Effect of the Retarder on Initial Hydration and Mechanical Properties of the"one-step"Alkaliactivated Composite Cementitious Materials

This paper studied the effects of different retarders on the performance of the"one-step"alkali-activated composite cementitious material(ACCM)which is composed of ground granulated blast slag(GGBS)and fly ash(FA),and analyzed its mechanical properties,hydration mechanism,and retardation mechanism.The effects of retarders on the hydration products,mechanical properties,and hydration kinetics of ACCM were investigated using XRD,SEM,FTIR,EDS,and thermoactive microcalorimetry.The results showed that Na_(2)B_(4)O_(7)·10H_(2)O(B)delayed the exotherm during the alkali activation process and could effectively delay the setting time of ACCM,but the mechanical properties were slightly decreased.The setting time of ACCM increased with the increase in SG content,but the mechanical properties of ACCM decreased with the increase in SG content.C1_(2)H_(22)O_(11)(CHO)could effectively delay the hydration reaction of ACCM and weakly enhanced the compressive strength.H_(3)PO_(4)(HP)at a concentration of 0.05 mol/L had a certain effect on ACCM retardation,but HP at a concentration of 0.07 and 0.09 mol/L had an effect of promoting the setting and hardening time of ACCM.

Deterioration Reason and Improvement Measure of the Retarding Effect of Protein Retarder on Phosphorus Building Gypsum

The retarding effect of protein retarder on phosphorus building gypsum(PBG)and desulfurization building gypsum(DBG)was investigated,and the results show that protein retarder for DBG can effectively prolong the setting time and displays a better retarding effect,but for PBG shows a poor retarding effect.Furthermore,the deterioration reason of the retarding effect of protein retarder on PBG was investigated by measuring the pH value and the retarder concentration of the liquid phase from vacuum filtration of PBG slurry at different hydration time,and the measure to improve the retarding effect of protein retarding on PBG was suggested.The pH value of PBG slurry(<5.0)is lower than that of DBG slurry(7.8-8.5).After hydration for 5 min,the concentration of retarder in liquid phase of DBG slurry gradually decreases,but in liquid phase of PBG slurry continually increases,which results in the worse retarding effect of protein retarder on PBG.The liquid phase pH value of PBG slurry can be adjusted higher by sodium silicate,which is beneficial to improvement in the retarding effect of the retarder.By adding 1.0%of sodium silicate,the initial setting time of PBG was efficiently prolonged from 17 to 210 min,but little effect on the absolute dry flexural strength was observed.

The Electrical Resistivity of Cement Paste Incorporated with Retarder

A non contacting electrical resistivity measurement device was used for measuring the electrical resistivity of cement paste incorporated with retarder.The hydration process was divided into dissolving period,setting period,hardening period.With the increase of the retarder,the dissolution time will increase.The setting time happens between minimum point time and inflexion point time based on the electrical resistivity curve.The strength isoline was proposed to predict the strength trend.

Irradiation study of liquid crystal variable retarder for Full-disk Magneto-Graph payload onboard ASO-S mission

The Advanced Space-based Solar Observatory(ASO-S)is a mission proposed by the Chinese Solar Physics Community.As one of the three payloads of ASO-S,the Full-disc Magneto-Graph(FMG)will measure the photospheric magnetic fields of the entire solar disk with high spatial and temporal resolution,and high magnetic sensitivity,where liquid crystal variable retarder(LCVR)is the key to whether FMG can achieve its scientific goal.So far,there is no space flight experience for LCVR.Therefore,irradiation study for LCVRs becomes more important and urgent in order to make sure their safety and reliability in space application.In this paper,γirradiation,proton irradiation,and ultra-violet(UV)irradiation are tested for LCVRs respectively.The optical and chemical properties during irradiation tests are measured and analyzed.For optical properties,there is no significant change in those parameters FMG payload concerned except the retardation.Although there is no drastic degradation in the retardation versus voltage during irradiations,the amount of retardation variation is much higher than the instrument requirements.Thus,an in-flight retardation versus voltage should be added in FMG payload,reducing or even avoiding the impact of retardation change.For chemical properties,the clearing point and birefringence of the LC materials almost have no change;the ion density dose not change below 60 krad[Si],but begin to increase dramatically above 60 krad[Si].

Modification of waste fluorgypsum and its applications as a cement retarder

The waste fiuorgypsum was modified and applied as a cement retarder. The main chemical composition and mineral structure of the waste fluorgypsum were analyzed. Scanning electron microscopy （SEM） and eight-channel micro-calorimeter （TAM Air） were employed to analyze the changes in morphology and study the application performance of the modified fluorgypsum, respectively. Experimental results indicate that the flexural strength and compressive strength of the modified fiuorgypsurn are roughly equal to those of the natural gypsum. The morphology of the crystal of the fiuorgypsum changes from block particle into trimetric short column. The fluorgypsum crystals stagger mutually and improve the strength of the hardened body. The modified fluorgypsum as cement retarder could delay the hydration, reduce the heat of the hydration and make the setting time, volume stability, and the S03 content of the cement meet the national standards. The modified fluorgypsum is a good substitute for the natural gypsum.

Modification of Fluorgypsum as Cement Retarder

The chemical composition and mineral structure of fluorgypsum as well as its harm to application in cement were elaborately analyzed. The primary fluorgypsum was modified and its applications in cement＇s production were studied. The technological flow chart of preparing modified fluorgypsum was given. Experimental results indicate that hydration ratio the modified fluorgypsum through adding compound additive for 14d is about 70%. The modified fluorgypsum as cement retarder has certain stimulation to fly ash and increases the strength of compound cement. In addition, its adding amount is lower than that of natural gypsum. The modified fluorgypsum is a good substitute for natural gypsum.

NUMERICAL ANALYSIS AND EXPERI-MENT OF UNSTEADY THERMAL FIELD OF ROTOR PLATE FOR EDDY CURRENT RETARDER

The physical model based on heat transfer theory and virtual boundary method for analyzing unsteady thermal field of rotor plate for eddy current retarder used in automobile is established and boundary conditions are also defined. The finite element governing equation is derived by Galerkin method. The time differential item is discrete based on Galerkin format that is stable at any condition. And a new style of varying time step method is used in iteration process. The thermal field on the rotor plate at the radial and axle directions is analyzed and varying temperature at appointed points on two side-surfaces is measured. The testing and analytical data are uniform approximately. Finite element method can be used for estimating thermal field of the rotor plate at initial design stage of eddy current retarder.

Research on the use of sintering flue gas desulphurization gypsum as a cement retarder

The characteristics of the desulphurized gypsum produced in the flue gas desulphurization （FGD） process of the Baosteel sintering plant are investigated in this study. According to the technical and quality requirements of gypsum in the cement industry ,the feasibility of using desulphurized gypsum as a cement retarder is also studied. The results show that desulphurized gypsum can be used as a cement retarder instead of natural gypsum.

Ellipsometric configurations using a phase retarder and a rotating polarizer and analyzer at any speed ratio

In this paper, we propose an ellipsometer using a phase retarder and rotating polarizer and analyzer at a speed ratio I：N. Different ellipsometric configurations are presented by assuming N = 1, 2, and 3. Moreover, two values of the offset angle of the retarder are considered for each ellipsometric configuration. The Mueller formalism is employed to extract the Stokes parameters, from which the intensity received by the detector is obtained. The optical properties of c-Si are calculated using all configurations. A comparison between different configurations is carried out considering the effect of the noise on the results and the uncertainties in the ellipsometric parameters as functions of the uncertainties of the Fourier coefficients. It is found that the alignment of the phase retarder has a crucial impact on the results and the ellipsometric configuration with speed ratio 1：1 is preferred over the other configurations.

Numerical Simulation of the Demagnetization of a Permanent Magnet Retarder in High Temperature

As a auxiliary brake, Permanent Magnet Retarder （PMR） generates lots of energy and has greater temperature-rise when PMR works, so that it has a direct impact on PMR work performance and even causes demagnetization seriously. In order to analyze permanent magnet （PM） demagnetization in high-temperature in PMR, PMR mathematical model is established firstly, and the boundary conditions of finite element analysis are determined. Then the eddy current field distribution in the rotor is determined by solving eddy current demagnetization field, and PM dynamic permeance coefficient is obtained. Combined with PM demagnetization curve analysis, PMR permanent magnet demagnetization properties are analyzed. The analysis result is validated by the bench test. It shows that part of PM is demagnetized when PRM continues working for about 15 minutes, and the braking performance is declined. Finally, three PMR optimization design methods are proposed.

Broadband achromatic phase retarder based on metal-multilayer dielectric grating

A new achromatic phase retarder based on a metal-multilayer dielectric grating structure is designed using the rigorous coupled wave analysis method and the genetic algorithm.The optimized phase retarder can maintain phase retardation around 90°from 900 nm to 1200 nm,and the maximum deviation is less than 4.5%while the diffraction efficiencies of TE and TM waves are both higher than 95%.Numerical analysis shows the designed phase retarder has a high fabrication tolerance of groove depth,duty cycle and incident angle.This achromatic phase retarder is simple in design and stable in performance,and can be widely used in optical systems.

An Investigation into the Influence of the Airflow Path on the Convective Heat Transfer for an Eddy Current Retarder Turntable

In order to improve the convective heat transfer relating to an eddy current retarder,the finite element model has been used to assess the performances of different possible designs.In particular,assuming the steady running state of retarder as the working condition,flow and temperature fields have been obtained for the rotor.The influence of airflow path on heat dissipation has been analysed,and the influence of the temperature field distribution on the performance of retarder has been discussed accordingly.The results show that when the steady running state of the turntable is considered,the maximum temperature is lower,the level of turbulence flow is mitigated,and the temperature distribution becomes more regular.These factors contribute to improve the heat dissipation ability of the retarder.

Design of broad angular phase retarders for the complete polarization analysis of extreme ultraviolet radiation

A method of designing broad angular phase retarders in the extreme ultraviolet （EUV） region is presented. The design is based on a standard Levenberg-Marquardt algorithm combined with a common merit function. Using this method, a series of broad angular EUV phase retarders were designed using aperiodic Mo/Si multilayers. At photon energy of 90 eV, broad angular phase retarders with 30°, 60°, and 90° phase retardations have been realized in the angular range of 39°-51°. By analyzing and comparing the performances of the designed broad angular phase retarders, we found that the Mo/Si multilayer with more layers could obtain higher phase retardation in broader angular range when used to design the broad angular phase retarder. Broad angular phase retarders possess lower sensitivity toward changing incident angle compared with the traditional phase retarders designed with transmission periodic multilayers, and can be used for the polarization control of broad angular EUV sources.

Spatially modulated polarimetry based on a vortex retarder and Fourier analysis

We report a spatially modulated polarimetry scheme by using a zero-order vortex half-wave retarder(ZVHR)and a spatial Fourier analysis method.A ZVHR is employed to analyze the input polarized light and convert it into a vectorial optical field,and an analyzer is set after the ZVHR to form an hourglass intensity pattern due to the spatial polarization modulation.Then,the input light’s Stokes parameters can be calculated by spatial Fourier analysis of the hourglass pattern with a single shot.The working principle of the polarimeter has been analyzed by the Stokes-Mueller formalism,and some quantitative measuring experiments of different polarization states have been demonstrated.The experimental results indicate that the proposed polarimeter is accurate,robust,and simple to use.

Scale-resolving simulations and investigations of the flow in a hydraulic retarder considering cavitation

Cavitation has a significant influence on the accurate control of the liquid filling rate and braking performance of a hydraulic retarder;however,previous studies of the flow field in hydraulic retarders have provided insufficient information in terms of considering cavitation.Here,the volume of fluid(VOF)method and a scale-resolving simulation(SRS)were employed to numerically and more comprehensively calculate and analyze the flow field in a retarder considering the cavitation phenomenon.The numerical models included the improved delayed detached eddy simulation(IDDES)model,stress-blended eddy simulation(SBES)model,dynamic large eddy simulation(DLES)model,and shear stress transport(SST)model in the Reynolds-averaged Navier-Stokes(RANS)model.All the calculations were typically validated by the brake torque in the impeller rather than the internal flow.The unsteady flow field indicated that the SBES and DLES models could better capture unsteady flow phenomena,such as the chord vortex.The SBES and DLES models could also better capture bubbles than the SST and IDDES models.Since the braking torque error of the SBES model was the smallest,the transient variation of the bubble volume fraction over time on a typical flow surface was analyzed in detail with the SBES model.It was found that bubbles mainly appeared in the center area of the blade suction surface,which coincided with the experiments.The accumulation of bubbles resulted in a larger bubble volume fraction in the center of the blade over time.In addition,the temperature variations of the pressure blade caused by heat transfer were further analyzed.More bubbles precipitated in the center of the blade,leading to a lower temperature in this area.

Water medium retarders for heavy-duty vehicles:Computational fluid dynamics and experimental analysis of filling ratio control method

The water medium（WM） retarder is an auxiliary braking device that could convert the kinetic energy of the vehicle to the thermal energy of the coolant, and it is used instead of the service brake under non-emergency braking conditions. This paper analyzes the flow distribution based on a mathematical model and analyzes the key factors that could affect the filling ratio and the braking torque of the WM retarder. Computational fluid dynamics（CFD） simulations are conducted to compute the braking torque, and theresults are verified by experiments. It is shown that the filling ratio and the braking torque can be expressed by the mathematical model proposed in this paper. Compared with the Reynolds averaged Navier-Stokes（RANS） turbulent model, the shear stress transport（SST） turbulent model can more accurately simulate the braking torque. Finally, the flow distribution and the flow character in the WM retarders are analyzed.

Noise suppression for the detection laser of a nuclear magnetic resonance gyroscope based on a liquid crystal variable retarder

Nuclear magnetic resonance gyroscopes （NMRGs） are a kind of rotation-speed sensor that senses the angular velocity by measuring a frequency shift in the Larmor pre- cession of the nuclear spin in a constant magnetic field.

Analytical model and finite element computation of braking torque in electromagnetic retarder

An analytical model has been developed for analyzing the braking torque in electromagnetic retarder by flux tube and armature reaction method. The magnetic field distribution in air gap, the eddy current induced in the rotor and the braking torque are calculated by the developed model. Two-dimensional and three-dimensional finite element models for retarder have also been developed. Results from the analytical model are compared with those from finite element models. The validity of these three models is checked by the comparison of the theoretical predictions and the measurements from an experimental prototype. The influencing factors of braking torque have been studied.

Preparation of Polyurea Elastomer with Flame Retardant, Insulation and Thermal Conductivity Properties

By using 6,6-((sulfonylbis(4,1-phenylene)bis(azanediyl))bis(thiophen-2-ylm-ethylene))bis6H-di-benzo[c,e][1,2]oxaphosphinine 6-oxide(DOPO-N)as phosphorus-nitrogen flame retardant,the polyurea(PUA)with flame retardant properties(PUA/DOPO-N)was prepared.In addition,organically modified montmorillonite(OMMT)and magnesium hydroxide(MH)were used as co-effectors respectively,and the flame retardant PUA(PUA/DOPO-N/OMMT and PUA/DOPO-N/MH)were also prepared.Thermal properties,flame retardant properties,flame retardant mechanism and mechanical properties of PUA/DOPO-N,PUA/DOPO-N/OMMT and PUA/DOPO-N/MH were investigated by thermogravimetric(TG)analysis,limiting oxygen index(LOI),UL 94,cone calorimeter test,scanning electron microscopy(SEM),and tensile test.The results show that the LOI value of PUA/20%DOPO-N,PUA/18%DOPO-N/2%OMMT and PUA/15%DOPO-N/5%MH are 27.1%,27.7%,and 28.3%,respectively,and UL 94 V-0 rating is attained.Compared with PUA,the peak heat release rate(pk-HRR),total heat release(THR)and average effective heat combustion(av-EHC)of PUA/20%DOPO-N,PUA/18%DOPO-N/2%OMMT and PUA/15%DOPO-N/5%MH decrease significantly.SEM results indicate that the residual chars of PUA/20%DOPO-N,PUA/18%DOPO-N/2%OMMT and PUA/15%DOPO-N/5%MH are completer and more compact.The complex of DOPO-N/OMMT and DOPO-N/MH have synergistic flame retardancy.The mechanical properties of PUA can be improved by the addition of DOPO-N,DOPO-N/OMMT and DOPO-N/MH,respectively.The insulation performance test shows that the volume resistivity of PUA/20%DOPO-N is 6.25×10^(16)Ω.cm.Furthermore,by using modified boron nitride(MBN)as heat dissipating material,the complex of PUA/MBN was prepared,and the thermal conductivity of PUA/MBN was investigated.The thermal conductivity of PUA/8%MBN complex coating at room temperature is 0.166 W/(M·K),which is a 163%improvement over pure PUA.