High angular resolution X-ray imaging is always useful in astrophysics and solar physics. In principle, it can be performed by using coded-mask imaging with a very long mask-detector distance. Previously, the diffract...High angular resolution X-ray imaging is always useful in astrophysics and solar physics. In principle, it can be performed by using coded-mask imaging with a very long mask-detector distance. Previously, the diffraction-interference effect was thought to degrade coded-mask imaging performance dramatically at the low energy end with its very long mask-detector distance. The diffraction-interference effect is described with numerical calculations, and the diffraction-interference cross correlation reconstruction method （DICC） is developed in order to overcome the imaging performance degradation. Based on the DICC, a super-high angular resolution principle （SHARP） for coded-mask X-ray imaging is proposed. The feasibility of coded mask imaging beyond the diffraction limit of a single pinhole is demonstrated with simulations. With the specification that the mask element size is 50 × 50 μm^2 and the mask-detector distance is 50 m, the achieved angular resolution is 0.32arcsec above about 10keV and 0.36arcsec at 1.24keV （λ = 1 nm）, where diffraction cannot be neglected. The on-axis source location accuracy is better than 0.02 arcsec. Potential applications for solar observations and wide-field X-ray monitors are also briefly discussed.展开更多
China's first Mars exploration mission will carry out comprehensive global surveys of the planet from data collected by instruments carried in orbit and roving on the planet itself.Goals of the mission include det...China's first Mars exploration mission will carry out comprehensive global surveys of the planet from data collected by instruments carried in orbit and roving on the planet itself.Goals of the mission include detailed inspections and surveys of key areas on the surface of Mars.One of the main scientific payloads installed on the orbiter is the moderate resolution camera.Its mission is to image the surface of Mars sufficiently to produce a global remote sensing image map of the planet,and to explore and record changes to the topography of Mars,including major geological structures,and to advance research on topography and geomorphology in general.The moderate resolution camera uses a lightweight and compact integrated design;its primary components are an optical module,a focal plane module,a camera control module,a power and interface module,a camera support module,a thermal control module,and a reference module.Radiometric calibration,color calibration,and geometric calibration have been carried out to ensure that the camera can acquire sufficient accurate data to complete mission goals.This paper introduces the camera's detection mission,its system composition,and its working principle;it also describes the camera's ground calibration tests and their results,and provides a reference for processing the camera's scientific data and for future applications.展开更多
The data obtained from a high resolution seismic refraction profile, which was carded out in Jiashi, Xinjiang, strong earthquake swarm area, were processed with both finite difference inversion and Hagedoorn refractor...The data obtained from a high resolution seismic refraction profile, which was carded out in Jiashi, Xinjiang, strong earthquake swarm area, were processed with both finite difference inversion and Hagedoorn refractor wavefront imaging technique and the fine upper crustal structure was determined. The results show that the upper crustal structure is relatively well-distributed in laterally and obviously by layers vertically.From surface to 11.0 km depth, there are about four layers. The P wave velocity of top two layers range from 1.65 to 4.5 km/s and their bottom boundaries, the buried depths of which are 0.4, 2.96-3.0 km respectively, are almost horizontal; The third layer is comparatively complicated and its P wave velocity presents inhomogeneous in both laterally and vertically. The bottom boundary of third layer is crystalline basement and shows a little uplift, which seemly suggest that the upper crust had been resisted while the hard Tarim block inserting into Tianshan Mountain; The forth layer is relatively even and its P wave velocity is about 6.3 km/s. There are a lateral velocity variation at the depth of about 4.0 km, and suggest that it has something to do with the hidden Meigaiti fault and Meigaiti-Xiasuhong fault but there are no the structure features about these faults stretching to the surface and passing through the crystalline basement. The seismogenic tectonic of Jiashi strong earthquake swarm at least lies in middle or lower crust beneath 11.0 km depth.展开更多
In view of the problem of fine characterization of narrow and thin channels,the maximum entropy criterion is used to enhance the focusing characteristics of Wigner-Ville Distribution.On the basis of effectively improv...In view of the problem of fine characterization of narrow and thin channels,the maximum entropy criterion is used to enhance the focusing characteristics of Wigner-Ville Distribution.On the basis of effectively improving the time-frequency resolution of seismic signal,a new method of microscopic ancient river channel identification is established.Based on the principle of the equivalence between the maximum entropy power spectrum and the AR model power spectrum,the prediction error and the autoregression coefficient of AR model are obtained using the Burg algorithm and Levinson-Durbin recurrence rule.Under the condition of the first derivative of autocorrelation function being 0,the Wigner-Ville Distribution of seismic signal is calculated,and the Wigner-Ville Distribution time-frequency power spectrum(MEWVD)is obtained under the maxi-mum entropy criterion of the microscopic ancient river channel.Through analysis of emulational seismic signal and forward numerical simulation signal of narrow thin model,it is found that MEWVD can effectively avoid the interference of cross term of Wigner-Ville Distribution,and obtain more accurate spectral characteristics than STFT and CWT signal analysis methods.It is also proved that the narrow and thin river channels of different scales can be identified effectively by MEWVD of different frequencies.The method is applied to the third member of Jurassic Shaximiao Formation(J2s33-2)gas reservoir of the Zhongji-ang gas field in Sichuan Basin.The spatial information of width and direction of narrow and thin river channels with width less than 500 m and sandstone thickness less than 35 m is accurately identified,providing bases for well deployment and horizontal well fracturing section selection.展开更多
High-resolution atomic-beam laser spectroscopy has been performed to study Stark effect of Ba atom. Stark spectra have been observed at various electric fields for Ba highly excited states. The scalar polarizability o...High-resolution atomic-beam laser spectroscopy has been performed to study Stark effect of Ba atom. Stark spectra have been observed at various electric fields for Ba highly excited states. The scalar polarizability of the transition from 6s5d3D2 to 5d6p3F3 at 728.0 nm and the tensor polarizability of the 3F3 level have been determined for the first time, to be αs = -89.8 (12) kHz/(kV/cm)2 and αt = -133.7 (20) kHz/(kV/cm)2, respectively.展开更多
Resolution is an useful tool for mechanical theorem proving in modelling the refutation proof procedure, which is mostly used in constructing a “proof” of a “theorem”. An attempt is made to utilize approximate rea...Resolution is an useful tool for mechanical theorem proving in modelling the refutation proof procedure, which is mostly used in constructing a “proof” of a “theorem”. An attempt is made to utilize approximate reasoning methodology in fuzzy resolution. Approximate reasoning is a methodology which can deduce a specific information from general knowledge and specific observation. It is dependent on the form of general knowledge and the corresponding deductive mechanism. In ordinary approximate reasoning, we derive from A→B and by some mechanism. In inverse approximate reasoning, we conclude from A→B and using an altogether different mechanism. An important observation is that similarity is inherent in fuzzy set theory. In approximate reasoning methodology-similarity relation is used in fuzzification while, similarity measure is used in fuzzy inference mechanism. This research proposes that similarity based approximate reasoning-modelling generalised modus ponens/generalised modus tollens—can be used to derive a resolution—like inference pattern in fuzzy logic. The proposal is well-illustrated with artificial examples.展开更多
This is a series of studies on Wu＇s conjecture and on its resolution to be presented herein. Both are devoted to expound all the comprehensive properties of Cauchy＇s function f（z） （z = x ＋ iy） and its integral ...This is a series of studies on Wu＇s conjecture and on its resolution to be presented herein. Both are devoted to expound all the comprehensive properties of Cauchy＇s function f（z） （z = x ＋ iy） and its integral J[f（z）]≡（2πi）-∮cf（t）（t-z）-1dt taken along the unit circle as contour C,inside which（the open domain D＋） f（z） is regular but has singularities distributed in open domain Doutside C. Resolution is given to the inverse problem that the singularities of f（z） can be determined in analytical form in terms of the values f（t） of f（z） numerically prescribed on C（｜t｜ = 1） ,as so enunciated by Wu＇s conjecture. The case of a single singularity is solved using complex algebra and analysis to acquire the solution structure for a standard reference. Multiple singularities are resolved by reducing them to a single one by elimination in principle,for which purpose a general asymptotic method is developed here for resolution to the conjecture by induction,and essential singularities are treated with employing the generalized Hilbert transforms. These new methods are applicable to relevant problems in mathematics,engineering and technology in analogy with resolving the inverse problem presented here.展开更多
We previously functionally characterized a novel marine microbial GDSL lipase MT6 and identified that the stereo-selectivity of MT6 was opposite to that of other common lipases in trans-esterification reactions.Herein...We previously functionally characterized a novel marine microbial GDSL lipase MT6 and identified that the stereo-selectivity of MT6 was opposite to that of other common lipases in trans-esterification reactions.Herein,we have investigated the use of MT6 in stereo-selective biocatalysis through direct hydrolysis reactions.Notably,the stereo-selectivity of MT6 was also demonstrated to be opposite to that of other common lipases in hydrolysis reactions.Parameters,including temperature,organic co-solvents,pH,ionic strength,catalyst loading,substrate concentration,and reaction time,affecting the enzymatic resolution of racemic 1-phenylethyl acetate were further investigated,with the e.e.of the final（S）-l-Phenylethanol product and the conversion being 97%and 28.5%,respectively,after process optimization.The lengths of side chains of 1-phenylethyl esters greatly affected the stereo-selectivity and conversion during kinetic resolutions.MT6 is a novel marine microbial GDSL lipase exhibiting opposite stereo-selectivities than other common lipases in both trans-esterification reactions and hydrolysis reactions.展开更多
We report here a generic,green synthesis of 17 valuable syn-aryl-(2S,3R)-2–chloro-3–hydroxy esters(syn-(2S,3R)-1)in 73%-99%isolated yields along with 6.1:1–83:1 dr and 31%~>99%ee,through dynamic reductive kineti...We report here a generic,green synthesis of 17 valuable syn-aryl-(2S,3R)-2–chloro-3–hydroxy esters(syn-(2S,3R)-1)in 73%-99%isolated yields along with 6.1:1–83:1 dr and 31%~>99%ee,through dynamic reductive kinetic resolution of racemic arylα–chloroβ-keto esters(2)catalyzed by an engineered ketoreductase which was obtained via ep PCR-based directed evolution.The hectogram scale synthesis of syn-(2S,3R)-1b at a substrate concentration of 120 g/L showcased the application potential of the biocatalytic method developed presently.展开更多
Silicon isotope analysis traditionally uses a standard-sample bracketing （SSB） method that relies upon greater instrument stability than can be consistently expected. The following proposed method reduces the level ...Silicon isotope analysis traditionally uses a standard-sample bracketing （SSB） method that relies upon greater instrument stability than can be consistently expected. The following proposed method reduces the level of instrumental stability required for the analysis process and provides a valid solution for high-precision and accurate studies of Si isotopic compositions. Rock samples were dissolved by using alkali fusion and acidification. Silicon isotopes were purified with an ion exchange resin. Interfering peaks for isotopes were separated by using a Nu Plasma 1700 multi-collector inductively coupled plasma mass spectrometry （MS） system in high-resolution mode （M/AM 〉 8000 RP）. Two magnesium isotopes （25Mg and 26Mg） and three silicon isotopes （28Si, 29Si, and 3;Si） were analyzed in the same data collection cycle. Mg isotopes were used as an internal standard to calibrate the mass discrimination effects in MS analysis of Si isotopes in combination with the SSB method in order to reduce the effects of MS interference and instrumental mass dis- crimination on the accuracy of measurements. The conventional SSB method without the Mg internal standard and the proposed SSB method with Mg calibration delivered consistent results within two standard deviations. When Mg was used as an internal standard for calibration, the analysis precision was better than 0.05 %0 amu.展开更多
基金Supported by the National Natural Science Foundation of China.
文摘High angular resolution X-ray imaging is always useful in astrophysics and solar physics. In principle, it can be performed by using coded-mask imaging with a very long mask-detector distance. Previously, the diffraction-interference effect was thought to degrade coded-mask imaging performance dramatically at the low energy end with its very long mask-detector distance. The diffraction-interference effect is described with numerical calculations, and the diffraction-interference cross correlation reconstruction method （DICC） is developed in order to overcome the imaging performance degradation. Based on the DICC, a super-high angular resolution principle （SHARP） for coded-mask X-ray imaging is proposed. The feasibility of coded mask imaging beyond the diffraction limit of a single pinhole is demonstrated with simulations. With the specification that the mask element size is 50 × 50 μm^2 and the mask-detector distance is 50 m, the achieved angular resolution is 0.32arcsec above about 10keV and 0.36arcsec at 1.24keV （λ = 1 nm）, where diffraction cannot be neglected. The on-axis source location accuracy is better than 0.02 arcsec. Potential applications for solar observations and wide-field X-ray monitors are also briefly discussed.
文摘China's first Mars exploration mission will carry out comprehensive global surveys of the planet from data collected by instruments carried in orbit and roving on the planet itself.Goals of the mission include detailed inspections and surveys of key areas on the surface of Mars.One of the main scientific payloads installed on the orbiter is the moderate resolution camera.Its mission is to image the surface of Mars sufficiently to produce a global remote sensing image map of the planet,and to explore and record changes to the topography of Mars,including major geological structures,and to advance research on topography and geomorphology in general.The moderate resolution camera uses a lightweight and compact integrated design;its primary components are an optical module,a focal plane module,a camera control module,a power and interface module,a camera support module,a thermal control module,and a reference module.Radiometric calibration,color calibration,and geometric calibration have been carried out to ensure that the camera can acquire sufficient accurate data to complete mission goals.This paper introduces the camera's detection mission,its system composition,and its working principle;it also describes the camera's ground calibration tests and their results,and provides a reference for processing the camera's scientific data and for future applications.
基金National Natural Science Foundation of China (40334040) and Joint Seismological Foundation (106076).
文摘The data obtained from a high resolution seismic refraction profile, which was carded out in Jiashi, Xinjiang, strong earthquake swarm area, were processed with both finite difference inversion and Hagedoorn refractor wavefront imaging technique and the fine upper crustal structure was determined. The results show that the upper crustal structure is relatively well-distributed in laterally and obviously by layers vertically.From surface to 11.0 km depth, there are about four layers. The P wave velocity of top two layers range from 1.65 to 4.5 km/s and their bottom boundaries, the buried depths of which are 0.4, 2.96-3.0 km respectively, are almost horizontal; The third layer is comparatively complicated and its P wave velocity presents inhomogeneous in both laterally and vertically. The bottom boundary of third layer is crystalline basement and shows a little uplift, which seemly suggest that the upper crust had been resisted while the hard Tarim block inserting into Tianshan Mountain; The forth layer is relatively even and its P wave velocity is about 6.3 km/s. There are a lateral velocity variation at the depth of about 4.0 km, and suggest that it has something to do with the hidden Meigaiti fault and Meigaiti-Xiasuhong fault but there are no the structure features about these faults stretching to the surface and passing through the crystalline basement. The seismogenic tectonic of Jiashi strong earthquake swarm at least lies in middle or lower crust beneath 11.0 km depth.
基金Supported by the General Project of National Natural Science Foundation(4207416041574099)the Sichuan Science and Tech-nology Plan Project(2020JDRC0013)。
文摘In view of the problem of fine characterization of narrow and thin channels,the maximum entropy criterion is used to enhance the focusing characteristics of Wigner-Ville Distribution.On the basis of effectively improving the time-frequency resolution of seismic signal,a new method of microscopic ancient river channel identification is established.Based on the principle of the equivalence between the maximum entropy power spectrum and the AR model power spectrum,the prediction error and the autoregression coefficient of AR model are obtained using the Burg algorithm and Levinson-Durbin recurrence rule.Under the condition of the first derivative of autocorrelation function being 0,the Wigner-Ville Distribution of seismic signal is calculated,and the Wigner-Ville Distribution time-frequency power spectrum(MEWVD)is obtained under the maxi-mum entropy criterion of the microscopic ancient river channel.Through analysis of emulational seismic signal and forward numerical simulation signal of narrow thin model,it is found that MEWVD can effectively avoid the interference of cross term of Wigner-Ville Distribution,and obtain more accurate spectral characteristics than STFT and CWT signal analysis methods.It is also proved that the narrow and thin river channels of different scales can be identified effectively by MEWVD of different frequencies.The method is applied to the third member of Jurassic Shaximiao Formation(J2s33-2)gas reservoir of the Zhongji-ang gas field in Sichuan Basin.The spatial information of width and direction of narrow and thin river channels with width less than 500 m and sandstone thickness less than 35 m is accurately identified,providing bases for well deployment and horizontal well fracturing section selection.
文摘High-resolution atomic-beam laser spectroscopy has been performed to study Stark effect of Ba atom. Stark spectra have been observed at various electric fields for Ba highly excited states. The scalar polarizability of the transition from 6s5d3D2 to 5d6p3F3 at 728.0 nm and the tensor polarizability of the 3F3 level have been determined for the first time, to be αs = -89.8 (12) kHz/(kV/cm)2 and αt = -133.7 (20) kHz/(kV/cm)2, respectively.
文摘Resolution is an useful tool for mechanical theorem proving in modelling the refutation proof procedure, which is mostly used in constructing a “proof” of a “theorem”. An attempt is made to utilize approximate reasoning methodology in fuzzy resolution. Approximate reasoning is a methodology which can deduce a specific information from general knowledge and specific observation. It is dependent on the form of general knowledge and the corresponding deductive mechanism. In ordinary approximate reasoning, we derive from A→B and by some mechanism. In inverse approximate reasoning, we conclude from A→B and using an altogether different mechanism. An important observation is that similarity is inherent in fuzzy set theory. In approximate reasoning methodology-similarity relation is used in fuzzification while, similarity measure is used in fuzzy inference mechanism. This research proposes that similarity based approximate reasoning-modelling generalised modus ponens/generalised modus tollens—can be used to derive a resolution—like inference pattern in fuzzy logic. The proposal is well-illustrated with artificial examples.
文摘This is a series of studies on Wu＇s conjecture and on its resolution to be presented herein. Both are devoted to expound all the comprehensive properties of Cauchy＇s function f（z） （z = x ＋ iy） and its integral J[f（z）]≡（2πi）-∮cf（t）（t-z）-1dt taken along the unit circle as contour C,inside which（the open domain D＋） f（z） is regular but has singularities distributed in open domain Doutside C. Resolution is given to the inverse problem that the singularities of f（z） can be determined in analytical form in terms of the values f（t） of f（z） numerically prescribed on C（｜t｜ = 1） ,as so enunciated by Wu＇s conjecture. The case of a single singularity is solved using complex algebra and analysis to acquire the solution structure for a standard reference. Multiple singularities are resolved by reducing them to a single one by elimination in principle,for which purpose a general asymptotic method is developed here for resolution to the conjecture by induction,and essential singularities are treated with employing the generalized Hilbert transforms. These new methods are applicable to relevant problems in mathematics,engineering and technology in analogy with resolving the inverse problem presented here.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences(XDA11030404),the Key Project from Chinese Academy of Sciences(KGZD-EW-606)the National Natural Science Foundation of China(21302199)Guangzhou Science and Technology Plan Projects(201510010012)
文摘We previously functionally characterized a novel marine microbial GDSL lipase MT6 and identified that the stereo-selectivity of MT6 was opposite to that of other common lipases in trans-esterification reactions.Herein,we have investigated the use of MT6 in stereo-selective biocatalysis through direct hydrolysis reactions.Notably,the stereo-selectivity of MT6 was also demonstrated to be opposite to that of other common lipases in hydrolysis reactions.Parameters,including temperature,organic co-solvents,pH,ionic strength,catalyst loading,substrate concentration,and reaction time,affecting the enzymatic resolution of racemic 1-phenylethyl acetate were further investigated,with the e.e.of the final（S）-l-Phenylethanol product and the conversion being 97%and 28.5%,respectively,after process optimization.The lengths of side chains of 1-phenylethyl esters greatly affected the stereo-selectivity and conversion during kinetic resolutions.MT6 is a novel marine microbial GDSL lipase exhibiting opposite stereo-selectivities than other common lipases in both trans-esterification reactions and hydrolysis reactions.
基金The National Key Research and Development Program of China(Nos.2021YFA0911400 and 2021YFF0600704)the National Natural Science Foundation of China(Nos.22071033 and 21801047)are acknowledged for the financial supports。
文摘We report here a generic,green synthesis of 17 valuable syn-aryl-(2S,3R)-2–chloro-3–hydroxy esters(syn-(2S,3R)-1)in 73%-99%isolated yields along with 6.1:1–83:1 dr and 31%~>99%ee,through dynamic reductive kinetic resolution of racemic arylα–chloroβ-keto esters(2)catalyzed by an engineered ketoreductase which was obtained via ep PCR-based directed evolution.The hectogram scale synthesis of syn-(2S,3R)-1b at a substrate concentration of 120 g/L showcased the application potential of the biocatalytic method developed presently.
基金funded by the National Natural Science Foundation of China(Grant Nos.41427804,41421002,41373004)Beijing SHRIMP Center Open Foundation,and Program for Changjiang Scholars and Innovative Research Team in University(Grant No.IRT1281)the MOST Research Foundation from the State Key Laboratory of Continental Dynamics(BJ08132-1)
文摘Silicon isotope analysis traditionally uses a standard-sample bracketing （SSB） method that relies upon greater instrument stability than can be consistently expected. The following proposed method reduces the level of instrumental stability required for the analysis process and provides a valid solution for high-precision and accurate studies of Si isotopic compositions. Rock samples were dissolved by using alkali fusion and acidification. Silicon isotopes were purified with an ion exchange resin. Interfering peaks for isotopes were separated by using a Nu Plasma 1700 multi-collector inductively coupled plasma mass spectrometry （MS） system in high-resolution mode （M/AM 〉 8000 RP）. Two magnesium isotopes （25Mg and 26Mg） and three silicon isotopes （28Si, 29Si, and 3;Si） were analyzed in the same data collection cycle. Mg isotopes were used as an internal standard to calibrate the mass discrimination effects in MS analysis of Si isotopes in combination with the SSB method in order to reduce the effects of MS interference and instrumental mass dis- crimination on the accuracy of measurements. The conventional SSB method without the Mg internal standard and the proposed SSB method with Mg calibration delivered consistent results within two standard deviations. When Mg was used as an internal standard for calibration, the analysis precision was better than 0.05 %0 amu.
