The similarity transformation model between different coordinate systems is not accurate enough to describe the discrepancy of them.Therefore,the coordinate transformation from the coordinate frame with poor accuracy ...The similarity transformation model between different coordinate systems is not accurate enough to describe the discrepancy of them.Therefore,the coordinate transformation from the coordinate frame with poor accuracy to that with high accuracy cannot guarantee a high precision of transformation.In this paper,a combined method of similarity transformation and regressive approximating is presented.The local error accumulation and distortion are taken into consideration and the precision of coordinate system is improved by using the recommended method展开更多
Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites...Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites with atomically dispersed oxygen(O)coordination on bacterial cellulose-converted graphitic carbon(Mn-O-C).Evidence of the atomically dispersed Mn-(O-C_(2))_(4)moieties embedding in the exposed basal plane of carbon surface is confirmed by X-ray absorption spectroscopy.As a result,the as-synthesized Mn-O-C catalyst exhibits superior NitRR activity with an NH_(3)yield rate(RNH_(3))of 1476.9±62.6μg h^(−1)cm^(−2)at−0.7 V(vs.reversible hydrogen electrode,RHE)and a faradaic efficiency(FE)of 89.0±3.8%at−0.5 V(vs.RHE)under ambient conditions.Further,when evaluated with a practical flow cell,Mn-O-C shows a high RNH_(3)of 3706.7±552.0μg h^(−1)cm^(−2)at a current density of 100 mA cm−2,2.5 times of that in the H cell.The in situ FT-IR and Raman spectroscopic studies combined with theoretical calculations indicate that the Mn-(O-C_(2))_(4)sites not only effectively inhibit the competitive hydrogen evolution reaction,but also greatly promote the adsorption and activation of nitrate(NO_(3)^(−)),thus boosting both the FE and selectivity of NH_(3)over Mn-(O-C_(2))_(4)sites.展开更多
Using a new tortoise coordinate transformation, this paper investigates the Hawking effect from an arbitrarily accelerating charged black hole by the improved Damour-Ruffini method. After the tortoise coordinate trans...Using a new tortoise coordinate transformation, this paper investigates the Hawking effect from an arbitrarily accelerating charged black hole by the improved Damour-Ruffini method. After the tortoise coordinate transformation, the Klein-Gordon equation can be written as the standard form at the event horizon. Then extending the outgoing wave from outside to inside of the horizon analytically, the surface gravity and Hawking temperature can be obtained automatically. It is found that the Hawking temperatures of different points on the surface are different. The quantum nonthermal radiation characteristics of a black hole near the event horizon is also discussed by studying the Hamilton-Jacobi equation in curved spacetime and the maximum overlap of the positive and negative energy levels near the event horizon is given. There is a dimensional problem in the standard tortoise coordinate and the present results may be more reasonable.展开更多
When linearizing three-dimensional(3 D)coordinate similarity transformation model with large rotations,we usually encounter the ill-posed normal matrix which may aggravate the instability of solutions.To alleviate the...When linearizing three-dimensional(3 D)coordinate similarity transformation model with large rotations,we usually encounter the ill-posed normal matrix which may aggravate the instability of solutions.To alleviate the problem,a series of conversions are contributed to the 3 D coordinate similarity transformation model in this paper.We deduced a complete solution for the 3 D coordinate similarity transformation at any rotation with the nonlinear adjustment methodology,which involves the errors of the common and the non-common points.Furthermore,as the large condition number of the normal matrix resulted in an intractable form,we introduced the bary-centralization technique and a surrogate process for deterministic element of the normal matrix,and proved its benefit for alleviating the condition number.The experimental results show that our approach can obtain the smaller condition number to stabilize the convergence of the interested parameters.Especially,our approach can be implemented for considering the errors of the common and the non-common points,thus the accuracy of the transformed coordinates improves.展开更多
Coordinate transformation parameters between two spatial Cartesian coordinate systems can be solved from the positions of non-colinear corresponding points. Based on the characteristics of translation, rotation and zo...Coordinate transformation parameters between two spatial Cartesian coordinate systems can be solved from the positions of non-colinear corresponding points. Based on the characteristics of translation, rotation and zoom components of the transformation, the complete solution is divided into three steps. Firstly, positional vectors are regulated with respect to the centroid of sets of points in order to separate the translation compo- nents. Secondly, the scale coefficient and rotation matrix are derived from the regulated positions independent- ly and correlations among transformation model parameters are analyzed. It is indicated that this method is applicable to other sets of non-position data to separate the respective attributions for transformation parameters.展开更多
Most surveying works for mapping or GIS applications are performed with total station. Due to the remote nature of many of the sites surveyed, the surveys are often done in unprojected, local, assumed coordinate syste...Most surveying works for mapping or GIS applications are performed with total station. Due to the remote nature of many of the sites surveyed, the surveys are often done in unprojected, local, assumed coordinate systems. However, without the survey data projected in real world coordinates, the range of possible analyses is limited and the value of existing imagery, elevation models, and hydrologic layers cannot be exploited. This requires a transformation from the local assumed to the real world coordinate systems. There are various built-in and add-in tools to perform transformations through GIS programs. This paper studies the effect of using Georeferencing tool, Spatial Adjustment tool (Affine and similarity) and CHaMP tool on the precision and relative accuracy of total station survey. This transformation requires real-world coordinates of at least two control points, which can be collected from different sources. This paper also studies the effect of using geodetic GPS, hand-held GPS, Google Earth (GE) and Bing Basemaps as sources for control points on the precision and relative accuracy of total station survey. These effects have been tested by using 111 points covered area of 60,000 m2and the results have shown that the CHaMP tool is the best for preserving the relative accuracy of the transformed points. The Georeferencing and spatial adjustment (similarity) tools give the same results and their accuracy are between 1/1000 and 1/300 depending on the source of control points. The results have also shown that the cornerstone to preserve the precision and relative accuracy of the transformed coordinates is the relative position of the control points despite their source.展开更多
Three transformation models (Bursa-Wolf, Molodensky, and WTUSM) are generally used between two data systems transformation. The linear models are used when the rotation angles are small; however, when the rotation a...Three transformation models (Bursa-Wolf, Molodensky, and WTUSM) are generally used between two data systems transformation. The linear models are used when the rotation angles are small; however, when the rotation angles get bigger, model errors will be produced. In this paper, we present a method with three main terms:① the traditional rotation angles θ,φ,ψ are substituted with a,b,c which are three respective values in the anti-symmetrical or Lodrigues matrix; ② directly and accurately calculating the formula of seven parameters in any value of rotation angles; and ③ a corresponding adjustment model is established. This method does not use the triangle function. Instead it uses addition, subtraction, multiplication and division, and the complexity of the equation is reduced, making the calculation easy and quick.展开更多
With the increasing penetration of wind and solar energies,the accompanying uncertainty that propagates in the system places higher requirements on the expansion planning of power systems.A source-grid-load-storage co...With the increasing penetration of wind and solar energies,the accompanying uncertainty that propagates in the system places higher requirements on the expansion planning of power systems.A source-grid-load-storage coordinated expansion planning model based on stochastic programming was proposed to suppress the impact of wind and solar energy fluctuations.Multiple types of system components,including demand response service entities,converter stations,DC transmission systems,cascade hydropower stations,and other traditional components,have been extensively modeled.Moreover,energy storage systems are considered to improve the accommodation level of renewable energy and alleviate the influence of intermittence.Demand-response service entities from the load side are used to reduce and move the demand during peak load periods.The uncertainties in wind,solar energy,and loads were simulated using stochastic programming.Finally,the effectiveness of the proposed model is verified through numerical simulations.展开更多
Lithium-sulfur batteries(LSBs)are widely regarded as promising next-generation batteries due to their high theoretical specific capacity and low material cost.However,the practical applications of LSBs are limited by ...Lithium-sulfur batteries(LSBs)are widely regarded as promising next-generation batteries due to their high theoretical specific capacity and low material cost.However,the practical applications of LSBs are limited by the shuttle effect of lithium polysulfides(LiPSs),electronic insulation of charge and discharge products,and slow LiPSs conversion reaction kinetics.Accordingly,the introduction of catalysts into LSBs is one of the effective strategy to solve the issues of the sluggished LiPS conversion.Because of their nearly 100%atom utilization and high electrocatalytic activity,single-atom catalysts(SACs)have been widely used as reaction mediators for LSBs’reactions.Excitingly,the SACs with asymmetric coordination structures have exhibited intriguing electronic structures and superior catalytic activities when compared to the traditional M-N_(4)active sites.In this review,we systematically describe the recent advancements in the installation of asymmetrically coordinated single-atom structure as reactions catalysts in LSBs,including asymmetrically nitrogen coordinated SACs,heteroatom coordinated SACs,support effective asymmetrically coordinated SACs,and bimetallic coordinated SACs.Particularly noteworthy is the discussion of the catalytic conversion mechanism of LiPSs spanning asymmetrically coordinated SACs.Finally,a perspective on the future developments of asymmetrically coordinated SACs in LSB applications is provided.展开更多
River ice is a natural phenomenon in cold regions, influenced by meteorology, geomorphology, and hydraulic conditions. River ice processes involve complex interactions between hydrodynamic, mechanical, and thermal pro...River ice is a natural phenomenon in cold regions, influenced by meteorology, geomorphology, and hydraulic conditions. River ice processes involve complex interactions between hydrodynamic, mechanical, and thermal processes, and they are also influenced by weather and hydrologic conditions. Because natural rivers are serpentine, with bends, narrows, and straight reaches, the commonly-used one-dimensional river ice models and two-dimensional models based on the rectangular Cartesian coordinates are incapable of simulating the physical phenomena accurately. In order to accurately simulate the complicated river geometry and overcome the difficulties of numerical simulation resulting from both complex boundaries and differences between length and width scales, a two-dimensional river ice numerical model based on a boundary-fitted coordinate transformation method was developed. The presented model considers the influence of the frazil ice accumulation under ice cover and the shape of the leading edge of ice cover during the freezing process. The model is capable of determining the velocity field, the distribution of water temperature, the concentration distribution of frazil ice, the transport of floating ice, the progression, stability, and thawing of ice cover, and the transport, accumulation, and erosion of ice under ice cover. A MacCormack scheme was used to solve the equations numerically. The model was validated with field observations from the Hequ Reach of the Yellow River. Comparison of simulation results with field data indicates that the model is capable of simulating the river ice process with high accuracy.展开更多
3D printing techniques offer an effective method in fabricating complex radially multi-material structures.However,it is challenging for complex and delicate radially multi-material model geometries without supporting...3D printing techniques offer an effective method in fabricating complex radially multi-material structures.However,it is challenging for complex and delicate radially multi-material model geometries without supporting structures,such as tissue vessels and tubular graft,among others.In this work,we tackle these challenges by developing a polar digital light processing technique which uses a rod as the printing platform.The 3D model fabrication is accomplished through line projection.The rotation and translation of the rod are synchronized to project and illuminate the photosensitive material volume.By controlling the distance between the rod and the printing window,we achieved the printing of tubular structures with a minimum wall thickness as thin as 50 micrometers.By controlling the width of fine slits at the printing window,we achieved the printing of structures with a minimum feature size of 10 micrometers.Our process accomplished the fabrication of thin-walled tubular graft structure with a thickness of only 100 micrometers and lengths of several centimeters within a timeframe of just 100 s.Additionally,it enables the printing of axial multi-material structures,thereby achieving adjustable mechanical strength.This method is conducive to rapid customization of tubular grafts and the manufacturing of tubular components in fields such as dentistry,aerospace,and more.展开更多
Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was pr...Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was proposed for a wind-PVhydrogen-storage multi-agent energy system.First,a coordinated operation model was formulated for each agent considering peer-to-peer power trading.Second,a coordinated operation interactive framework for a multi-agent energy system was proposed based on the theory of the alternating direction method of multipliers.Third,a distributed interactive algorithm was proposed to protect the privacy of each agent and solve coordinated operation strategies.Finally,the effectiveness of the proposed coordinated operation method was tested on multi-agent energy systems with different structures,and the operational revenues of the wind power,PV,hydrogen,and energy storage agents of the proposed coordinated operation model were improved by approximately 59.19%,233.28%,16.75%,and 145.56%,respectively,compared with the independent operation model.展开更多
After implementing CGCS2000,establishing grid models for high-accuracy coordinate transformation which are mainly used to transform border lines and coordinate grids of topographic maps becomes an important issue in m...After implementing CGCS2000,establishing grid models for high-accuracy coordinate transformation which are mainly used to transform border lines and coordinate grids of topographic maps becomes an important issue in mapping applications.Consequently,a grid model for high-accuracy coordinate transformation of CGCS2000 is proposed.Specifically,we firstly analyze a minimum curvature equation of coordinate transformation,which possesses the characteristics of both the global and local smoothness,achieving better consistency with the consecutive smoothness for the coordinate transformation of map’s linear feature.Then an iterative calculation method of grid nodes and an approach for establishing regional grid models based on collocation by two-step minimization are proposed.Meanwhile,a data structure of grid model is constructed.Finally we give the optimized grid interval and transformation accuracy in China corresponding to the proposed grid model.Using 48 433 points of 2000 National Geodetic Control Network of China,we take the proposed model into practice by constructing grid models for coordinate transformation from BJS54 and XAS80 to CGCS2000,and the external positional accuracies for both models are 0.26 m and 0.03 m respectively.展开更多
Currently,the iron chromium redox flow battery(ICRFB)has become a research hotspot in the energy storage field owing to its low cost and easily-scaled-up.However,the activity of electrolyte is still ambiguous due to i...Currently,the iron chromium redox flow battery(ICRFB)has become a research hotspot in the energy storage field owing to its low cost and easily-scaled-up.However,the activity of electrolyte is still ambiguous due to its complicated solution environment.Herein,we performed a pioneering investigation on the coordination behavior and transformation mechanism of Cr^(3+)in electrolyte and prediction of impurity ions impact through quantum chemistry computations.Based on the structure and symmetry of electrostatic potential distribution,the activity of different Cr^(3+)complex ions is confirmed as[Cr(H2O)5Cl]^(2+)>[Cr(H2O)4Cl2]+>[Cr(H2O)6]^(3+).The transformation mechanism between[Cr(H2O)6]^(3+)and[Cr(H2O)5Cl]^(2+)is revealed.We find the metal impurity ions(especially Mg^(2+))can exacerbate the electrolyte deactivation by reducing the transformation energy barrier from[Cr(H2O)5Cl]^(2+)(24.38 kcal mol^(−1))to[Cr(H2O)6]^(3+)(16.23 kcal mol^(−1)).The solvent radial distribution and mean square displacement in different solvent environments are discussed and we conclude that the coordination configuration limits the diffusivity of Cr^(3+).This work provides new insights into the activity of electrolyte,laying a fundamental sense for the electrolyte in ICRFB.展开更多
Coordinative development across various systems,particularly the economic,social,cultural,and human resources subsystems,is a key aspect of urban sustainability and has a direct impact on the quality of urbanization.T...Coordinative development across various systems,particularly the economic,social,cultural,and human resources subsystems,is a key aspect of urban sustainability and has a direct impact on the quality of urbanization.The Hangzhou Metropolitan Circle,comprising Hangzhou City,Huzhou City,Jiaxing City,and Shaoxing City,was the first metropolitan circle approved by the National Development and Reform Commission(NDRC)as a demonstration of economic transformation in China.To evaluate the coupling coordination degree of the four cities and analyze the coordinative development in three systems(including digital economy,regional innovation,and talent employment),we collected panel data during 2015–2022 from these four cities.The development level of the three systems was evaluated by the standard deviation method and comprehensive development index.The results are as follows:(1)the level of coupling coordinated development of the three systems in the Hangzhou Metropolitan Circle was relatively low;(2)the coupling coordination degree of the four cities in the Hangzhou Metropolitan Circle showed significant regional differences,among which Hangzhou City was in the leading position,and Huzhou,Jiaxing,and Shaoxing cities made steady but slow progress in the coupling development of the three systems;and(3)the development of digital economy and talent employment needs to be strengthened.This study contributes to the coordinative development of Hangzhou Metropolitan Circle by innovatively focusing on the coupling coordination relationship among digital economy,regional innovation,and talent employment,which also meets the industrial layout of Hangzhou Metropolitan Circle.In this way,the optimal allocation and sustainable development of digital economy,regional innovation,and talent employment in the Hangzhou Metropolitan Circle can be achieved.展开更多
This paper primarily concerns the effective coordination of the procedures and methods employed in open pit mining operations under the background of river management.The central objective of this study is to identify...This paper primarily concerns the effective coordination of the procedures and methods employed in open pit mining operations under the background of river management.The central objective of this study is to identify a viable approach for ensuring rational and efficient development of open pit mineral resources while simultaneously protecting and restoring the ecological environment of the river.This approach should facilitate the realization of a harmonious symbiosis between mining and river management.The intricate mutual influence relationship between river management and open pit mining is first analyzed in depth,which provides a solid foundation for the subsequent coordination strategy development.In light of the aforementioned considerations,a set of coordination procedures for open pit mining based on river management conditions is proposed.These procedures emphasize the integration of river protection into the overall layout of mining at the planning stage.The implementation of scientific mining schemes,accompanied by rigorous control of the scope and depth of mining operations,has proven to be an effective means of reducing the impact of mining activities on river environments.This approach has also facilitated the achievement of a balance and coordination between mining and river management.展开更多
We give a proof of an explicit formula for affine coodinates of points in the Sato’s infinite Grassmannian corresponding to tau-functions for the KdV hierarchy.
The 3-dimension coordinate datum transformation is very important in geomatics.Generally,there are small angle coordinate transformation model (i.e.,Bursa model,et al) and large angle coordinate transformation model (...The 3-dimension coordinate datum transformation is very important in geomatics.Generally,there are small angle coordinate transformation model (i.e.,Bursa model,et al) and large angle coordinate transformation model (i.e.,Rodrigo matrix model,et al).However,these papers only focus on the fixed and static situation regardless of the small or large angle.This paper proposes the conception of coordinate transformation gradient field,which can realize the space coordinate transformation from small angle to arbitrary angle,and from static to dynamical.Based on the equivalent characteristics of the unit quaternion rotation matrix and the Rodrigo matrix,through studying the mathematical relationship between the spatial coordinate transformation and the functional gradient,we derive a functional gradient expression of the arbitrary transformation formula in space.The study shows that the essence of spatial coordinate transformation is a kind of potential field mathematically.This potential field conception can unify all the space coordinate transformations.It is the theoretical foundation for the further study of time continuous space coordinate transformation,and this study gives a new solution for the attitude determination of motion carriers.展开更多
A so called sine-sigma vertical coordinate transformation is proposed. A vertical implicit scheme is de-rived by using cubic-spline representation of vertical current profiles. The derived 3-D nurmericalmodel has been...A so called sine-sigma vertical coordinate transformation is proposed. A vertical implicit scheme is de-rived by using cubic-spline representation of vertical current profiles. The derived 3-D nurmericalmodel has been applied to simulate the water leved field and the vertical structures of wind-induced cur-rents in an enclosed rectangular region, and the tides in the Bohai Sea. The model is believed to besatisfactory after comparing its results with an analytical soclution and observed data from tidal staions.展开更多
文摘The similarity transformation model between different coordinate systems is not accurate enough to describe the discrepancy of them.Therefore,the coordinate transformation from the coordinate frame with poor accuracy to that with high accuracy cannot guarantee a high precision of transformation.In this paper,a combined method of similarity transformation and regressive approximating is presented.The local error accumulation and distortion are taken into consideration and the precision of coordinate system is improved by using the recommended method
基金the financial support from the Natural Science Foundation of China(Grant No.52172106)Anhui Provincial Natural Science Foundation(Grant Nos.2108085QB60 and 2108085QB61)China Postdoctoral Science Foundation(Grant Nos.2020M682057 and 2023T160651).
文摘Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites with atomically dispersed oxygen(O)coordination on bacterial cellulose-converted graphitic carbon(Mn-O-C).Evidence of the atomically dispersed Mn-(O-C_(2))_(4)moieties embedding in the exposed basal plane of carbon surface is confirmed by X-ray absorption spectroscopy.As a result,the as-synthesized Mn-O-C catalyst exhibits superior NitRR activity with an NH_(3)yield rate(RNH_(3))of 1476.9±62.6μg h^(−1)cm^(−2)at−0.7 V(vs.reversible hydrogen electrode,RHE)and a faradaic efficiency(FE)of 89.0±3.8%at−0.5 V(vs.RHE)under ambient conditions.Further,when evaluated with a practical flow cell,Mn-O-C shows a high RNH_(3)of 3706.7±552.0μg h^(−1)cm^(−2)at a current density of 100 mA cm−2,2.5 times of that in the H cell.The in situ FT-IR and Raman spectroscopic studies combined with theoretical calculations indicate that the Mn-(O-C_(2))_(4)sites not only effectively inhibit the competitive hydrogen evolution reaction,but also greatly promote the adsorption and activation of nitrate(NO_(3)^(−)),thus boosting both the FE and selectivity of NH_(3)over Mn-(O-C_(2))_(4)sites.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10873003 and 11045005)the Natural Science Foundation of Zhejiang Province,China (Grant No. Y6090739)
文摘Using a new tortoise coordinate transformation, this paper investigates the Hawking effect from an arbitrarily accelerating charged black hole by the improved Damour-Ruffini method. After the tortoise coordinate transformation, the Klein-Gordon equation can be written as the standard form at the event horizon. Then extending the outgoing wave from outside to inside of the horizon analytically, the surface gravity and Hawking temperature can be obtained automatically. It is found that the Hawking temperatures of different points on the surface are different. The quantum nonthermal radiation characteristics of a black hole near the event horizon is also discussed by studying the Hamilton-Jacobi equation in curved spacetime and the maximum overlap of the positive and negative energy levels near the event horizon is given. There is a dimensional problem in the standard tortoise coordinate and the present results may be more reasonable.
基金supported by the National Natural Science Foundation of China,Nos.41874001 and 41664001Support Program for Outstanding Youth Talents in Jiangxi Province,No.20162BCB23050National Key Research and Development Program,No.2016YFB0501405。
文摘When linearizing three-dimensional(3 D)coordinate similarity transformation model with large rotations,we usually encounter the ill-posed normal matrix which may aggravate the instability of solutions.To alleviate the problem,a series of conversions are contributed to the 3 D coordinate similarity transformation model in this paper.We deduced a complete solution for the 3 D coordinate similarity transformation at any rotation with the nonlinear adjustment methodology,which involves the errors of the common and the non-common points.Furthermore,as the large condition number of the normal matrix resulted in an intractable form,we introduced the bary-centralization technique and a surrogate process for deterministic element of the normal matrix,and proved its benefit for alleviating the condition number.The experimental results show that our approach can obtain the smaller condition number to stabilize the convergence of the interested parameters.Especially,our approach can be implemented for considering the errors of the common and the non-common points,thus the accuracy of the transformed coordinates improves.
基金supported by the National Natural Science Foundation of China(41174025,41174026)
文摘Coordinate transformation parameters between two spatial Cartesian coordinate systems can be solved from the positions of non-colinear corresponding points. Based on the characteristics of translation, rotation and zoom components of the transformation, the complete solution is divided into three steps. Firstly, positional vectors are regulated with respect to the centroid of sets of points in order to separate the translation compo- nents. Secondly, the scale coefficient and rotation matrix are derived from the regulated positions independent- ly and correlations among transformation model parameters are analyzed. It is indicated that this method is applicable to other sets of non-position data to separate the respective attributions for transformation parameters.
文摘Most surveying works for mapping or GIS applications are performed with total station. Due to the remote nature of many of the sites surveyed, the surveys are often done in unprojected, local, assumed coordinate systems. However, without the survey data projected in real world coordinates, the range of possible analyses is limited and the value of existing imagery, elevation models, and hydrologic layers cannot be exploited. This requires a transformation from the local assumed to the real world coordinate systems. There are various built-in and add-in tools to perform transformations through GIS programs. This paper studies the effect of using Georeferencing tool, Spatial Adjustment tool (Affine and similarity) and CHaMP tool on the precision and relative accuracy of total station survey. This transformation requires real-world coordinates of at least two control points, which can be collected from different sources. This paper also studies the effect of using geodetic GPS, hand-held GPS, Google Earth (GE) and Bing Basemaps as sources for control points on the precision and relative accuracy of total station survey. These effects have been tested by using 111 points covered area of 60,000 m2and the results have shown that the CHaMP tool is the best for preserving the relative accuracy of the transformed points. The Georeferencing and spatial adjustment (similarity) tools give the same results and their accuracy are between 1/1000 and 1/300 depending on the source of control points. The results have also shown that the cornerstone to preserve the precision and relative accuracy of the transformed coordinates is the relative position of the control points despite their source.
文摘Three transformation models (Bursa-Wolf, Molodensky, and WTUSM) are generally used between two data systems transformation. The linear models are used when the rotation angles are small; however, when the rotation angles get bigger, model errors will be produced. In this paper, we present a method with three main terms:① the traditional rotation angles θ,φ,ψ are substituted with a,b,c which are three respective values in the anti-symmetrical or Lodrigues matrix; ② directly and accurately calculating the formula of seven parameters in any value of rotation angles; and ③ a corresponding adjustment model is established. This method does not use the triangle function. Instead it uses addition, subtraction, multiplication and division, and the complexity of the equation is reduced, making the calculation easy and quick.
基金supported by Science and Technology Project of SGCC(SGSW0000FZGHBJS2200070)。
文摘With the increasing penetration of wind and solar energies,the accompanying uncertainty that propagates in the system places higher requirements on the expansion planning of power systems.A source-grid-load-storage coordinated expansion planning model based on stochastic programming was proposed to suppress the impact of wind and solar energy fluctuations.Multiple types of system components,including demand response service entities,converter stations,DC transmission systems,cascade hydropower stations,and other traditional components,have been extensively modeled.Moreover,energy storage systems are considered to improve the accommodation level of renewable energy and alleviate the influence of intermittence.Demand-response service entities from the load side are used to reduce and move the demand during peak load periods.The uncertainties in wind,solar energy,and loads were simulated using stochastic programming.Finally,the effectiveness of the proposed model is verified through numerical simulations.
基金supported by the National Natural Science Foundation of China(Grant Nos.22108133,51972180)Science,Education and Industry Integration of Basic Research Projects of Qilu University of Technology(Grant No.2022PY062,2023PY034,2023PY022)
文摘Lithium-sulfur batteries(LSBs)are widely regarded as promising next-generation batteries due to their high theoretical specific capacity and low material cost.However,the practical applications of LSBs are limited by the shuttle effect of lithium polysulfides(LiPSs),electronic insulation of charge and discharge products,and slow LiPSs conversion reaction kinetics.Accordingly,the introduction of catalysts into LSBs is one of the effective strategy to solve the issues of the sluggished LiPS conversion.Because of their nearly 100%atom utilization and high electrocatalytic activity,single-atom catalysts(SACs)have been widely used as reaction mediators for LSBs’reactions.Excitingly,the SACs with asymmetric coordination structures have exhibited intriguing electronic structures and superior catalytic activities when compared to the traditional M-N_(4)active sites.In this review,we systematically describe the recent advancements in the installation of asymmetrically coordinated single-atom structure as reactions catalysts in LSBs,including asymmetrically nitrogen coordinated SACs,heteroatom coordinated SACs,support effective asymmetrically coordinated SACs,and bimetallic coordinated SACs.Particularly noteworthy is the discussion of the catalytic conversion mechanism of LiPSs spanning asymmetrically coordinated SACs.Finally,a perspective on the future developments of asymmetrically coordinated SACs in LSB applications is provided.
基金supported by the National Natural Science Foundation of China(Grant No.50579030)
文摘River ice is a natural phenomenon in cold regions, influenced by meteorology, geomorphology, and hydraulic conditions. River ice processes involve complex interactions between hydrodynamic, mechanical, and thermal processes, and they are also influenced by weather and hydrologic conditions. Because natural rivers are serpentine, with bends, narrows, and straight reaches, the commonly-used one-dimensional river ice models and two-dimensional models based on the rectangular Cartesian coordinates are incapable of simulating the physical phenomena accurately. In order to accurately simulate the complicated river geometry and overcome the difficulties of numerical simulation resulting from both complex boundaries and differences between length and width scales, a two-dimensional river ice numerical model based on a boundary-fitted coordinate transformation method was developed. The presented model considers the influence of the frazil ice accumulation under ice cover and the shape of the leading edge of ice cover during the freezing process. The model is capable of determining the velocity field, the distribution of water temperature, the concentration distribution of frazil ice, the transport of floating ice, the progression, stability, and thawing of ice cover, and the transport, accumulation, and erosion of ice under ice cover. A MacCormack scheme was used to solve the equations numerically. The model was validated with field observations from the Hequ Reach of the Yellow River. Comparison of simulation results with field data indicates that the model is capable of simulating the river ice process with high accuracy.
基金supported financially by the Fundamental Research Funds for the Central Universities (YWF-22-K-101,YWF-23-L-805 and YWF-23-YG-QB-006)the support from the National Natural Science Foundation of China (12372106)Fundamental Research Funds for the Central Universities
文摘3D printing techniques offer an effective method in fabricating complex radially multi-material structures.However,it is challenging for complex and delicate radially multi-material model geometries without supporting structures,such as tissue vessels and tubular graft,among others.In this work,we tackle these challenges by developing a polar digital light processing technique which uses a rod as the printing platform.The 3D model fabrication is accomplished through line projection.The rotation and translation of the rod are synchronized to project and illuminate the photosensitive material volume.By controlling the distance between the rod and the printing window,we achieved the printing of tubular structures with a minimum wall thickness as thin as 50 micrometers.By controlling the width of fine slits at the printing window,we achieved the printing of structures with a minimum feature size of 10 micrometers.Our process accomplished the fabrication of thin-walled tubular graft structure with a thickness of only 100 micrometers and lengths of several centimeters within a timeframe of just 100 s.Additionally,it enables the printing of axial multi-material structures,thereby achieving adjustable mechanical strength.This method is conducive to rapid customization of tubular grafts and the manufacturing of tubular components in fields such as dentistry,aerospace,and more.
基金supported by the Key Research and Development Program of Jiangsu Provincial Department of Science and Technology(BE2020081).
文摘Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was proposed for a wind-PVhydrogen-storage multi-agent energy system.First,a coordinated operation model was formulated for each agent considering peer-to-peer power trading.Second,a coordinated operation interactive framework for a multi-agent energy system was proposed based on the theory of the alternating direction method of multipliers.Third,a distributed interactive algorithm was proposed to protect the privacy of each agent and solve coordinated operation strategies.Finally,the effectiveness of the proposed coordinated operation method was tested on multi-agent energy systems with different structures,and the operational revenues of the wind power,PV,hydrogen,and energy storage agents of the proposed coordinated operation model were improved by approximately 59.19%,233.28%,16.75%,and 145.56%,respectively,compared with the independent operation model.
基金The National Natural Science Foundation Program(41674019)The National Plan on Key Basic Research and Development of China(2016YFB0501701).
文摘After implementing CGCS2000,establishing grid models for high-accuracy coordinate transformation which are mainly used to transform border lines and coordinate grids of topographic maps becomes an important issue in mapping applications.Consequently,a grid model for high-accuracy coordinate transformation of CGCS2000 is proposed.Specifically,we firstly analyze a minimum curvature equation of coordinate transformation,which possesses the characteristics of both the global and local smoothness,achieving better consistency with the consecutive smoothness for the coordinate transformation of map’s linear feature.Then an iterative calculation method of grid nodes and an approach for establishing regional grid models based on collocation by two-step minimization are proposed.Meanwhile,a data structure of grid model is constructed.Finally we give the optimized grid interval and transformation accuracy in China corresponding to the proposed grid model.Using 48 433 points of 2000 National Geodetic Control Network of China,we take the proposed model into practice by constructing grid models for coordinate transformation from BJS54 and XAS80 to CGCS2000,and the external positional accuracies for both models are 0.26 m and 0.03 m respectively.
基金Fundamental Research Funds for the Central Universities(2023MS125)。
文摘Currently,the iron chromium redox flow battery(ICRFB)has become a research hotspot in the energy storage field owing to its low cost and easily-scaled-up.However,the activity of electrolyte is still ambiguous due to its complicated solution environment.Herein,we performed a pioneering investigation on the coordination behavior and transformation mechanism of Cr^(3+)in electrolyte and prediction of impurity ions impact through quantum chemistry computations.Based on the structure and symmetry of electrostatic potential distribution,the activity of different Cr^(3+)complex ions is confirmed as[Cr(H2O)5Cl]^(2+)>[Cr(H2O)4Cl2]+>[Cr(H2O)6]^(3+).The transformation mechanism between[Cr(H2O)6]^(3+)and[Cr(H2O)5Cl]^(2+)is revealed.We find the metal impurity ions(especially Mg^(2+))can exacerbate the electrolyte deactivation by reducing the transformation energy barrier from[Cr(H2O)5Cl]^(2+)(24.38 kcal mol^(−1))to[Cr(H2O)6]^(3+)(16.23 kcal mol^(−1)).The solvent radial distribution and mean square displacement in different solvent environments are discussed and we conclude that the coordination configuration limits the diffusivity of Cr^(3+).This work provides new insights into the activity of electrolyte,laying a fundamental sense for the electrolyte in ICRFB.
基金supported by the Ningbo Polytechnic Industry-Education Integration Research Project(NZ23CJ05Z)the Ningbo Municipal Philosophy and Social Science Project(G2023-2-Z11)the Soft Science Project of Zhejiang Science and Technology Department,China(2024C35096).
文摘Coordinative development across various systems,particularly the economic,social,cultural,and human resources subsystems,is a key aspect of urban sustainability and has a direct impact on the quality of urbanization.The Hangzhou Metropolitan Circle,comprising Hangzhou City,Huzhou City,Jiaxing City,and Shaoxing City,was the first metropolitan circle approved by the National Development and Reform Commission(NDRC)as a demonstration of economic transformation in China.To evaluate the coupling coordination degree of the four cities and analyze the coordinative development in three systems(including digital economy,regional innovation,and talent employment),we collected panel data during 2015–2022 from these four cities.The development level of the three systems was evaluated by the standard deviation method and comprehensive development index.The results are as follows:(1)the level of coupling coordinated development of the three systems in the Hangzhou Metropolitan Circle was relatively low;(2)the coupling coordination degree of the four cities in the Hangzhou Metropolitan Circle showed significant regional differences,among which Hangzhou City was in the leading position,and Huzhou,Jiaxing,and Shaoxing cities made steady but slow progress in the coupling development of the three systems;and(3)the development of digital economy and talent employment needs to be strengthened.This study contributes to the coordinative development of Hangzhou Metropolitan Circle by innovatively focusing on the coupling coordination relationship among digital economy,regional innovation,and talent employment,which also meets the industrial layout of Hangzhou Metropolitan Circle.In this way,the optimal allocation and sustainable development of digital economy,regional innovation,and talent employment in the Hangzhou Metropolitan Circle can be achieved.
文摘This paper primarily concerns the effective coordination of the procedures and methods employed in open pit mining operations under the background of river management.The central objective of this study is to identify a viable approach for ensuring rational and efficient development of open pit mineral resources while simultaneously protecting and restoring the ecological environment of the river.This approach should facilitate the realization of a harmonious symbiosis between mining and river management.The intricate mutual influence relationship between river management and open pit mining is first analyzed in depth,which provides a solid foundation for the subsequent coordination strategy development.In light of the aforementioned considerations,a set of coordination procedures for open pit mining based on river management conditions is proposed.These procedures emphasize the integration of river protection into the overall layout of mining at the planning stage.The implementation of scientific mining schemes,accompanied by rigorous control of the scope and depth of mining operations,has proven to be an effective means of reducing the impact of mining activities on river environments.This approach has also facilitated the achievement of a balance and coordination between mining and river management.
文摘We give a proof of an explicit formula for affine coodinates of points in the Sato’s infinite Grassmannian corresponding to tau-functions for the KdV hierarchy.
文摘The 3-dimension coordinate datum transformation is very important in geomatics.Generally,there are small angle coordinate transformation model (i.e.,Bursa model,et al) and large angle coordinate transformation model (i.e.,Rodrigo matrix model,et al).However,these papers only focus on the fixed and static situation regardless of the small or large angle.This paper proposes the conception of coordinate transformation gradient field,which can realize the space coordinate transformation from small angle to arbitrary angle,and from static to dynamical.Based on the equivalent characteristics of the unit quaternion rotation matrix and the Rodrigo matrix,through studying the mathematical relationship between the spatial coordinate transformation and the functional gradient,we derive a functional gradient expression of the arbitrary transformation formula in space.The study shows that the essence of spatial coordinate transformation is a kind of potential field mathematically.This potential field conception can unify all the space coordinate transformations.It is the theoretical foundation for the further study of time continuous space coordinate transformation,and this study gives a new solution for the attitude determination of motion carriers.
文摘A so called sine-sigma vertical coordinate transformation is proposed. A vertical implicit scheme is de-rived by using cubic-spline representation of vertical current profiles. The derived 3-D nurmericalmodel has been applied to simulate the water leved field and the vertical structures of wind-induced cur-rents in an enclosed rectangular region, and the tides in the Bohai Sea. The model is believed to besatisfactory after comparing its results with an analytical soclution and observed data from tidal staions.