Preparation of Cellulose Acetate Butyrate Porous Micro/Nanofibrous Membranes and Their Properties

Cellulose acetate butyrate(CAB)is a cellulose ester that is commonly used in applications such as coatings and leather brighteners.However,its appearance in a fibrous form is rarely reported.CAB porous micro/nanofibrous membranes with a large number of nanopores on the fiber surface were successfully prepared by electrospinning with dichloromethane(DCM)/acetone(AC)as the mixed solvent.Apparent morphology,porosity,moisture permeability,air permeability,static water contact angles,and thermal conductivity of the fibrous membranes were investigated at different spinning voltages.The results showed that with the increase of the spinning voltage,the average fiber diameter of the CAB porous micro/nanofibrous membranes gradually decreased and the fiber diameter distribution was more uniform.When the spinning voltage reached 40 kV,the porosity reached 91.38%,the moisture permeability was up to 7430 g/(m^(2)·d),the air permeability was up to 36.289 mm/s,the static water contact angle was up to 145.0°,while the thermal conductivity of the fibrous membranes reached 0.030 W/(m·K).The material can be applied as thermal-insulation,waterproof and moisture-permeable membranes.

A novel tunnel waterproof-drainage system based on double-bonded waterproofing materials and its seepage characteristics

Double-bonded spray membrane waterproofing materials have excellent waterproofing performance and can improve the load-bearing capacity of tunnel linings,leading to an increasing global application.However,due to the double-bonded capability of spray membrane materials,traditional interlayer drainage methods cannot be applied.This limitation makes it difficult to use them in drainage-type tunnels,significantly restricting their range of applications.In this regard,a novel tunnel waterproof-drainage system based on double-bonded spray membrane materials was proposed in this paper.The proposed drainage system primarily comprises upper drainage sheets and bottom drainage blind pipes,both located in the tunnel circumferential direction,as well as longitudinal drainage pipes within the tunnel.Subsequently,numerical calculation methods are employed to analyze the seepage characteristics of this system,revealing the water pressure distribution around the tunnel.The results indicate that in the novel waterproof-drainage system,the water pressure in the secondary lining exhibits a“mushroom-shaped”distribution in the circumferential direction,while the water pressure in the longitudinal direction exhibits a“wave-like”distribution.Furthermore,comparative results with other waterproof-drainage systems indicate that under typical working conditions with a water head of 160 m and a rock permeability coefficient of 10^(−6)m/s,the maximum water pressure in the secondary lining of the novel waterproof-drainage system is 0.6 MPa.This represents a significant reduction compared to fully encapsulated waterproofing and traditional drainage systems,which respectively reduce the water pressure by 65%and 30%.The applicability analysis of the double-bonded waterproofing and drainage system reveals that it can reduce at least 40%of the static water pressure in any groundwater environments.The novel drainage system provides a valuable reference for the application of double-bonded spray membrane waterproofing materials in drainage-type tunnels.

Numerical analysis and capacity evaluation of composite sprayed concrete lined tunnels

Spray-applied membranes for waterproofing of sprayed concrete tunnels have led to the possibility of shear transfer between primary and secondary linings through the membrane interface,with the potential for reducing overall lining thickness.Laboratory tests have shown a reasonable degree of composite action in beam specimens.In this study,a numerical model previously calibrated against such tests is applied to a whole tunnel,considering soil–structure interaction and staged lining construction.The model shows composite action,and load sharing between the lining layers is expected in the tunnel as in the beams.Parametric studies over the practical range of interface stiffness values show that composite action is maintained,although at high interface stiffness,excessive bending may be imposed on the secondary lining,requiring additional reinforcement.An effcient composite shell design with minimal additional rein-forcement is achievable if the secondary lining thickness is reduced as compared to current practice.Robustness of the system,measured in terms of the interface’s ability to transfer stress under unequal loading causing distortion on the tunnel,is found to be generally ade-quate.However,adjacent construction in close proximity may provide insuffcient margin on membrane tensile de-bonding,particularly if the membrane is partially or fully saturated.