Complex Cobalt(III) di[N-(p-methyl)phenyl-2 -pyridinecarboxamide] dihydrate chloride [Co(p-Me-PPA)2(H2O)2] Cl hadbeen synthesised. The single crystal strUcture of the metal complex had been successfully prepared and d...Complex Cobalt(III) di[N-(p-methyl)phenyl-2 -pyridinecarboxamide] dihydrate chloride [Co(p-Me-PPA)2(H2O)2] Cl hadbeen synthesised. The single crystal strUcture of the metal complex had been successfully prepared and determined by fourcircle single crystal diffractometer. When the oxidation of cyclohexene was catalyzed by [Co(p-Me-PPA)2(H2O)2]Cl withmolecular oxygen as oxidant, the conversion reached 59% , the selectivity of cyclohexenone being 75%.展开更多
文摘Complex Cobalt(III) di[N-(p-methyl)phenyl-2 -pyridinecarboxamide] dihydrate chloride [Co(p-Me-PPA)2(H2O)2] Cl hadbeen synthesised. The single crystal strUcture of the metal complex had been successfully prepared and determined by fourcircle single crystal diffractometer. When the oxidation of cyclohexene was catalyzed by [Co(p-Me-PPA)2(H2O)2]Cl withmolecular oxygen as oxidant, the conversion reached 59% , the selectivity of cyclohexenone being 75%.
