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Influences of operating conditions on biocatalytic activity and reusability of Novozym 435 for esterification of free fatty acids with short-chain alcohols:A case study of palm fatty acid distillate 被引量:1
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作者 Sawittree Mulalee Pongrumpa Srisuwan Muenduen Phisalaphong 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第11期1851-1856,共6页
In the present study, the effects of operating conditions on biocatalytic activity and stability of Novozym 435 for repeated-batch biodiesel production from free fatty acid (FFA) were investigated. Thermal deactivat... In the present study, the effects of operating conditions on biocatalytic activity and stability of Novozym 435 for repeated-batch biodiesel production from free fatty acid (FFA) were investigated. Thermal deactivation caused by increased operating temperature from 45 to 50 ℃ could seriously affect the reusability of Novozym 435. The deactivation of Novozym 435 during the esterification of oleic acid with ethanol tended to be stronger than that in the system with methanol. Under the optimal conditions, considering both biocatalytic activity and stability of the enzyme, Novozym 435 could be reused for 13 cycles for biodiesel productions from oleic acid and absolute alcohols (methanol and ethanol) with FFA conversions of at least 90%. The presence of 4%-5% water in ethanol significantly affected the reusability of Novozym 435. Changes in the surface morphology of Novozym 435 during the esterification with various conditions were observed. It was revealed that the reduction in catalytic activity was related to the swelling degree of the catalyst surface, Additionally, biodiesel production from low cost renewable feedstocks, such as palm fatty acid distillate (PFAD) and 95% ethanol was examined, The esterification of PFAD with 95% ethanol catalyzed by Novozym 435 in 10-repeated batch operation showed the similar results in FFA conversion as compared to those using oleic acid. Novozym 435 remained active and could maintain 97.6% of its initial conversion after being used for 10 hatches. 展开更多
关键词 Biodiesel Oleic acid Novozym 435reusability Palm fatty acid distillate
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Artificial Intelligence Model for Software Reusability Prediction System
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作者 R.Subha Anandakumar Haldorai Arulmurugan Ramu 《Intelligent Automation & Soft Computing》 SCIE 2023年第3期2639-2654,共16页
The most significant invention made in recent years to serve various applications is software.Developing a faultless software system requires the soft-ware system design to be resilient.To make the software design more... The most significant invention made in recent years to serve various applications is software.Developing a faultless software system requires the soft-ware system design to be resilient.To make the software design more efficient,it is essential to assess the reusability of the components used.This paper proposes a software reusability prediction model named Flexible Random Fit(FRF)based on aging resilience for a Service Net(SN)software system.The reusability predic-tion model is developed based on a multilevel optimization technique based on software characteristics such as cohesion,coupling,and complexity.Metrics are obtained from the SN software system,which is then subjected to min-max nor-malization to avoid any saturation during the learning process.The feature extrac-tion process is made more feasible by enriching the data quality via outlier detection.The reusability of the classes is estimated based on a tool called Soft Audit.Software reusability can be predicted more effectively based on the pro-posed FRF-ANN(Flexible Random Fit-Artificial Neural Network)algorithm.Performance evaluation shows that the proposed algorithm outperforms all the other techniques,thus ensuring the optimization of software reusability based on aging resilient.The model is then tested using constraint-based testing techni-ques to make sure that it is perfect at optimizing and making predictions. 展开更多
关键词 Service net aging resilient software reusability evolutionary computing intelligent computing
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Quantifying Reusability of Object Oriented Design: A Testability Perspective
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作者 Mahfuzul Huda Yagya Dutt Sharma Arya Mahmoodul Hasan Khan 《Journal of Software Engineering and Applications》 2015年第4期175-183,共9页
The quality factor of class diagram is critical because it has a significant influence on overall quality of the product, delivered finally. Testability analysis, when done early in the software creation process, is a... The quality factor of class diagram is critical because it has a significant influence on overall quality of the product, delivered finally. Testability analysis, when done early in the software creation process, is a criterion of critical importance to software quality. Reusability is an important quality factor to testability. Its early measurement in object oriented software especially at design phase, allows a design to be reapplied to a new problem without much extra effort. This research paper proposes a research framework for quantification process and does an extensive review on reusability of object oriented software. A metrics based model “Reusability Quantification of Object Oriented Design” has been proposed by establishing the relationship among design properties and reusability and justifying the correlation with the help of statistical measures. Also, “Reusability Quantification Model” is empirically validated and contextual significance of the study shows the high correlation for model acceptance. This research paper facilitates to software developers and designer, the inclusion of reusability quantification model to access and quantify software reusability for quality product. 展开更多
关键词 reusability TESTABILITY OBJECT ORIENTED DESIGN DESIGN Metrics OBJECT ORIENTED SOFTWARE SOFTWARE Quality Model SOFTWARE Testing Effort
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Software Reusability Classification and Predication Using Self-Organizing Map (SOM)
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作者 Amjad Hudaib Ammar Huneiti Islam Othman 《Communications and Network》 2016年第3期179-192,共14页
Due to rapid development in software industry, it was necessary to reduce time and efforts in the software development process. Software Reusability is an important measure that can be applied to improve software deve... Due to rapid development in software industry, it was necessary to reduce time and efforts in the software development process. Software Reusability is an important measure that can be applied to improve software development and software quality. Reusability reduces time, effort, errors, and hence the overall cost of the development process. Reusability prediction models are established in the early stage of the system development cycle to support an early reusability assessment. In Object-Oriented systems, Reusability of software components (classes) can be obtained by investigating its metrics values. Analyzing software metric values can help to avoid developing components from scratch. In this paper, we use Chidamber and Kemerer (CK) metrics suite in order to identify the reuse level of object-oriented classes. Self-Organizing Map (SOM) was used to cluster datasets of CK metrics values that were extracted from three different java-based systems. The goal was to find the relationship between CK metrics values and the reusability level of the class. The reusability level of the class was classified into three main categorizes (High Reusable, Medium Reusable and Low Reusable). The clustering was based on metrics threshold values that were used to achieve the experiments. The proposed methodology succeeds in classifying classes to their reusability level (High Reusable, Medium Reusable and Low Reusable). The experiments show how SOM can be applied on software CK metrics with different sizes of SOM grids to provide different levels of metrics details. The results show that Depth of Inheritance Tree (DIT) and Number of Children (NOC) metrics dominated the clustering process, so these two metrics were discarded from the experiments to achieve a successful clustering. The most efficient SOM topology [2 × 2] grid size is used to predict the reusability of classes. 展开更多
关键词 Component Based System Development (CBSD) Software reusability Software Metrics CLASSIFICATION Self-Organizing Map (SOM)
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Low Cost and Reusability of Launch Vehicle 被引量:2
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作者 LU Yu QIN Xudong CHEN Haipeng 《Aerospace China》 2016年第2期37-44,共8页
This paper analyzes the launch price of the launch vehicles, domestic and abroad, studies the status and trend of the low cost launch vehicles, and introduces two measures to reduce the cost by means of evolved and di... This paper analyzes the launch price of the launch vehicles, domestic and abroad, studies the status and trend of the low cost launch vehicles, and introduces two measures to reduce the cost by means of evolved and disruptive technologies, utilizing the concept of low cost manufacturing and operating modes as well. This paper also analyzes the launch strategies for small satellites such as piggyback, networking launch, and single launch with a small launch vehicle(SLV). Finally, the development trend of reusable launch vehicles is discussed as well as the development prospects for China's reusable launch vehicle. 展开更多
关键词 Launch vehicle Low cost Small satellite Commercial space REUSABLE
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Numerical and experimental analysis of the reusability of spring energized metal C rings 被引量:10
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作者 LIU Ying ZHOU Kun +2 位作者 HUANG WeiFeng GAO Zhi WANG YuMing 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第8期1670-1676,共7页
It is well known that static seals are usually designed to be used once. In this paper, we discuss the reusability of a type of static seal called the spring energized metal C ring, which is required to be reused 4-5 ... It is well known that static seals are usually designed to be used once. In this paper, we discuss the reusability of a type of static seal called the spring energized metal C ring, which is required to be reused 4-5 times without maintenance during the lifetime of the pump. A theoretical analysis based on the nonlinear finite element method and an experimental investigation of the reusability of the C ring are carried out. The effects of the elastic modulus of the ring material, the ring wall thickness, the amount of assembly interference between the spring and the C ring, the operating temperature and the compression ratio are discussed. The parameter S, which denotes the reaction force difference percentage, is determined to measure the reusability of the C ring. The results show that the ring wall thickness plays an important role in the reusability. Although the normal force of a thick wall decreases after the ring is reused eight times, the value is still higher than the first normal force of a thin wall. In contrast, the elastic modulus of the material has the lowest impact. Here, a pre-compression ratio of 18.2% not only produces a larger first normal force but also leads to a smaller reduction in the normal force when the ring is reused. A simulated experiment is carried out to investigate the influence of the coating of the C ring on its reusability. The results show that when plastic deformation occurs on the contact surface, the contact state of the C ring coating becomes a major factor that affects the seal performance. Aging treatment at high temperatures (250℃) reduces gized metal C ring, which leads to the deterioration in the reusability the binding force of the silver coating on the spring ener of the ring. 展开更多
关键词 reusability spring energized metal C ring nonlinear finite element analysis
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A Method of Minimum Reusability Estimation for Automated Software Testing 被引量:2
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作者 KAN Hong-xing WANG Guo-qiang +1 位作者 WANG Zong-dian DING Shuai 《Journal of Shanghai Jiaotong university(Science)》 EI 2013年第3期360-365,共6页
Through reusing software test components, automated software testing generally costs less than manual software testing. There has been much research on how to develop the reusable test components, but few fall on how ... Through reusing software test components, automated software testing generally costs less than manual software testing. There has been much research on how to develop the reusable test components, but few fall on how to estimate the reusability of test conlponents for automated testing. The purpose of this paper is to present a method of minimum reusability estimation for automated testing based on the return on investment (ROI) model. Minimum reusability is a benchmark for the whole automated testing process. If the reusability in one test execution is less than the minimum reusability, some new strategies must be adopted ill the next test execution to increase the reusability. Only by this way, we can reduce unnecessary costs and finally get a return on the investment of automated testing. 展开更多
关键词 automated software testing manual software testing mean maintenance costs multiplier reusable software test components THRESHOLD minimum reusability estimation
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Enhancing the reusability and interoperability of artificial neural networks with DEVS modeling and simulation
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作者 David Ifeoluwa Adelani Mamadou Kaba Traore 《International Journal of Modeling, Simulation, and Scientific Computing》 EI 2016年第2期88-108,共21页
Artificial neural networks(ANNs),a branch of artificial intelligence,has become a very interesting domain since the eighties when back-propagation(BP)learning algorithm for multilayer feed-forward architecture was int... Artificial neural networks(ANNs),a branch of artificial intelligence,has become a very interesting domain since the eighties when back-propagation(BP)learning algorithm for multilayer feed-forward architecture was introduced to solve nonlinear problems.It is used extensively to solve complex nonalgorithmic problems such as prediction,pattern recognition and clustering.However,in the context of a holistic study,there may be a need to integrate ANN with other models developed in various paradigms to solve a problem.In this paper,we suggest discrete event system specification(DEVS)be used as a model of computation(MoC)to make ANN models interoperable with other models(since all discrete event models can be expressed in DEVS,and continuous models can be approximated by DEVS).By combining ANN and DEVS,we can model the complex configuration of ANNs and express its internal workings.Therefore,we are extending the DEVS-based ANN proposed by Toma et al.[A new DEVS-based generic art-ficial neural network modeling approach,The 23rd European Modeling and Simulation Symp.(Simulation in Industry),Rome,Italy,2011]for comparing multiple configuration parameters and learning algorithms and also to do prediction.The DEVS models are described using the high level language for system specification(HiLLS),[Ma¨ıga et al.,A new approach to modeling dynamic structure systems,The 29th European Modeling and Simulation Symp.(Simulation in Industry),Leicester,United Kingdom,2015]a graphical modeling language for clarity.The developed platform is a tool to transform ANN models into DEVS computational models,making them more reusable and more interoperable in the context of larger multi-perspective modeling and simulation(MAS). 展开更多
关键词 Artificial neural networks DEVS Z-schema reusability INTEROPERABILITY HiLLS learning algorithm modeling and simulation
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Superwetting Ag/α-Fe_(2)O_(3) anchored mesh with enhanced photocatalytic and antibacterial activities for efficient water purification 被引量:1
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作者 Jiakai Li Changpeng Lv +5 位作者 Jiajia Song Xiaoling Zhang Xizhen Huang Yingzhuo Ma Haijie Cao Na Liu 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第1期89-103,共15页
Superwetting materials have drawn unprecedented attention in the treatment of oily wastewater due to their preferable anti-fouling property and selective oil/water separation.However,it is still a challenge to fabrica... Superwetting materials have drawn unprecedented attention in the treatment of oily wastewater due to their preferable anti-fouling property and selective oil/water separation.However,it is still a challenge to fabricate multifunctional and environmentally friendly materials,which can be stably applied to purify the actual complicated wastewater.Here,a Ag/Ag/α-Fe_(2)O_(3) heterostructure anchored copper mesh was intentionally synthesized using a facile two-step hydrothermal method.The resultant mesh with superhydrophilicity and underwater superoleophobicity was capable of separating various oil/water mixtures with superior separation efficiency and high permeationflux driven by gravity.Benefiting from the joint effects of the smaller band gap of Ag/α-Fe_(2)O_(3) heterojunction,inherent antibacterial capacity of Ag/α-Fe_(2)O_(3) and Ag nanoparticles,favorable conductive substrate,as well as the hierarchical structure with superwettability,such mesh presented remarkably enhanced degradation capability toward organic dyes under visible light irradiation and antibacterial activity against both Escherichia coli(E.coli)and Staphylococcus aureus(S.aureus)compared with the pure Ag/α-Fe_(2)O_(3) coated mesh.Impressively,the mesh exhibited bifunctional water purification performance,in which organic dyes were eliminated simultaneously from water during oil/water separation in onefiltration process.More importantly,this mesh behaved exceptional chemical resistance,mechanical stability and long-term reusability.Therefore,this material with multifunctional integration may hold promising potential for steady water purification in practice. 展开更多
关键词 Superwetting Ag/α-Fe_(2)O_(3)heterostructure Enhanced photocatalytic and antibacterial activities Water purification Long-term reusability
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Towards cultivar-oriented gene discovery for better crops
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作者 Dengcai Liu 《The Crop Journal》 SCIE CSCD 2024年第3期670-675,共6页
The continued expansion of the world population,increasingly inconsistent climate and shrinking agricultural resources present major challenges to crop breeding.Fortunately,the increasing ability to discover and manip... The continued expansion of the world population,increasingly inconsistent climate and shrinking agricultural resources present major challenges to crop breeding.Fortunately,the increasing ability to discover and manipulate genes creates new opportunities to develop more productive and resilient cultivars.Many genes have been described in papers as being beneficial for yield increase.However,few of them have been translated into increased yield on farms.In contrast,commercial breeders are facing gene decidophobia,i.e.,puzzled about which gene to choose for breeding among the many identified,a huge chasm between gene discovery and cultivar innovation.The purpose of this paper is to draw attention to the shortfalls in current gene discovery research and to emphasise the need to align with cultivar innovation.The methodology dictates that genetic studies not only focus on gene discovery but also pay good attention to the genetic backgrounds,experimental validation in relevant environments,appropriate crop management,and data reusability.The close of the gaps should accelerate the application of molecular study in breeding and contribute to future global food security. 展开更多
关键词 Cultivar innovation Data reusability Gene discovery Gene decidophobia Omnigenic model
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Biocatalytic enhancement of laccase immobilized on ZnFe_(2)O_(4) nanoparticles and its application for degradation of textile dyes
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作者 Yuhang Wei Qingpeng Zhu +3 位作者 Weiwei Xie Xinyue Wang Song Li Zhiming Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期216-223,共8页
Efficient and convenient treatment of industrial dyeing wastewater is of great significance to guarantee human and animal health.This work presented the enhanced catalytic activity at pH 3.0 of laccase immobilized on ... Efficient and convenient treatment of industrial dyeing wastewater is of great significance to guarantee human and animal health.This work presented the enhanced catalytic activity at pH 3.0 of laccase immobilized on amino-functionalized ZnFe_(2)O_(4) nanoparticles(ZnFe_(2)O_(4)-laccase)and its application for the degradation of textile dyes.Due to the existence of a large number of oxygen vacancies on the surface of the ZnFe_(2)O_(4) nanoparticles,negative ions accumulated on the magnetic carriers,which resulted in a harsh optimal pH value of the ZnFe_(2)O_(4)-laccase.Laccase activity assays revealed that the ZnFe_(2)O_(4)-laccase possessed superior pH and thermal stabilities,excellent reusability,and noticeable organic solvent tolerance.Meanwhile,the ZnFe_(2)O_(4) laccase presented efficient and sustainable degradation of high concentrations of textile dyes.The initial decoloration efficiencies of malachite green(MG),brilliant green(BG),azophloxine,crystal violet(CV),reactive blue 19(RB19),and procion red MX-5B were approximately 99.1%,95.0%,93.3%,87.4%,86.1%,and 85.3%,respectively.After 10 consecutive reuses,the degradation rates of the textile dyes still maintained about 98.2%,92.5%,83.2%,81.5%,79.8%and 65.9%,respectively.The excellent dye degradation properties indicate that the ZnFe_(2)O_(4)-laccase has a technical application in high concentrations of dyestuff treatment. 展开更多
关键词 ZnFe_(2)O_(4)-laccase Catalytic activity Stability and reusability Degradation of textile dye
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Leveraging React Components in Business Process Management (BPM) Applications
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作者 Ashok Reddy Annaram 《Journal of Computer and Communications》 2024年第4期86-94,共9页
As organizations increasingly embrace digital transformation, the integration of modern web technologies like React.js with Business Process Management (BPM) applications has become essential. React components offer f... As organizations increasingly embrace digital transformation, the integration of modern web technologies like React.js with Business Process Management (BPM) applications has become essential. React components offer flexibility, reusability, and scalability, making them ideal for enhancing user interfaces and driving user engagement within BPM environments. This article explores the benefits, challenges, and best practices of leveraging React components in BPM applications, along with real-world examples of successful implementations. 展开更多
关键词 React.js Digital Transformation User Interface (UI) Development Component-Based Architecture Declarative UI Development User Experience (UX) reusability Modularity INTEGRATION CUSTOMIZATION Developer Productivity Legacy System Integration
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Study on the Treatment of Reusable Care Equipment in Public and Private Dental Practices in the City of Conakry
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作者 Magna Condé Aly Badara Nabé +4 位作者 Moussa Doré Julie Gaëlle Yepmo Sambou Alhassane Alpha Camara Amadou Traoré Kouamé Patrice Attogbain 《Open Journal of Stomatology》 2024年第8期351-361,共11页
Introduction: The effective sterilization of reusable instruments in dental care is a crucial issue for public health. The aim of this study was to contribute to improving the processing conditions of reusable care in... Introduction: The effective sterilization of reusable instruments in dental care is a crucial issue for public health. The aim of this study was to contribute to improving the processing conditions of reusable care instruments in dental practices in the city of Conakry. Methods: We carried out an observational and cross-sectional study of a descriptive type lasting three months from January to April 2022 in public and private dental practices approved for activities. Results: A total of 48 dental practices were surveyed, including 7 public and 41 private. 91.67% had the trays for instrument sterilization. 77.08% had a sterilization device. The instruments were: cleaned 100%, disinfected 70.83%, sterilized 20.83% and 20.83% reused the instruments without being sterilized. 72.97% sterilized the instruments at the end of the day. 50% of respondents declared that there were six stages of sterilization. According to standard standards, one dental office or 2.70% respected the normal sterilization process and 13.51% respected the duration and temperature. The storage quality was inadequate at 95.83%. 95.83% of dental practices are at high risk of contamination. The difficulties encountered by staff in daily activity during our study were lack of hygienists (87.50%), insufficient material resources (58.33%), and lack of protocol procedure (45.83%). Conclusion: This study allowed us to note shortcomings of dental surgeons in the process of processing reusable care materials. 展开更多
关键词 TREATMENT MATERIALS CARE REUSABLE Dental Practices Conakry
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Robust Attitude Control for Reusable Launch Vehicles Based on Fractional Calculus and Pigeon-inspired Optimization 被引量:5
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作者 Qiang Xue Haibin Duan 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2017年第1期89-97,共9页
In this paper, a robust attitude control system based on fractional order sliding mode control and dynamic inversion approach is presented for the reusable launch vehicle RLV during the reentry phase. By introducing t... In this paper, a robust attitude control system based on fractional order sliding mode control and dynamic inversion approach is presented for the reusable launch vehicle RLV during the reentry phase. By introducing the fractional order sliding surface to replace the integer order one, we design robust outer loop controller to compensate the error introduced by inner loop controller designed by dynamic inversion approach. To take the uncertainties of aerodynamic parameters into account, stochastic robustness design approach based on the Monte Carlo simulation and Pigeon-inspired optimization is established to increase the robustness of the controller. Some simulation results are given out which indicate the reliability and effectiveness of the attitude control system. © 2014 Chinese Association of Automation. 展开更多
关键词 Attitude control Calculations Communication satellites Control systems Intelligent systems Launch vehicles LAUNCHING Monte Carlo methods Nonlinear control systems reusability Reusable rockets Robustness (control systems) Sliding mode control Stochastic systems Vehicles
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Ferrous methanesulfonate as an efficient and recyclable catalyst for chemoselective synthesis of 1,1-diacetate from aldehydes 被引量:5
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作者 Min Wang Gui Fu Tian +1 位作者 Zhi Guo Song Heng Jiang 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第9期1034-1038,共5页
Ferrous methanesulfonate catalysing the conversion of aromatic, heteroaromatic, unsaturated, and aliphatic aldehydes to 1,1- diacetates at room temperature under solvent-free condition has been developed. The catalyti... Ferrous methanesulfonate catalysing the conversion of aromatic, heteroaromatic, unsaturated, and aliphatic aldehydes to 1,1- diacetates at room temperature under solvent-free condition has been developed. The catalytic activity of seventeen metal methanesulfonates was compared under the same condition, ferrous methanesufonate proved to be the best. It can be easily recovered and reused for several times without distinct deterioration in catalytic activity. During the competitive protection between a ketone and an aldehyde group with Ac20, 1,1-diacetate formed exclusively with the aldehyde group. 2009 Min Wang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved. 展开更多
关键词 1 1-DIACETATE ALDEHYDE CHEMOSELECTIVITY reusability
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An efficient synthesis of ampicillin on magnetically separable immobilized penicillin G acylase 被引量:6
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作者 Ping Xue Xiao Dan Song Xue Rong Cao 《Chinese Chemical Letters》 SCIE CAS CSCD 2010年第7期765-768,共4页
Penicillin G acylase(PGA) was immobilized on the magnetic hydrophilic polymer microspheres with average pore size of 17.1 nm,specific surface area of 128.2 m2/g and saturate magnetization of 6.4 emu/g.The 96.7%ampicil... Penicillin G acylase(PGA) was immobilized on the magnetic hydrophilic polymer microspheres with average pore size of 17.1 nm,specific surface area of 128.2 m2/g and saturate magnetization of 6.4 emu/g.The 96.7%ampicillin yield with 1.60 of the synthesis/hydrolysis(S/H) ratio from 6-aminopenicillanic acid(6-APA) and D-(-)-alpha-phenylglycine methyl ester(D-PGME) can be achieved using the resultant magnetic biocatalyst in ethylene glycol,where only 82.1%yield with 1.40 of the S/H ratio was obtained using the free PGA under the identical reaction conditions.The immobilized PGA can be separated magnetically and recycled for five times without obvious loss of its catalytic activity. 展开更多
关键词 Immobilized penicillin G acylase Magnetic polymer microspheres Ampicillin synthesis reusability
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A new approach to the synthesis of diacetals(diketals) pentaerythritol catalyzed by SO_3H-functionalized ionic liquids 被引量:4
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作者 Yuan Yuan Wang,Yan Nan Xu,Zhi Zhong Wang,Li Yi Dai Shanghai Key Laboratory of Green Chemistry and Chemical Process,Department of Chemistry, East China Normal University,Shanghai 200062,China 《Chinese Chemical Letters》 SCIE CAS CSCD 2010年第5期524-528,共5页
In this article,an efficient,simple and environmentally friendly approach to the synthesis of diacetals(diketals) pentaerythritol using SOH-functionalized ionic liquids(ILs) as catalysts was reported.The ILs show high... In this article,an efficient,simple and environmentally friendly approach to the synthesis of diacetals(diketals) pentaerythritol using SOH-functionalized ionic liquids(ILs) as catalysts was reported.The ILs show high catalytic activity and reusability with good to excellent yields of the desired products.Hammett method has been used to determine the acidity order of these ionic liquids and the results are consistent with the catalytic activities observed in acetalization reaction.Maximum product yield of 93%was observed on using[PSPy][OTf]as catalyst and it can be reused at least 8 times without obvious activity loss. 展开更多
关键词 SO3H-functionalized ionic liquids Diacetals(diketals) pentaerythritol CATALYZE Hammett method reusability
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Tailoring polymeric composite gel beads-encapsulated microorganism for efficient degradation of phenolic compounds 被引量:2
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作者 Xueping Liu Ping Xue +3 位作者 Feng Jia Dongya Qiu Keren Shi Weiwei Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第4期301-306,共6页
Phenol and its derivatives are highly toxic pollutants in industrial wastewater for the ecological environments,so there is essential attention to develop effective means of removing these harmful substances from wate... Phenol and its derivatives are highly toxic pollutants in industrial wastewater for the ecological environments,so there is essential attention to develop effective means of removing these harmful substances from water.In this work,the microorganism was immobilized into polymeric composite gel beads prepared by the effective recombination of natural abundant chitosan(CS)and industrial polyvinyl alcohol(PVA)for treating phenolic compounds.The degradation rate of 99.5%can be achieved to treat 100 mg·L^(1)of phenol at 30℃using the fresh resultant immobilized microorganism,where only 21.1%degradation rate was obtained by the free microorganism under the identical conditions.The recycling experiments of repeated 90 times to treat 100 mg·L^(1)of phenol displayed that the degradation rate of phenol was stable to 99%with the appearance of beads unchanged significantly,indicating the immobilized microorganism possessed excellent operating stability.Moreover,while the phenol derivatives of 100 mg·L^(1)were treated catalytically including pmethylphenol,catechol,and oaminophenol for 24 h by the immobilized microorganism,the degradation rates were all above 95%.The immobilized microorganism into PVACS polymeric composite with excellent operating stability and degradation activity would provide a feasible solution for treating phenolic compounds in water in industrial applications. 展开更多
关键词 Polymeric composite Immobilization BIOCATALYSIS Phenolic compounds Degradation reusability
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Synthesis of magnetically modified palygorskite composite for immobilization of Candida sp. 99–125 lipase via adsorption 被引量:6
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作者 Ya Li Jicheng Hu Pingfang Han 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第5期822-826,共5页
Magnetically modified palygorskite composites were synthesized with γ-Fe2O3 dispersing on the external surface of clay mineral. The magnetic clay was characterized with Fourier transform infrared, X-ray diffrac- tion... Magnetically modified palygorskite composites were synthesized with γ-Fe2O3 dispersing on the external surface of clay mineral. The magnetic clay was characterized with Fourier transform infrared, X-ray diffrac- tion, transmission electron microscopy, and vibrating sample magnetometer. Candida sp. 99-125 lipase was immobilized on magnetic palygorskite composites by physical adsorption with enzyme loading of 41.5 mg· g^-1 support and enzyme activity of 2631.6 U· (g support)^-1. The immobilized lipase exhibit better thermal and broader pH stability and excellent reusabilitV compared with free lipase. 展开更多
关键词 Magnetically modified palygorskite Immobilized lipase Adsorption Stability reusability
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Sustainable electrochemical cross‐dehydrogenative coupling of4‐quinolones and diorganyl diselenides 被引量:1
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作者 Jin‐Yang Chen Hong‐Yu Wu +5 位作者 Qing‐Wen Gui Shan‐Shu Yan Jie Deng Ying‐Wu Lin Zhong Cao Wei‐Min He 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第9期1445-1450,共6页
An environmentally friendly method for the synthesis of 3‐organylselenyl quinolones through theelectrochemical cross‐dehydrogenative coupling of 4‐quinolones and diorganyl diselenides wasdeveloped.As a green,atom e... An environmentally friendly method for the synthesis of 3‐organylselenyl quinolones through theelectrochemical cross‐dehydrogenative coupling of 4‐quinolones and diorganyl diselenides wasdeveloped.As a green,atom economic and self‐separating process,the present reaction requiresneither external oxidants nor electrolytes,forming a recyclable catalytic system. 展开更多
关键词 Green chemistry Cross‐dehydrogenative coupling Atom ecomnomy reusability ELECTROCHEMISTRY
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