为了阐明裸子植物中纤维素与木素之间的连接方式,从多糖的角度分析糖单元与木素苯丙烷结构单元之间的共价键连接方式,合成了带6-13 C标记的纤维素前驱物尿苷二磷酸葡萄糖,并将其与PAL酶的抑制剂AOPP及外源性木素前驱物松柏醇-β-D-葡萄...为了阐明裸子植物中纤维素与木素之间的连接方式,从多糖的角度分析糖单元与木素苯丙烷结构单元之间的共价键连接方式,合成了带6-13 C标记的纤维素前驱物尿苷二磷酸葡萄糖,并将其与PAL酶的抑制剂AOPP及外源性木素前驱物松柏醇-β-D-葡萄糖苷一起投入生长中的银杏植物体内。碳13丰度检测得知纤维素在细胞壁的沉积主要是从在初生壁开始,高分辨率固体核磁13 C NMR分析证实了纤维素6位碳与木素以苯甲醚键等方式连接。展开更多
Coalification temperatures are often considered to be approximately 100-170 ℃ for bituminous coal and 170-275 ℃ for anthracite. However, our micropetrographic observations, solid state ^27Al magic-angle spinning nuc...Coalification temperatures are often considered to be approximately 100-170 ℃ for bituminous coal and 170-275 ℃ for anthracite. However, our micropetrographic observations, solid state ^27Al magic-angle spinning nuclear magnetic resonance measurements, interpretation of δ^13C values for whewellite in pelosiderite concretions from Carboniferous sediments, and assessment of whewellite thermal stability show that coalification temperatures can be significantly lower. Also the temperatures of coal alteration may be substantially lower than is stated. Ordinarily, high- temperature alteration is reported, but microthermometric measurements of fluids temperatures and micropetrographic observations show that the coal alteration can take place at low temperatures. For this reason, coals from the Kladno- Rakovnik Basin, part of Late Paleozoic continental basins of the Czech Republic, were analyzed. Regarding coalification, micropetrographic characterizations of unaltered coals, the presence of thermally unstable Al complexes in the coal organic mass documented using ^27Al MAS NMR method, and proven occurrence of whewellite in pelosiderite concretions suggest a lower coalification temperature, max. -70 ℃. Regarding coal alteration, micropetrographic observations revealed （a） the weaker intensity of fluorescence of liptinite, （b） mylonitic structures and microbreccia with carbonate fluid penetration, and （c） high oxygen content in coals （37-38 wt.%）. These phenomena are typical for thermal and oxidative alteration of coal. As the temperature of carbonate fluids inferred from fluid inclusion analysis was evaluated as -100-113 ℃, the temperature of coal alteration was suggested as -113℃; the alteration was caused by hot hydrothermal fluids.展开更多
The humic acids (HAs) isolated from the sediments of the various rivers,lakes,and reservoirs in China were studied using elemental analyzer,fourier transform infrared (FT-IR),and CP/MAS 13C nuclear magnetic resonance ...The humic acids (HAs) isolated from the sediments of the various rivers,lakes,and reservoirs in China were studied using elemental analyzer,fourier transform infrared (FT-IR),and CP/MAS 13C nuclear magnetic resonance (NMR) spectroscopy.The results showed that the HAs were characterized by some common chemical and physicochemical properties,but they also pose some differences in the C-containing functional groups.The C/N,C/H,O/C,and O/H ratios differ widely for the various HAs,showing that the elemental comp...展开更多
文摘为了阐明裸子植物中纤维素与木素之间的连接方式,从多糖的角度分析糖单元与木素苯丙烷结构单元之间的共价键连接方式,合成了带6-13 C标记的纤维素前驱物尿苷二磷酸葡萄糖,并将其与PAL酶的抑制剂AOPP及外源性木素前驱物松柏醇-β-D-葡萄糖苷一起投入生长中的银杏植物体内。碳13丰度检测得知纤维素在细胞壁的沉积主要是从在初生壁开始,高分辨率固体核磁13 C NMR分析证实了纤维素6位碳与木素以苯甲醚键等方式连接。
文摘Coalification temperatures are often considered to be approximately 100-170 ℃ for bituminous coal and 170-275 ℃ for anthracite. However, our micropetrographic observations, solid state ^27Al magic-angle spinning nuclear magnetic resonance measurements, interpretation of δ^13C values for whewellite in pelosiderite concretions from Carboniferous sediments, and assessment of whewellite thermal stability show that coalification temperatures can be significantly lower. Also the temperatures of coal alteration may be substantially lower than is stated. Ordinarily, high- temperature alteration is reported, but microthermometric measurements of fluids temperatures and micropetrographic observations show that the coal alteration can take place at low temperatures. For this reason, coals from the Kladno- Rakovnik Basin, part of Late Paleozoic continental basins of the Czech Republic, were analyzed. Regarding coalification, micropetrographic characterizations of unaltered coals, the presence of thermally unstable Al complexes in the coal organic mass documented using ^27Al MAS NMR method, and proven occurrence of whewellite in pelosiderite concretions suggest a lower coalification temperature, max. -70 ℃. Regarding coal alteration, micropetrographic observations revealed （a） the weaker intensity of fluorescence of liptinite, （b） mylonitic structures and microbreccia with carbonate fluid penetration, and （c） high oxygen content in coals （37-38 wt.%）. These phenomena are typical for thermal and oxidative alteration of coal. As the temperature of carbonate fluids inferred from fluid inclusion analysis was evaluated as -100-113 ℃, the temperature of coal alteration was suggested as -113℃; the alteration was caused by hot hydrothermal fluids.
基金the National Basic Research Program (973) of China (No.2004CB418502,2003CB415002)the National Natural Science Foundation of China (No.29977002).
文摘The humic acids (HAs) isolated from the sediments of the various rivers,lakes,and reservoirs in China were studied using elemental analyzer,fourier transform infrared (FT-IR),and CP/MAS 13C nuclear magnetic resonance (NMR) spectroscopy.The results showed that the HAs were characterized by some common chemical and physicochemical properties,but they also pose some differences in the C-containing functional groups.The C/N,C/H,O/C,and O/H ratios differ widely for the various HAs,showing that the elemental comp...
