Experimental Study on Phase Characteristics of CO2 Injection in BZ13-2 Strong Volatile Oil Reservoir in Bohai Sea Buried Hills

BZ13-2 oil field is a deep submerged strongly volatile reservoir in Bohai Sea. This oil reservoir has the characteristics of high gas oil ratio and small difference in formation pressure and saturation point pressure. It usually adopts gas injection development to avoid crude oil degassing and fast decreasing production capacity. However, the phase characteristics and miscibility mechanism of this high-temperature and high-pressure fluid after gas injection are not clear. Therefore, it is necessary to study the feasibility of CO2 injection to improve oil recovery in near critical volatile oil reservoirs through CO2 injection experiments. In the early stage of the depletion experiment, the content of heavy components in the remaining oil increased significantly, so the depletion method is not conducive to the development of such reservoirs. With the increase of CO2 injection, the volumetric expansion coefficient of formation crude oil increases significantly, while the saturation pressure and formation crude oil viscosity remain basically unchanged. The minimum miscible pressure experiment shows that CO2 injection under formation pressure conditions can achieve multiphase miscibility. Based on experimental research results, the BZ13-2 oilfield is suitable for early gas injection development and can significantly improve recovery.

Effects of persulfate-assisted hydrothermal treatment of municipal sludge on aqueous phase characteristics and phytotoxicity

Hydrothermal technology (HT) has received much attention in recent years as a process to convert wet organic waste into hydrochar.The aqueous phase (HTAP) produced by this process is still a burden and has become a bottleneck issue for HT process development.In this study,we provide the?rst investigation of the HTAP characteristics,phytotoxicity,and their correlation with persulfate (PS)(PS,2.0 mmol/g TS)-assisted municipal sludge HT.The results showed that PS accelerated the hydrolysis of protein substances and increased the concentration of NH_(4)^(+)by 13.4%to 190.5%and that of PO_(4)^(3-)by 24.2%to 1103.7%in HTAP at hydrothermal temperatures of 120 to 240℃.PS can reduce the phytotoxicity of HTAP by reducing aldehydes,ketones,N heterocyclic compounds,and particle size and by increasing its humi?cation index.The maximum values of the root length and biomass of pakchoi(Brassica chinensis L.) seedlings occurred when electrical conductivity was 0.2 mS/cm of HTAP.This work provided a new strategy for the selection and design of HTAP management strategies.

The Kinetic Energy Budget and Circulation Characteristics of the Tropical Storm Irma during AMEX Phase Ⅱ

By using the data from observation on the Chinese research vessel Xiang Yang Hong No.5 and other sources during AMEX phase II, the kinetic energy budget and circulation characteristics of the tropical storm Irma were analyzed.Irma formed on the ITCZ of the Southern Hemisphere. During the formative stage of the storm, the SE trades and monsoon westerlies on both sides of the ITCZ strengthened, and more importantly, there was a strong divergent flow in upper troposphere. These contributed to the intensification of Irma. At the time when Irma formed, the Richardson number (Ri) in middle and lower troposphere was much smaller than that prior to and post the formation.When Irma intensified rapidly, the area-averaged kinetic energy in the general flow increased in the whole troposphere . The largest contribution came from kinetic energy generation term, -[v.(?)(?)] .indicates that there existed a strong ageostrophic accetration. As to the generation term , the conversion of available potential energy to kinetic energy, - |ωα|, made the largest contribution. This illustrates the importance of internal sources and of the ensemble effect of cumulus convection to the kinetic energy.To the increase of area-averaged eddy kinetic energy during the rapid intensification of Irma, the most impor tant source in the whole troposphere was the dissipation term - [E'], that should be interpreted as the. feeding of eddy kinetic energy from smaller to larger scale disturbances. Another important source was generation term, - [v' (?)(?)'], in the lower troposphere. Rather small contribution came from the energy conversion from the kinetic energy of area-mean flow to eddy kinetic energy. Therefore, the eddy kinetic energy of the developing tropical disturbance extracted both from smaller an, .arger scale motions. The former was much more important than the latter In addition, the disturbance acting as a generator and exporter, generated and exported eddy kinetic energy to the environmental atmosphere.

Change of phase state during multi-cycle injection and production process of condensate gas reservoir based underground gas storage

Based on the differences in production mode and operation process between gas storage and gas reservoir,we established a phase balance test procedure and a theoretical simulation model of phase balance during multi-cycles of injection and production of underground gas storage(UGS)rebuilt from condensate gas reservoir to study the phase characteristics of produced and remaining fluids during multi-cycles of injection and production.Take condensate reservoir gas storage as example,the composition of produced fluid and remaining fluid,phase state of remaining fluid,retrograde condensate saturation and condensate recovery degree in the process of multi-cycles of injection-production were studied through multi-cycle injection-production experiment and phase equilibrium theory simulation.The injected gas could greatly improve the recovery of condensate oil in the gas reservoir,and the condensate oil recovery increased by 42% after 5 cycles of injection and production;the injected gas had significant evaporative and extraction effects on the condensate,especially during the first two cycles;the condensate oil saturation of the formation decreased with the increase of injection-production cycles,and the condensate oil saturation after multi-cycles of injection-production was almost 0;the storage capacity increased by about 7.5% after multi-cycles of injection and production,and the cumulative gas injection volume in the 5 th cycle increased by about 25%compared with that in the 1 st cycle.

Simulation of petroleum phase behavior in injection and production process of underground gas storage in a gas reservoir

On the basis of analyzing the fluid phase behavior during the transformation from gas reservoir to gas storage,a mathematical model and an experimental simulation method are established to describe the oil-gas phase behavior during the whole injection-production process of gas storage.The underground gas storage in the Liaohe Shuang 6 gas reservoir with oil rim is taken as a typical example to verify the reliability and accuracy of the mathematical model and reveal characteristics and mechanisms of fluid phase behavior.In the gas injection stage of the gas storage,the phase behavior is characterized by mainly evaporation and extraction and secondarily dissolution and diffusion of gas in the cap to oil in the oil rim of the reservoir;the gas in gas cap increases in light component content,decreases in contents of intermediate and heavy components,and increases in density and viscosity.The oil of the ring decreases in content of heavy components,increases in contents of light and intermediate components,decreases in density and viscosity,and increases in volume factor and solution gas oil ratio.In the stable operation stage of periodic injection-production of gas storage,the phase behavior shows that the evaporation and extraction capacity of injection gas in the cap to oil rim is weakened step by step,the phase behavior gradually changes into dissolution and diffusion.The gas in gas cap decreases in content of intermediate components,increases in content of light components slowly,and becomes lighter;but changes hardly in density and viscosity.The oil in the oil rim increases in content of heavy components,decreases in content of intermediate components,rises in density and viscosity,and drops in volume factor and solution gas oil ratio.

Damage Characteristic of Interpenetrating Phase Composites under Dynamic Loading

In order to investigate the damage characteristic of ceramic-metal interpenetrating phase composite（IPC） under dynamic loading, uniaxial dynamic compression was performed to characterize the failure of SiC/Al composite with 15% porosity using a modifi ed Split Hopkinson Pressure Bar（SHPB）. High speed photography was used to capture the failure procedure and set up the relationship between deformation and real stress. The deformation control technology was used to obtain collected samples in different deformations under dynamic loading. Micro CT technology was utilized to acquire real damage distribution of these specimens. Moreover, SEM was employed in comparing the damage characteristics in IPC. A summary of the available experimental results showed that IPC without lateral confi nement formed double cones. The different features compared with ceramic materials without restraint was shown to be the result of the lateral restraint effect provided by metal phase to ceramics skeleton.

Direct Digital Frequency Control Based on the Phase Step Change Characteristic between Signals

We present a new digital phase lock technology to achieve the frequency control and transformation through high precision multi-cycle group synchronization between signals without the frequency transformation circuit. In the case of digital sampling, the passing zero point of the phase of the controlled signal has the phase step characteristic, the phase step of the passing zero point is monotonic continuous with high resolution in the phase lock process, and using the border effect of digital fuzzy area, the gate can synchronize with the two signals, the quantization error is reduced. This technique is quite different from the existing methods of frequency transformation and frequency synthesis, the phase change characteristic between the periodic signals with different nominal is used. The phase change has the periodic phenomenon, and it has the high resolution step value. With the application of the physical law, the noise is reduced because of simplifying frequency transformation circuits, and the phase is locked with high precision. The regular phase change between frequency signals is only used for frequency measurement, and the change has evident randomness, but this randomness is greatly reduced in frequency control, and the certainty of the process result is clear. The experiment shows that the short term frequency stability can reach 10-12/s orders of magnitude.

Research on Magnetically Coupled Resonant Detection Method for Breakpoint of Four Mesh Grounding Grid

Magnetically coupled resonant technology is a novel method for solving the breakpoint locating of power grounding grid.But the method can only detect breakpoints of a single mesh grounding grid at present.In this paper,a magnetically coupled resonant detection method for four-hole grounding grid breakpoint is proposed.Firstly,the equivalent circuit model of the four mesh grounding grid with two types of breakpoints,namely edge branch and intermediate branch,is established.The input impedance and phase angle of the system are obtained by analyzing the equivalent capacitance and equivalent resistance in the model.Secondly,the magnetically coupled resonant physical process of grounding grid faults is solved via HFSS software.The magnetic field intensity and phase frequency characteristic curves of four mesh holes with different branches and positions of breakpoints and different corrosion degrees are studied,and an experimental system is built to verify the feasibility.The results show that under the condition of grounding grid buried depth of 0.5 m and input frequency of 1~15MHz,and there is an inverse relationship between equivalent capacitance and distortion frequency,the phase angle is positively correlated with the degree of corrosion of grounding grid,and the error of signal distortion frequency can be positioned at 5%.This paper provides some ideas for the application of magnetic coupling grounding grid detection technology.

Melting Characteristics and Wettability of Binding Phase in Sinter

The melting characteristics and wettability of the binding phase in high basicity sinter were studied. By changing nCaO∶nFe2O3 （molar ratio of CaO to Fe2O3） as well as the percentage of MgO,SiO2,and Al2O3,the melting characteristics and wettability of the binding phase were discussed. The results indicated that the characteristic melting temperature was the lowest and wettability was the best at nCaO∶nFe2O3=1∶1 （without addition）; the addition of MgO increased the characteristic melting temperature and contact angles; when the percentage of SiO2 or Al2O3 was 3%,the characteristic melting temperature was the lowest,whereas the contact angles increased with an increase in SiO2 and Al2O3 contents.

STUDY ON THE STABILITY STRUCTURE OF SYNOPTIC SCALE SYSTEMS,THE BIFURCATION OF PHASE.PATH CHARACTERISTICS AND THE INFLUENCE OF THE TIME-OSCILLATION OF HEAT SOURCE

This paper discusses the stability structure and the bifurcation of phase path characteristics of synoptic scale system.The analytic results show that the catastrophe of the synoptic scale disturbance may be caused by the nonlinear effects of barotropic and baroclinic instability and advection of ambient large-scale flow.Also, foregoing nonlinear effects on the speed of development and decay of the system are presented in the processes deviating from or approaching to equilibrium state.It has been found that there is a resonance phenomenon between the time-oscillation of heat source and the atmospheric disturbance.

Fractional-order L_βC_a filter circuit network

In this paper we introduce the new fundamentals of the conventional LC filter circuit network in the fractional domain.First, we derive the general formulae of the impedances for the conventional and fractional-order filter circuit network.Based on this, the impedance characteristics and phase characteristics with respect to the system variables of the filter circuit network are studied in detail, which shows the greater flexibility of the fractional-order filter circuit network in design.Moreover, from the point of view of the filtering property, we systematically study the effects of the filter units and fractional orders on the amplitude–frequency characteristics and phase–frequency characteristics. In addition, numerical tables of the cut-off frequency are presented. Finally, two typical examples are presented to promote the industrial applications of the fractional-order filter circuit network. Numerical simulations are presented to verify the theoretical results introduced in this paper.

A Study on the Early Warning Time of Strong Earthquakes in Taiwan

The paper collects the records by the Fujian Digital Seismic Network of 40 shallow earthquakes in Taiwan with M_S≥5.0 from 1999 to 2013,analyzes the seismic phase(Pn,Sn phase)characteristics and travel-time rules,determines travel-time models and develops a seismic phase travel-time equation based on the two-step fitting algorithm.With the deduction of processing time and network delay time,this method can provide an accurate estimation of early warning time of Taiwan earthquakes for the Fujian region,and has been officially employed in the earthquake early warning system of Fujian Province.

Thermodynamic Characteristic and Phase Evolution in Immiscible Cr–Mo Binary Alloys

This paper systematically reports the thermodynamic characteristic and phase evolution of immiscible Cr–Mo binary alloy during mechanical alloying（MA） process. The Cr–35Mo（in at%） powder mixture was milled at 243 and258 K, respectively, for different time. For comparative study, Cr–15Mo and Cr–62Mo powder mixtures were milled at 243 K for 18 h. Solid solution Cr（Mo） with body-centered cubic（bcc） crystal structure and amorphous Cr（Mo） alloy was obtained during MA process caused by high-energy ball milling. Based on the Miedema＇s model, the free-energy change for forming either a solid solution or an amorphous in Cr–Mo alloy system is positive but small at a temperature range between 200 and 300 K. The thermodynamical barrier for forming alloy in Cr–Mo system can be overcome when MA occurs at 243 K, and the supersaturated solid solution crystal nuclei with bcc structure form continually, and three supersaturated solid solutions of Cr–62Mo, Cr–35Mo and Cr–15Mo formed. Milling the Cr–35Mo powder mixture at 258 K, the solid solution Cr（Mo） forms firstly, and then the solid solution Cr（Mo） transforms into the amorphous Cr（Mo）alloy with a few of nanocrystallines when milling is prolonged. At higher milling temperature, it is favorable for the formation of the amorphous phase, as indicated by the thermodynamical calculation for immiscible Cr–Mo alloy system.

Simulation of Analog Costas Loop Circuits

The analysis of stability and numerical simulation of Costas loop circuits for the high-frequency signals is a challenging task. The problem lies in the fact that it is necessary to observe very fast time scale of input signals and slow time scale of signal s phases simultaneously. To overcome this difficulty, it is possible to follow the classical ideas of Gardner and Viterbi to construct a mathematical model of Costas loop, in which only slow time change of signal s phases and frequencies is considered. Such an construction, in turn,requires the computation of phase detector characteristic, depending on the waveforms of the considered signals. In this paper, the problems of nonlinear analysis of Costas loops and the approaches to the simulation of the classical Costas loop, the quadrature phase shift keying(QPSK) Costas loop, and the two-phase Costas loop are discussed. The analytical method for the computation of phase detector characteristics of Costas loops is described.