A novel integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide(KCuFC/SPSG)was used for selectively extracting rubidium ion(Rb^(+))from brine.To form KCuFC/SPSG,the precursor film of sulfonate...A novel integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide(KCuFC/SPSG)was used for selectively extracting rubidium ion(Rb^(+))from brine.To form KCuFC/SPSG,the precursor film of sulfonated polysulfone/graphene(SPSG)was synthesized by phase conversion process,which was alternately immersed in 0.1 mol·L^(-1)CuSO_(4)/K_(4)[Fe(CN)_(6)]by in-situ adsorption coupled co-precipitation method.Various data such as nuclear magnetic resonance spectrometer,Fourier transform infrared spectroscope,X-ray photoelectron spectroscope,X-ray diffraction,scanning electron microscope,and energy dispersive spectroscopy all verified that abundant KCuFC were uniformly located on the film.The resulting KCuFC/SPSG was used in film separation system.As the solution was fed into the system,the Rb^(+)could be selectively adsorption by KCuFC/SPSG.After the saturation adsorption,0.5 mol·L^(-1)NH_(4)Cl/HCl was fed into the film cell,Rb^(+)could be quickly desorbed by ion-exchange between Rb^(+)and NH_(4)^(+)in the lattice of KCuFC.The purpose of separating and recovering Rb^(+)from the brine can be achieved after the repeated operation.The effects of pH,adsorption time,and interferential ions on the adsorption capacity of Rb^(+)were investigated by batch experiments.The adsorption behavior fits the pseudo-second order kinetic process,while KCuFC has a higher adsorption capacity(Langmuir maximum sorption 165.4 mg·g^(-1)).In addition,KCuFC/SPSG shows excellent selectivity for Rb^(+)even in complex brine systems.KCuFC/SPSG could maintain 93.5%extraction efficiency after five adsorption/desorption cycles.展开更多
空间变化PSF(Space-variant Point Spread Function,SVPSF)图像,即物空间各点的退化随位置的改变而改变的图像,由于其复原技术涉及到多个甚至海量PSF的提取、存储和运算,相对于空间不变PSF(Space-Invariant Point Spread Function,SIPSF...空间变化PSF(Space-variant Point Spread Function,SVPSF)图像,即物空间各点的退化随位置的改变而改变的图像,由于其复原技术涉及到多个甚至海量PSF的提取、存储和运算,相对于空间不变PSF(Space-Invariant Point Spread Function,SIPSF)图像复原要困难得多。目前处理此类图像的主要方法包括空间坐标转换法,等晕区分块复原法,以减少数据存储量,降低计算量,提高收敛速度为目标的直接复原法等。本文回顾了这一课题的研究历史,对目前的研究工作进行了分析和总结,介绍了本实验室提出的结合GRM(Gradient Ringing Metric)评价算法的总变分最小化图像分块复原法,并提出了未来工作关注重点的展望。展开更多
基金supported by the Ministry of Science and Technology of China(Science and Technology to Boost Economy 2020 Key Project,SQ2020YFF0412719 and SQ2020YFF0404901)The Key Research and Development and Transformation Program Funding in Qinghai Province(2021-GX-105)Major projects of Anhui Province and Anhui Province Key Research and Development Plan(202104e11020005)。
文摘A novel integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide(KCuFC/SPSG)was used for selectively extracting rubidium ion(Rb^(+))from brine.To form KCuFC/SPSG,the precursor film of sulfonated polysulfone/graphene(SPSG)was synthesized by phase conversion process,which was alternately immersed in 0.1 mol·L^(-1)CuSO_(4)/K_(4)[Fe(CN)_(6)]by in-situ adsorption coupled co-precipitation method.Various data such as nuclear magnetic resonance spectrometer,Fourier transform infrared spectroscope,X-ray photoelectron spectroscope,X-ray diffraction,scanning electron microscope,and energy dispersive spectroscopy all verified that abundant KCuFC were uniformly located on the film.The resulting KCuFC/SPSG was used in film separation system.As the solution was fed into the system,the Rb^(+)could be selectively adsorption by KCuFC/SPSG.After the saturation adsorption,0.5 mol·L^(-1)NH_(4)Cl/HCl was fed into the film cell,Rb^(+)could be quickly desorbed by ion-exchange between Rb^(+)and NH_(4)^(+)in the lattice of KCuFC.The purpose of separating and recovering Rb^(+)from the brine can be achieved after the repeated operation.The effects of pH,adsorption time,and interferential ions on the adsorption capacity of Rb^(+)were investigated by batch experiments.The adsorption behavior fits the pseudo-second order kinetic process,while KCuFC has a higher adsorption capacity(Langmuir maximum sorption 165.4 mg·g^(-1)).In addition,KCuFC/SPSG shows excellent selectivity for Rb^(+)even in complex brine systems.KCuFC/SPSG could maintain 93.5%extraction efficiency after five adsorption/desorption cycles.
文摘空间变化PSF(Space-variant Point Spread Function,SVPSF)图像,即物空间各点的退化随位置的改变而改变的图像,由于其复原技术涉及到多个甚至海量PSF的提取、存储和运算,相对于空间不变PSF(Space-Invariant Point Spread Function,SIPSF)图像复原要困难得多。目前处理此类图像的主要方法包括空间坐标转换法,等晕区分块复原法,以减少数据存储量,降低计算量,提高收敛速度为目标的直接复原法等。本文回顾了这一课题的研究历史,对目前的研究工作进行了分析和总结,介绍了本实验室提出的结合GRM(Gradient Ringing Metric)评价算法的总变分最小化图像分块复原法,并提出了未来工作关注重点的展望。
