In view of the limited space of offshore platform and the large amount of polymer injection, the dissolution time method, solution viscosity method, conductivity method, undissolved filtration method and falling ball ...In view of the limited space of offshore platform and the large amount of polymer injection, the dissolution time method, solution viscosity method, conductivity method, undissolved filtration method and falling ball method are used as the rapid detection methods of polymer dissolution. The results show that the error of conductivity method is the largest, and that of dissolution time method is the second, and both methods are time-consuming. Solution viscosity method and insolubles filtration method have small error, but they are time-consuming, especially for offshore platforms, which makes detection inconvenient. The drop ball method is simple in operation and has a small error, so it is a promising method for rapid determination of polymer dissolution time.展开更多
Cation exchange capacity (CEC) is one of the most important properties of soils. The NH<sub>4</sub>OAc (pH = 7.0) exchange method is usually recommended to determine CEC (CEC<sub>1</sub>) of al...Cation exchange capacity (CEC) is one of the most important properties of soils. The NH<sub>4</sub>OAc (pH = 7.0) exchange method is usually recommended to determine CEC (CEC<sub>1</sub>) of all soils with different pH values, particularly for studies on soil taxonomy. But comparatively the BaCl<sub>2</sub>-MgSO<sub>4</sub> forced-exchange method is more authentic in determining CEC (CEC<sub>2</sub>) of tropical and subtropical highly-weathered acid soils. But so far little is known about the difference between CEC<sub>1</sub> and CEC<sub>2</sub>. In this study, the physiochemical data of 114 acid B horizon soils from 112 soil series of tropical and subtropical China were used, CEC<sub>1</sub> and CEC<sub>2</sub> were determined and compared, the influencing factors were analyzed for the difference between CEC<sub>1</sub> and CEC<sub>2</sub>, and then a regression model was established between CEC<sub>1</sub> and CEC<sub>2</sub>. The results showed that CEC<sub>2</sub> was significantly lower than CEC<sub>1</sub> (p < 0.01), CEC<sub>2</sub> was 14.76% - 63.31% with a mean of 36.32% of CEC<sub>1</sub>. In view of the contribution to CEC from other properties, CEC<sub>2</sub> was mainly determined by pH (45.92%), followed by silt (21.05%), free Fe<sub>2</sub>O<sub>3</sub> (17.35%) and clay contents (12.76%), CEC<sub>1</sub> was mainly decided by free Fe<sub>2</sub>O<sub>3</sub> content (40.38%), followed by pH (28.39%) and silt content (27.29%;and the difference between CEC<sub>1</sub> and CEC<sub>2</sub> was mainly affected by free Fe<sub>2</sub>O<sub>3</sub> (50.92%), followed by silt content (26.46%) and pH (21.80%). The acceptable optimal regression model between CEC<sub>2</sub> and CEC<sub>1</sub> was established as CEC<sub>2</sub> = 2.3114 × CEC<sub>1</sub><sup>1.1496</sup> (R<sup>2</sup> = 0.410, P < 0.001, RMSE = 0.15). For the studies on soil taxonomy, the BaCl<sub>2</sub>-MgSO<sub>4</sub> forced-exchange method is recommended in determining CEC of the highly-weathered acid soils in the tropical and subtropical regions.展开更多
[Objectives]To determine active components of Lamiophlomis rotata(Benth.)Kudo.[Methods]A new method was developed for the quantitative determination of L.rotata by using Ultra-performance convergence chromatography.Th...[Objectives]To determine active components of Lamiophlomis rotata(Benth.)Kudo.[Methods]A new method was developed for the quantitative determination of L.rotata by using Ultra-performance convergence chromatography.The separation of active components of L.rotata was successfully achieved on Waters ACQUITY UPC column,with gradient elution carbon dioxide and methanol solvent at flow rate of 0.7 mL/min.The separation gradient elution rate was as follows:15%methanol 0-1 min,18%methanol 1-5 min,20%methanol 5-6 min,25%methanol 6-7 min,30%methanol 7-8 min,30%methanol 8-9 min,15%methanol 9-10 min.The conditions used in the separation process was as follows:column temperature 30℃;injection volume 2μL.Under the abovementioned conditions,the content of methyl glucoside was measured by 3D-full wavelength scanning.The validity of the method was tested by analyzing the precision,reproducibility,stability and accuracy.[Results]The results indicated that in terms of extraction and separation of compounds,supercritical CO2 not only has the diffusion property of gas,but also has the density and fluidity of liquid.[Conclusions]The ultra-high performance chromatography is a new technique for drug analysis.展开更多
The HY-2 satellite carrying a satellite-borne GPS receiver is the first Chinese radar altimeter satellite, whose radial orbit determination precision must reach the centimeter level. Now HY-2 is in the test phase so t...The HY-2 satellite carrying a satellite-borne GPS receiver is the first Chinese radar altimeter satellite, whose radial orbit determination precision must reach the centimeter level. Now HY-2 is in the test phase so that the observations are not openly released. In order to study the precise orbit determination precision and procedure for HY-2 based on the satellite- borne GPS technique, the satellite-borne GPS data are simulated in this paper. The HY-2 satellite-borne GPS antenna can receive at least seven GPS satellites each epoch, which can validate the GPS receiver and antenna design. What＇s more, the precise orbit determination processing flow is given and precise orbit determination experiments are conducted using the HY-2-borne GPS data with both the reduced-dynamic method and the kinematic geometry method. With the 1 and 3 mm phase data random errors, the radial orbit determination precision can achieve the centimeter level using these two methods and the kinematic orbit accuracy is slightly lower than that of the reduced-dynamic orbit. The earth gravity field model is an important factor which seriously affects the precise orbit determination of altimeter satellites. The reduced-dynamic orbit determination experiments are made with different earth gravity field models, such as EIGEN2, EGM96, TEG4, and GEMT3. Using a large number of high precision satellite-bome GPS data, the HY-2 precise orbit determination can reach the centimeter level with commonly used earth gravity field models up to above 50 degrees and orders.展开更多
In Europe, computation of displacement demand for seismic assessment of existing buildings is essentially based on a simplified formulation of the N2 method as prescribed by Eurocode 8(EC8). However, a lack of accurac...In Europe, computation of displacement demand for seismic assessment of existing buildings is essentially based on a simplified formulation of the N2 method as prescribed by Eurocode 8(EC8). However, a lack of accuracy of the N2 method in certain conditions has been pointed out by several studies. This paper addresses the assessment of effectiveness of the N2 method in seismic displacement demand determination in non-linear domain. The objective of this work is to investigate the accuracy of the N2 method through comparison with displacement demands computed using non-linear timehistory analysis(NLTHA). Results show that the original N2 method may lead to overestimation or underestimation of displacement demand predictions. This may affect results of mechanical model-based assessment of seismic vulnerability at an urban scale. Hence, the second part of this paper addresses an improvement of the N2 method formula by empirical evaluation of NLTHA results based on EC8 ground-classes. This task is formulated as a mathematical programming problem in which coefficients are obtained by minimizing the overall discrepancy between NLTHA and modified formula results. Various settings of the mathematical programming problem have been solved using a global optimization metaheuristic. An extensive comparison between the original N2 method formulation and optimized formulae highlights benefits of the strategy.展开更多
文摘In view of the limited space of offshore platform and the large amount of polymer injection, the dissolution time method, solution viscosity method, conductivity method, undissolved filtration method and falling ball method are used as the rapid detection methods of polymer dissolution. The results show that the error of conductivity method is the largest, and that of dissolution time method is the second, and both methods are time-consuming. Solution viscosity method and insolubles filtration method have small error, but they are time-consuming, especially for offshore platforms, which makes detection inconvenient. The drop ball method is simple in operation and has a small error, so it is a promising method for rapid determination of polymer dissolution time.
文摘Cation exchange capacity (CEC) is one of the most important properties of soils. The NH<sub>4</sub>OAc (pH = 7.0) exchange method is usually recommended to determine CEC (CEC<sub>1</sub>) of all soils with different pH values, particularly for studies on soil taxonomy. But comparatively the BaCl<sub>2</sub>-MgSO<sub>4</sub> forced-exchange method is more authentic in determining CEC (CEC<sub>2</sub>) of tropical and subtropical highly-weathered acid soils. But so far little is known about the difference between CEC<sub>1</sub> and CEC<sub>2</sub>. In this study, the physiochemical data of 114 acid B horizon soils from 112 soil series of tropical and subtropical China were used, CEC<sub>1</sub> and CEC<sub>2</sub> were determined and compared, the influencing factors were analyzed for the difference between CEC<sub>1</sub> and CEC<sub>2</sub>, and then a regression model was established between CEC<sub>1</sub> and CEC<sub>2</sub>. The results showed that CEC<sub>2</sub> was significantly lower than CEC<sub>1</sub> (p < 0.01), CEC<sub>2</sub> was 14.76% - 63.31% with a mean of 36.32% of CEC<sub>1</sub>. In view of the contribution to CEC from other properties, CEC<sub>2</sub> was mainly determined by pH (45.92%), followed by silt (21.05%), free Fe<sub>2</sub>O<sub>3</sub> (17.35%) and clay contents (12.76%), CEC<sub>1</sub> was mainly decided by free Fe<sub>2</sub>O<sub>3</sub> content (40.38%), followed by pH (28.39%) and silt content (27.29%;and the difference between CEC<sub>1</sub> and CEC<sub>2</sub> was mainly affected by free Fe<sub>2</sub>O<sub>3</sub> (50.92%), followed by silt content (26.46%) and pH (21.80%). The acceptable optimal regression model between CEC<sub>2</sub> and CEC<sub>1</sub> was established as CEC<sub>2</sub> = 2.3114 × CEC<sub>1</sub><sup>1.1496</sup> (R<sup>2</sup> = 0.410, P < 0.001, RMSE = 0.15). For the studies on soil taxonomy, the BaCl<sub>2</sub>-MgSO<sub>4</sub> forced-exchange method is recommended in determining CEC of the highly-weathered acid soils in the tropical and subtropical regions.
基金Collaborative Innovation in Tibetan Medicine(2019XTC013)Open Laboratory of Key Laboratory of Tibetan Medicine Basic Education(ZYYJC-19-01).
文摘[Objectives]To determine active components of Lamiophlomis rotata(Benth.)Kudo.[Methods]A new method was developed for the quantitative determination of L.rotata by using Ultra-performance convergence chromatography.The separation of active components of L.rotata was successfully achieved on Waters ACQUITY UPC column,with gradient elution carbon dioxide and methanol solvent at flow rate of 0.7 mL/min.The separation gradient elution rate was as follows:15%methanol 0-1 min,18%methanol 1-5 min,20%methanol 5-6 min,25%methanol 6-7 min,30%methanol 7-8 min,30%methanol 8-9 min,15%methanol 9-10 min.The conditions used in the separation process was as follows:column temperature 30℃;injection volume 2μL.Under the abovementioned conditions,the content of methyl glucoside was measured by 3D-full wavelength scanning.The validity of the method was tested by analyzing the precision,reproducibility,stability and accuracy.[Results]The results indicated that in terms of extraction and separation of compounds,supercritical CO2 not only has the diffusion property of gas,but also has the density and fluidity of liquid.[Conclusions]The ultra-high performance chromatography is a new technique for drug analysis.
基金supported partially by the National Natural Science Foundation of China (Nos. 40974004 and 40974016)Key Laboratory of Dynamic Geodesy of CAS, China (No. L09-01) R&I Team Support Program and the Graduate Science and Technology Foundation of SDUST, China (No. YCA110403)
文摘The HY-2 satellite carrying a satellite-borne GPS receiver is the first Chinese radar altimeter satellite, whose radial orbit determination precision must reach the centimeter level. Now HY-2 is in the test phase so that the observations are not openly released. In order to study the precise orbit determination precision and procedure for HY-2 based on the satellite- borne GPS technique, the satellite-borne GPS data are simulated in this paper. The HY-2 satellite-borne GPS antenna can receive at least seven GPS satellites each epoch, which can validate the GPS receiver and antenna design. What＇s more, the precise orbit determination processing flow is given and precise orbit determination experiments are conducted using the HY-2-borne GPS data with both the reduced-dynamic method and the kinematic geometry method. With the 1 and 3 mm phase data random errors, the radial orbit determination precision can achieve the centimeter level using these two methods and the kinematic orbit accuracy is slightly lower than that of the reduced-dynamic orbit. The earth gravity field model is an important factor which seriously affects the precise orbit determination of altimeter satellites. The reduced-dynamic orbit determination experiments are made with different earth gravity field models, such as EIGEN2, EGM96, TEG4, and GEMT3. Using a large number of high precision satellite-bome GPS data, the HY-2 precise orbit determination can reach the centimeter level with commonly used earth gravity field models up to above 50 degrees and orders.
文摘In Europe, computation of displacement demand for seismic assessment of existing buildings is essentially based on a simplified formulation of the N2 method as prescribed by Eurocode 8(EC8). However, a lack of accuracy of the N2 method in certain conditions has been pointed out by several studies. This paper addresses the assessment of effectiveness of the N2 method in seismic displacement demand determination in non-linear domain. The objective of this work is to investigate the accuracy of the N2 method through comparison with displacement demands computed using non-linear timehistory analysis(NLTHA). Results show that the original N2 method may lead to overestimation or underestimation of displacement demand predictions. This may affect results of mechanical model-based assessment of seismic vulnerability at an urban scale. Hence, the second part of this paper addresses an improvement of the N2 method formula by empirical evaluation of NLTHA results based on EC8 ground-classes. This task is formulated as a mathematical programming problem in which coefficients are obtained by minimizing the overall discrepancy between NLTHA and modified formula results. Various settings of the mathematical programming problem have been solved using a global optimization metaheuristic. An extensive comparison between the original N2 method formulation and optimized formulae highlights benefits of the strategy.
