Microstructure of Solid Phase Reduction on Manganese Oxide Ore Fines Containing Coal by Microwave Heating

Microstructure of solid phase reduction on manganese oxide ore fines containing coal （MOOFCC） is one of important kinetics conditions of influencing microwave heating. On condition thai an atomic molar ratio of ro ： rc in MOOFCC is 1 ： 1.06 as well as a molecular molar ratio of rSiO2： rCaO is 1 ： 1.28, 1 kg of MOOFCC is heated by microwave to reach 1 000-1 300℃ and hold different time respectively. Experiments show that the metal phase takes the iron-based metal compounds containing manganese as the main content. The manganese content of metal phase increases with the xise of temperature. The particle size of the metal phase is within the range from 0. 01 to 0.05 mm. MO2 phase in the stuff is entirely changed into MnO phase and the slag phase is mainly composed of wollastonite and manganese olivine. The stuff reduced is loose and massive as a whole and its porosity is from 30% to 45%. The low softening-melting property and the low density of the stuff impact, to some degree, the solid phase reduction of powder by microwave heating.

Synthesis of Subnanometer-Sized Gold Clusters by a Simple Milling- Mediated Solid Reduction Method

An effective solvent-free method based on a solid-reduction process was developed to fabricate ultrafine gold catalysts. By this method we revealed a strong size-dependent activity of Au species in which subnanometer-sized clusters exhibited the best activity in the hydrogenation of CO_2 to formate, with a turnover number of up to 9278 over 7 h at 90 ℃.

Cr(Ⅵ) reduction capability of humic acid extracted from the organic component of municipal solid waste

The capacity of humic acid extracted from organic waste （HAw） to reduce Cr（Ⅵ） was tested at pH 2.5,4 and 6 and compared with coal-derived humic acid （HAc）.HAw was more effective than HAc in reducing Cr（Ⅵ）.The kinetics of Cr（Ⅵ） reductions depended strongly on pH.The calculation of the apparent rate coefficients indicated that HAw was more efficient at reducing Cr（Ⅵ） than HAc,but was also more efficient than HAs from soil and peat.The reduction capability of HAs depends on the type of functional groups （i.e.,thiols and phenols） present,rather than the free radicals.HAw was more efficient at reducing Cr（Ⅵ） than HAc because more reactive phenols were present,i.e.,methoxy-and methyl-phenols.

Quantification of emission reduction potentials of primary air pollutants from residential solid fuel combustion by adopting cleaner fuels in China

Residential low efficient fuel burning is a major source of many air pollutants produced during incomplete combustions, and household air pollution has been identified as one of the top environmental risk factors. Here we compiled literature-reported emission factors of pollutants including carbon monoxide（CO）, total suspended particles（TSPs）, PM2.5, organic carbon（OC）,elemental carbon（EC） and polycyclic aromatic hydrocarbons（PAHs） for different household energy sources, and quantified the potential for emission reduction by clean fuel adoption. The burning of crop straws, firewood and coal chunks in residential stoves had high emissions per unit fuel mass but lower thermal efficiencies, resulting in high levels of pollution emissions per unit of useful energy, whereas pelletized biofuels and coal briquettes had lower pollutant emissions and higher thermal efficiencies. Briquetting coal may lead to 82%–88% CO, 74%–99%TSP, 73%–76% PM2.5, 64%–98% OC, 92%–99% EC and 80%–83% PAH reductions compared to raw chunk coal. Biomass pelletizing technology would achieve 88%–97% CO, 73%–87% TSP, 79%–88%PM2.5, 94%–96% OC, 91%–99% EC and 63%–96% PAH reduction compared to biomass burning. The adoption of gas fuels（i.e., liquid petroleum gas, natural gas） would achieve significant pollutant reduction, nearly 96% for targeted pollutants. The reduction is related not only to fuel change, but also to the usage of high efficiency stoves.

Investigation on the application of reformed coke oven gas in direct reduction iron production with a mathematical model

To investigate the application of reformed coke oven gas （COG） in producing the direct reduction iron （DRI）, we simulated a countercurrent gas solid moving bed reactor in which the iron ore pellet was reduced by reformed COG. An ordinary differential equation （ODE） was set based on the unreacted shrinking core model considering both mass and energy balances of the reactor. The concentration and temperature profiles of all species within the reactor were obtained by solving the ODE sys tem. The solid conversion and gas utilization were studied by changing gas flow rate, solid flow rate, reactor length, and the ratio of O/CHa to guide the practical application of COG in DRI production. Model results showed that COG was suitable for the DRI production. In order to meet the requirement of the industrial production, the minimum gas flow rate was set as 130,000 Nm3/h, and the maximum production was 90 t/h. The reactor length and the mole ratio x（O）： x（CH4） were depended on the actual industrial situations.

Thermochemical pretreatment of meat and bone meal and its effect on methane production

Since the solubilization of meat and bone meal(MBM)is a prerequisite in many MBM disposal approaches,enhancement of the solubilization by means of thermochemical pretreatment was investigated in this study at two temperatures(55℃and 131℃)and six sodium hydroxide(NaOH)concentrations(0,1.25,2.5,5,10 and 20 g/L).The MBM volatile solid(VS)reduction ratio was up to 66%and 70%at 55℃and 131℃,respectively.At the same temperature,the VS reduction ratio increased with the increase in the dosage of NaOH.The study on the methane(CH4)production potential of pretreated MBM shows that the addition of NaOH at 55℃did not cause the inhibition of the succeeding CH4 production process.However,CH4 production was inhibited by the addition of NaOH at 131℃.The CH4 production potential was in the range of 389 to 503 mL CH4/g VS MBM and 464 to 555 mL CH4/g VS MBM at 55℃and 131℃,respectively.