Spatio-temporal evolution and topographic gradient effect of land use and ecosystem service value in the Lhasa River Basin

The Lhasa River Basin forms an essential human settlement area in the southern part of the Qinghai-Tibet Plateau.This study employed ecosystem service value(ESV)evaluation model,terrain gradient grading,and Geodetector to analyze land use and ESV in the Lhasa River Basin from 1985 to 2020.The findings reveal that:(1)From 1985 to 2020,grassland was the dominant land use.There was a trend of grassland reduction and the expansion of other land types.(2)ESV has increased over the research period(with a total increase of 0.84%),with higher values in the southeast and lower values in the northwest.Grassland contributed the most to ESV,and climate regulation and hydrological regulation were the ecosystem services that contribute the most to ESV.(3)Natural factors like NDVI and altitude,as well as economic factors like population density and distance from roads,influenced the spatial differentiation of ESV,the explanatory power of NDVI reached up to 0.47.The interaction between factors had a greater impact than individual factors.These research results can provide theoretical support for national spatial planning and ecological environment protection in the Lhasa River Basin and other similar areas.

Examining the evolution of tidal creeks in the Huanghe River delta using multi-temporal Landsat images

Coastal tidal creeks are important channels for exchanges of material and energy between sea and land,and play an important role in the ecological protection of tidal flats.Although tidal creeks have evolved differently in various regions,the evolutionary process of tidal creeks in the Huanghe(Yellow)River delta of China,one of the most active deltas worldwide,is not entirely clear.Therefore,the evolution of tidal creeks in the delta from 1981 to 2021 was investigated by quantitatively analysing the tidal creeks and developing a standard for dividing their evolution periods.Visual interpretation and supervised classification methods were applied to the Landsat images to extract the tidal creek network,and 17 groups of tidal creek systems were selected.Results indicate that Creek S 1 was the most developed creek for having 113 tidal creeks totaling 65.8 km in length,while Creek E 3 had the fastest growth rate for having average annual increase of 1.9 km.Meanwhile,the level of tidal creeks increased,the average and median lengths of tidal creeks increased,and the number of tidal creeks decreased since 1981.The evolution of the tidal creek system could be divided into four stages,namely,rising,developing,stabilizing,and degrading.Analyses of a representative tidal creek show that there was no degenerated tidal creek during the rising period,with an increase in the number of 50 and a length increase of 57.9 km between 1981 and 1989.The proportion of new tidal creeks in the developing period was more than 50%and the new tidal creeks in the stabilizing period were equal to the degraded tidal creeks.Extinct tidal creeks were greater than 50%during the degrading period.There was no fixed order of tidal creek evolution in each period,and there may be a skip in evolution.Our findings provided a reference for studying the evolution of tidal creeks.

Spatiotemporal evolution and influencing factors of urban resilience in the Yellow River Basin,China

The Yellow River Basin of China is a key region that contains myriad interactions between human activities and natural environment.Industrialization and urbanization promote social-economic development,but they also have generated a series of environmental and ecological issues in this basin.Previous researches have evaluated urban resilience at the national,regional,urban agglomeration,city,and prefecture levels,but not at the watershed level.To address this research gap and elevate the Yellow River Basin’s urban resilience level,we constructed an urban resilience evaluation index system from five dimensions:industrial resilience,social resilience,environmental resilience,technological resilience,and organizational resilience.The entropy weight method was used to comprehensively evaluate urban resilience in the Yellow River Basin.The exploratory spatial data analysis method was employed to study the spatiotemporal differences in urban resilience in the Yellow River Basin in 2010,2015,and 2020.Furthermore,the grey correlation analysis method was utilized to explore the influencing factors of these differences.The results of this study are as follows:(1)the overall level of urban resilience in the Yellow River Basin was relatively low but showed an increasing trend during 2010–2015,and significant spatial distribution differences were observed,with a higher resilience level in the eastern region and a low-medium resilience level in the western region;(2)the differences in urban resilience were noticeable,with industrial resilience and social resilience being relatively highly developed,whereas organizational resilience and environmental resilience were relatively weak;and(3)the correlation ranking of resilience influencing factors was as follows:science and technology level>administrative power>openness>market forces.This research can provide a basis for improving the resilience level of cities in the Yellow River Basin and contribute to the high-quality development of the region.

Spatio-temporal evolution of the coordinated development of high-tech industry agglomeration and resource-environmental carrying capacity in the Yellow River Basin

Under the background of new infrastructure,the Yellow River Basin’s superior growth cannot be separated originating with the synergistic effect of scientific and technological inventiveness and ecological civilization construction.In light of the coupling coordination analysis of the coordination effect of provincial high-tech industry agglomeration and resource carrying capacity in the Yellow River Basin from 2009 to 2021,The evolution of the geographical and temporal pattern of development was investigated using the Moran index and kernel density estimation.The results show that the agglomeration of high-tech industries in the Yellow River Basin presents a development trend of seek improvement in stability,and there is a good coupling and coordination throughout the progression of scientific and technological innovation and the loading capacity of the resource,from the viewpoint of a time series.From the perspective of spatial pattern distribution,the whole basin aims at the lower reaches,accelerates the optimization of digital industry and promotes Yellow River Basin development of superior quality through innovation support and increase of input,and based on policy guidance.

Late Mesozoic Exhumation of the Huangling Massif:Constraints on the Evolution of the Middle Yangtze River

Plate subduction leads to complex exhumation processes on continents.The Huangling Massif lies at the northern margin of the South China Block.Whether the Huangling Massif was exhumed as a watershed of the middle reaches of the Paleo-Yangtze River during the Mesozoic remains under debate.We examined the exhumation history of the Huangling Massif based on six granite bedrock samples,using apatite fission track(AFT)and apatite and zircon(U-Th)/He(AHe and ZHe)thermochronology.These samples yielded ages of 157–132 Ma(ZHe),119–106 Ma(AFT),and 114–72 Ma(AHe),respectively.Thermal modeling revealed that three phases of rapid cooling occurred during the Late Jurassic–Early Cretaceous,late Early Cretaceous,and Late Cretaceous.These exhumation processes led to the high topographic relief responsible for the emergence of the Huangling Massif.The integrated of our new data with published sedimentological records suggests that the Huangling Massif might have been the watershed of the middle reaches of the Paleo-Yangtze River since the Cretaceous.At that time,the rivers flowed westward into the Sichuan Basin and eastward into the Jianghan Basin.The subduction of the Pacific Plate beneath the Asian continent in the Mesozoic deeply influenced the geomorphic evolution of the South China Block.

Disentangling the influencing factors of spatiotemporal evolution of sloping farmland in the Yangtze River Economic Belt, China

Sloping farmland(SpF)is not only an important space for food production and supply in China’s hilly areas,but also a major source of soil erosion.Thus,it is important to achieve a healthy balance between regional food security and environmental protection.Yangtze River Economic Belt(YREB),an important grain production base where SpF concentrated in China,is also faced with serious soil erosion.However,research at the macro scale on the spatiotemporal change of SpF and its driving forces in YREB is still lacking.To bridge the gap,we first analyzed the long-term evolution characteristics of SpF in 1069 counties in the YREB and then explored the driving mechanism of SpF changes during 1980-2020.Results showed that the SpF in the YREB continuously decreased during the study period,with a total area decreasing by 26,300 km2.SpF was primarily concentrated in the upper reaches of the YREB while SpF use dynamic degree varied significantly with the most active change in the lower reaches,reaching to a maximum of 0.324%.The spatial gravity of SpF distribution relocated 20.15 km towards the southwest.As for the driving factors,the socioeconomic factors contributed greater to SpF changes in the whole YREB and its subregions.The intensity of human activities is the most crucial,with factor contribution rate constantly above 0.76.The interactive detection revealed that the prevailing interaction format was primarily bi-enhanced,supplemented with nonlinear-enhanced,which amplified the role of different factors after interacting with them.The pair-wise interaction involving socioeconomic factors had a more potential effect on SpF changes compared to those between physical geography and locational factors.The influence of the intensity of human activities on SpF changes is greatly enhanced after interacting with any factor.It dominated SpF changes in the YREB and its interaction with GDP played an important role at all times.These findings can enlighten differential management strategies of SpF use and ecological conservation in the YREB.

The Response of Carbonate System to Watershed Urbanization Process in a Semi-Arid River

Different from rivers in humid areas,the variability of riverine CO_(2) system in arid areas is heavily impacted by anthropogenic disturbance with the increasing urbanization and water withdrawals.In this study,the water chemistry and the controls of carbonate system in an urbanized river(the Fenhe River)on the semi-arid Loess Plateau were analyzed.The water chemistry of the river water showed that the high dissolved inorganic carbon(DIC)concentration(about 37 mg L^(-1))in the upstream with a karst land type was mainly sourced from carbonate weathering involved by H_(2)CO_(3) and H_(2)SO_(4),resulting in an oversaturated partial pressure of CO_(2)(pCO_(2))(about 800μatm).In comparison,damming resulted in the widespread appearance of non-free flowing river segments,and aquatic photosynthesis dominated the DIC and pCO_(2) spatiality demonstrated by the enriched stable isotope of DIC(δ^(13)CDIC).Especially in the mid-downstream flowing through major cities in warm and low-runoff August,some river segments even acted as an atmospheric CO_(2) sink.The noteworthy is wastewater input leading to a sudden increase in DIC(>55 mg L^(-1))and pCO_(2)(>4500μatm)in the downstream of Taiyuan City,and in cold November the increased DIC even extended to the outlet of the river.Our results highlight the effects of aquatic production induced by damming and urban sewage input on riverine CO_(2) system in semi-arid areas,and reducing sewage discharge may mitigate CO_(2) emission from the rivers.

Assessment of CH_(4) flux and its influencing drivers in the rice-wheat agroecosystem of the Huai River Basin,China

To understand the CH_(4) flux variations and their climatic drivers in the rice-wheat agroecosystem in the Huai River Basin of China,the CH_(4) flux was observed by using open-path eddy covariance at a typical rice-wheat rotation system in Anhui Province,China from November 2019 to October 2021.The variations and their drivers were then analyzed with the Akaike information criterion method.CH_(4) flux showed distinct diurnal variations with single peaks during 9:00-13:00 local time.The highest peak was 2.15μg m^(-2)s^(-1)which occurred at 11:00 in the vegetative growth stage in the rice growing season(RGS).CH_(4) flux also showed significant seasonal variations.The average CH_(4)flux in the vegetative growth stage in the RGS(193.8±74.2 mg m^(-2)d^(-1))was the highest among all growth stages.The annual total CH_(4) flux in the non-rice growing season(3.2 g m^(-2))was relatively small compared to that in the RGS(23.9 g m^(-2)).CH_(4) flux increased significantly with increase in air temperature,soil temperature,and soil water content in both the RGS and the non-RGS,while it decreased significantly with increase in vapor pressure deficit in the RGS.This study provided a comprehensive understanding of the CH_(4) flux and its drivers in the rice-wheat rotation agroecosystem in the Huai River Basin of China.In addition,our findings will be helpful for the validation and adjustment of the CH_(4) models in this region.

Control of Earth system evolution on the formation and enrichment of marine ultra-deep petroleum in China

Taking the Paleozoic of the Sichuan and Tarim basins in China as example,the controlling effects of the Earth system evolution and multi-spherical interactions on the formation and enrichment of marine ultra-deep petroleum in China have been elaborated.By discussing the development of“source-reservoir-seal”controlled by the breakup and assembly of supercontinents and regional tectonic movements,and the mechanisms of petroleum generation and accumulation controlled by temperature-pressure system and fault conduit system,Both the South China and Tarim blocks passed through the intertropical convergence zone(ITCZ)of the low-latitude Hadley Cell twice during their drifts,and formed hydrocarbon source rocks with high quality.It is proposed that deep tectonic activities and surface climate evolution jointly controlled the types and stratigraphic positions of ultra-deep hydrocarbon source rocks,reservoirs,and seals in the Sichuan and Tarim basins,forming multiple petroleum systems in the Ediacaran-Cambrian,Cambrian-Ordovician,Cambrian-Permian and Permian-Triassic strata.The matching degree of source-reservoir-seal,the type of organic matter in source rocks,the deep thermal regime of basin,and the burial-uplift process across tectonic periods collectively control the entire process from the generation to the accumulation of oil and gas.Three types of oil and gas enrichment models are formed,including near-source accumulation in platform marginal zones,distant-source accumulation in high-energy beaches through faults,and three-dimensional accumulation in strike-slip fault zones,which ultimately result in the multi-layered natural gas enrichment in ultra-deep layers of the Sichuan Basin and co-enrichment of oil and gas in the ultra-deep layers of the Tarim Basin.

Impacts of multi-scenario land use change on ecosystem services and ecological security pattern: A case study of the Yellow River Delta

The Yellow River Delta(YRD), a critical economic zone along China's eastern coast, also functions as a vital ecological reserve in the lower Yellow River. Amidst rapid industrialization and urbanization, the region has witnessed significant land use/cover changes(LUCC), impacting ecosystem services(ES) and ecological security patterns(ESP). Investigating LUCC's effects on ES and ESP in the YRD is crucial for ecological security and sustainable development. This study utilized the PLUS model to simulate 2030 land use scenarios, including natural development(NDS), economic development(EDS), and ecological protection scenarios(EPS). Subsequently, the InVEST model and circuit theory were applied to assess ES and ESP under varying LUCC scenarios from 2010 to 2030. Findings indicate:(1) Notable LUCC from 2010 to 2030, marked by decreasing cropland and increasing construction land and water bodies.(2) From 2010 to 2020, improvements were observed in carbon storage,water yield, soil retention, and habitat quality, whereas 2020–2030 saw increases in water yield and soil retention but declines in habitat quality and carbon storage. Among the scenarios, EPS showed superior performance in all four ES.(3) Between 2010 and 2030, ecological sources, corridors, and pinchpoints expanded, displaying significant spatial heterogeneity. The EPS scenario yielded the most substantial increases in ecological sources,corridors, and pinchpoints, totaling 582.89 km^(2), 645.03 km^(2),and 64.43 km^(2), respectively. This study highlights the importance of EPS, offering insightful scientific guidance for the YRD's sustainable development.

Impact of Tethyan domain evolution on the formation of petroleum systems in the Sichuan super basin,SW China

Based on the“unidirectional break-up and convergence”geodynamic model,this study investigates the impact of the evolution of the Tethyan domain on the formation of petroleum systems in the Sichuan super basin and explores the enrichment pattern of natural gas.The results show that,firstly,the Sichuan Basin and its surrounding areas have experienced two unidirectional rifting-aggregation cycles triggered by the Proto-Tethys Ocean and the Paleo-Tethys Ocean during the Neoproterozoic to Triassic.During Jurassic–Cenozoic,the Sichuan Basin is incorporated in the circum-Tibetan plateau basin-mountain coupled tectonic domain system.The episodic tectonic movements within the plate control the sedimentary infill styles.Second,the evolution of the Tethyan domain,paleoclimatic environment and major geological events controlled the formation and distribution of high-quality source rocks within the basin.The rift valley and intracratonic rift,passive continental margin slope,and intracratonic sags are favorable areas for the development of source rocks.Third,the evolution of the Tethyan domain,supercontinent cycles,global sea level changes,and tectono-climatic events controlled the distribution of carbonate platform and reservoir-caprock combinations.The cratonic platform margins and sub-platform internal high terrains are key areas for finding carbonate high-energy facies belts.Syndepositional paleo-uplifts and surrounding slopes,regional unconformities,and later faults zone are areas where large-scale carbonate reservoirs are distributed.The regional evaporite or shale caprock are beneficial for the large-scale preservation of oil and gas in the basin.Fourth,the spatio-temporal matching relationship of reservoir forming factors influenced by the early tectonic-sedimentary evolution pattern and the degree of later tectonic modification is the key to oil and gas enrichment.Future oil and gas exploration should focus on potential gas systems during the Sinian rift period,Cambrian pre-salt gas systems in the eastern and southern Sichuan,as well as whole oil and gas systems of Permian and Triassic.

Hydrogeochemical Characterization of Aquifer Systems and Surface Water/Groundwater Relations in the Lower Senegal River Valley

This study assesses the chemical quality of water resources in the Lower Senegal River valley, based on 35 samples collected in November 2022. Major ion concentrations in surface water and groundwater were analyzed using classical geochemical interpretation diagrams (Piper, GIBBS, etc.) and multivariate geostatistical analyses, including hierarchical cluster analysis (HCA) and principal component analysis (PCA). The results revealed three types of facies: Ca-Mg-HCO3-type facies, characteristic of poorly mineralized waters such as surface waters and groundwater from dune formations and the alluvial plain close to the hydraulic axis;Na-Cl type facies associated with well waters located in the alluvial plain that tap Inchirian or Nouakchottian shallow reservoirs and Maastrichtian deep borehole waters;and mixed Ca-Cl and Na-HCO3 type facies observed in certain floodplain and dune reservoirs. The results showed a strong correlation between sodium, chlorides, bromides, and electrical conductivity, indicating a significant contribution of these ions to groundwater mineralization. The various sources of water mineralization include mixing processes between surface water or rainwater, or calcite or dolomite dissolution processes (for weakly mineralized waters), basic exchanges or inverse basic exchanges between the aquifer and the water table (for moderately mineralized waters), and evaporation processes, halite dissolution, and paleosalinity during periods of marine transgression and regression (for highly mineralized waters). The study also highlighted the high vulnerability of the alluvial aquifer to pollution from intensive irrigated agriculture, as significant quantities of sulfates and nitrates were measured in some samples. These results also highlight the importance of water quality management in the Lower Senegal Valley, particularly as concerns the protection of the alluvial aquifer against pollution from irrigated agriculture.

Spatiotemporal Characteristics of Typical Ecosystem Services and Their Spatial Responses to Driving Factors in Ecologically Fragile Areas in Upper Yellow River,China

The identification of dominant driving factors for different ecosystem services(ESs)is crucial for ecological conservation and sustainable development.However,the spatial heterogeneity of the dominant driving factors affecting various ESs has not been adequately elucidated,particularly in ecologically fragile regions.This study employed the integrated valuation of ESs and trade-offs(InVEST)model to evaluate four ESs,namely,water yield(WY),soil conservation(SC),habitat quality(HQ),and carbon storage(CS),and then to identify the dominant driving factors of spatiotemporal differentiation of ES and further to characterize the spatial heterogeneity characteristics of the dominant driving factors in the eco-fragile areas of the upper Yellow River,China from 2000 to 2020.The results demonstrated that WY exhibited northeast-high and northwest-low patterns in the upper Yellow River region,while high values of SC and CS were distributed in central forested areas and a high value of HQ was distributed in vast grassland areas.The CS,WY,and SC exhibited decreasing trends over time.The most critical factors affecting WY,SC,HQ,and CS were the actual evapotranspiration,precipitation,slope,and normalized difference vegetation index,respectively.In addition,the effects of different factors on various ESs exhibited spatial heterogeneity.These results could provide spatial decision support for eco-protection and rehabilitation in ecologically fragile areas.

Spatiotemporal evolution of water conservation function and its driving factors in the Huangshui River Basin, China

The Grain for Green project has had a substantial influence on water conservation in the Huangshui River Basin,China through afforestation and grassland restoration over the past two decades.However,a comprehensive understanding of the spatiotemporal evolution of water conservation function and its driving factors remains incomplete in this basin.In this study,we utilized the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST)model to examine the spatiotemporal evolution of water conservation function in the Huangshui River Basin from 2000 to 2020.Additionally,we employed the random forest model,Pearson correlation analysis,and geographical detector(Geodetector)techniques to investigate the primary factors and factor interactions affecting the spatial differentiation of water conservation function.The findings revealed several key points.First,the high-latitude northern region of the study area experienced a significant increase in water conservation over the 21-a period.Second,the Grain for Green project has played a substantial role in improving water conservation function.Third,precipitation,plant available water content(PAWC),grassland,gross domestic product(GDP),and forest land were primary factors influencing the water conservation function.Finally,the spatial differentiation of water conservation function was determined by the interactions among geographical conditions,climatic factors,vegetation biophysical factors,and socio-economic factors.The findings have significant implications for advancing ecological protection and restoration initiatives,enhancing regional water supply capabilities,and safeguarding ecosystem health and stability in the Huangshui River Basin.

Response of ecosystem carbon storage to land use change from 1985 to 2050 in the Ningxia Section of Yellow River Basin,China

Regional sustainable development necessitates a holistic understanding of spatiotemporal variations in ecosystem carbon storage(ECS),particularly in ecologically sensitive areas with arid and semi-arid climate.In this study,we calculated the ECS in the Ningxia Section of Yellow River Basin,China from 1985 to 2020 using the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST)model based on land use data.We further predicted the spatial distribution of ECS in 2050 under four land use scenarios:natural development scenario(NDS),ecological protection scenario(EPS),cultivated land protection scenario(CPS),and urban development scenario(UDS)using the patch-generating land use simulation(PLUS)model,and quantified the influences of natural and human factors on the spatial differentiation of ECS using the geographical detector(Geodetector).Results showed that the total ECS of the study area initially increased from 1985 until reaching a peak at 402.36×10^(6) t in 2010,followed by a decreasing trend to 2050.The spatial distribution of ECS was characterized by high values in the eastern and southern parts of the study area,and low values in the western and northern parts.Between 1985 and 2020,land use changes occurred mainly through the expansion of cultivated land,woodland,and construction land at the expense of unused land.The total ECS in 2050 under different land use scenarios(ranked as EPS>CPS>NDS>UDS)would be lower than that in 2020.Nighttime light was the largest contributor to the spatial differentiation of ECS,with soil type and annual mean temperature being the major natural driving factors.Findings of this study could provide guidance on the ecological construction and high-quality development in arid and semi-arid areas.

Geomorphological Evolution and Fluvial System Development during the Holocene: The Case of Vouraikos River Evolution in Kalavrita Plain, Northern Peloponnese, Greece

Fluvial geomorphology is affected by physical conditions which allow its adaptation due to high dynamics and environmental influences. Fluvial morphological changes are manifested as a result of tendency of the river system to maintain its physical balance. Our study area is the upper and middle flow part of Vouraikos river and surrounding area, near the NW border of Chelmos mountain in Northern Peloponnese, near the town of Kalavrita, at an altitude of 800 m. The area is part of the Skepasto basin, constituting of a graben with a general E-W direction that was developed NW of Kalavrita. The area comprises of Mesozoic, Upper Triassic-Jurassic limestone and dolomite of the Tripolitsa unit External Hellenides and Plio-Pleistocene fluvio-lacustrine sequences, while its tectonic structure is characterized mainly by normal faults. The geomorphological landscape is characterized by alluvial deposits and important geomorphological features including fluvial terraces, alluvial fans, fluvial scarps and their main rill washes. This area has been a place of major human activity as shown by the findings of many uncovered artifacts and a settlement. Through a paleographic reconstruction, detailed field investigations, in combination with the compilation of geomorphological maps using GIS software and archaeological evidence found in the area, we attempted to reconstruct the fluvial evolution of Vouraikos river and identify the major geomorphological factors that led to, and influenced it. Finally, the link between cultural activities and sedimentary processes is also studied. The recorded environmental variations had a great impact on the geomorphological shaping and instability of Kalavrita plain and Vouraikos river and are being reflected on the buried settlement. Sediment fluxes were high enough to form strath terraces, while local tectonics aided in the strath and fill terrace creation. Smaller and younger strath terraces, formed during increased sediment supply periods, when the valley was at a higher level.

Uphill or downhill?Cropland use change and its drivers from the perspective of slope spectrum

The continuous decrease of low-slope cropland resources caused by construction land crowding poses huge threat to regional sustainable development and food security.Slope spectrum analysis of topographic and geomorphic features is considered as a digital terrain analysis method which reflects the macro-topographic features by using micro-topographic factors.However,pieces of studies have extended the concept of slope spectrum in the field of geoscience to construction land to explore its expansion law,while research on the slope trend of cropland from that perspective remains rare.To address the gap,in virtue of spatial analysis and geographically weighted regression(GWR)model,the cropland use change in the Yangtze River Basin(YRB)from 2000 to 2020 was analyzed and the driving factors were explored from the perspective of slope spectrum.Results showed that the slope spectrum curves of cropland area-frequency in the YRB showed a first upward then a downward trend.The change curve of the slope spectrum of cropland in each province(municipality)exhibited various distribution patterns.Quantitative analysis of morphological parameters of cropland slope spectrum revealed that the further down the YRB,the stronger the flattening characteristics,the more obvious the concentration.The province experienced the greatest downhill cropland climbing(CLC)was Shannxi,while province experienced the highest uphill CLC was Zhejiang.The most common cropland use change type in the YRB was horizontal expansion type.The factors affecting average cropland climbing index(ACCI)were quite stable in different periods,while population density(POP)changed from negative to positive during the study period.This research is of practical significance for the rational utilization of cropland at the watershed scale.

Microwave shock motivating the Sr substitution of 2D porous GdFeO_(3) perovskite for highly active oxygen evolution

The incorporation of partial A-site substitution in perovskite oxides represents a promising strategy for precisely controlling the electronic configuration and enhancing its intrinsic catalytic activity.Conventional methods for A-site substitution typically involve prolonged high-temperature processes.While these processes promote the development of unique nanostructures with highly exposed active sites,they often result in the uncontrolled configuration of introduced elements.Herein,we present a novel approach for synthesizing two-dimensional(2D)porous GdFeO_(3) perovskite with A-site strontium(Sr)substitution utilizing microwave shock method.This technique enables precise control of the Sr content and simultaneous construction of 2D porous structures in one step,capitalizing on the advantages of rapid heating and cooling(temperature~1100 K,rate~70 K s^(-1)).The active sites of this oxygen-rich defect structure can be clearly revealed through the simulation of the electronic configuration and the comprehensive analysis of the crystal structure.For electrocatalytic oxygen evolution reaction application,the synthesized 2D porous Gd_(0.8)Sr_(0.2)FeO_(3) electrocatalyst exhibits an exceptional overpotential of 294 mV at a current density of 10 mA cm^(-2)and a small Tafel slope of 55.85 mV dec^(-1)in alkaline electrolytes.This study offers a fresh perspective on designing crystal configurations and the construction of nanostructures in perovskite.

Strong metal–support interaction boosts the electrocatalytic hydrogen evolution capability of Ru nanoparticles supported on titanium nitride

Ruthenium(Ru)has been regarded as one of the most promising alternatives to substitute Pt for catalyzing alkaline hydrogen evolution reaction(HER),owing to its inherent high activity and being the cheapest platinum-group metal.Herein,based on the idea of strong metal–support interaction(SMSI)regulation,Ru/TiN catalysts with different degrees of TiN overlayer over Ru nanoparticles were fabricated,which were applied to the alkaline electrolytic water.Characterizations reveal that the TiN overlayer would gradually encapsulate the Ru nanoparticles and induce more electron transfer from Ru nanoparticles to TiN support by the Ru–N–Ti bond as the SMSI degree increased.Further study shows that the exposed Ru–TiN interfaces greatly promote the H_(2) desorption capacity.Thus,the Ru/TiN-300 with a moderate SMSI degree exhibits excellent HER performance,with an overpotential of 38 mV at 10 mA cm^(−2).Also,due to the encapsulation role of TiN overlayer on Ru nanoparticles,it displays super long-term stability with a very slight potential change after 24 h.This study provides a deep insight into the influence of the SMSI effect between Ru and TiN on HER and offers a novel approach for preparing efficient and stable HER electrocatalysts through SMSI engineering.

Monitoring and evaluation of the water quality of the Lower Neches River, Texas, USA

Increasing bacteria levels in the Lower Neches River caused by Hurricane Harvey has been of a serious concern.This study is to analyze the historical water sampling measurements and real-time water quality data collected with wireless sensors to monitor and evaluate water quality under different hydrological and hydraulic conditions.The statistical and Pearson correlation analysis on historical water samples determines that alkalinity,chloride,hardness,conductivity,and pH are highly correlated,and they decrease with increasing flow rate due to dilution.The flow rate has positive correlations with Escherichia coli,total suspended solids,and turbidity,which demonstrates that runoff is one of the causes of the elevated bacteria and sediment loadings in the river.The correlation between E.coli and turbidity indicates that turbidity greater than 45 nephelometric turbidity units in the Neches River can serve as a proxy for E.coli to indicate the bacterial outbreak.A series of statistical tools and an innovative two-layer data smoothing filter are developed to detect outliers,fill missing values,and filter spikes of the sensor measurements.The correlation analysis on the sensor data illustrates that the elevated sediment/bacteria/algae in the river is either caused by the first flush rain and heavy rain events in December to March or practices of land use and land cover.Therefore,utilizing sensor measurements along with rainfall and discharge data is recommended to monitor and evaluate water quality,then in turn to provide early alerts on water resources management decisions.