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SENSITIVITY AND SEPARABILITY OF DEFORMATION MODELS WITH REGARD TO PRIOR INFORMATION 被引量:1
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作者 Zhu, Jianjun 《中国有色金属学会会刊:英文版》 EI CSCD 1997年第4期157-160,共4页
SENSITIVITYANDSEPARABILITYOFDEFORMATIONMODELSWITHREGARDTOPRIORINFORMATION①ZhuJianjunColegeofResource,Environ... SENSITIVITYANDSEPARABILITYOFDEFORMATIONMODELSWITHREGARDTOPRIORINFORMATION①ZhuJianjunColegeofResource,EnvironmentandCivilEngin... 展开更多
关键词 sensitivity separability prior INFORMATION BAYESIAN HYPOTHESIS test
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On a biseparability criterion of bipartite qudit state
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作者 B Benzimoun M Daoud 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第8期42-49,共8页
In this paper,we propose a new approach to tackle the separability problem for bipartite qudit mixed-states.This is based on the Majorana representation which allows to represent a N-spinors(qudit)as a symmetric state... In this paper,we propose a new approach to tackle the separability problem for bipartite qudit mixed-states.This is based on the Majorana representation which allows to represent a N-spinors(qudit)as a symmetric state of N spin-1/2.We also discuss how we can exploit such representation and the notion of the biseparability of multipartite qubit states in the sense to establish new criteria of the separability problem based on the PPT and concurrence. 展开更多
关键词 separability BIPARTITE QUBIT STATE partial separability MAJORANA representation
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The separability of two-mode Gaussian state under amplification and symmetric damping
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作者 陈小余 蒋丽珍 邬良能 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第8期2237-2243,共7页
The performances of a two-mode Gaussian state under paxametric amplification, symmetric amplitude damping and thermal noise axe studied. The time-dependent complex correlation matrix of the state in evolution is given... The performances of a two-mode Gaussian state under paxametric amplification, symmetric amplitude damping and thermal noise axe studied. The time-dependent complex correlation matrix of the state in evolution is given. The sepaxability of the final two-mode Gaussian state is examined under symmetric amplification and asymmetric amplification separately. 展开更多
关键词 parametric amplifier amplitude damping characteristic function separability
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APPLICATION OF SEPARABILITY ORITERION IN DESIGN OF DEFORMATION MONITORING NETWORKS
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作者 CHEN Yongqi TANG Hongwai 《Geo-Spatial Information Science》 1998年第1期70-73,共4页
A monitoring scheme must be so designed that several possible mod-els can be efficiently separated in the stage of analysis of deformation measure-ments.Based on the concept of separability developed by Chen and Chrza... A monitoring scheme must be so designed that several possible mod-els can be efficiently separated in the stage of analysis of deformation measure-ments.Based on the concept of separability developed by Chen and Chrzanowski,a methodology for the design of monitoring schemes has been developed by the au-thors.In the method a computer simulation technique is employed,into whichsome rules have been elaborated allowing minimal human intervention.In this pa-per the criterion is first presented and the design technique using the step one up-dating procedure is discussed.Finally,design of a simulated monitoring networkis made as a demonstrating example. 展开更多
关键词 OPTIMAL DESIGN DEFORMATION MONITORING NETWORK separability
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Separability criteria based on Heisenberg–Weyl representation of density matrices
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作者 常景美 崔美钰 +1 位作者 张廷桂 费少明 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第3期132-136,共5页
Separability is an important problem in theory of quantum entanglement. By using the Bloch representation of quantum states in terms of the Heisenberg-Weyl observable basis, we present a new separability criterion for... Separability is an important problem in theory of quantum entanglement. By using the Bloch representation of quantum states in terms of the Heisenberg-Weyl observable basis, we present a new separability criterion for bipartite quantum systems. It is shown that this criterion can be better than the previous ones in detecting entanglement. The results are generalized to multipartite quantum states. 展开更多
关键词 Heisenberg-Weyl observable basis Bloch representation separability criterion multipartite quan- tuna states
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A sufficient and necessary criterion for separability of bipartite quantum states
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作者 赵慧 于欣玉 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第8期252-255,共4页
A sufficient and necessary criterion for separability of bipartite quantum states is presented. We construct a class of mixed states in 2 k quantum systems and in 3 k quantum systems, respectively and show that thes... A sufficient and necessary criterion for separability of bipartite quantum states is presented. We construct a class of mixed states in 2 k quantum systems and in 3 k quantum systems, respectively and show that these states are separable if and only if they are positive partial transpositions. 展开更多
关键词 positive partial transposition separability
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One Parameter Family of N-Qudit Werner-Popescu States: Bipartite Separability Using Conditional Quantum Relative Tsallis Entropy
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作者 Anantha S. Nayak Sudha   +1 位作者 A. R. Usha Devi A. K. Rajagopal 《Journal of Quantum Information Science》 2018年第1期12-23,共12页
The conditional version of sandwiched Tsallis relative entropy (CSTRE) is employed to study the bipartite separability of one parameter family of N-qudit Werner-Popescu states in their 1:N-1 partition. For all N, the ... The conditional version of sandwiched Tsallis relative entropy (CSTRE) is employed to study the bipartite separability of one parameter family of N-qudit Werner-Popescu states in their 1:N-1 partition. For all N, the strongest limitation on bipartite separability is realized in the limit and is found to match exactly with the separability range obtained using an algebraic method which is both necessary and sufficient. The theoretical superiority of using CSTRE criterion to find the bipartite separability range over the one using Abe-Rajagopal (AR) q-conditional entropy is illustrated by comparing the convergence of the parameter x with respect to q, in the implicit plots of AR q-conditional entropy and CSTRE. 展开更多
关键词 Entropic separability Criterion q-Conditional ENTROPIES Non-Commuting Version of RELATIVE Entropy
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Necessary and Sufficient Conditions for the Separability and the R-Separability of the Irrotational Stokes Equation and Applications
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作者 Eleftherios Protopapas Maria Hadjinicolaou 《Journal of Applied Mathematics and Physics》 2020年第11期2379-2401,共23页
In the present manuscript, we formulate and prove rigorously, necessary and sufficient conditions for all kinds of separation of variables that a solution of the irrotational Stokes equation may exhibit, in any orthog... In the present manuscript, we formulate and prove rigorously, necessary and sufficient conditions for all kinds of separation of variables that a solution of the irrotational Stokes equation may exhibit, in any orthogonal axisymmetric system, namely: simple separation and R-separation. These conditions may serve as a road map for obtaining the corresponding solution space of the irrotational Stokes equation, in any orthogonal axisymmetric coordinate system. Additionally, we investigate how the inversion of the coordinate system, with respect to a sphere, affects the type of separation. Specifically, we prove that if the irrotational Stokes equation separates variables in an axisymmetric coordinate system, then it R-separates variables in the corresponding inverted coordinate system. This is a quite useful outcome since it allows the derivation of solutions for a problem, from the knowledge of the solution of the same problem in the inverted geometry and vice-versa. Furthermore, as an illustration, we derive the eigenfunctions of the irrotational Stokes equation governing the flow past oblate spheroid particles and inverted oblate spheroidal particles. 展开更多
关键词 Axisymmetric Flow Stokes Operator Analytical Solution Separation and R-Separation of Variables Axisymmetric Orthogonal Coordinate Systems
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Separability criteria based on a class of symmetric measurements
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作者 Lemin Lai Shunlong Luo 《Communications in Theoretical Physics》 SCIE CAS CSCD 2023年第6期51-58,共8页
Highly symmetric quantum measurements,such as mutually unbiased measurements(MUMs)and general symmetric informationally complete positive-operator-valued measures(GSICPOVMs),play an important role in both foundational... Highly symmetric quantum measurements,such as mutually unbiased measurements(MUMs)and general symmetric informationally complete positive-operator-valued measures(GSICPOVMs),play an important role in both foundational and practical aspects of quantum information theory.Recently,a broad class of symmetric measurements were introduced[K Siudzińska,(2022)Phys.Rev.A 105,042209],which can be viewed as a common generalization of MUMs and GSIC-POVMs.In this work,the role of these symmetric measurements in entanglement detection is studied.More specifically,based on the correlation matrices defined via(informationally complete)symmetric measurements,a separability criterion for arbitrary dimensional bipartite systems is proposed.It is shown that the criterion is stronger than the method provided by Siudzińska,meanwhile,it can unify several popular separability criteria based on MUMs or GSIC-POVMs.Furthermore,using these(informationally complete)symmetric measurements,two efficient criteria are presented to detect the entanglement of tripartite quantum states.The detection power and advantages of these criteria are illustrated through several examples. 展开更多
关键词 entanglement detection separability criterion symmetric measurement correlation matrix
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The pathogenic mechanism of TAR DNA-binding protein 43(TDP-43)in amyotrophic lateral sclerosis 被引量:1
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作者 Xinxin Wang Yushu Hu Renshi Xu 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第4期800-806,共7页
The onset of amyotrophic lateral sclerosis is usually characterized by focal death of both upper and/or lower motor neurons occurring in the motor cortex,basal ganglia,brainstem,and spinal cord,and commonly involves t... The onset of amyotrophic lateral sclerosis is usually characterized by focal death of both upper and/or lower motor neurons occurring in the motor cortex,basal ganglia,brainstem,and spinal cord,and commonly involves the muscles of the upper and/or lower extremities,and the muscles of the bulbar and/or respiratory regions.However,as the disease progresses,it affects the adjacent body regions,leading to generalized muscle weakness,occasionally along with memory,cognitive,behavioral,and language impairments;respiratory dysfunction occurs at the final stage of the disease.The disease has a complicated pathophysiology and currently,only riluzole,edaravone,and phenylbutyrate/taurursodiol are licensed to treat amyotrophic lateral sclerosis in many industrialized countries.The TAR DNA-binding protein 43 inclusions are observed in 97%of those diagnosed with amyotrophic lateral sclerosis.This review provides a preliminary overview of the potential effects of TAR DNAbinding protein 43 in the pathogenesis of amyotrophic lateral sclerosis,including the abnormalities in nucleoplasmic transport,RNA function,post-translational modification,liquid-liquid phase separation,stress granules,mitochondrial dysfunction,oxidative stress,axonal transport,protein quality control system,and non-cellular autonomous functions(e.g.,glial cell functions and prion-like propagation). 展开更多
关键词 amyotrophic lateral sclerosis axonal transport liquid-liquid phase separation noncellular autonomous functions oxidative stress PATHOGENESIS post-translational modification protein quality control system stress granules TAR DNA-binding protein 43(TDP-43)
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Review on current development of polybenzimidazole membrane for lithium battery
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作者 Yonggui Deng Arshad Hussain +3 位作者 Waseem Raza Xingke Cai Dongqing Liu Jun Shen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期579-608,共30页
With the rapid development of portable technology,lithium batteries have emerged as potential candidates for high-performance energy storage systems owing to their high energy density and cycling stability.Among the k... With the rapid development of portable technology,lithium batteries have emerged as potential candidates for high-performance energy storage systems owing to their high energy density and cycling stability.Among the key components of a lithium battery system,the separator plays a critical role as it directly influences the battery performance benchmark(cycling performance and safety).However,traditional polyolefin separators(polypropylene/polyethylene)are unable to meet the demands of highperformance and safer battery systems due to their poor electrolyte compatibility,thermal runaways,and ultimate growth of dendrites.In contrast,membranes fabricated using polybenzimidazole(PBI)exhibit excellent electrolyte wettability and outstanding thermal dimensional stability,thus holding great potential as separators for high-performance and high-safety batteries.In this paper,we present a comprehensive review of the general requirements for separators,synthesis technology for separators,and research trends focusing PBI membranes in lithium batteries to alleviate the current commercial challenges faced by conventional polyolefin separators.In addition,we discuss the future development direction for PBI battery separators by considering various factors such as production cost,ecological footprint,preparation technology,and battery component compatibility.By exploring these perspectives,we aim to promote the continued application and exploration of PBI-based materials to advance lithium battery technology. 展开更多
关键词 Lithium batteries SEPARATORS Porous separators Polybenzimidazole Membrane
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The flow behavior of droplet adsorption on a liquid-liquid interface accompanied by cross-linking reaction and phase separation in a microchannel
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作者 Haozhe Yi Taotao Fu +1 位作者 Chunying Zhu Youguang Ma 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期60-70,共11页
The adsorption process of droplets on the liquid-liquid interface and phase separation process can regulate the spatial distribution of the fluid system,which are crucial for chemical engineering.However,the cross-lin... The adsorption process of droplets on the liquid-liquid interface and phase separation process can regulate the spatial distribution of the fluid system,which are crucial for chemical engineering.However,the cross-linking reaction,which is widely used in the field of polymers,can change the physical properties of the fluids and affect the flow behavior accordingly.A configuration of microchannels is designed to conveniently generate uniform droplets in one phase of the parallel flow.The flow behavior of the adsorption process of sodium alginate droplets on the liquid-liquid interface is investigated,and the subsequent process of phase separation is studied.In the process of droplet adsorption,the crosslinking reaction occurs synchronously,which makes the droplet viscosity and the elasticity modules of the droplet surface increase,thus affecting the dynamics of the adsorption process and the equilibrium shape of the droplet.The variation of the adsorption length with time is divided into three stages,which all conform to power law relationship.The exponents of the second and third stages deviate from the results of the Tanner's law.The flow pattern maps of droplet adsorption and phase separation are drawn,and the operating ranges of complete adsorption and complete separation are provided.This study provides a theoretical basis for further studying the flow behavior of droplets with cross-linking reaction in a microchannel. 展开更多
关键词 MICROFLUIDICS DROPLET Dynamics CROSSLINK ADSORPTION Separation
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Flotation separation of scheelite from calcite using luteolin as a novel depressant
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作者 Xiaokang Li Ying Zhang +3 位作者 Haiyang He Yu Wu Danyu Wu Zhenhao Guan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期462-472,共11页
This paper proposes luteolin(LUT)as a novel depressant for the flotation-based separation of scheelite and calcite in a sodium oleate(NaOL)system.The suitability of LUT as a calcite depressant is confirmed through mic... This paper proposes luteolin(LUT)as a novel depressant for the flotation-based separation of scheelite and calcite in a sodium oleate(NaOL)system.The suitability of LUT as a calcite depressant is confirmed through micro-flotation testing.At pH=9,with LUT concentration of 50 mg·L^(-1) and NaOL concentration of 50 mg·L^(-1),scheelite recovery reaches 80.3%.Calcite,on the other hand,exhibits a recovery rate of 17.6%,indicating a significant difference in floatability between the two minerals.Subsequently,the surface modifica-tions of scheelite and calcite following LUT treatment are characterized using adsorption capacity testing,Zeta potential analysis,Fourier transform infrared spectroscopy(FT-IR),X-ray photoelectron spectroscopy(XPS),and atomic force microscopy(AFM).The study in-vestigates the selective depressant mechanism of LUT on calcite.Adsorption capacity testing and Zeta potential analysis demonstrate sub-stantial absorption of LUT on the surface of calcite,impeding the further adsorption of sodium oleate,while its impact on scheelite is min-imal.FT-IR and XPS analyses reveal the selective adsorption of LUT onto the surface of calcite,forming strong chemisorption bonds between the hydroxyl group and calcium ions present.AFM directly illustrates the distinct adsorption densities of LUT on the two miner-al types.Consequently,LUT can effectively serve as a depressant for calcite,enabling the successful separation of scheelite and calcite. 展开更多
关键词 SCHEELITE CALCITE LUTEOLIN FLOTATION depressant SEPARATION
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Novel uses of ensiled biomasses as feedstocks for green biorefineries
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作者 Marketta Rinne 《Journal of Animal Science and Biotechnology》 SCIE CAS CSCD 2024年第3期945-955,共11页
Perennial forage plants are efficient utilizers of solar radiation and nutrients so that there is a lot of scope to increase the production of green biomass in many areas.Currently,grasses are mainly used as feeds for... Perennial forage plants are efficient utilizers of solar radiation and nutrients so that there is a lot of scope to increase the production of green biomass in many areas.Currently,grasses are mainly used as feeds for ruminants and equines,but there could be higher added value use for several components of the green biomass.Interest in green biorefin-ing has risen recently motivated by the increased sustainability pressures and need to break the reliance on fossil fuels.Novel products derived from grass,such as paper and packaging,nanofibers,animal bedding,novel protein feeds,extracted proteins,biochemicals,nutraceuticals,bioactive compounds,biogas and biochar could create new sustainable business opportunities in rural areas.Most green biorefinery concepts focus on using fresh green biomass as the feedstock,but preservation of it by ensiling would provide several benefits such as all-year-around avail-ability of the feedstock and increased stability of the press juice and press cake.The major difference between fresh and ensiled grass is the conversion of water soluble carbohydrates into fermentation end products,mainly lactic and acetic acids,that lower the pH of the silage so that it becomes stable in anaerobic conditions.This has some important consequences on the processability and quality of products,which are partly positive and partly negative,e.g.,degradation of protein into peptides,amino acids and ammonia.These aspects are discussed in this review. 展开更多
关键词 ADDITIVE FERMENTATION Liquid-solid separation Protein SILAGE
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Environmental,economic and exergy analysis of separation of ternary azeotrope by variable pressure extractive distillation based on multi-objective optimization
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作者 Peizhe Cui Jiafu Xing +5 位作者 Chen Li Mengjin Zhou Jifu Zhang Yasen Dai Limei Zhong Yinglong Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期145-157,共13页
In this work,the ternary azeotrope of tert-butyl alcohol/ethyl acetate/water is separated by extractive distillation(ED)to recover the available constituents and protect the environment.Based on the conductor like shi... In this work,the ternary azeotrope of tert-butyl alcohol/ethyl acetate/water is separated by extractive distillation(ED)to recover the available constituents and protect the environment.Based on the conductor like shielding model and relative volatility method,ethylene glycol was selected as the extractant in the separation process.In addition,in view of the characteristic that the relative volatility between components changes with pressure,the multi-objective optimization method based on nondominated sorting genetic algorithm II optimizes the pressure and the amount of solvent cooperatively to avoid falling into the optimal local solution.Based on the optimal process parameters,the proposed heat-integrated process can reduce the gas emissions by 29.30%.The heat-integrated ED,further coupled with the pervaporation process,can reduce gas emission by 42.36%and has the highest exergy efficiency of 47.56%.In addition,based on the heat-integrated process,the proposed two heat pump assisted heat-integrated ED processes show good economic and environmental performance.The double heat pump assisted heat-integrated ED can reduce the total annual cost by 28.78%and the gas emissions by 55.83%compared with the basis process,which has a good application prospect.This work provides a feasible approach for the separation of ternary azeotropes. 展开更多
关键词 Extractive distillation Optimization MIXTURES SEPARATION
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Metal-organic frameworks and their composites for advanced lithium-ion batteries:Synthesis,progress and prospects
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作者 Chengcai Liu Borong Wu +7 位作者 Tao Liu Yuanxing Zhang Jingwen Cui Lingjun Huang Guoqiang Tan Ling Zhang Yuefeng Su Feng Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期449-470,I0011,共23页
Metal-organic frameworks(MOFs)are among the most promising materials for lithium-ion batteries(LIBs)owing to their high surface area,periodic porosity,adjustable pore size,and controllable chemical composition.For ins... Metal-organic frameworks(MOFs)are among the most promising materials for lithium-ion batteries(LIBs)owing to their high surface area,periodic porosity,adjustable pore size,and controllable chemical composition.For instance,their unique porous structures promote electrolyte penetration,ions transport,and make them ideal for battery separators.Regulating the chemical composition of MOF can introduce more active sites for electrochemical reactions.Therefore,MOFs and their related composites have been extensively and thoroughly explored for LIBs.However,the reported reviews solely include the applications of MOFs in the electrode materials of LIBs and rarely involve other aspects.A systematic review of the application of MOFs in LIBs is essential for understanding the mechanism of MOFs and better designing related MOFs battery materials.This review systematically evaluates the latest developments in pristine MOFs and MOF composites for LIB applications,including MOFs as the main materials(anode,cathode,separators,and electrolytes)to auxiliary materials(coating layers and additives for electrodes).Furthermore,the synthesis,modification methods,challenges,and prospects for the application of MOFs in LIBs are discussed. 展开更多
关键词 Metal-organic frameworks ELECTRODES Electrolytes SEPARATORS Lithium-ion batteries
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Role of tannin pretreatment in flotation separation of magnesite and dolomite
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作者 Xiufeng Gong Jin Yao +5 位作者 Jun Guo Bin Yang Haoran Sun Wanzhong Yin Yulian Wang Yafeng Fu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期452-461,共10页
Flotation separation of magnesite and its calcium-containing carbonate minerals is a difficult problem.Recently,new regulat-ors have been proposed for magnesite flotation decalcification,although traditional regulator... Flotation separation of magnesite and its calcium-containing carbonate minerals is a difficult problem.Recently,new regulat-ors have been proposed for magnesite flotation decalcification,although traditional regulators such as tannin,water glass,sodium carbon-ate,and sodium hexametaphosphate are more widely used in industry.However,they are rarely used as the main regulators in research because they perform poorly in magnesite and dolomite single-mineral flotation tests.Inspired by the limonite presedimentation method and the addition of a regulator to magnesite slurry mixing,we used a tannin pretreatment method for separating magnesite and dolomite.Microflotation experiments confirmed that the tannin pretreatment method selectively and largely reduces the flotation recovery rate of dolomite without affecting the flotation recovery rate of magnesite.Moreover,the contact angles of the tannin-pretreated magnesite and dolomite increased and decreased,respectively,in the presence of NaOl.Zeta potential and Fourier transform infrared analyses showed that the tannin pretreatment method efficiently hinders NaOl adsorption on the dolomite surface but does not affect NaOl adsorption on the magnesite surface.X-ray photoelectron spectroscopy and density functional theory calculations confirmed that tannin interacts more strongly with dolomite than with magnesite. 展开更多
关键词 tannin pretreatment selective inhibition flotation separation MAGNESITE DOLOMITE
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Boosting kinetic separation of ethylene and ethane on microporous materials via crystal size control
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作者 Yixuan Ma Cong Yu +5 位作者 Lifeng Yang Rimin You Yawen Bo Qihan Gong Huabin Xing Xili Cui 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期85-91,共7页
The adsorptive separation of C_(2)H_(4)and C_(2)H_(6),as an alternative to distillation units consuming high energy,is a promising yet challenging research.The great similarity in the molecular size of C_(2)H_(4)and C... The adsorptive separation of C_(2)H_(4)and C_(2)H_(6),as an alternative to distillation units consuming high energy,is a promising yet challenging research.The great similarity in the molecular size of C_(2)H_(4)and C_(2)H_(6)brings challenges to the regulation of adsorbents to realize efficient dynamic separation.Herein,we reported the enhancement of the kinetic separation of C_(2)H_(4)/C_(2)H_(6)by controlling the crystal size of ZnAtzPO_(4)(Atz=3-amino-1,2,4-triazole)to amplify the diffusion difference of C_(2)H_(4)and C_(2)H_(6).Through adjusting the synthesis temperature,reactant concentration,and ligands/metal ions molar ratio,ZnAtzPO4 crystals with different sizes were obtained.Both single-component kinetic adsorption tests and binary-component dynamic breakthrough experiments confirmed the enhancement of the dynamic separation of C_(2)H_(4)/C_(2)H_(6)with the increase in the crystal size of ZnAtzPO_(4).The separation selectivity of C_(2)H_(4)/C_(2)H_(6)increased from 1.3 to 98.5 with the increase in the crystal size of ZnAtzPO_(4).This work demonstrated the role of morphology and size control of adsorbent crystals in the improvement of the C_(2)H_(4)/C_(2)H_(6)kinetic separation performance. 展开更多
关键词 ADSORPTION ADSORBENT ETHYLENE Binary mixture Crystal size control Kinetic separation
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Ferric ion-triggered surface oxidation of galena for efficient chalcopyrite-galena separation
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作者 Qiancheng Zhang Limin Zhang +3 位作者 Feng Jiang Honghu Tang Li Wang Wei Sun 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第2期261-267,共7页
The efficient separation of chalcopyrite(CuFeS2)and galena(PbS)is essential for optimal resource utilization.However,find-ing a selective depressant that is environmentally friendly and cost effective remains a challe... The efficient separation of chalcopyrite(CuFeS2)and galena(PbS)is essential for optimal resource utilization.However,find-ing a selective depressant that is environmentally friendly and cost effective remains a challenge.Through various techniques,such as mi-croflotation tests,Fourier transform infrared spectroscopy,scanning electron microscopy(SEM)observation,X-ray photoelectron spec-troscopy(XPS),and Raman spectroscopy measurements,this study explored the use of ferric ions(Fe^(3+))as a selective depressant for ga-lena.The results of flotation tests revealed the impressive selective inhibition capabilities of Fe^(3+)when used alone.Surface analysis showed that Fe^(3+)significantly reduced the adsorption of isopropyl ethyl thionocarbamate(IPETC)on the galena surface while having a minimal impact on chalcopyrite.Further analysis using SEM,XPS,and Raman spectra revealed that Fe^(3+)can oxidize lead sulfide to form compact lead sulfate nanoparticles on the galena surface,effectively depressing IPETC adsorption and increasing surface hydrophilicity.These findings provide a promising solution for the efficient and environmentally responsible separation of chalcopyrite and galena. 展开更多
关键词 GALENA CHALCOPYRITE ferric ions flotation separation surface oxidation
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Energy-saving design and optimization of pressure-swing-assisted ternary heterogenous azeotropic distillations
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作者 Lianjie Wu Kun Lu +3 位作者 Qirui Li Lianghua Xu Yiqing Luo Xigang Yuan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期1-7,共7页
A huge amount of energy is always consumed to separate the ternary azeotropic mixtures by distillations.The heterogeneous azeotropic distillation and the pressure-swing distillation are two kinds of effective technolo... A huge amount of energy is always consumed to separate the ternary azeotropic mixtures by distillations.The heterogeneous azeotropic distillation and the pressure-swing distillation are two kinds of effective technologies to separate heterogeneous azeotropes without entrainer addition.To give better play to the synergistic energy-saving effect of these two processes,a novel pressure-swing-assisted ternary heterogeneous azeotropic distillation(THAD)process is proposed firstly.In this process,the ternary heterogeneous azeotrope is decanted into two liquid phases before being refluxed into the azeotropic distillation column to avoid the aqueous phase remixing,and three columns'pressures are modified to decrease the flowrates of the recycle streams.Then the dividing wall column and heat integration technologies are introduced to further reduce its energy consumption,and the pressureswing-assisted ternary heterogeneous azeotropic dividing-wall column and its heat integration structure are achieved.A genetic algorithm procedure is used to optimize the proposed processes.The design results show that the proposed processes have higher energy efficiencies and lower CO_(2)emissions than the published THAD process. 展开更多
关键词 DISTILLATION SEPARATION Process control Process systems
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