficult to observe and demonstrate in hafnium-based films.This difficulty is closely related to the polycrystalline and multi-phase structure of hafnium-based films fabricated by atomic layer deposition or chemical solution deposition.Here,we prepare epitaxial ferroelectric Hf_(0.5)Zr_(0.5)O_(2) and antiferroelectric ZrO_(2) films with single-phase structure and observe the capacitance enhancement effect of Hf_(0.5)Zr_(0.5)O_(2)/Al_(2)O_(3) and ZrO_(2)/Al_(2)O_(3) capacitors compared to that of the isolated Al_(2)O_(3) capacitor,verifying the stabilized NC effect.The capacitance of Hf_(0.5)Zr_(0.5)O_(2) and ZrO_(2) is evaluated as−17.41 and−27.64 pF,respectively.The observation of the stabilized NC effect in hafnium-based films sheds light on NC studies and paves the way for low-power transistors.