期刊文献+
共找到118,124篇文章
< 1 2 250 >
每页显示 20 50 100
Improved spatio-temporal alignment measurement method for hull deformation
1
作者 XU Dongsheng YU Yuanjin +1 位作者 ZHANG Xiaoli PENG Xiafu 《Journal of Systems Engineering and Electronics》 SCIE CSCD 2024年第2期485-494,共10页
In this paper,an improved spatio-temporal alignment measurement method is presented to address the inertial matching measurement of hull deformation under the coexistence of time delay and large misalignment angle.Lar... In this paper,an improved spatio-temporal alignment measurement method is presented to address the inertial matching measurement of hull deformation under the coexistence of time delay and large misalignment angle.Large misalignment angle and time delay often occur simultaneously and bring great challenges to the accurate measurement of hull deformation in space and time.The proposed method utilizes coarse alignment with large misalignment angle and time delay estimation of inertial measurement unit modeling to establish a brand-new spatiotemporal aligned hull deformation measurement model.In addition,two-step loop control is designed to ensure the accurate description of dynamic deformation angle and static deformation angle by the time-space alignment method of hull deformation.The experiments illustrate that the proposed method can effectively measure the hull deformation angle when time delay and large misalignment angle coexist. 展开更多
关键词 inertial measurement spatio-temporal alignment hull deformation
下载PDF
An Intelligent Framework for Resilience Recovery of FANETs with Spatio-Temporal Aggregation and Multi-Head Attention Mechanism
2
作者 Zhijun Guo Yun Sun +2 位作者 YingWang Chaoqi Fu Jilong Zhong 《Computers, Materials & Continua》 SCIE EI 2024年第5期2375-2398,共24页
Due to the time-varying topology and possible disturbances in a conflict environment,it is still challenging to maintain the mission performance of flying Ad hoc networks(FANET),which limits the application of Unmanne... Due to the time-varying topology and possible disturbances in a conflict environment,it is still challenging to maintain the mission performance of flying Ad hoc networks(FANET),which limits the application of Unmanned Aerial Vehicle(UAV)swarms in harsh environments.This paper proposes an intelligent framework to quickly recover the cooperative coveragemission by aggregating the historical spatio-temporal network with the attention mechanism.The mission resilience metric is introduced in conjunction with connectivity and coverage status information to simplify the optimization model.A spatio-temporal node pooling method is proposed to ensure all node location features can be updated after destruction by capturing the temporal network structure.Combined with the corresponding Laplacian matrix as the hyperparameter,a recovery algorithm based on the multi-head attention graph network is designed to achieve rapid recovery.Simulation results showed that the proposed framework can facilitate rapid recovery of the connectivity and coverage more effectively compared to the existing studies.The results demonstrate that the average connectivity and coverage results is improved by 17.92%and 16.96%,respectively compared with the state-of-the-art model.Furthermore,by the ablation study,the contributions of each different improvement are compared.The proposed model can be used to support resilient network design for real-time mission execution. 展开更多
关键词 RESILIENCE cooperative mission FANET spatio-temporal node pooling multi-head attention graph network
下载PDF
Approaches to Improving Selectivity During Photoelectrochemical Transformation of Small Molecules
3
作者 Sipeng Yang Jie Yang +3 位作者 Mengyu Duan Shirong Kang Shaohua He Chuncheng Chen 《Transactions of Tianjin University》 EI CAS 2024年第2期167-177,共11页
Photoelectrochemical (PEC) small-molecule oxidation can selectively transform substrates into high-value-added fine chemicals and increase the rate of cathode hydrogen evolution. Nevertheless, achieving high-selectivi... Photoelectrochemical (PEC) small-molecule oxidation can selectively transform substrates into high-value-added fine chemicals and increase the rate of cathode hydrogen evolution. Nevertheless, achieving high-selectivity PEC oxidation of small molecules to produce specific products is a very challenging task. In general, selectivity can be improved by changing the surface catalyticsites of the photoanode and modulating the interfacial environments of the reactions. Herein, recent advances in approaches to improving selective PEC oxidation of small molecules are introduced. We first briefly discuss the basic concept and fundamentals of small-molecule PEC oxidation. The reported approaches to improving the performance of selective PEC oxidation of small molecules are highlighted from two aspects: (1) changing the surface properties of photoanodes by selecting suitable materials or modifying the photoanodes and (2) mediating the oxidation reactions using redox mediators. The PEC oxidation mechanism of these studies is emphasized. We also discuss the challenges in this research direction and offer a perspective on the further development of selective PEC-based small-molecule transformation. 展开更多
关键词 PHOTOELECTROCATALYTIC Small-molecule oxidation Improving selectivity Surface properties Mediating
下载PDF
An mmWave Dual-Band Integrated Substrate Gap Waveguide Single Cavity Filter with Frequency Selectivity
4
作者 Qiuhua Lin Dongya Shen +1 位作者 Lihui Wang Zhiyong Luo 《China Communications》 SCIE CSCD 2024年第1期188-199,共12页
A novel dual-band ISGW cavity filter with enhanced frequency selectivity is proposed in this paper by utilizing a multi-mode coupling topology.Its cavity is designed to control the number of modes,and then the ports a... A novel dual-band ISGW cavity filter with enhanced frequency selectivity is proposed in this paper by utilizing a multi-mode coupling topology.Its cavity is designed to control the number of modes,and then the ports are determined by analyzing the coupling relationship between these selected modes.By synthesizing the coupling matrix of the filter,a nonresonating node(NRN)structure is introduced to flexibly tune the frequency of modes,which gets a dualband and quad-band filtering response from a tri-band filter no the NRN.Furthermore,a frequency selective surface(FSS)has been newly designed as the upper surface of the cavity,which significantly improves the bad out-of-band suppression and frequency selectivity that often exists in most traditional cavity filter designs and measurements.The results show that its two center frequencies are f01=27.50 GHz and f02=32.92GHz,respectively.Compared with the dual-band filter that there is no the FSS metasurface,the out-of-band suppression level is improved from measured 5 dB to18 dB,and its finite transmission zero(FTZ)numbers is increased from measured 1 to 4 between the two designed bands.Compared with the tri-band and quadband filter,its passband bandwidth is expanded from measured 1.17%,1.14%,and 1.13% or 1.31%,1.50%,0.56%,and 0.57% to 1.71% and 1.87%.In addition,the filter has compact,small,and lightweight characteristics. 展开更多
关键词 coupling topology frequency selectivity non-resonating node(NRN) out-of-band suppression single ISGW cavity filter
下载PDF
High adsorption selectivity of activated carbon and carbon molecular sieve boosting CO_(2)/N_(2) and CH_(4)/N_(2) separation
5
作者 Siang Chen Wenling Wu +4 位作者 Zhaoyang Niu Deqi Kong Wenbin Li Zhongli Tang Donghui Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期282-297,共16页
Flue gas and coal bed methane are two important sources of greenhouse gases.Pressure swing adsorption process has a wide range of application in the field of gas separation,and the selection of adsorbent is crucial.In... Flue gas and coal bed methane are two important sources of greenhouse gases.Pressure swing adsorption process has a wide range of application in the field of gas separation,and the selection of adsorbent is crucial.In this regard,in order to assess the better adsorbent for separating CO_(2) from flue gas and CH_(4) from coal bed methane,adsorption isotherms of CO_(2),CH_(4) and N_(2) on activated carbon and carbon molecular sieve are measured at 303.15,318.15 and 333.15 K,and up to 250 kPa.The experimental data fit better with Langmuir 2 compared to Langmuir 3 and Langmuir-Freundlich models,and Clausius-Clapeyron equation was used to calculate the isosteric heat.Both the order of the adsorbed amount and the adsorption heat on the two adsorbents are CO_(2)>CH_(4)>N_(2).The adsorption kinetics are calculated by the pseudo-first kinetic model,and the order of adsorption rates on activated carbon is N_(2)-CH_(4)>CO_(2),while on carbon molecular sieve,it is CO_(2)-N_(2)>CH_(4).It is shown that relative molecular mass and adsorption heat are the primary effect on kinetics for activated carbon,while kinetic diameter is the main resistance factor for carbon molecular sieve.Moreover,the adsorption selectivity of CH_(4)/N_(2) and CO_(2)/N_(2) were estimated with the ideal adsorption solution theory,and carbon molecular sieve performed best at 318.15 K for both CO_(2) and CH_(4) separation.The study suggested that activated carbon is a better choice for separating flue gas and carbon molecular sieve can be a strong candidate for separating coal bed methane. 展开更多
关键词 Activated carbon Carbon molecular sieve Adsorbent evaluation Adsorption equilibrium and kinetics Heat of adsorption selectivity
下载PDF
Spatio-Temporal Change of Dispersal Areas of Greater Kudu (Tragelaphus strepsiceros) in Lake Bogoria Landscape, Kenya
6
作者 Beatrice Chepkoech Cheserek George Morara Ogendi Paul Mutua Makenzi 《Open Journal of Ecology》 2024年第3期183-198,共16页
Decline in wildlife populations is manifest globally, regionally and locally. A wildlife decline of 68% has been reported in Kenya’s rangelands with Baringo County experiencing more than 85% wildlife loss in the last... Decline in wildlife populations is manifest globally, regionally and locally. A wildlife decline of 68% has been reported in Kenya’s rangelands with Baringo County experiencing more than 85% wildlife loss in the last four decades. Greater Kudu (Tragelaphus strepsiceros) is endemic to Lake Bogoria landscape in Baringo County and constitutes a major tourist attraction for the region necessitating use of its photo on the County’s logo and thus a flagship species. Tourism plays a central role in Baringo County’s economy and is a major source of potential growth and employment creation. The study was carried out to assess spatio-temporal change of dispersal areas of Greater Kudu (GK) in Lake Bogoria landscape in the last four years for enhanced adaptive management and improved livelihoods. GK population distribution primary data collected in December 2022 and secondary data acquired from Lake Bogoria National Game Reserve (LBNGR) for 2019 and 2020 were digitized using in a Geographic Information System (GIS). Measures of dispersion and point pattern analysis (PPA) were used to analyze dispersal of GK population using GIS. Spatio-temporal change of GK dispersal in LBNR was evident thus the null hypothesis was rejected. It is recommended that anthropogenic activities contributing to GK’s habitat degradation be curbed by providing alternative livelihood sources and promoting community adoption of sustainable technologies for improved livelihoods. 展开更多
关键词 spatio-temporal Change Dispersal Greater Kudu (Tragelaphus Strepsiceros) Point Pattern Analysis (PPA) GIS
下载PDF
Research on the Spatio-Temporal Evolution and Driving Forces of Green Spaces in the Central Urban Area of Zunyi City
7
作者 Juan Du 《Journal of Architectural Research and Development》 2024年第4期8-16,共9页
Green space,as a medium for carrying out urban functions and guiding urban development,is becoming a scarce resource along with the urbanization process and the intensification of environmental problems.In the face of... Green space,as a medium for carrying out urban functions and guiding urban development,is becoming a scarce resource along with the urbanization process and the intensification of environmental problems.In the face of the spatial mismatch between high demand and low supply,it is of great significance to clarify the evolution mechanism of green space to undertake national spatial planning,protect the natural strategic resources in the urban fringe area,and promote the sustainable development of the“three living spaces.”The study focuses on the Zunyi City Center,selecting the 20 years of rapid development following its establishment as a city as the study period.It explores the dynamic evolution of green space and the main driving forces during different periods using remote-sensing image data.The study shows that from 2003 to 2023,the total scale of green space has an obvious decreasing trend along with the expansion of the urban built-up area.A large amount of arable land is being converted to construction land,resulting in a sudden decrease in arable land area.In the past 10 years,the comprehensive land use dynamics have accelerated.Still,the spatial difference has gradually narrowed,indicating that the overall development intensity of Zunyi City’s central urban area has increased.There is a gradual spread of the trend to the hilly areas.The limiting effect of the mountainous natural environment on the city’s development has gradually diminished under the superposition of external factors,such as economic development,industrial technological upgrading,and policy orientation so the importance of the effective protection and rational utilization of urban green space has become more prominent. 展开更多
关键词 Green space spatio-temporal evolution Driving force Zunyi city center
下载PDF
基于SELECT理念腹腔镜下保留脾脏的胰体尾切除
8
作者 李爽 张标 +5 位作者 刘航宇 祁冰 Thomas Juby 张桂信 张庆凯 尚东 《临床外科杂志》 2024年第7期776-779,共4页
腹腔镜下胰体尾切除术目前已经成为治疗胰腺体尾部肿瘤的标准术式。而腹腔镜下保留脾脏的胰体尾切除术由于可保留脾脏功能,减少脾切除术后并发症,越来越受到重视。然而,胰腺肿瘤发病隐匿、解剖位置复杂,这些对其诊断和保留脾脏的胰体尾... 腹腔镜下胰体尾切除术目前已经成为治疗胰腺体尾部肿瘤的标准术式。而腹腔镜下保留脾脏的胰体尾切除术由于可保留脾脏功能,减少脾切除术后并发症,越来越受到重视。然而,胰腺肿瘤发病隐匿、解剖位置复杂,这些对其诊断和保留脾脏的胰体尾切除术带来了挑战。近年来,我们团队积累了丰富的胰腺肿瘤诊疗经验,创新提出“SELECT”(S-Single-Operator Cholangiopancreatoscopy,E-ERCP,L-Laparoscopy,E-Endoscopic ultrasound,C-Choledochoscopy/Confocal laser endomicroscopy,T-Traditional Chinese medicine)多镜组合中西医微创诊治理念。根据胰腺肿瘤的类型及特点,应用多种内镜和腹腔镜技术,多种不同微创诊疗方法的优选组合,围手术期采用中医药,进行中西医结合加速康复。将SELECT理念充分应用于腹腔镜下保留脾脏的胰体尾切除术,有利于术前精准诊断、术中精准切除、术后并发症预判和治疗,一站式诊治胰腺肿瘤,使病人利益最大化。 展开更多
关键词 select理念 多镜联合 胰腺肿瘤 保留脾脏 胰体尾切除术
下载PDF
Tuning the selectivity of natural oils and fatty acids/esters deoxygenation to biofuels and fatty alcohols:A review 被引量:2
9
作者 Yingdong Zhou Javier Remon +2 位作者 Zhicheng Jiang Avtar S.Matharu Changwei Hu 《Green Energy & Environment》 SCIE EI CAS CSCD 2023年第3期722-743,共22页
The chemical transformation of natural oils provides alternatives to limited fossil fuels and produces compounds with added value for the chemical industries.The selective deoxygenation of natural oils to diesel-range... The chemical transformation of natural oils provides alternatives to limited fossil fuels and produces compounds with added value for the chemical industries.The selective deoxygenation of natural oils to diesel-ranged hydrocarbons,bio-jet fuels,or fatty alcohols with controllable selectivity is especially attractive in natural oil feedstock biorefineries.This review presents recent progress in catalytic deoxygenation of natural oils or related model compounds(e.g.,fatty acids)to renewable liquid fuels(green diesel and bio-jet fuels)and valuable fatty alcohols(unsaturated and saturated fatty alcohols).Besides,it discusses and compares the existing and potential strategies to control the product selectivity over heterogeneous catalysts.Most research conducted and reviewed has only addressed the production of one category;therefore,a new integrative vision exploring how to direct the process toward fuel and/or chemicals is urgently needed.Thus,work conducted to date addressing the development of new catalysts and studying the influence of the reaction parameters(e.g.,temperature,time and hydrogen pressure)is summarized and critically discussed from a green and sustainable perspective using efficiency indicators(e.g.,yields,selectivity,turnover frequencies and catalysts lifetime).Special attention has been given to the chemical transformations occurring to identify key descriptors to tune the selectivity toward target products by manipulating the reaction conditions and the structures of the catalysts.Finally,the challenges and future research goals to develop novel and holistic natural oil biorefineries are proposed.As a result,this critical review provides the readership with appropriate information to selectively control the transformation of natural oils into either biofuels and/or value-added chemicals.This new flexible vision can help pave the wave to suit the present and future market needs. 展开更多
关键词 Natural oil DEOXYGENATION Controllable selectivity Biofuels Fatty alcohols
下载PDF
Leveraging Transfer Learning for Spatio-Temporal Human Activity Recognition from Video Sequences 被引量:1
10
作者 Umair Muneer Butt Hadiqa Aman Ullah +3 位作者 Sukumar Letchmunan Iqra Tariq Fadratul Hafinaz Hassan Tieng Wei Koh 《Computers, Materials & Continua》 SCIE EI 2023年第3期5017-5033,共17页
Human Activity Recognition(HAR)is an active research area due to its applications in pervasive computing,human-computer interaction,artificial intelligence,health care,and social sciences.Moreover,dynamic environments... Human Activity Recognition(HAR)is an active research area due to its applications in pervasive computing,human-computer interaction,artificial intelligence,health care,and social sciences.Moreover,dynamic environments and anthropometric differences between individuals make it harder to recognize actions.This study focused on human activity in video sequences acquired with an RGB camera because of its vast range of real-world applications.It uses two-stream ConvNet to extract spatial and temporal information and proposes a fine-tuned deep neural network.Moreover,the transfer learning paradigm is adopted to extract varied and fixed frames while reusing object identification information.Six state-of-the-art pre-trained models are exploited to find the best model for spatial feature extraction.For temporal sequence,this study uses dense optical flow following the two-stream ConvNet and Bidirectional Long Short TermMemory(BiLSTM)to capture longtermdependencies.Two state-of-the-art datasets,UCF101 and HMDB51,are used for evaluation purposes.In addition,seven state-of-the-art optimizers are used to fine-tune the proposed network parameters.Furthermore,this study utilizes an ensemble mechanism to aggregate spatial-temporal features using a four-stream Convolutional Neural Network(CNN),where two streams use RGB data.In contrast,the other uses optical flow images.Finally,the proposed ensemble approach using max hard voting outperforms state-ofthe-art methods with 96.30%and 90.07%accuracies on the UCF101 and HMDB51 datasets. 展开更多
关键词 Human activity recognition deep learning transfer learning neural network ensemble learning spatio-temporal
下载PDF
Relationship between spatio-temporal evolution of soil pH and geological environment/surface cover in the eastern Nenjiang River Basin of Northeast China during the past 30 years 被引量:2
11
作者 Guo-dong Liu Ming-hui Wei +3 位作者 Ze Yang Hong-ye Xiao Yi-he Zhang Na-na Fang 《China Geology》 CAS CSCD 2023年第3期369-382,共14页
To illuminate the spatio-temporal variation characteristics and geochemical driving mechanism of soil pH in the Nenjiang River Basin,the National Multi-objective Regional Geochemical Survey data of topsoil,the Second ... To illuminate the spatio-temporal variation characteristics and geochemical driving mechanism of soil pH in the Nenjiang River Basin,the National Multi-objective Regional Geochemical Survey data of topsoil,the Second National Soil Survey data and Normalized Difference Vegetation Index(NDVI)were analyzed.The areas of neutral and alkaline soil decreased by 21100 km^(2)and 30500 km^(2),respectively,while that of strongly alkaline,extremely alkaline,and strongly acidic soil increased by 19600 km^(2),18200 km^(2),and 15500 km^(2),respectively,during the past 30 years.NDVI decreased with the increase of soil pH when soil pH>8.0,and it was reversed when soil pH<5.0.There were significant differences in soil pH with various surface cover types,which showed an ascending order:Arbor<reed<maize<rice<high and medium-covered meadow<low-covered meadow<Puccinellia.The weathering products of minerals rich in K_(2)O,Na_(2)O,CaO,and MgO entered into the low plain and were enriched in different parts by water transportation and lake deposition,while Fe and Al remained in the low hilly areas,which was the geochemical driving mechanism.The results of this study will provide scientific basis for making scientific and rational decisions on soil acidification and salinization. 展开更多
关键词 Soil pH spatio-temporal variation Surface cover Soybean-maize-rice Woodland-grassland-wetland Saline-alkali land-sandy land Geological environment Land quality geochemical survey engineering Nenjiang River Basin
下载PDF
Switching CO_(2) Electroreduction Selectivity Between C_(1) and C_(2) Hydrocarbons on Cu Gas-Diffusion Electrodes 被引量:1
12
作者 Jianfang Zhang Zhengyuan Li +6 位作者 Rui Cai Tianyu Zhang Shize Yang Lu Ma Yan Wang Yucheng Wu Jingjie Wu 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第2期17-25,共9页
Regulating the selectivity toward a target hydrocarbon product is still the focus of CO_(2)electroreduction.Here,we discover that the original surface Cu species in Cu gas-diffusion electrodes plays a more important r... Regulating the selectivity toward a target hydrocarbon product is still the focus of CO_(2)electroreduction.Here,we discover that the original surface Cu species in Cu gas-diffusion electrodes plays a more important role than the surface roughness,local pH,and facet in governing the selectivity toward C_(1)or C_(2)hydrocarbons.The selectivity toward C_(2)H_(4) progressively increases,while CH_(4) decreases steadily upon lowering the Cu oxidation species fraction.At a relatively low electrodeposition voltage of 1.5 V,the Cu gas-diffusion electrode with the highest Cu^(δ+)/Cu^(0)ratio favors the pathways of∗CO hydrogenation to form CH_(4) with maximum Faradaic efficiency of 65.4%and partial current density of 228 mA cm^(−2)at−0.83 V vs RHE.At 2.0 V,the Cu gas-diffusion electrode with the lowest Cu^(δ+)/Cu^(0)ratio prefers C-C coupling to form C_(2)+products with Faradaic efficiency topping 80.1%at−0.75 V vs RHE,where the Faradaic efficiency of C_(2)H_(4) accounts for 46.4%and the partial current density of C_(2)H_(4) achieves 279 mA cm^(−2).This work demonstrates that the selectivity from CH_(4) to C_(2)H_(4) is switchable by tuning surface Cu species composition of Cu gas-diffusion electrodes. 展开更多
关键词 C_(2)H_(4) CH_(4) CO_(2)electroreduction ELECTRODEPOSITION switchable selectivity
下载PDF
Effect of samarium on the N_(2) selectivity of Sm_(x)Mn_(0.3-x)Ti catalysts during selective catalytic reduction of NO_(x) with NH_(3)
13
作者 Shengyang Zhang Bolin Zhang +2 位作者 Boyu Wu Bo Liu Shengen Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第4期642-652,共11页
This work aims to study the improvement effect of Sm on Mn-based catalysts for selective catalytic reduction (SCR) of NO with NH3.A series of Sm_(x)Mn_(0.3-x)-xTi catalysts (x=0,0.1,0.15,0.2,and 0.3) were prepared by ... This work aims to study the improvement effect of Sm on Mn-based catalysts for selective catalytic reduction (SCR) of NO with NH3.A series of Sm_(x)Mn_(0.3-x)-xTi catalysts (x=0,0.1,0.15,0.2,and 0.3) were prepared by co-precipitation.Activity tests indicated that the Sm_(0.15)Mn_(0.15)Ti catalyst showed superior performances,with a NO conversion of 100%and N_(2)selectivity above 87%at 180–300℃.The characterizations showed that Sm doping suppressed the crystallization of TiO_(2)and Mn2O3phases and increased the specific surface area and acidity.In particular,the surface area increased from 152.2 m^(2)·g^(-1)for Mn0.3Ti to 241.7 m^(2)·g^(-1)for Sm_(0.15)Mn_(0.15)Ti.These effects contributed to the high catalytic activity.The X-ray photoelectron spectroscopy (XPS) results indicated that the relative atomic ratios of Sm^(3+)/Sm and Oβ/O of Sm_(0.15)Mn_(0.15)Ti were 76.77at%and 44.11at%,respectively.The presence of Sm contributed to an increase in surface-absorbed oxygen (Oβ) and a decrease in Mn^(4+)surface concentration,which improved the catalytic activity.In the results of hydrogen temperature-programmed reduction(H_(2)-TPR),the presence of Sm induced a higher reduction temperature and lower H_(2)consumption (0.3 mmol·g^(-1)) for the Sm_(0.15)Mn_(0.15)Ti catalyst compared to the Mn0.3Ti catalyst.The decrease in Mn^(4+)weakened the redox property of the catalysts and increased the N_(2)selectivity by suppressing N_(2)O formation from NH3oxidation and the nonselective catalytic reduction reaction.The in situ diffuse reflectance infrared Fourier transform spectra (DRIFTs) revealed that NH3-SCR of NO over the Sm_(0.15)Mn_(0.15)Ti catalyst mainly followed the Eley–Rideal mechanism.Sm doping increased surface-absorbed oxygen and weakened the redox property to improve the NO conversion and N_(2)selectivity of the Sm_(0.15)Mn_(0.15)Ti catalyst. 展开更多
关键词 manganese oxides nitric oxide nitrous oxide SAMARIUM selective catalytic reduction nitrogen selectivity
下载PDF
Dealuminated Hβ zeolite for selective conversion of fructose to furfural and formic acid 被引量:1
14
作者 Rui Li Qixuan Lin +3 位作者 Junli Ren Xiaobao Yang Yingxiong Wang Lingzhao Kong 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第2期311-320,共10页
The fructose-to-furfural transformation is facing major challenges in the selectivity and high efficiency. Herein, we have developed a simple and effective approach for the selective conversion of fructose to furfural... The fructose-to-furfural transformation is facing major challenges in the selectivity and high efficiency. Herein, we have developed a simple and effective approach for the selective conversion of fructose to furfural using Hβ zeolite modified by organic acids for dealuminization to regulate its textural and acidic properties. It was found that citric acid-dealuminized Hβ zeolite possessed high specific surface areas, wide channels and high Brønsted acid amount, which facilitated the selective conversion of fructose to furfural with a maximum yield of 76.2% at433 K for 1 h in the γ-butyrolactone(GBL)-H_(2)O system, as well as the concomitant formation of 83.0% formic acid. The^(13)C-isotope labelling experiments and the mechanism revealed that the selective cleavage of C1–C2 or C5–C6 bond on fructose was firstly occurred to form pentose or C5 intermediate by weak Brønsted acid, which was then dehydrated to furfural by strong Brønsted acid. Also this dealuminized Hβ catalyst showed the great recycling performance and was active for the conversion of glucose and mannose. 展开更多
关键词 FRUCTOSE Dealuminated-Hb zeolite selective conversion FURFURAL
下载PDF
Grazing rate and feeding selectivity of small and large bodied cladocerans in waters from lakes with different salinity and phytoplankton structure
15
作者 Egor ZADEREEV Tatiana LOPATINA +1 位作者 Svyatoslav OVCHINNIKOV Alexander TOLOMEEV 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2023年第4期1341-1351,共11页
Cladocera are filter feeders abundant in freshwaters,which consume phytoplankton particles in wide size and taxonomic ranges.The ability of cladocerans to control phytoplankton abundance by grazing is determined by va... Cladocera are filter feeders abundant in freshwaters,which consume phytoplankton particles in wide size and taxonomic ranges.The ability of cladocerans to control phytoplankton abundance by grazing is determined by various factors including the characteristics of phytoplankton.Freshwater salinization may reduce the strength of top-down grazing control of phytoplankton because of the detrimental effects of salinity on the grazing intensity of zooplankters.We performed grazing experiments with two species of Cladocera of different body lengths to test their ability to graze on phytoplankton in natural waters differing in salinity and size and taxonomic composition of food particles.Grazing experiments demonstrated that the grazing rate was mostly controlled by the abundance of phytoplankton in the medium.The grazing rate was reduced at salinity ca.above 3 g/L of NaCl in the medium.The lower grazing rate was observed in the medium with larger phytoplankton particles.Both species predominantly consumed phytoplankton particles with a diameter of 6-12μm,which may shift the size distribution of phytoplankton towards a larger average diameter of particles.The taxon-specific feeding was also observed,as both species predominantly consumed diatom algae.Thus,we found that because of grazing,the size and taxonomic characteristics of phytoplankton are shifted towards a less edible community.The detrimental effect of elevated salinity on grazing rate supports growing concern about freshwater salinization negatively affecting water quality,particularly reducing top-down grazing control of phytoplankton. 展开更多
关键词 selective feeding DAPHNIA MOINA top-down control PHYTOPLANKTON SALINITY
下载PDF
A review on the extraction and separation of andrographolide from Andrographis paniculata:extraction selectivity,current challenges and strategies
16
作者 Di Liang Wei-Mei Zhang +4 位作者 Xu Liang Hong-Yue Tian Xue-Min Zhang Xia Li Wen-Yuan Gao 《Traditional Medicine Research》 2023年第7期11-23,共13页
Andrographolide is the main active ingredient of Andrographis paniculata(Burm.f.)Nees,known as“natural antibiotic”.Here,for the purpose of discovering a more efficient,low-cost extraction and separation method,the r... Andrographolide is the main active ingredient of Andrographis paniculata(Burm.f.)Nees,known as“natural antibiotic”.Here,for the purpose of discovering a more efficient,low-cost extraction and separation method,the research status of andrographolide was reviewed.At present,researches only take extraction rate as the only index to optimize extraction parameters,but ignores the importance of extraction selectivity.It is usually meaningless to blindly pursue the extraction rate without considering the difficulty and cost of subsequent separation.So,factors affecting extraction selectivity such as solvent choice,temperature and physicochemical effects caused by extraction technique itself,are first discussed.Different extraction techniques for andrographolide were discussed by comparing the selectivity,efficiency and cost of extraction.The separation procedures of andrographolide such as decolorization,impurity removal,crystallization,membrane separation,solid-phase extraction and partition chromatography and their challenges and possible strategies are also discussed.It is hoped that this review can provide guidance for researchers who are committed to advancing the field of andrographolide extraction and purification. 展开更多
关键词 ANDROGRAPHOLIDE extraction techniques extraction selectivity SEPARATION
下载PDF
Towards the selectivity distinction of phenol hydrogenation on noble metal catalysts
17
作者 Shanjun Mao Zhe Wang +7 位作者 Zhirong Chen Kejun Wu Kaichao Zhang Qichuan Li Huihuan Yan Guofeng Lü Guodong Huang Yong Wang 《Nano Materials Science》 EI CAS CSCD 2023年第1期91-100,共10页
Selective hydrogenation of phenol to cyclohexanone is intriguing in chemical industry.Though a few catalysts with promising performances have been developed in recent years,the basic principle for catalyst design is s... Selective hydrogenation of phenol to cyclohexanone is intriguing in chemical industry.Though a few catalysts with promising performances have been developed in recent years,the basic principle for catalyst design is still missing owing to the unclear catalytic mechanism.This work tries to unravel the mechanism of phenol hydro-genation and the reasons causing the selectivity discrepancy on noble metal catalysts under mild conditions.Results show that different reaction pathways always firstly converge to the formation of cyclohexanone under mild conditions.The selectivity discrepancy mainly depends on the activity for cyclohexanone sequential hy-drogenation,in which two factors are found to be responsible,i.e.the hydrogenation energy barrier and the competitive chemisorption between phenol and cyclohexanone,if the specific co-catalyzing effect of H 2 O on Ru is not considered.Based on the above results,a quantitative descriptor,E b(one/pl)/E a,in which E a can be further correlated to the d band center of the noble metal catalyst,is proposed by the first time to roughly evaluate and predict the selectivity to cyclohexanone for catalyst screening. 展开更多
关键词 PHENOL selective hydrogenation CYCLOHEXANONE DFT Noble metal catalysts
下载PDF
High Ion-Selectivity of Garnet Solid Electrolyte Enabling Separation of Metallic Lithium
18
作者 Haitian Zhang Jialiang Lang +8 位作者 Kai Liu Yang Jin Kuangyu Wang Yulong Wu Siqi Shi Li Wang Hong Xu Xiangming He Hui Wu 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第6期236-242,共7页
Ionic selectivity is of significant importance in both fundamental science and practical applications.For instance,an ion-selective material allows the passage of a particular kind of ions while blocking the others,wh... Ionic selectivity is of significant importance in both fundamental science and practical applications.For instance,an ion-selective material allows the passage of a particular kind of ions while blocking the others,which could be used for purification of materials.Herein,the Li-ion-selectivity of a garnet-type solid electrolyte is discussed by comparing the difference of activation energy between different ions migrating in solids.The high ion-selectivity is confirmed by harvesting high-purity metallic lithium(99.98 wt%)from low-lithium-purity sources(80 wt%)at a moderate temperature(190℃).This gives it huge potential in separating lithium with impurities especially alkali and alkali-earth elements.The cost of metallic lithium production is only 25%of the international lithium price.The proposed electrochemical metallic lithium separating method is advantageous compared with the traditional process in terms of efficiency,safety,and cost. 展开更多
关键词 ion separating ionic selectivity lithium metal solid electrolyte
下载PDF
Spatio-Temporal Analysis of Drought in the North-Eastern Coastal Region of Vietnam Using the Standardized Precipitation Index (SPI)
19
作者 Nguyen Van Tuan Nguyen Van Hieu +5 位作者 Nguyen Khac Bang Pham Hoang Hai Nguyen Khanh Van Le Vinh Ha Tran Thi Hoa Lê Trọng Hiếu 《Atmospheric and Climate Sciences》 CAS 2023年第2期175-200,共26页
Spatio-temporal analysis of drought provides valuable information for drought management and damage mitigation. In this study, the Standardized Precipitation Index at the time scale of 6 months (SPI-6) is selected to ... Spatio-temporal analysis of drought provides valuable information for drought management and damage mitigation. In this study, the Standardized Precipitation Index at the time scale of 6 months (SPI-6) is selected to reflect drought conditions in the North-Eastern coastal region of Vietnam. The drought events and their characteristics from 1981 to 2019 are detected at 9 meteorological stations and 10 Chirps rainfall stations. The spatio-temporal variation of drought in the study region is analyzed on the basis of the number, duration, severity, intensity, and peak of the detected drought events at the 19 stations. The results show that from 1981 to 2019 the drought events mainly occurred with 1-season duration and moderate intensity and peak. The number, duration, severity, and peak of the drought events were the greatest in the period 2001-2010 and were the smallest in the period 2011-2019. Among the 19 stations, the drought duration tends to decrease at 11 stations, increase at 7 stations, and has a slight variant at 1 station;the drought severity tends to decrease at 14 stations, increase at 4 stations, and has not a significant trend at 1 station;the drought intensity tends to decrease at 17 stations, increase at 1 station, and has a slight variant at 1 station;and the drought peak tends to decrease at 18 stations and increase at 1 station. 展开更多
关键词 spatio-temporal Analysis of Drought Standardized Precipitation Index (SPI) Drought Characteristics
下载PDF
Dynamic Spatio-Temporal Modeling in Disease Mapping
20
作者 Flavian Awere Otieno Cox Lwaka Tamba +1 位作者 Justin Obwoge Okenye Luke Akong’o Orawo 《Open Journal of Statistics》 2023年第6期893-916,共24页
Spatio-temporal models are valuable tools for disease mapping and understanding the geographical distribution of diseases and temporal dynamics. Spatio-temporal models have been proven empirically to be very complex a... Spatio-temporal models are valuable tools for disease mapping and understanding the geographical distribution of diseases and temporal dynamics. Spatio-temporal models have been proven empirically to be very complex and this complexity has led many to oversimply and model the spatial and temporal dependencies independently. Unlike common practice, this study formulated a new spatio-temporal model in a Bayesian hierarchical framework that accounts for spatial and temporal dependencies jointly. The spatial and temporal dependencies were dynamically modelled via the matern exponential covariance function. The temporal aspect was captured by the parameters of the exponential with a first-order autoregressive structure. Inferences about the parameters were obtained via Markov Chain Monte Carlo (MCMC) techniques and the spatio-temporal maps were obtained by mapping stable posterior means from the specific location and time from the best model that includes the significant risk factors. The model formulated was fitted to both simulation data and Kenya meningitis incidence data from 2013 to 2019 along with two covariates;Gross County Product (GCP) and average rainfall. The study found that both average rainfall and GCP had a significant positive association with meningitis occurrence. Also, regarding geographical distribution, the spatio-temporal maps showed that meningitis is not evenly distributed across the country as some counties reported a high number of cases compared with other counties. 展开更多
关键词 spatio-temporal Model Matern Exponential Covariance Function Spatial and Temporal Dependencies Markov Chain Monte Carlo (MCMC)
下载PDF
上一页 1 2 250 下一页 到第
使用帮助 返回顶部