To overcome the problems of natural decreases in power quality,and to eliminate wind speed fluctuation due to wind shear and tower shadow effect arising from wind turbine structural parameters,an improved prediction m...To overcome the problems of natural decreases in power quality,and to eliminate wind speed fluctuation due to wind shear and tower shadow effect arising from wind turbine structural parameters,an improved prediction model accounting for the dual effect of wind shear and tower shadow is,in this paper,built.Compared to the conventional prediction model,the proposed model contains a new constraint condition,which makes the disturbance term caused by the tower shadow effect always negative so that the prediction result is closer to the actual situation.Furthermore,wind turbine structural parameters such as hub height,rotor diameter,the diameter of the tower top,and rotor overhang on wind shear and tower shadow effect are also explored in detail.The results show that the wind shear effect became weaker with the increase in hub height.The hub height is independent of the tower shadow effect.The rotor diameter is positively correlated with the wind shear and tower shadow effect.The tower shadow effect is positively correlated with the diameter of the tower top and negatively correlated with the rotor overhang.展开更多
Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working co...Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working condition of an inert anode. To reduce its thermal stress, the effect of some parameters on the thermal stress distribution was investigated, including the anode height, the anode radius, the hole depth, the hole radius, and the radius of inner chamfer and outer chamfer. The results showed that in the actual working condition of an inert anode, there existed a large axial tensile stress near the tangent interface between the anode and bath, which was the major cause of anode breaking. Increasing the anode height and reducing the hole depth properly seemed to be beneficial for the stress distribution. With the increase of anode radius, the stress distribution became better first and then deteriorated, the reasonable value was between 0.045 to 0.06m. The hole radius had a significant effect on the stress and a smaller radius would reduce the thermal stress. The effect of the radius of the inner chamfer and the outer chamfer was less than other parameters.展开更多
The geometry of an inductively coupled plasma (ICP) etcher is usually considered to be an important factor for determining both plasma and process uniformity over a large wafer. During the past few decades, these pa...The geometry of an inductively coupled plasma (ICP) etcher is usually considered to be an important factor for determining both plasma and process uniformity over a large wafer. During the past few decades, these parameters were determined by the "trial and error" method, resulting in wastes of time and funds. In this paper, a new approach of regression orthogonal design with plasma simulation experiments is proposed to investigate the sensitivity of the structural parameters on the uniformity of plasma characteristics. The tool for simulating plasma is CFD-ACE+, which is commercial multi-physical modeling software that has been proven to be accurate for plasma simulation. The simulated experimental results are analyzed to get a regression equation on three structural parameters. Through this equation, engineers can compute the uniformity of the electron number density rapidly without modeling by CFD-ACE+. An optimization performed at the end produces good results.展开更多
Some approaches to measure parallel 6-degree of freedom platform's posturestatically and to calibrate the platform's actual structural parameters by measuring a series of theplatform's varying postures are...Some approaches to measure parallel 6-degree of freedom platform's posturestatically and to calibrate the platform's actual structural parameters by measuring a series of theplatform's varying postures are studied. In the case where high posture accuracy is requiredrelatively, to obtain the platform's actual structural parameters is very important. Threedimensions measurement with 2 theodolites are used to obtain the platform's postures statically andNewton iterative method is adopted to calibrate structural parameters. Some measures taken in themeasurement and the calibration are discussed in detail. And the experiment results of theplatform's posture control before and after the calibration are given. The results show that theplatform's posture control accuracy after the calibration is improved notably.展开更多
The atomic structural parameter P-i = (Z(i)*/n(i)*) (1 + n(i)*/n(i)) (1 + m(i)/Z) and the molecular structural parameter [GRAPHICS] are defined. The standard formation enthalpies (Delta(f)H(m)(phi)) of 74 species of r...The atomic structural parameter P-i = (Z(i)*/n(i)*) (1 + n(i)*/n(i)) (1 + m(i)/Z) and the molecular structural parameter [GRAPHICS] are defined. The standard formation enthalpies (Delta(f)H(m)(phi)) of 74 species of rare earth compounds were studied with P, and the correlation coefficient is R > 0.94. The structural factors and the properties of rare earth compounds are influenced by the Z(i)*, n(i)*, n(i), m(i), Z. This study has special referential value to predict the properties of rare earth compounds.展开更多
Elemental analysis, Fourier transform infrared (FTIR), 1H-NMR, fluorescence spectroscopy, and surface tension methods have been used to characterize the molecular structure and the aggregation behaviors of two aspha...Elemental analysis, Fourier transform infrared (FTIR), 1H-NMR, fluorescence spectroscopy, and surface tension methods have been used to characterize the molecular structure and the aggregation behaviors of two asphaltenic fractions derived, respectively, from an Alge- rian petroleum well and a corresponding storage tank deposit. Elemental analysis, FTIR, ~H-NMR, and fluores- cence spectroscopy were used to investigate the chemical composition and structural parameters of asphaltenes, while the surface tension method was used to measure the critical micelle concentration (CMC) in organic solvents with different solubility parameters and polarities in order to characterize the asphaltenes' aggregation behaviors. Results show that the unstable asphaltenes fraction extracted from the storage tank deposit possesses a higher polarity (higher heteroatoms content) and a lower aro- maticity than stable asphaltenes from the petroleum well. The CMC results indicate that asphaltenes with high polarity and low aromaticity have a high solubility in polar solvents such as nitrobenzene, whereas asphaltenes with low polarity and high aromaticity are more soluble in solvents with weak polarity, like toluene. It is concludedthat the difference of structure of asphaltene samples and polarity of solvents can lead to difference of aggregation behaviors.展开更多
Superconductive properties for oxides were predicted by artificial neural network (ANN) method with structural and chemical parameters as inputs. The predicted properties include superconductivity for oxides, distribu...Superconductive properties for oxides were predicted by artificial neural network (ANN) method with structural and chemical parameters as inputs. The predicted properties include superconductivity for oxides, distributed ranges of the superconductive transition temperature (Tc) for complex oxides, and Tc values for cuprate superconductors. The calculated results indicated that the adjusted ANN can be used to predict superconductive properties for unknown oxides.展开更多
In this paper, the design optimization of the structural parameters of multilayer conductors in high temperature superconducting (HTS) cable is reviewed. Various optimization methods, such as the particle swarm opti...In this paper, the design optimization of the structural parameters of multilayer conductors in high temperature superconducting (HTS) cable is reviewed. Various optimization methods, such as the particle swarm optimization (PSO), the genetic algorithm (GA), and a robust optimization method based on design for six sigma (DFSS), have been applied to realize uniform current distribution among the multilayer HTS conductors. The continuous and discrete variables, such as the winding angle, radius, and winding direction of each layer, are chosen as the design parameters. Under the constraints of the mechanical properties and critical current, PSO is proven to be a more powerful tool than GA for structural parameter optimization, and DFSS can not only achieve a uniform current distribution, but also improve significantly the reliability and robustness of the HTS cable quality.展开更多
The phase diagrams of microemulsion CTAB/butanol/cyclohexane/aqueous solution of nitrate (or aqueous solution of ammonium salt) were determined and the structural parameters and ΔG*o→i were obtained by means of dilu...The phase diagrams of microemulsion CTAB/butanol/cyclohexane/aqueous solution of nitrate (or aqueous solution of ammonium salt) were determined and the structural parameters and ΔG*o→i were obtained by means of dilution method and theoretical calculation. The effect of different w/s and salt concentration on the stability and structural parameters of microemulsion were investigated. The result shows that with the increase of w/s, the area of microemulsion and Nd decrease, Rw, l and n increase; with the increase of salt concentration, the area of microemulsion, l and Nd decrease, ΔG*o→I, Rw and n increase. Theoretical basis of preparing size-controlled long afterglow luminescence materials and study of the relationship between fluorescence properties and particle size are provided.展开更多
For accurate aeroelastic analysis,the unsteady rotor flowfield is solved by computational fluid dynamics(CFD)module based on RANS/Euler equations and moving-embedded grid system,while computational structural dynamics...For accurate aeroelastic analysis,the unsteady rotor flowfield is solved by computational fluid dynamics(CFD)module based on RANS/Euler equations and moving-embedded grid system,while computational structural dynamics(CSD)module is introduced to handle blade flexibility.In CFD module,dual time-stepping algorithm is employed in temporal discretization,Jameson two-order central difference(JST)scheme is adopted in spatial discretization and B-L turbulent model is used to illustrate the viscous effect.The CSD module is developed based on Hamilton′s variational principles and moderate deflection beam theory.Grid deformation is implemented using algebraic method through coordinate transformations to achieve deflections with high quality and efficiency.A CFD/CSD loose coupling strategy is developed to transfer information between rotor flowfield and blade structure.The CFD and the CSD modules are verified seperately.Then the CFD/CSD loose coupling is adopted in airloads prediction of UH-60A rotor under high speed forward flight condition.The calculated results agree well with test data.Finally,effects of torsional stiffness properties on airloads of rotors with different tip swept angles(from 10° forward to 30° backward)are investigated.The results are evaluated through pressure distribution and airloads variation,and some meaningful conclusions are drawn the moderated shock wave strength and pressure gradient caused by varied tip swept angle and structural properties.展开更多
Two body centered tetragonal (bet) crystal structures of α'-Fe_(16)N_2 with x=0.25, z=0.3125 (Jack-1) and x=0.222, z=0.306 (Jack-2) respectively, were analyzed theoretically with EMS software package. The simulat...Two body centered tetragonal (bet) crystal structures of α'-Fe_(16)N_2 with x=0.25, z=0.3125 (Jack-1) and x=0.222, z=0.306 (Jack-2) respectively, were analyzed theoretically with EMS software package. The simulation of diffraction patterns indicates that both diffraction patterns of the same axis in these two structures obey bcc extinction rule. The conclusion is also obtained from the analyses of the diffracted waves. α'-Fe_(16)N_2 precipitates in the diffusion layer of ion-nitrided α-iron have been studied with transmission electron microscope (TEM). We have distinctly observed the electron diffraction patterns of α'-Fe_(16)N_2 in [100], [111], [110], [011], [210], [021], [311], [113], [331] and [133] zone axes with perfect symmetry, which indicate the parallel orientation relationship with α matrix:<001>α'//<001>α'// {100}.α'// {100}tα. The analyses of diffraction patterns, which obey bcc extinction rule, verify the bct structure of α'-Fe_(16)N_2 discovered by X-ray diffraction.展开更多
Based on the characteristics of atom types, Hall's electrotopological state indices (En) are calculated for 165 nonionic organic compounds. On the basis of the characteristics of substituent and conjugated matrix, ...Based on the characteristics of atom types, Hall's electrotopological state indices (En) are calculated for 165 nonionic organic compounds. On the basis of the characteristics of substituent and conjugated matrix, a novel molecular structure parameter (G) is defined and calculated for 165 molecules in this paper. En and G show good structural selectivity for organic molecules. G, a satisfactory relationship between bioconcentration factor (BCF) and En, is expressed as: 1gBCF = -0.283 + 1.246G + 0.079E42 + 0.351E9- 0.063E17 (n' = 122, R = 0.967, F = 425.636, s = 0.394), which could provide estimation and prediction for the lgBCF of nonionic organic chemicals. Furthermore, the model is examined to validate overall robustness with Jackknife tests, and the independent variables in model do not exist cross correlation with VIF. All these regression results show that the new parameter G and electrotopological state index have good rationality and efficiency. It is concluded that the En and G will be used widely in quantitative structure-property/activity relationship (QSPR/QSAR) research.展开更多
The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this ...The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this paper,the influence of structural parameters of the turbocharger floating bearing on its dynamic characteristic coefficientsis systematically investigated based on the theories of hydrodynamic lubrication and tribology.The influence of clearance ratio on eccentricity and the influence of internal to external radius ratios,and Sommerfeld number were analyzed.A new formula of responding characteristics of the oil film force caused by the displacement or velocity disturbance was deduced near an equilibrium in the steady state.Applying the newly developed formula,the dynamic characteristic was studied for floating bearings.Regularity for change of oil film stiffness and damping was analyzed with the structural parameters of floating bearing such as radius ratios and eccentricity.It has been found that the clearance ratio increases with eccentricity when the radius ratio is unchanged.The eccentricity decreases with the internal to external radius ratio of floating rings when the clearance ratio is constant.The absolute value of total principal stiffness and total main damping decrease with the clearance ratio and radius ratio of floating rings when the total cross damping is stable.The results and findings in this paper can contribute to nonlinear dynamics designs of turbocharger rotor-bearing systems.展开更多
In order to improve the performance of vehicle radiators, a two-dimensional heat transfer steady-state model of the radiator was set up. The influence of the structural parameters (axial ratio) of the heat exchange tu...In order to improve the performance of vehicle radiators, a two-dimensional heat transfer steady-state model of the radiator was set up. The influence of the structural parameters (axial ratio) of the heat exchange tube on the windward side on the heat transfer performance of the radiator was studied. With the increase of the axial ratio of the heat exchange tube on the windward side, the heat exchange capacity of the heat exchange tube surface slightly decreases. The heat exchange area increases significantly, which increases the total heat exchange of the radiator and improves the heat transfer performance of the radiator. When the axial ratio increases from 1.0 to 2.0, the average surface heat transfer capacity decreases from 5664.16</span><span style="font-family:""> </span><span style="font-family:Verdana;">W/m<sup>2</sup> to 5623.57</span><span style="font-family:""> </span><span style="font-family:Verdana;">W/m<sup>2</sup>.展开更多
For combined sensible-latent heat storage system(CSLHS)(termed as the hybrid configuration),macro encapsulation can effectively solve the leakage problem of PCMs.However,due to the poor thermal conductivity of PCMs,th...For combined sensible-latent heat storage system(CSLHS)(termed as the hybrid configuration),macro encapsulation can effectively solve the leakage problem of PCMs.However,due to the poor thermal conductivity of PCMs,the charging performance of the hybrid configuration slightly increases compared to the solid structure(with only sensible materials).Meanwhile,the natural convection in the PCMs zone could improve the charging performance.So,how to improve natural convection intensity is a key issue for the CSLHS by macro encapsulating.It is found that adding fins can significantly enhance natural convection and accelerate the melting of PCM.In this paper,we proposed the hybrid configuration with fins built-in by macro encapsulation,and analyzed its charging performance with different fin structural parameters in the PCM zone by CFD simulation.In the case,the sensible heat storage material is high-temperature concrete and the PCM is a low-melting-point mixed molten salt.We analyzed the effects of fin number,fin length and fin thickness on the charging performance of the hybrid configuration respectively.From the result,the charging performance increases with the fin number,but the increase rate gradually decreases.When the fin number is 6,the charging performance increases by 20.18%compared to the situation without fin.The charging performance increases gradually with the fin length.Compared with the hybrid configuration without fin,for each 10 mm increase in fin length,its charging performances increase by 4.09%,5.26%,7.02%,8.77%,11.70%,and 15.79%,respectively.Different from number and length of fins,the effect of thickness on the charging performance is very small.When the fin thickness increased from 1 mm to 4 mm,the charging performance only increased by 2.3%.It indicates that the main reason for the improving the charging performance is to increase the natural convection intensity by dividing the PCM zone through fins.These results show that the charging performance of the CSLHS with macro encapsulation can be improved by optimizing fin structural parameters.展开更多
The effects of double shielded TIG (tungsten inert gas) torch's structural parameters, including the flow rate ratio between the inner and outer layers of gas and the extended length of the electrode (abbreviated ...The effects of double shielded TIG (tungsten inert gas) torch's structural parameters, including the flow rate ratio between the inner and outer layers of gas and the extended length of the electrode (abbreviated as ELE in this work), on the fusion zone profile have been investigated for OCrl3NiSMo martensitic stainless steel. Results show that the double shielded TIG process yields relatively high penetration of the weld pool in a broad range of the structural parameters. ELE over 3 mm is too large and causes adverse reactions on the protection of electrode. The outer gas with relatively high flow rate or the outer layer with high oxygen content is conducive to the oxygen dissolved into the arc, which results in the oxidation of the weld pool surface and the electrode tip. The double shielded TIG welded metal was tested and presented good impact property.展开更多
The effect of structural parameters of TiO2 nanotube arrays (TNAs) upon their photocatalytic/photoelectro- catalytic performance is studied by comparing the morphological characteristics and physicochemical properti...The effect of structural parameters of TiO2 nanotube arrays (TNAs) upon their photocatalytic/photoelectro- catalytic performance is studied by comparing the morphological characteristics and physicochemical properties with different tube lengths prepared from three kinds of electrolytes. The results show that the UV-Vis absorption edge of TNAs red-shifted with the increment of tube length and the short TNAs possess higher bandgap energy. The variation tendency of electrochemical window of TNAs is DMSO (5.5 V)〉Cit (3.2 V)〉HF (1.8 V). The long TNAs possess higher photocatalytic (PC) reactivity suggesting the surface roughness factor is the main determinant of PC efficiency, although, there is obvious recombination effects for the long TNAs. Evidenced by the positive correlation between tube length and photoelectrocatalytic (PEC) efficiency for TNAs from the same electrolyte, the enhancement of the tube length could lead to better PEC reactivity, but when the tube length is over a certain value, the PEC degradation rate no longer increases but decreases. The long TNAs with large surface roughness factor prepared from Cit and DMSO electrolytes exhibit comparative or even lower PEC performance compared with the short TNAs prepared from HF electrolyte, indicating that the PEC performance of TNAs was dominated by charge separation and photoelectron transfer properties rather than surface roughness coefficient and the tube length.展开更多
Failure mechanism and impact resistance of a human porous cranium are studied in detail by means of theoretical and numerical methods.It is hypothesized that pore distribution of a cranium directly affects cranial ene...Failure mechanism and impact resistance of a human porous cranium are studied in detail by means of theoretical and numerical methods.It is hypothesized that pore distribution of a cranium directly affects cranial energy absorption,and a stretched beam model and a real beam model are taken as the example for the verification.Meanwhile,for the purpose of comparison with numerical results,a theoretical model is also proposed for the prediction of residual velocity and contact force of the impactor for an impacted skull.Compared with the real beam model,the stretched beam model containing through-thickness pores is easily deformed under the impact,thereby buffering well the external impact energy.The energy absorption efficiency of both the stretched beam model and real beam model is concerned with the threshold velocity for penetration which is directly related to the size of the structural damage area.Overall,there is good agreement between numerical and theoretical results.In addition,the effect of structural geometric parameters(shape and size of the impactor)on the impact resistance of the skull bone is theoretically investigated.The study provides reference for the evaluation of the energy absorption and failure mechanism of the skull under impact loads.展开更多
Using a full-vector finite-difference time-domain (FDTD) method, this article explores the propagation characteristics of photonic crystal fiber (PCF) theoretically. The dependence of structural parameters on the ...Using a full-vector finite-difference time-domain (FDTD) method, this article explores the propagation characteristics of photonic crystal fiber (PCF) theoretically. The dependence of structural parameters on the effective index of the fundamental guided mode, effective index of the fundamental cladding mode, mode field diameter, confinement loss, effective mode area, and chromatic dispersion in PCF have been studied, respectively. The research presents a reference for designing of PCF with a specific purpose.展开更多
An enclosed cyclone passageway(ECP)dust-collecting fan is discussed.The ECP fan separates dust by centrifugal force originating from a driven spiral airflow,and its design takes the constraints of Chinese underground ...An enclosed cyclone passageway(ECP)dust-collecting fan is discussed.The ECP fan separates dust by centrifugal force originating from a driven spiral airflow,and its design takes the constraints of Chinese underground coal mines into consideration.Using the force equilibrium law,a general equation for dust removal in the centrifugal dust removal section(CDRS)of the ECP fan is deduced.This general equation is simplified using the CDRS structure and the fan operating parameters and is analysed numerically.The attractive results show that increases in the airflow rate of the fan,the structural ratio of the ECPs and the radius of the extended axis can improve the dust removal performance of the CDRS.Furthermore,the effects of the structural ratio and the radius on dust removal dominate over that of the flow rate,and the effect of the structural ratio is more significant than that of the radius.展开更多
基金funded by the National Natural Science Foundation of China(51866012).
文摘To overcome the problems of natural decreases in power quality,and to eliminate wind speed fluctuation due to wind shear and tower shadow effect arising from wind turbine structural parameters,an improved prediction model accounting for the dual effect of wind shear and tower shadow is,in this paper,built.Compared to the conventional prediction model,the proposed model contains a new constraint condition,which makes the disturbance term caused by the tower shadow effect always negative so that the prediction result is closer to the actual situation.Furthermore,wind turbine structural parameters such as hub height,rotor diameter,the diameter of the tower top,and rotor overhang on wind shear and tower shadow effect are also explored in detail.The results show that the wind shear effect became weaker with the increase in hub height.The hub height is independent of the tower shadow effect.The rotor diameter is positively correlated with the wind shear and tower shadow effect.The tower shadow effect is positively correlated with the diameter of the tower top and negatively correlated with the rotor overhang.
基金supported by the National Key Basic Research and Development Programme of China(No.2005CB623703)the National Natural Science Foundation of China(No.50474051 and No.50374081).
文摘Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working condition of an inert anode. To reduce its thermal stress, the effect of some parameters on the thermal stress distribution was investigated, including the anode height, the anode radius, the hole depth, the hole radius, and the radius of inner chamfer and outer chamfer. The results showed that in the actual working condition of an inert anode, there existed a large axial tensile stress near the tangent interface between the anode and bath, which was the major cause of anode breaking. Increasing the anode height and reducing the hole depth properly seemed to be beneficial for the stress distribution. With the increase of anode radius, the stress distribution became better first and then deteriorated, the reasonable value was between 0.045 to 0.06m. The hole radius had a significant effect on the stress and a smaller radius would reduce the thermal stress. The effect of the radius of the inner chamfer and the outer chamfer was less than other parameters.
基金supported by Important National Science & Technology Specific Projects of China (No.2) (Nos.2009ZX02001,2011ZX02403)
文摘The geometry of an inductively coupled plasma (ICP) etcher is usually considered to be an important factor for determining both plasma and process uniformity over a large wafer. During the past few decades, these parameters were determined by the "trial and error" method, resulting in wastes of time and funds. In this paper, a new approach of regression orthogonal design with plasma simulation experiments is proposed to investigate the sensitivity of the structural parameters on the uniformity of plasma characteristics. The tool for simulating plasma is CFD-ACE+, which is commercial multi-physical modeling software that has been proven to be accurate for plasma simulation. The simulated experimental results are analyzed to get a regression equation on three structural parameters. Through this equation, engineers can compute the uniformity of the electron number density rapidly without modeling by CFD-ACE+. An optimization performed at the end produces good results.
基金This project is supported by National Defense Science and Technology Multi-vocation Foundation in Advance Research of China(No. 97J465JW0408).
文摘Some approaches to measure parallel 6-degree of freedom platform's posturestatically and to calibrate the platform's actual structural parameters by measuring a series of theplatform's varying postures are studied. In the case where high posture accuracy is requiredrelatively, to obtain the platform's actual structural parameters is very important. Threedimensions measurement with 2 theodolites are used to obtain the platform's postures statically andNewton iterative method is adopted to calibrate structural parameters. Some measures taken in themeasurement and the calibration are discussed in detail. And the experiment results of theplatform's posture control before and after the calibration are given. The results show that theplatform's posture control accuracy after the calibration is improved notably.
文摘The atomic structural parameter P-i = (Z(i)*/n(i)*) (1 + n(i)*/n(i)) (1 + m(i)/Z) and the molecular structural parameter [GRAPHICS] are defined. The standard formation enthalpies (Delta(f)H(m)(phi)) of 74 species of rare earth compounds were studied with P, and the correlation coefficient is R > 0.94. The structural factors and the properties of rare earth compounds are influenced by the Z(i)*, n(i)*, n(i), m(i), Z. This study has special referential value to predict the properties of rare earth compounds.
文摘Elemental analysis, Fourier transform infrared (FTIR), 1H-NMR, fluorescence spectroscopy, and surface tension methods have been used to characterize the molecular structure and the aggregation behaviors of two asphaltenic fractions derived, respectively, from an Alge- rian petroleum well and a corresponding storage tank deposit. Elemental analysis, FTIR, ~H-NMR, and fluores- cence spectroscopy were used to investigate the chemical composition and structural parameters of asphaltenes, while the surface tension method was used to measure the critical micelle concentration (CMC) in organic solvents with different solubility parameters and polarities in order to characterize the asphaltenes' aggregation behaviors. Results show that the unstable asphaltenes fraction extracted from the storage tank deposit possesses a higher polarity (higher heteroatoms content) and a lower aro- maticity than stable asphaltenes from the petroleum well. The CMC results indicate that asphaltenes with high polarity and low aromaticity have a high solubility in polar solvents such as nitrobenzene, whereas asphaltenes with low polarity and high aromaticity are more soluble in solvents with weak polarity, like toluene. It is concludedthat the difference of structure of asphaltene samples and polarity of solvents can lead to difference of aggregation behaviors.
文摘Superconductive properties for oxides were predicted by artificial neural network (ANN) method with structural and chemical parameters as inputs. The predicted properties include superconductivity for oxides, distributed ranges of the superconductive transition temperature (Tc) for complex oxides, and Tc values for cuprate superconductors. The calculated results indicated that the adjusted ANN can be used to predict superconductive properties for unknown oxides.
文摘In this paper, the design optimization of the structural parameters of multilayer conductors in high temperature superconducting (HTS) cable is reviewed. Various optimization methods, such as the particle swarm optimization (PSO), the genetic algorithm (GA), and a robust optimization method based on design for six sigma (DFSS), have been applied to realize uniform current distribution among the multilayer HTS conductors. The continuous and discrete variables, such as the winding angle, radius, and winding direction of each layer, are chosen as the design parameters. Under the constraints of the mechanical properties and critical current, PSO is proven to be a more powerful tool than GA for structural parameter optimization, and DFSS can not only achieve a uniform current distribution, but also improve significantly the reliability and robustness of the HTS cable quality.
文摘The phase diagrams of microemulsion CTAB/butanol/cyclohexane/aqueous solution of nitrate (or aqueous solution of ammonium salt) were determined and the structural parameters and ΔG*o→i were obtained by means of dilution method and theoretical calculation. The effect of different w/s and salt concentration on the stability and structural parameters of microemulsion were investigated. The result shows that with the increase of w/s, the area of microemulsion and Nd decrease, Rw, l and n increase; with the increase of salt concentration, the area of microemulsion, l and Nd decrease, ΔG*o→I, Rw and n increase. Theoretical basis of preparing size-controlled long afterglow luminescence materials and study of the relationship between fluorescence properties and particle size are provided.
文摘For accurate aeroelastic analysis,the unsteady rotor flowfield is solved by computational fluid dynamics(CFD)module based on RANS/Euler equations and moving-embedded grid system,while computational structural dynamics(CSD)module is introduced to handle blade flexibility.In CFD module,dual time-stepping algorithm is employed in temporal discretization,Jameson two-order central difference(JST)scheme is adopted in spatial discretization and B-L turbulent model is used to illustrate the viscous effect.The CSD module is developed based on Hamilton′s variational principles and moderate deflection beam theory.Grid deformation is implemented using algebraic method through coordinate transformations to achieve deflections with high quality and efficiency.A CFD/CSD loose coupling strategy is developed to transfer information between rotor flowfield and blade structure.The CFD and the CSD modules are verified seperately.Then the CFD/CSD loose coupling is adopted in airloads prediction of UH-60A rotor under high speed forward flight condition.The calculated results agree well with test data.Finally,effects of torsional stiffness properties on airloads of rotors with different tip swept angles(from 10° forward to 30° backward)are investigated.The results are evaluated through pressure distribution and airloads variation,and some meaningful conclusions are drawn the moderated shock wave strength and pressure gradient caused by varied tip swept angle and structural properties.
文摘Two body centered tetragonal (bet) crystal structures of α'-Fe_(16)N_2 with x=0.25, z=0.3125 (Jack-1) and x=0.222, z=0.306 (Jack-2) respectively, were analyzed theoretically with EMS software package. The simulation of diffraction patterns indicates that both diffraction patterns of the same axis in these two structures obey bcc extinction rule. The conclusion is also obtained from the analyses of the diffracted waves. α'-Fe_(16)N_2 precipitates in the diffusion layer of ion-nitrided α-iron have been studied with transmission electron microscope (TEM). We have distinctly observed the electron diffraction patterns of α'-Fe_(16)N_2 in [100], [111], [110], [011], [210], [021], [311], [113], [331] and [133] zone axes with perfect symmetry, which indicate the parallel orientation relationship with α matrix:<001>α'//<001>α'// {100}.α'// {100}tα. The analyses of diffraction patterns, which obey bcc extinction rule, verify the bct structure of α'-Fe_(16)N_2 discovered by X-ray diffraction.
基金the State Key Laboratory of Pollution Control and Reuse of China Project Proposal (PCRRF07009)the University Natural Science Foundation of Jiangsu Province (05KJD150221)Natural Science Incubation Foundation of Xuzhou Normal University (05PLY04)
文摘Based on the characteristics of atom types, Hall's electrotopological state indices (En) are calculated for 165 nonionic organic compounds. On the basis of the characteristics of substituent and conjugated matrix, a novel molecular structure parameter (G) is defined and calculated for 165 molecules in this paper. En and G show good structural selectivity for organic molecules. G, a satisfactory relationship between bioconcentration factor (BCF) and En, is expressed as: 1gBCF = -0.283 + 1.246G + 0.079E42 + 0.351E9- 0.063E17 (n' = 122, R = 0.967, F = 425.636, s = 0.394), which could provide estimation and prediction for the lgBCF of nonionic organic chemicals. Furthermore, the model is examined to validate overall robustness with Jackknife tests, and the independent variables in model do not exist cross correlation with VIF. All these regression results show that the new parameter G and electrotopological state index have good rationality and efficiency. It is concluded that the En and G will be used widely in quantitative structure-property/activity relationship (QSPR/QSAR) research.
基金Supported by the Natural Science Foundation of Shanxi Province Project(2012011023-2)
文摘The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this paper,the influence of structural parameters of the turbocharger floating bearing on its dynamic characteristic coefficientsis systematically investigated based on the theories of hydrodynamic lubrication and tribology.The influence of clearance ratio on eccentricity and the influence of internal to external radius ratios,and Sommerfeld number were analyzed.A new formula of responding characteristics of the oil film force caused by the displacement or velocity disturbance was deduced near an equilibrium in the steady state.Applying the newly developed formula,the dynamic characteristic was studied for floating bearings.Regularity for change of oil film stiffness and damping was analyzed with the structural parameters of floating bearing such as radius ratios and eccentricity.It has been found that the clearance ratio increases with eccentricity when the radius ratio is unchanged.The eccentricity decreases with the internal to external radius ratio of floating rings when the clearance ratio is constant.The absolute value of total principal stiffness and total main damping decrease with the clearance ratio and radius ratio of floating rings when the total cross damping is stable.The results and findings in this paper can contribute to nonlinear dynamics designs of turbocharger rotor-bearing systems.
文摘In order to improve the performance of vehicle radiators, a two-dimensional heat transfer steady-state model of the radiator was set up. The influence of the structural parameters (axial ratio) of the heat exchange tube on the windward side on the heat transfer performance of the radiator was studied. With the increase of the axial ratio of the heat exchange tube on the windward side, the heat exchange capacity of the heat exchange tube surface slightly decreases. The heat exchange area increases significantly, which increases the total heat exchange of the radiator and improves the heat transfer performance of the radiator. When the axial ratio increases from 1.0 to 2.0, the average surface heat transfer capacity decreases from 5664.16</span><span style="font-family:""> </span><span style="font-family:Verdana;">W/m<sup>2</sup> to 5623.57</span><span style="font-family:""> </span><span style="font-family:Verdana;">W/m<sup>2</sup>.
基金supported by National Key R&D Program of China(Grant numbers 2022YFB2405202)。
文摘For combined sensible-latent heat storage system(CSLHS)(termed as the hybrid configuration),macro encapsulation can effectively solve the leakage problem of PCMs.However,due to the poor thermal conductivity of PCMs,the charging performance of the hybrid configuration slightly increases compared to the solid structure(with only sensible materials).Meanwhile,the natural convection in the PCMs zone could improve the charging performance.So,how to improve natural convection intensity is a key issue for the CSLHS by macro encapsulating.It is found that adding fins can significantly enhance natural convection and accelerate the melting of PCM.In this paper,we proposed the hybrid configuration with fins built-in by macro encapsulation,and analyzed its charging performance with different fin structural parameters in the PCM zone by CFD simulation.In the case,the sensible heat storage material is high-temperature concrete and the PCM is a low-melting-point mixed molten salt.We analyzed the effects of fin number,fin length and fin thickness on the charging performance of the hybrid configuration respectively.From the result,the charging performance increases with the fin number,but the increase rate gradually decreases.When the fin number is 6,the charging performance increases by 20.18%compared to the situation without fin.The charging performance increases gradually with the fin length.Compared with the hybrid configuration without fin,for each 10 mm increase in fin length,its charging performances increase by 4.09%,5.26%,7.02%,8.77%,11.70%,and 15.79%,respectively.Different from number and length of fins,the effect of thickness on the charging performance is very small.When the fin thickness increased from 1 mm to 4 mm,the charging performance only increased by 2.3%.It indicates that the main reason for the improving the charging performance is to increase the natural convection intensity by dividing the PCM zone through fins.These results show that the charging performance of the CSLHS with macro encapsulation can be improved by optimizing fin structural parameters.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.50874101 and 51104142)
文摘The effects of double shielded TIG (tungsten inert gas) torch's structural parameters, including the flow rate ratio between the inner and outer layers of gas and the extended length of the electrode (abbreviated as ELE in this work), on the fusion zone profile have been investigated for OCrl3NiSMo martensitic stainless steel. Results show that the double shielded TIG process yields relatively high penetration of the weld pool in a broad range of the structural parameters. ELE over 3 mm is too large and causes adverse reactions on the protection of electrode. The outer gas with relatively high flow rate or the outer layer with high oxygen content is conducive to the oxygen dissolved into the arc, which results in the oxidation of the weld pool surface and the electrode tip. The double shielded TIG welded metal was tested and presented good impact property.
基金Project supported by the National High Technology Research and Development Program of China (No. 2009AA063003), the State Key Development Program for Basic Research of China (No. 2009CB220004), the National Natural Science Foundation of China (No. 21177085) and the Research & Development Foundation of Shanghai Jiao Tong University.
文摘The effect of structural parameters of TiO2 nanotube arrays (TNAs) upon their photocatalytic/photoelectro- catalytic performance is studied by comparing the morphological characteristics and physicochemical properties with different tube lengths prepared from three kinds of electrolytes. The results show that the UV-Vis absorption edge of TNAs red-shifted with the increment of tube length and the short TNAs possess higher bandgap energy. The variation tendency of electrochemical window of TNAs is DMSO (5.5 V)〉Cit (3.2 V)〉HF (1.8 V). The long TNAs possess higher photocatalytic (PC) reactivity suggesting the surface roughness factor is the main determinant of PC efficiency, although, there is obvious recombination effects for the long TNAs. Evidenced by the positive correlation between tube length and photoelectrocatalytic (PEC) efficiency for TNAs from the same electrolyte, the enhancement of the tube length could lead to better PEC reactivity, but when the tube length is over a certain value, the PEC degradation rate no longer increases but decreases. The long TNAs with large surface roughness factor prepared from Cit and DMSO electrolytes exhibit comparative or even lower PEC performance compared with the short TNAs prepared from HF electrolyte, indicating that the PEC performance of TNAs was dominated by charge separation and photoelectron transfer properties rather than surface roughness coefficient and the tube length.
基金This study was funded in part by the National Natural Science Foundation of China(Grant 12002107)the National Postdoctoral Program for Innovative Talents(Grant BX20190101)+3 种基金the China Postdoctoral Science Foundation(Grant 2019M661268)the Heilongjiang Postdoctoral Financial Assistance(Grant LBH-Z19061)The present work was also supported in part by Alexander von Humboldt Foundation(Grant 1155520)(University of Siegen,Germany)the Science and Technology on Advanced Composites in Special Environment Laboratory,Young Elite Scientist Sponsorship Program by CAST(Grant YESS20160190).
文摘Failure mechanism and impact resistance of a human porous cranium are studied in detail by means of theoretical and numerical methods.It is hypothesized that pore distribution of a cranium directly affects cranial energy absorption,and a stretched beam model and a real beam model are taken as the example for the verification.Meanwhile,for the purpose of comparison with numerical results,a theoretical model is also proposed for the prediction of residual velocity and contact force of the impactor for an impacted skull.Compared with the real beam model,the stretched beam model containing through-thickness pores is easily deformed under the impact,thereby buffering well the external impact energy.The energy absorption efficiency of both the stretched beam model and real beam model is concerned with the threshold velocity for penetration which is directly related to the size of the structural damage area.Overall,there is good agreement between numerical and theoretical results.In addition,the effect of structural geometric parameters(shape and size of the impactor)on the impact resistance of the skull bone is theoretically investigated.The study provides reference for the evaluation of the energy absorption and failure mechanism of the skull under impact loads.
基金supported by the National Natural Science Foundation of China(60644004)the National Basic Research Program of China(2003CB314901)
文摘Using a full-vector finite-difference time-domain (FDTD) method, this article explores the propagation characteristics of photonic crystal fiber (PCF) theoretically. The dependence of structural parameters on the effective index of the fundamental guided mode, effective index of the fundamental cladding mode, mode field diameter, confinement loss, effective mode area, and chromatic dispersion in PCF have been studied, respectively. The research presents a reference for designing of PCF with a specific purpose.
基金supported by the Natural Science Foundation of China and Shenhua Group Corporation Limited(U1361118)the Hunan Provincial Natural Science Foundation of China(13JJ8016,2015JJ2061)+1 种基金the State Key Laboratory for Geomechanics and Deep Underground Engineering(SKLGDUEK1018)the Project of Scientific Research Fund of Hunan Provincial Education Department(Nos.12C1099,14C0425).
文摘An enclosed cyclone passageway(ECP)dust-collecting fan is discussed.The ECP fan separates dust by centrifugal force originating from a driven spiral airflow,and its design takes the constraints of Chinese underground coal mines into consideration.Using the force equilibrium law,a general equation for dust removal in the centrifugal dust removal section(CDRS)of the ECP fan is deduced.This general equation is simplified using the CDRS structure and the fan operating parameters and is analysed numerically.The attractive results show that increases in the airflow rate of the fan,the structural ratio of the ECPs and the radius of the extended axis can improve the dust removal performance of the CDRS.Furthermore,the effects of the structural ratio and the radius on dust removal dominate over that of the flow rate,and the effect of the structural ratio is more significant than that of the radius.