On account of the high theoretical capacity, high corrosion resistance, environmental benignity, abundant availability and low cost, the research on a-Fe_2O_3 has been gradually fastened on as promising anodes materia...On account of the high theoretical capacity, high corrosion resistance, environmental benignity, abundant availability and low cost, the research on a-Fe_2O_3 has been gradually fastened on as promising anodes materials toward lithium-ion batteries(LIBs). A high-performance anode for LIBs based on α-Fe_2O_3 nanoplates have been selectively prepared. The α-Fe_2O_3 nanoplates can be synthesized with iron ionbased ionic liquid as iron source and template. The α-Fe_2O_3 nanoplates as the anode of LIBs can display high capacity of around1950 mAh g^(-1) at 0.5 A g^(-1) which have exceeded the theoretical capacity of α-Fe_2O_3. On account of unique nanoplate structures and gum arabic as binder, the α-Fe_2O_3 nanoplates also exhibit high rate capability and excellent cycling performance.展开更多
Nanocomposites of PAn-DBSA/γ-Fe 2O 3 with electrical and ferromagnetic behavior(σ= 2.18×10 -3-5.00×10 -5 S/cm, M s=3.7-16.6 m 2·A/kg, H c=8 805.2-9 133.1 A/m) were prepared by a chemical modification-...Nanocomposites of PAn-DBSA/γ-Fe 2O 3 with electrical and ferromagnetic behavior(σ= 2.18×10 -3-5.00×10 -5 S/cm, M s=3.7-16.6 m 2·A/kg, H c=8 805.2-9 133.1 A/m) were prepared by a chemical modification-redoping method in a neutral medium. The products were characterized by TEM, XRD, UV-Vis, four-probe method, and magnetometer. The results indicate that the electrical and magnetic properties of the nanocomposites strongly depend on γ-Fe 2O 3 content. With the increase of γ-Fe 2O 3 content, the electrical conductivity is decreased and saturation magnetization is increased.展开更多
Cubic and ellipsoide ultrafine monodispersed hematite colloidal particles wereprepared by hydrothermal reaction from Fe(OH)3 get in the presence of Sn4+ ions. Thenumbers of nuclei increase with the concentration of ...Cubic and ellipsoide ultrafine monodispersed hematite colloidal particles wereprepared by hydrothermal reaction from Fe(OH)3 get in the presence of Sn4+ ions. Thenumbers of nuclei increase with the concentration of Sn4+ ions. The initial concentrationof Fe(OH)3 gel might approach to 0.5 mol.L- 1. The products were characterized by TEMand XRD.展开更多
基金financially supported by the National Natural Science Foundation of China (No.21506081,21506077)Jiangsu University Scientific Research Funding (15JDG048)+1 种基金Chinese Postdoctoral Foundation (2016M590420)Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘On account of the high theoretical capacity, high corrosion resistance, environmental benignity, abundant availability and low cost, the research on a-Fe_2O_3 has been gradually fastened on as promising anodes materials toward lithium-ion batteries(LIBs). A high-performance anode for LIBs based on α-Fe_2O_3 nanoplates have been selectively prepared. The α-Fe_2O_3 nanoplates can be synthesized with iron ionbased ionic liquid as iron source and template. The α-Fe_2O_3 nanoplates as the anode of LIBs can display high capacity of around1950 mAh g^(-1) at 0.5 A g^(-1) which have exceeded the theoretical capacity of α-Fe_2O_3. On account of unique nanoplate structures and gum arabic as binder, the α-Fe_2O_3 nanoplates also exhibit high rate capability and excellent cycling performance.
文摘Nanocomposites of PAn-DBSA/γ-Fe 2O 3 with electrical and ferromagnetic behavior(σ= 2.18×10 -3-5.00×10 -5 S/cm, M s=3.7-16.6 m 2·A/kg, H c=8 805.2-9 133.1 A/m) were prepared by a chemical modification-redoping method in a neutral medium. The products were characterized by TEM, XRD, UV-Vis, four-probe method, and magnetometer. The results indicate that the electrical and magnetic properties of the nanocomposites strongly depend on γ-Fe 2O 3 content. With the increase of γ-Fe 2O 3 content, the electrical conductivity is decreased and saturation magnetization is increased.
文摘Cubic and ellipsoide ultrafine monodispersed hematite colloidal particles wereprepared by hydrothermal reaction from Fe(OH)3 get in the presence of Sn4+ ions. Thenumbers of nuclei increase with the concentration of Sn4+ ions. The initial concentrationof Fe(OH)3 gel might approach to 0.5 mol.L- 1. The products were characterized by TEMand XRD.