Impact of Increasing Stratospheric Water Vapor on Ozone Depletion and Temperature Change

Using a detailed, fully coupled chemistry climate model （CCM）, the effect of increasing stratospheric H20 on ozone and temperature is investigated. Different CCM time-slice runs have been performed to investigate the chemical and radiative impacts of an assumed 2 ppmv increase in H20. The chemical effects of this H20 increase lead to an overall decrease of the total column ozone （TCO） by ～1% in the tropics and by a maximum of 12% at southern high latitudes. At northern high latitudes, the TCO is increased by only up to 5% due to stronger transport in the Arctic. A 2-ppmv H2O increase in the model＇s radiation scheme causes a cooling of the tropical stratosphere of no more than 2 K, but a cooling of more than 4 K at high latitudes. Consequently, the TCO is increased by about 2%-6%. Increasing stratospheric H2O, therefore, cools the stratosphere both directly and indirectly, except in the polar regions where the temperature responds differently due to feedbacks between ozone and H2O changes. The combined chemical and radiative effects of increasing H2O may give rise to more cooling in the tropics and middle latitudes but less cooling in the polar stratosphere. The combined effects of H2O increases on ozone tend to offset each other, except in the Arctic stratosphere where both the radiative and chemical impacts give rise to increased ozone. The chemical and radiative effects of increasing H2O cause dynamical responses in the stratosphere with an evident hemispheric asymmetry. In terms of ozone recovery, increasing the stratospheric H2O is likely to accelerate the recovery in the northern high latitudes and delay it in the southern high latitudes. The modeled ozone recovery is more significant between 2000 ～2050 than between 2050～2100, driven mainly by the larger relative change in chlorine in the earlier period.

Modelling,Validation,and Calculations of Stratospheric Ozone Dynamics and Latitudinal Changes

This paper presents an engineering system approach of 2-D cylindrical model of mass balance calculations with convection,diffusion,and all potential photolysis,ozone generating and depleting chemical reactions considered.This model was developed,validated,and tested under different conditions for the stratospheric ozone.The calculated ozone concentrations and profile in the stratosphere at both the Equator and mid-latitudinal location of 40°S were found to exhibit a similar and close profile and peak value of the published measured data.The discrepancy between the calculations and measurements for the average ozone concentration was shown to be less than 1%and the variation of distributions to be less than 19%.The latitudinal changes of ozone concentrations,distribution,and peak of the layer were found to shift from 9.41 ppm at mid-altitude of z=30 km at the Equator,to 7.81 ppm at z=34.5 km at 40°S,to 5.78 ppm at higher altitude z=39 km at the South Pole.The total ozone abundances at strategic latitudes at 0°S,20°S,40°S,60°S,and 90°S,were found to remain stable and not much changed,from 305 DU to 335 DU,except a smaller value of 288 DU at the South Pole.The possible explanations of ozone profile change and peak shifting as affected by solar/UV radiation,latitudinal locations,and ozone-depleting reactions were discussed and elaborated.The 2-D ozone Model presented in this paper is a robust,efficient,executable,and validated model for studying the complex ozone phenomena in the stratosphere.

Simulation of the Influence of Ion-Produced NO_X and HO_X Radicals on the Antarctic Ozone Depletion with a One-Dimensional Model

A one -dimensional time-dependent photochemical model is used to simulate the influence of ion-produced NOx and HOx radicals on the Antarctic ozone depletion in polar night and polar spring at a latitude of 73 degrees south.Vertical transport and nitrogen-oxygen (NOx). hydrogen-oxygen (HOx) production by ionic reactions have been introduced into the model.NOx and HOx produced by precipitating ions are transported into the lower stratosphere by vertical motion and have some effects in the development of the Antarctic ozone depletion.From winter through spring the calculated ozone column decreases to 269.4 DU. However, this value is significantly higher than the total ozone observed at several Antarctic ozone stations.

Experimental study on zero excess sludge production process with ozonation unit in MBR process

In order to investigate the influence factors of zero excess activated sludge (EAS) process by ozonation, a 100 L membrane bioreactor coupled with a sludge ozonation unit (MBR-SO) was performed for 80 d without EAS wasting. Some mathematical models were developed to elucidate the relationship between process parameters and the operating effects. It is considered that the sludge lysing ratio (ξ), produced COD per unit mass lysed MLSS (η), observed sludge yield coefficient (Yobs) and intrinsic yield coefficient for COD produced by lysed sludge (Y2) significantly affect the flowrate to ozonation unit (q). When q is 0.0067 times of influent flowrate (Q) and ξ is about 0.72 for each batch ozonation, a relatively stable MLSS concentration of 8168 mg/L and zero Yobs are achieved in the MBR-SO system. The calculation of sludge disintegration number indicates that the high ξ can apparently decrease the sludge amount needed for ozonation. At the same ozone dose, the low input ozone concentration and high flowrate can enhance the sludge lysing effects and a low energy consumption of 0.041 Yuan/m3 wastewater is obtained.