The principle for blood pressure measurement using pulse transit time is introduced in this paper.And the math model of synergetics theory is studied in detail.The synergetics theory is applied in the analysis of bloo...The principle for blood pressure measurement using pulse transit time is introduced in this paper.And the math model of synergetics theory is studied in detail.The synergetics theory is applied in the analysis of blood pressure measurement data.The simulation results show that the application of synergetics theory is helpful to judge the normal blood pressure,and the accuracy is up to 80%.展开更多
This paper substantiates the idea that particular science reflects only a certain angle of a complex model of the world. Guidance as to "adding" particular science data in order to achieve a holistic picture of the ...This paper substantiates the idea that particular science reflects only a certain angle of a complex model of the world. Guidance as to "adding" particular science data in order to achieve a holistic picture of the world is a philosophical outlook. The meaning of each relatively closed system is revealed only in the context of a more capacious system. According to the author, as the material world itself, its epistemic models as well are built according to the principle of "matryoshka dolls." The rational and irrational are discussed in the paper as equal moments of scientific knowledge. Contrary to the importance given to randomness in synergy, the author considers if it is possible to find out the causes of all events. In order to do this, other viewpoints and structure levels should be considered. There is a hidden order in every chaos, and that is revealed only in a certain situation. The main issue is taking into account the counter action of the system with the environment.展开更多
As a nonmetallic charge carrier,ammonium ion(NH_(4)^(+))has garnered significant attention in the construction of aqueous batteries due to its advantages of low molar mass,small hydration size and rapid diffusion in a...As a nonmetallic charge carrier,ammonium ion(NH_(4)^(+))has garnered significant attention in the construction of aqueous batteries due to its advantages of low molar mass,small hydration size and rapid diffusion in aqueous solutions.Polymers are a kind of potential electro-active materials for aqueous NH_(4)^(+)storage.However,traditional polymer electrodes are typically created by covering the bulky collectors with excessive additives,which could lead to low volume capacity and unsatisfactory stability.Herein,a nanoparticle-like polyimide(PI)was synthesized and then combined with MXene nanosheets to synergistically construct an additive-free and self-standing PI@MXene composite electrode.Significantly,the redox-active PI nanoparticles are enclosed between conductive MXene flakes to create a 3D lamination-like network that promotes electron transmission,while theπ-πinteractions existing between PI and MXene contribute to the enhanced structural integrity and stability within the composite electrode.As such,it delivers superior aqueous NH_(4)^(+)storage behaviors in terms of a notable specific capacity of 110.7 mA·h·cm^(–3) and a long lifespan with only 0.0064%drop each cycle.Furthermore,in-situ Raman and UV–Vis examinations provide evidence of reversible and stable redox mechanism of the PI@MXene composite electrode during NH_(4)^(+)uptake/removal,highlighting its significance in the area of electrochemical energy storage.展开更多
This work presents the development of hierarchical niobium pentoxide(Nb_(2)O_(5))-based composite nanofiber membranes for integrated adsorption and photocatalytic degradation of methylene blue(MB)pollutants from aqueo...This work presents the development of hierarchical niobium pentoxide(Nb_(2)O_(5))-based composite nanofiber membranes for integrated adsorption and photocatalytic degradation of methylene blue(MB)pollutants from aqueous solutions.The Nb_(2)O_(5) nanorods were vertically grown using a hydrothermal process on a base electrospun nanofibrous membrane made of polyacrylonitrile/polyvinylidene fluoride/ammonium niobate(V)oxalate hydrate(Nb_(2)O_(5)@PAN/PVDF/ANO).They were characterized using field-emission scanning electron microscopy(FE-SEM),X-ray diffraction(XRD)analysis,and Fourier transform infrared(FTIR)spectroscopy.These composite nanofibers possessed a narrow optical bandgap energy of 3.31 eV and demonstrated an MB degradation efficiency of 96%after 480 min contact time.The pseudo-first-order kinetic study was also conducted,in which Nb_(2)O_(5)@PAN/PVDF/ANO nanofibers have kinetic constant values of 1.29×10^(-2) min^(-1) and 0.30×10^(-2) min^(-1) for adsorption and photocatalytic degradation of MB aqueous solutions,respectively.These values are 17.7 and 7.8 times greater than those of PAN/PVDF/ANO nanofibers without Nb_(2)O_(5) nanostructures.Besides their outstanding photocatalytic performance,the developed membrane materials exhibit advantageous characteristics in recycling,which subsequently widen their practical use in environmental remediation applications.展开更多
The exploration of sustainable energy utilization requires the imple-mentation of advanced electrochemical devices for efficient energy conversion and storage,which are enabled by the usage of cost-effective,high-perf...The exploration of sustainable energy utilization requires the imple-mentation of advanced electrochemical devices for efficient energy conversion and storage,which are enabled by the usage of cost-effective,high-performance electro-catalysts.Currently,heterogeneous atomically dispersed catalysts are considered as potential candidates for a wide range of applications.Compared to conventional cata-lysts,atomically dispersed metal atoms in carbon-based catalysts have more unsatu-rated coordination sites,quantum size effect,and strong metal-support interactions,resulting in exceptional catalytic activity.Of these,dual-atomic catalysts(DACs)have attracted extensive attention due to the additional synergistic effect between two adja-cent metal atoms.DACs have the advantages of full active site exposure,high selectiv-ity,theoretical 100%atom utilization,and the ability to break the scaling relationship of adsorption free energy on active sites.In this review,we summarize recent research advancement of DACs,which includes(1)the comprehensive understanding of the synergy between atomic pairs;(2)the synthesis of DACs;(3)characterization meth-ods,especially aberration-corrected scanning transmission electron microscopy and synchrotron spectroscopy;and(4)electrochemical energy-related applications.The last part focuses on great potential for the electrochemical catalysis of energy-related small molecules,such as oxygen reduction reaction,CO_(2) reduction reaction,hydrogen evolution reaction,and N_(2) reduction reaction.The future research challenges and opportunities are also raised in prospective section.展开更多
Deep degradation of organic pollutants by sunlight-induced coupled photocatalytic and Fenton (photo-Fenton) reactions is of immense importance for water purification. In this work, we report a novel bifunctional catal...Deep degradation of organic pollutants by sunlight-induced coupled photocatalytic and Fenton (photo-Fenton) reactions is of immense importance for water purification. In this work, we report a novel bifunctional catalyst (Fe-PEI-CN) by codoping graphitic carbon nitride (CN) with polyethyleneimine ethoxylated (PEI) and Fe species, which demonstrated high activity during p-chlorophenol (p-ClPhOH) degradation via H_(2)O_(2) from the photocatalytic process. The relationship between the catalytic efficiency and the structure was explored using diff erent characterization methods. The Fe modification of CN was achieved through Fe-N coordination, which ensured high dispersion of Fe species and strong stability against leaching during liquid- phase reactions. The Fe modification initiated the Fenton reaction by activating H_(2)O_(2) into ·OH radicals for deep degradation of p-ClPhOH. In addition, it eff ectively promoted light absorption and photoelectron-hole (e-h ^(+) ) separation, corresponding to improved photocatalytic activity. On the other hand, PEI could significantly improve the ability of CN to generate H_(2)O_(2) through visible light photocatalysis. The maximum H_(2)O_(2) yield reached up to 102.6 μmol/L, which was 22 times higher than that of primitive CN. The cooperation of photocatalysis and the self-Fenton reaction has led to high-activity mineralizing organic pollutants with strong durability, indicating good potential for practical application in wastewater treatment.展开更多
The integration of distributed generation brings in new challenges for the operation of distribution networks,including out-of-limit voltage and power flow control.Soft open points(SOP)are new power electronic devices...The integration of distributed generation brings in new challenges for the operation of distribution networks,including out-of-limit voltage and power flow control.Soft open points(SOP)are new power electronic devices that can flexibly control active and reactive power flows.With the exception of active power output,photovoltaic(PV)devices can provide reactive power compensation through an inverter.Thus,a synergetic optimization operation method for SOP and PV in a distribution network is proposed.A synergetic optimization model was developed.The voltage deviation,network loss,and ratio of photovoltaic abandonment were selected as the objective functions.The PV model was improved by considering the three reactive power output modes of the PV inverter.Both the load fluctuation and loss of the SOP were considered.Three multi-objective optimization algorithms were used,and a compromise optimal solution was calculated.Case studies were conducted using an IEEE 33-node system.The simulation results indicated that the SOP and PVs complemented each other in terms of active power transmission and reactive power compensation.Synergetic optimization improves power control capability and flexibility,providing better power quality and PV consumption rate.展开更多
Direct alcohol fuel cells(DAFCs)are powered by the alcohol electro-oxidation reaction(AOR),where an electrocatalyst with an optimal electronic structure can accelerate the sluggish AOR.Interestingly,strain engineering...Direct alcohol fuel cells(DAFCs)are powered by the alcohol electro-oxidation reaction(AOR),where an electrocatalyst with an optimal electronic structure can accelerate the sluggish AOR.Interestingly,strain engineering in hetero-catalysis offers a promising route to boost their catalytic activity.Herein,we report on a class of monodispersed ultrathin twisty PdBi alloy nanowires(TNWs)assemblies with face-centered structures that drive AORs.These thin nanowire structures expose a large number of reactive sites.Strikingly,Pd_(6)Bi_(1)TNWs show an excellent current density of 2066,3047,and 1231 mA mg_(Pd)^(-1)for oxidation of ethanol,ethylene glycol,and glycerol,respectively.The“volcano-like”behaviors observed on PdBi TNWs for AORs indicate that the maximum catalytic mass activity is a well balance between active intermediates and blocking species at the interface.This study offers an effective and universal method to build novel nanocatalysts in various applications by rationally designing highly efficient catalysts with specific strain.展开更多
The direct tandem oxidation synthesis of benzenediol from benzene could simplify or even avoid the separation and purification of reaction intermediates, which is promising but challenged because of the further requir...The direct tandem oxidation synthesis of benzenediol from benzene could simplify or even avoid the separation and purification of reaction intermediates, which is promising but challenged because of the further required immediate consecutive activation of intermediate phenol. In this work, a synergistic benzene tandem-oxidation catalyst that V-Cu bimetallic oxides modified nanoporous silica(VCu-NS)was constructed via a facile assembly strategy which involves addictive negative anion citric acid mediating the intercalation of metal-citric acid chelate in mesopore of silica and subsequent thermal calcination inducing dual-metal active site formation. Such a tactic could make amorphous VOxspecies well covered on the surface of mesopore, and ultrafine copper oxide particles surrounded and neighbored by highly dispersed VOxwith strong interplay in mesopore, which was comprehensively confirmed by various characterizations. Benefiting from the unique V-Cu neighboring effect, the desorption of formed phenol over the catalytic site might be restricted therefore easily further activated by the formed reactive oxidative species, 3VCu-NS shows synergetic tandem-oxidation catalytic activities for benzene towards benzenediol with a selectivity of 57%. The result allows optimal 3VCu-NS to be a promising catalyst for benzenediol synthesis from benzene.展开更多
Efficient sterilization by a plasma photocatalytic system(PPS)requires strong synergy between plasma and photocatalyst to inactivate microorganisms while suppressing the formation of secondary pollutants.Here,we repor...Efficient sterilization by a plasma photocatalytic system(PPS)requires strong synergy between plasma and photocatalyst to inactivate microorganisms while suppressing the formation of secondary pollutants.Here,we report that a PPS constructed from a needle array corona discharge and Au/TiO2plasmonic nanocatalyst could remarkably improve the sterilization of Escherichia coli(E.coli)and alleviate formation of the discharge pollutant O3.At 6 kV,the combination of corona discharge and Au/TiO2achieves sterilization efficiency of 100%within an exposure time of 5 min.At 5 kV and an exposure time of 8 min,the presence of Au/TiO2improves sterilization efficiency of the corona discharge from 73%to 91%and reduces the O3concentration from 0.38 to 0.04 ppm,whereas the presence of TiO2reduces the sterilization efficiency and O3concentration to 66%and 0.17 ppm,respectively.The Au/TiO2in the PPS enables a uniform corona discharge,enhances the interaction between plasma,E.coli and nanocatalysts,and suppresses the formation of O3.Further,the Au/TiO2can be excited by ultraviolet-visible light emitted from the plasma to generate electron-hole pairs,and thus contributes to the formation of reactive radicals and the oxidative inactivation of E.coli.The PPS constructed from a needle array corona discharge and Au-based plasmonic nanocatalyst provides a promising approach for developing high-efficiency sterilization techniques.展开更多
Engineering the specific active sites of photocatalysts for simultaneously promoting CO_(2)and H_(2)O activation is important to achieve the efficient conversion of CO_(2)to hydrocarbon with H_(2)O as a proton source ...Engineering the specific active sites of photocatalysts for simultaneously promoting CO_(2)and H_(2)O activation is important to achieve the efficient conversion of CO_(2)to hydrocarbon with H_(2)O as a proton source under sunlight.Herein,we delicately design the In/TiO_(2)-VOphotocatalyst by engineering In single atoms(SAs)and oxygen vacancies(VOs)on porous TiO_(2).The relation between structure and performance of the photocatalyst is clarified by both experimental and theoretical analyses at the atomic levels.The In/TiO_(2)-VOphotocatalyst furnish a high CH_(4)production rate up to 35.49μmol g^(-1)h^(-1)with a high selectivity of 91.3%under simulated sunlight,while only CO is sluggishly generated on TiO_(2)-VO.The combination of in situ spectroscopic analyses with theoretical calculations reveal that the VOsites accelerate H_(2)O dissociation and increase proton feeding for CO_(2)reduction.Furthermore,the VOregulated In-Ti dual sites enable the formation of a stable adsorption conformation of In-C-O-Ti intermediate,which is responsible for the highly selective reduction of CO_(2)to CH_(4).This work demonstrates a new strategy for the development of effective photocatalysts by coupling metal SA sites with the adjacent metal sites of support to synergistically enhance the activity and selectivity of CO_(2)photoreduction.展开更多
The article is focused on discussing a new methodological approach to the study on specifics of transferring human beings to the posthuman cyber society.The approach in question assists in rethinking interconnected pr...The article is focused on discussing a new methodological approach to the study on specifics of transferring human beings to the posthuman cyber society.The approach in question assists in rethinking interconnected problems both of human origins in the universe and mankind’s digital future.And,besides,such an approach allows to deal with self-organising interconversions between the poles of the cardinal dual opposition of the Global Noosphere Brain and the Artificial General Intelligence.Herewith such phenomena of digital social life as Global Digitalisation,Digital Immortality,Mindcloning,and Technological Zombification being the constituents of Technological Singularity Concept,are rethought as paving the way for oncoming Posthuman Digital Era.This concept is evidently exemplified by a bifurcation resulting in two alternatives to be chosen by human beings,to wit,either to be undergone Mindcloning and become digitally immortal or being destroyed by powerful intelligent machines.The investigation in question is based on such a progressive methodology as the Law of Self-Organizing Ideals,as well as on the Method of Dual Oppositions.Rethinking interrelationships between the problem of a sense of social history and the meaning-of-life of local societies members which any intelligent machine is devoid of permits to substantiate specific regularities of Self-Transforming Homo Faber into Homo Digitalis and Technological Zombies ready to be transferred to posthuman cyberspace.展开更多
This work aimed to demonstrate possibilities for both active and passive control of the vortex-induced vibration and fatigue life of steel catenary risers via an analysis of the self-organization and evolution of the ...This work aimed to demonstrate possibilities for both active and passive control of the vortex-induced vibration and fatigue life of steel catenary risers via an analysis of the self-organization and evolution of the structural vibration based on synergetic theory. An analysis of the complex interrelated and synergistic relationship between the order parameter and the fast variable was performed, and the master equation of the nodal displacements was established as the order parameter for the evolution of the riser's structural vibration. Passive control methods include modifying the structure's elastic modulus, the internal fluid velocity, the top tension and the structural damping ratio, while an active control involves adjusting the external flow rate. Optimized parameters were obtained by analyzing the non-steady state solution of the master equation. The results show that the fatigue life greatly increases as the riser's elastic modulus decreases. In contrast, the fatigue life decreases with an increase of the internal fluid velocity. With an increase of the top tension, the vibration amplitudes and the number of modes may decrease, resulting in fewer bending stress cycles and a longer fatigue life. Furthermore, the structural damping ratio should be as large as possible. Finally, an active and passive control of the riser structure's response to vortex-induced vibration and its fatigue life can be achieved by carefully modifying the parameters mentioned above. The results may provide a theoretical framework for engineering practice concerning the design and control of steel catenary riser structures which are affected by vortex-induced vibration.展开更多
Based on the sharp contradiction between the economic benefits and adverse ecological impact of coal development in China's west,this paper establishes an evaluation model for the synergetic eco-environmental deve...Based on the sharp contradiction between the economic benefits and adverse ecological impact of coal development in China's west,this paper establishes an evaluation model for the synergetic eco-environmental development in Shendong Coal Mining Area through using synergism of five laws and the fuzzy comprehensive evaluation method. The analysis on synergy between large-scale coal mining and the eco-environment protection in Shendong is also conducted,arriving at the conclusion that synergetics of Shendong 's eco-environment protection is"good". And thus,the result sheds light on the fact that while working to quench China's energy demand on its path towards a modernized large coal mine complex,Shendong,as part of Shenhua Group's mining operation,has applied innovative management concepts and models to improve eco-environment for harmony and win-win results between resource exploration and environmental protection.展开更多
Hydrogenation and ammoniation of SrTiOa (STO), a normal ultraviolet photocatalyst, were performed by annealing STO(100) in Hz:N2=5%:95% and NH3, respectively, at various temperatures T. It was found that hydroge...Hydrogenation and ammoniation of SrTiOa (STO), a normal ultraviolet photocatalyst, were performed by annealing STO(100) in Hz:N2=5%:95% and NH3, respectively, at various temperatures T. It was found that hydrogenation at T≥900℃ remarkably enhanced the UV photocatalytic ability of STO, but the visible-light photocatalysis was still unavailable, while ammoniation at T≥800℃ introduced the N doping, resulting in visible-light photocat- alytie activity. Furthermore, when a hydrogenated STO was subjected to ammoniation, the visible-light photocatalytie ability was nearly the same as that of the ammoniated one; but the hydrogenation of an ammoniated one significantly enhanced visible-light photoeatalysis, indicating a synergetic effect of hydrogenation and ammoniation. Discussions and identifications have been made to analyze these results.展开更多
Hydrogen storage composite alloy Ti0.10Zr0.15V0.35Cr0.10Ni0.30–10% LaNi3 was prepared by two-step arc-melting to improve the electro-catalytic activity and the kinetic performance of Ti-V-based solid solution alloy. ...Hydrogen storage composite alloy Ti0.10Zr0.15V0.35Cr0.10Ni0.30–10% LaNi3 was prepared by two-step arc-melting to improve the electro-catalytic activity and the kinetic performance of Ti-V-based solid solution alloy. The electrochemical properties and synergetic effect of the composite alloy electrode were systematically investigated by using X-ray diffractometry, field emission scanning electron microscopy, energy-dispersive spectrometry, electrochemical impedance spectroscopy and galvanostatic charge/discharge test. It is found that the main phase of the composite alloy is composed of V-based solid solution phase with a BCC structure and C14 Laves phase with hexagonal structure, while the secondary phase is formed in the composite alloy. The comprehensive electrochemical properties of the composite alloy electrode are significantly improved. The activation cycle number, the maximum discharge capacity and the low temperature dischargeability of the composite alloy are 5 cycles, 362.5 mA-h/g and 65.84% at 233 K, respectively. It is suggested that distinct synergetic effect occurs in the activation process, composite process, cyclic process and discharge process at a low or high temperature under different current densities, in the charge–transfer resistance and exchange current density.展开更多
This paper is a continuous study of references[1-2].At first,we introduce the concept of assembles of ecosystems,and then discuss macro-and micro-synergetical methods for ecology study.Combining the two methods,by use...This paper is a continuous study of references[1-2].At first,we introduce the concept of assembles of ecosystems,and then discuss macro-and micro-synergetical methods for ecology study.Combining the two methods,by use of the macroscopic data(observable)outputted from the ecosystems,we can construct their GGLE,master their information changes between,before and after the generalized phase changes(e.g.community successions),and find out the action mechanisms of microscopic factors on macroscopic results.This may be a new approach to the study of action mechanisms of complex ecosystems.展开更多
In Synergetics, when a complex system evolves from one sate to another, the order parameter plays a dominant role. We can analyze the complex system state by studying the dynamic of order parameter. We developed a syn...In Synergetics, when a complex system evolves from one sate to another, the order parameter plays a dominant role. We can analyze the complex system state by studying the dynamic of order parameter. We developed a synergetic model of electricity market operation system, and studied the dynamic process of the system with empirical example, which revealed the internal mechanism of the system evolution. In order to verify the accuracy of the synergetic model, fourth-order Runge-Kutta algorithm and grey relevance method were used. Finally, we found that the reserve rate of generation was the order parameter of the system. Then we can use the principle of Synergetics to evaluate the efficiency of electricity market operation.展开更多
Financial regulation and supervision is an important subject in finance research. After the U. S. subprime mortgage crisis,the weakness in this field becomes the research focus. Every country attaches importance to st...Financial regulation and supervision is an important subject in finance research. After the U. S. subprime mortgage crisis,the weakness in this field becomes the research focus. Every country attaches importance to strengthen the financial supervision and management. But the financial regulatory system is a large system,and the process of model building and index selection is very complicated. A model for China's financial regulation and supervision system was proposed and a system evaluation method was improved. A more exact result was drawn by choosing 2003- 2009 index data.展开更多
Based on some basic principles of self-organization theory including dissipation structure and synergy,the author analyzes the condition,dynamic and evolving route of the self-organization evolution of the real estate...Based on some basic principles of self-organization theory including dissipation structure and synergy,the author analyzes the condition,dynamic and evolving route of the self-organization evolution of the real estate industry,and builds synergetic evolution model,calculates out the order parameter of the real estate industry. The paper supplies new methods and tools for further research of real estate industry and contributes to reference of the government for its direction of macro-control.展开更多
文摘The principle for blood pressure measurement using pulse transit time is introduced in this paper.And the math model of synergetics theory is studied in detail.The synergetics theory is applied in the analysis of blood pressure measurement data.The simulation results show that the application of synergetics theory is helpful to judge the normal blood pressure,and the accuracy is up to 80%.
文摘This paper substantiates the idea that particular science reflects only a certain angle of a complex model of the world. Guidance as to "adding" particular science data in order to achieve a holistic picture of the world is a philosophical outlook. The meaning of each relatively closed system is revealed only in the context of a more capacious system. According to the author, as the material world itself, its epistemic models as well are built according to the principle of "matryoshka dolls." The rational and irrational are discussed in the paper as equal moments of scientific knowledge. Contrary to the importance given to randomness in synergy, the author considers if it is possible to find out the causes of all events. In order to do this, other viewpoints and structure levels should be considered. There is a hidden order in every chaos, and that is revealed only in a certain situation. The main issue is taking into account the counter action of the system with the environment.
基金supported by the National Natural Science Foundation of China(52002157)the Undergraduate Research&Practice Innovation Program of Jiangsu Province(202310289033Z).
文摘As a nonmetallic charge carrier,ammonium ion(NH_(4)^(+))has garnered significant attention in the construction of aqueous batteries due to its advantages of low molar mass,small hydration size and rapid diffusion in aqueous solutions.Polymers are a kind of potential electro-active materials for aqueous NH_(4)^(+)storage.However,traditional polymer electrodes are typically created by covering the bulky collectors with excessive additives,which could lead to low volume capacity and unsatisfactory stability.Herein,a nanoparticle-like polyimide(PI)was synthesized and then combined with MXene nanosheets to synergistically construct an additive-free and self-standing PI@MXene composite electrode.Significantly,the redox-active PI nanoparticles are enclosed between conductive MXene flakes to create a 3D lamination-like network that promotes electron transmission,while theπ-πinteractions existing between PI and MXene contribute to the enhanced structural integrity and stability within the composite electrode.As such,it delivers superior aqueous NH_(4)^(+)storage behaviors in terms of a notable specific capacity of 110.7 mA·h·cm^(–3) and a long lifespan with only 0.0064%drop each cycle.Furthermore,in-situ Raman and UV–Vis examinations provide evidence of reversible and stable redox mechanism of the PI@MXene composite electrode during NH_(4)^(+)uptake/removal,highlighting its significance in the area of electrochemical energy storage.
基金funded by the Minister of Education,Culture,Research,and Technology of Indonesia through a research scheme of“Penelitian Fundamental–Reguler(PFR)2023”under a contract number of 1115c/IT9.2.1/PT.01.03/2023.
文摘This work presents the development of hierarchical niobium pentoxide(Nb_(2)O_(5))-based composite nanofiber membranes for integrated adsorption and photocatalytic degradation of methylene blue(MB)pollutants from aqueous solutions.The Nb_(2)O_(5) nanorods were vertically grown using a hydrothermal process on a base electrospun nanofibrous membrane made of polyacrylonitrile/polyvinylidene fluoride/ammonium niobate(V)oxalate hydrate(Nb_(2)O_(5)@PAN/PVDF/ANO).They were characterized using field-emission scanning electron microscopy(FE-SEM),X-ray diffraction(XRD)analysis,and Fourier transform infrared(FTIR)spectroscopy.These composite nanofibers possessed a narrow optical bandgap energy of 3.31 eV and demonstrated an MB degradation efficiency of 96%after 480 min contact time.The pseudo-first-order kinetic study was also conducted,in which Nb_(2)O_(5)@PAN/PVDF/ANO nanofibers have kinetic constant values of 1.29×10^(-2) min^(-1) and 0.30×10^(-2) min^(-1) for adsorption and photocatalytic degradation of MB aqueous solutions,respectively.These values are 17.7 and 7.8 times greater than those of PAN/PVDF/ANO nanofibers without Nb_(2)O_(5) nanostructures.Besides their outstanding photocatalytic performance,the developed membrane materials exhibit advantageous characteristics in recycling,which subsequently widen their practical use in environmental remediation applications.
基金This work was financially supported by the National Key Research and Development Program of China(2018YFA0702002)the Beijing Natural Science Foundation(Z210016)+1 种基金the National Natural Science Foundation of China(51967020,21935001)Shanxi Energy Internet Research Institute(SXEI 2023A004).
文摘The exploration of sustainable energy utilization requires the imple-mentation of advanced electrochemical devices for efficient energy conversion and storage,which are enabled by the usage of cost-effective,high-performance electro-catalysts.Currently,heterogeneous atomically dispersed catalysts are considered as potential candidates for a wide range of applications.Compared to conventional cata-lysts,atomically dispersed metal atoms in carbon-based catalysts have more unsatu-rated coordination sites,quantum size effect,and strong metal-support interactions,resulting in exceptional catalytic activity.Of these,dual-atomic catalysts(DACs)have attracted extensive attention due to the additional synergistic effect between two adja-cent metal atoms.DACs have the advantages of full active site exposure,high selectiv-ity,theoretical 100%atom utilization,and the ability to break the scaling relationship of adsorption free energy on active sites.In this review,we summarize recent research advancement of DACs,which includes(1)the comprehensive understanding of the synergy between atomic pairs;(2)the synthesis of DACs;(3)characterization meth-ods,especially aberration-corrected scanning transmission electron microscopy and synchrotron spectroscopy;and(4)electrochemical energy-related applications.The last part focuses on great potential for the electrochemical catalysis of energy-related small molecules,such as oxygen reduction reaction,CO_(2) reduction reaction,hydrogen evolution reaction,and N_(2) reduction reaction.The future research challenges and opportunities are also raised in prospective section.
基金the National Key Research and Development Program of China (No. 2020YFA0211004)Key Grant of Nation Science Funding of China (No. 22236005)+5 种基金Nation Science Funding of China (No. 22376141)Ministry of Education of China (No. PCSIRT_IRT_16R49)“111” Innovation and Talent Recruitment Base (D18020)Shanghai Government (No. 20ZR1440700)Shanghai Engineering Research Center of Green Energy Chemical Engineering (No. 18DZ2254200)Scientific and Technological Innovation Team for Green Catalysis and Energy Materialien Yunnan Institutions of Higher Learning, and Surface project of Yunnan Province science and technology Department (No. 20210 A070001-050).
文摘Deep degradation of organic pollutants by sunlight-induced coupled photocatalytic and Fenton (photo-Fenton) reactions is of immense importance for water purification. In this work, we report a novel bifunctional catalyst (Fe-PEI-CN) by codoping graphitic carbon nitride (CN) with polyethyleneimine ethoxylated (PEI) and Fe species, which demonstrated high activity during p-chlorophenol (p-ClPhOH) degradation via H_(2)O_(2) from the photocatalytic process. The relationship between the catalytic efficiency and the structure was explored using diff erent characterization methods. The Fe modification of CN was achieved through Fe-N coordination, which ensured high dispersion of Fe species and strong stability against leaching during liquid- phase reactions. The Fe modification initiated the Fenton reaction by activating H_(2)O_(2) into ·OH radicals for deep degradation of p-ClPhOH. In addition, it eff ectively promoted light absorption and photoelectron-hole (e-h ^(+) ) separation, corresponding to improved photocatalytic activity. On the other hand, PEI could significantly improve the ability of CN to generate H_(2)O_(2) through visible light photocatalysis. The maximum H_(2)O_(2) yield reached up to 102.6 μmol/L, which was 22 times higher than that of primitive CN. The cooperation of photocatalysis and the self-Fenton reaction has led to high-activity mineralizing organic pollutants with strong durability, indicating good potential for practical application in wastewater treatment.
基金supported by the Science and Technology Project of SGCC(kj2022-075).
文摘The integration of distributed generation brings in new challenges for the operation of distribution networks,including out-of-limit voltage and power flow control.Soft open points(SOP)are new power electronic devices that can flexibly control active and reactive power flows.With the exception of active power output,photovoltaic(PV)devices can provide reactive power compensation through an inverter.Thus,a synergetic optimization operation method for SOP and PV in a distribution network is proposed.A synergetic optimization model was developed.The voltage deviation,network loss,and ratio of photovoltaic abandonment were selected as the objective functions.The PV model was improved by considering the three reactive power output modes of the PV inverter.Both the load fluctuation and loss of the SOP were considered.Three multi-objective optimization algorithms were used,and a compromise optimal solution was calculated.Case studies were conducted using an IEEE 33-node system.The simulation results indicated that the SOP and PVs complemented each other in terms of active power transmission and reactive power compensation.Synergetic optimization improves power control capability and flexibility,providing better power quality and PV consumption rate.
基金supported by the National Natural Science Foundation of China(22172084 and 21773133)the World-Class Discipline Program of Shandong Province,China。
文摘Direct alcohol fuel cells(DAFCs)are powered by the alcohol electro-oxidation reaction(AOR),where an electrocatalyst with an optimal electronic structure can accelerate the sluggish AOR.Interestingly,strain engineering in hetero-catalysis offers a promising route to boost their catalytic activity.Herein,we report on a class of monodispersed ultrathin twisty PdBi alloy nanowires(TNWs)assemblies with face-centered structures that drive AORs.These thin nanowire structures expose a large number of reactive sites.Strikingly,Pd_(6)Bi_(1)TNWs show an excellent current density of 2066,3047,and 1231 mA mg_(Pd)^(-1)for oxidation of ethanol,ethylene glycol,and glycerol,respectively.The“volcano-like”behaviors observed on PdBi TNWs for AORs indicate that the maximum catalytic mass activity is a well balance between active intermediates and blocking species at the interface.This study offers an effective and universal method to build novel nanocatalysts in various applications by rationally designing highly efficient catalysts with specific strain.
基金financially supported by the National Natural Science Foundation of China (21908085)Natural Science Foundation of Jiangsu Province, China (BK20190961)+1 种基金Postdoctoral Research Foundation of Jiangsu Province (2020Z291)the Jiangsu Provincial Key Laboratory of Environmental Science and Engineering (JSHJZDSYS-202103)。
文摘The direct tandem oxidation synthesis of benzenediol from benzene could simplify or even avoid the separation and purification of reaction intermediates, which is promising but challenged because of the further required immediate consecutive activation of intermediate phenol. In this work, a synergistic benzene tandem-oxidation catalyst that V-Cu bimetallic oxides modified nanoporous silica(VCu-NS)was constructed via a facile assembly strategy which involves addictive negative anion citric acid mediating the intercalation of metal-citric acid chelate in mesopore of silica and subsequent thermal calcination inducing dual-metal active site formation. Such a tactic could make amorphous VOxspecies well covered on the surface of mesopore, and ultrafine copper oxide particles surrounded and neighbored by highly dispersed VOxwith strong interplay in mesopore, which was comprehensively confirmed by various characterizations. Benefiting from the unique V-Cu neighboring effect, the desorption of formed phenol over the catalytic site might be restricted therefore easily further activated by the formed reactive oxidative species, 3VCu-NS shows synergetic tandem-oxidation catalytic activities for benzene towards benzenediol with a selectivity of 57%. The result allows optimal 3VCu-NS to be a promising catalyst for benzenediol synthesis from benzene.
基金National Natural Science Foundation of China(Nos.52041001,21808024)Natural Science Foundation of Liaoning Province(No.2020-MS-126)Special Foundation for Key Fields of Colleges and Universities in Guangdong Province(No.2021ZDZX4094)。
文摘Efficient sterilization by a plasma photocatalytic system(PPS)requires strong synergy between plasma and photocatalyst to inactivate microorganisms while suppressing the formation of secondary pollutants.Here,we report that a PPS constructed from a needle array corona discharge and Au/TiO2plasmonic nanocatalyst could remarkably improve the sterilization of Escherichia coli(E.coli)and alleviate formation of the discharge pollutant O3.At 6 kV,the combination of corona discharge and Au/TiO2achieves sterilization efficiency of 100%within an exposure time of 5 min.At 5 kV and an exposure time of 8 min,the presence of Au/TiO2improves sterilization efficiency of the corona discharge from 73%to 91%and reduces the O3concentration from 0.38 to 0.04 ppm,whereas the presence of TiO2reduces the sterilization efficiency and O3concentration to 66%and 0.17 ppm,respectively.The Au/TiO2in the PPS enables a uniform corona discharge,enhances the interaction between plasma,E.coli and nanocatalysts,and suppresses the formation of O3.Further,the Au/TiO2can be excited by ultraviolet-visible light emitted from the plasma to generate electron-hole pairs,and thus contributes to the formation of reactive radicals and the oxidative inactivation of E.coli.The PPS constructed from a needle array corona discharge and Au-based plasmonic nanocatalyst provides a promising approach for developing high-efficiency sterilization techniques.
基金financially supported by the Joint Funds of the Zhejiang Provincial Natural Science Foundation of China(Grant No.LZY23B030006)the Natural Science Foundation of Zhejiang Province of China(LY19B010005)the Fundamental Research Funds of Zhejiang Sci-Tech University(2020Y003)。
文摘Engineering the specific active sites of photocatalysts for simultaneously promoting CO_(2)and H_(2)O activation is important to achieve the efficient conversion of CO_(2)to hydrocarbon with H_(2)O as a proton source under sunlight.Herein,we delicately design the In/TiO_(2)-VOphotocatalyst by engineering In single atoms(SAs)and oxygen vacancies(VOs)on porous TiO_(2).The relation between structure and performance of the photocatalyst is clarified by both experimental and theoretical analyses at the atomic levels.The In/TiO_(2)-VOphotocatalyst furnish a high CH_(4)production rate up to 35.49μmol g^(-1)h^(-1)with a high selectivity of 91.3%under simulated sunlight,while only CO is sluggishly generated on TiO_(2)-VO.The combination of in situ spectroscopic analyses with theoretical calculations reveal that the VOsites accelerate H_(2)O dissociation and increase proton feeding for CO_(2)reduction.Furthermore,the VOregulated In-Ti dual sites enable the formation of a stable adsorption conformation of In-C-O-Ti intermediate,which is responsible for the highly selective reduction of CO_(2)to CH_(4).This work demonstrates a new strategy for the development of effective photocatalysts by coupling metal SA sites with the adjacent metal sites of support to synergistically enhance the activity and selectivity of CO_(2)photoreduction.
文摘The article is focused on discussing a new methodological approach to the study on specifics of transferring human beings to the posthuman cyber society.The approach in question assists in rethinking interconnected problems both of human origins in the universe and mankind’s digital future.And,besides,such an approach allows to deal with self-organising interconversions between the poles of the cardinal dual opposition of the Global Noosphere Brain and the Artificial General Intelligence.Herewith such phenomena of digital social life as Global Digitalisation,Digital Immortality,Mindcloning,and Technological Zombification being the constituents of Technological Singularity Concept,are rethought as paving the way for oncoming Posthuman Digital Era.This concept is evidently exemplified by a bifurcation resulting in two alternatives to be chosen by human beings,to wit,either to be undergone Mindcloning and become digitally immortal or being destroyed by powerful intelligent machines.The investigation in question is based on such a progressive methodology as the Law of Self-Organizing Ideals,as well as on the Method of Dual Oppositions.Rethinking interrelationships between the problem of a sense of social history and the meaning-of-life of local societies members which any intelligent machine is devoid of permits to substantiate specific regularities of Self-Transforming Homo Faber into Homo Digitalis and Technological Zombies ready to be transferred to posthuman cyberspace.
基金Financial support from the China Postdoctoral Science Foundation Fund (Grant No.2013M531563)the Qingdao Agricultural University High-Level Talents Research Fund (Grant No. 631424)is gratefully acknowledged
文摘This work aimed to demonstrate possibilities for both active and passive control of the vortex-induced vibration and fatigue life of steel catenary risers via an analysis of the self-organization and evolution of the structural vibration based on synergetic theory. An analysis of the complex interrelated and synergistic relationship between the order parameter and the fast variable was performed, and the master equation of the nodal displacements was established as the order parameter for the evolution of the riser's structural vibration. Passive control methods include modifying the structure's elastic modulus, the internal fluid velocity, the top tension and the structural damping ratio, while an active control involves adjusting the external flow rate. Optimized parameters were obtained by analyzing the non-steady state solution of the master equation. The results show that the fatigue life greatly increases as the riser's elastic modulus decreases. In contrast, the fatigue life decreases with an increase of the internal fluid velocity. With an increase of the top tension, the vibration amplitudes and the number of modes may decrease, resulting in fewer bending stress cycles and a longer fatigue life. Furthermore, the structural damping ratio should be as large as possible. Finally, an active and passive control of the riser structure's response to vortex-induced vibration and its fatigue life can be achieved by carefully modifying the parameters mentioned above. The results may provide a theoretical framework for engineering practice concerning the design and control of steel catenary riser structures which are affected by vortex-induced vibration.
文摘Based on the sharp contradiction between the economic benefits and adverse ecological impact of coal development in China's west,this paper establishes an evaluation model for the synergetic eco-environmental development in Shendong Coal Mining Area through using synergism of five laws and the fuzzy comprehensive evaluation method. The analysis on synergy between large-scale coal mining and the eco-environment protection in Shendong is also conducted,arriving at the conclusion that synergetics of Shendong 's eco-environment protection is"good". And thus,the result sheds light on the fact that while working to quench China's energy demand on its path towards a modernized large coal mine complex,Shendong,as part of Shenhua Group's mining operation,has applied innovative management concepts and models to improve eco-environment for harmony and win-win results between resource exploration and environmental protection.
文摘Hydrogenation and ammoniation of SrTiOa (STO), a normal ultraviolet photocatalyst, were performed by annealing STO(100) in Hz:N2=5%:95% and NH3, respectively, at various temperatures T. It was found that hydrogenation at T≥900℃ remarkably enhanced the UV photocatalytic ability of STO, but the visible-light photocatalysis was still unavailable, while ammoniation at T≥800℃ introduced the N doping, resulting in visible-light photocat- alytie activity. Furthermore, when a hydrogenated STO was subjected to ammoniation, the visible-light photocatalytie ability was nearly the same as that of the ammoniated one; but the hydrogenation of an ammoniated one significantly enhanced visible-light photoeatalysis, indicating a synergetic effect of hydrogenation and ammoniation. Discussions and identifications have been made to analyze these results.
基金Project (B2011203074) supported by the Natural Science Foundation of Hebei Province, ChinaProject (201101A129) supported by the Technology Research and Development Program of Qinhuangdao, Hebei Province, China
文摘Hydrogen storage composite alloy Ti0.10Zr0.15V0.35Cr0.10Ni0.30–10% LaNi3 was prepared by two-step arc-melting to improve the electro-catalytic activity and the kinetic performance of Ti-V-based solid solution alloy. The electrochemical properties and synergetic effect of the composite alloy electrode were systematically investigated by using X-ray diffractometry, field emission scanning electron microscopy, energy-dispersive spectrometry, electrochemical impedance spectroscopy and galvanostatic charge/discharge test. It is found that the main phase of the composite alloy is composed of V-based solid solution phase with a BCC structure and C14 Laves phase with hexagonal structure, while the secondary phase is formed in the composite alloy. The comprehensive electrochemical properties of the composite alloy electrode are significantly improved. The activation cycle number, the maximum discharge capacity and the low temperature dischargeability of the composite alloy are 5 cycles, 362.5 mA-h/g and 65.84% at 233 K, respectively. It is suggested that distinct synergetic effect occurs in the activation process, composite process, cyclic process and discharge process at a low or high temperature under different current densities, in the charge–transfer resistance and exchange current density.
基金Supported by the Youth Fund of Chinese Academy of Sciencethe Youth Fund of Lanzhou University
文摘This paper is a continuous study of references[1-2].At first,we introduce the concept of assembles of ecosystems,and then discuss macro-and micro-synergetical methods for ecology study.Combining the two methods,by use of the macroscopic data(observable)outputted from the ecosystems,we can construct their GGLE,master their information changes between,before and after the generalized phase changes(e.g.community successions),and find out the action mechanisms of microscopic factors on macroscopic results.This may be a new approach to the study of action mechanisms of complex ecosystems.
文摘In Synergetics, when a complex system evolves from one sate to another, the order parameter plays a dominant role. We can analyze the complex system state by studying the dynamic of order parameter. We developed a synergetic model of electricity market operation system, and studied the dynamic process of the system with empirical example, which revealed the internal mechanism of the system evolution. In order to verify the accuracy of the synergetic model, fourth-order Runge-Kutta algorithm and grey relevance method were used. Finally, we found that the reserve rate of generation was the order parameter of the system. Then we can use the principle of Synergetics to evaluate the efficiency of electricity market operation.
文摘Financial regulation and supervision is an important subject in finance research. After the U. S. subprime mortgage crisis,the weakness in this field becomes the research focus. Every country attaches importance to strengthen the financial supervision and management. But the financial regulatory system is a large system,and the process of model building and index selection is very complicated. A model for China's financial regulation and supervision system was proposed and a system evaluation method was improved. A more exact result was drawn by choosing 2003- 2009 index data.
文摘Based on some basic principles of self-organization theory including dissipation structure and synergy,the author analyzes the condition,dynamic and evolving route of the self-organization evolution of the real estate industry,and builds synergetic evolution model,calculates out the order parameter of the real estate industry. The paper supplies new methods and tools for further research of real estate industry and contributes to reference of the government for its direction of macro-control.