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三元复合物Ag/Cu_(2)O/g-C_(3)N_(4)的制备及其光催化降解和抗菌性能研究 被引量:1
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作者 武华乙 游晓平 +2 位作者 陈欢生 熊银 何玮娟 《化学与生物工程》 CAS 北大核心 2024年第3期41-45,52,共6页
以尿素、硫酸铜、乙酸银为原料,采用溶液法制备了三元复合物Ag/Cu_(2)O/g-C_(3)N_(4),通过XRD、XPS、SEM、TEM、UV-Vis等手段对三元复合物的结构进行了表征;以罗丹明B为模型研究了三元复合物的光催化降解性能,以大肠杆菌和金黄色葡萄球... 以尿素、硫酸铜、乙酸银为原料,采用溶液法制备了三元复合物Ag/Cu_(2)O/g-C_(3)N_(4),通过XRD、XPS、SEM、TEM、UV-Vis等手段对三元复合物的结构进行了表征;以罗丹明B为模型研究了三元复合物的光催化降解性能,以大肠杆菌和金黄色葡萄球菌为模型研究了三元复合物的抗菌性能,并探究了三元复合物的光催化降解机理。结果表明,Ag和Cu_(2)O粒子沉积在g-C_(3)N_(4)片层结构上,Ag、Cu_(2)O和g-C_(3)N_(4)三者之间的协同作用使得三元复合物的光催化降解性能和抗菌性能大幅提高。为构建用于实际水体污染处理的g-C_(3)N_(4)基复合材料提供了新思路。 展开更多
关键词 ag/Cu_(2)o/g-C_(3)N_(4) 可见光 光催化降解 抗菌性能
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g-C_(3)N_(4)/Ag/Ag_(2)O复合材料低功率紫外照射下降解罗丹明B
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作者 苏春雨 秦娇 +4 位作者 常璐 耿悦 虞阿芳 吕东军 张晓蕾 《山东化工》 CAS 2024年第10期13-16,共4页
光催化降解技术高效、环保、节能的优点使其在环保领域具有广泛应用前景,为解决环境污染问题提供了新的思路。其中高效催化剂是实现污染物高效光催化降解的关键。g-C_(3)N_(4)半导体材料因优良的热稳定性和化学稳定性、易于合成以及能... 光催化降解技术高效、环保、节能的优点使其在环保领域具有广泛应用前景,为解决环境污染问题提供了新的思路。其中高效催化剂是实现污染物高效光催化降解的关键。g-C_(3)N_(4)半导体材料因优良的热稳定性和化学稳定性、易于合成以及能带结构易调控等优点在催化领域具有广阔的应用前景,但由于纯g-C_(3)N_(4)可见光利用率低、表面积小、导带位置较低,限制了其实际应用中的催化活性。本文通过光诱导还原方法实现了g-C_(3)N_(4)材料表面Ag/Ag_(2)O的原位负载,系统研究了Ag/Ag_(2)O负载量对材料催化性能的影响,实现低功率紫外光催化下水中罗丹明B的快速高效去除,研究发现50 mg的g-C_(3)N_(4)中在0.24 g/L的AgNO3溶液还原得到的g-C_(3)N_(4)/Ag/Ag_(2)O复合材料具有最佳的催化性能。同时将复合材料应用于实际水体中罗丹明B染料的催化降解,取得了良好催化效果。本研究为去除水环境有机物污染提供了一种高效、绿色的解决方法。 展开更多
关键词 g-C_(3)N_(4) ag ag_(2)o 罗丹明B 光催化
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放电电压对Ag-30vol%Ti_(3)SiC_(2)复合材料电弧烧蚀性能的影响
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作者 黄晓晨 颜宇 +3 位作者 丁云飞 葛金龙 吕长鹏 赵浩 《热加工工艺》 北大核心 2024年第14期73-78,共6页
采用热压烧结法制备Ag-30vol%Ti_(3)SiC_(2)复合材料,Ti_(3)SiC_(2)颗粒均匀分布于Ag基体上,无团聚和扩散现象。分别在3、6、8和10 kV的放电电压下,对Ag-30vol%Ti_(3)SiC_(2)复合材料进行了电弧烧蚀试验。结果表明,随着放电电压的增加,... 采用热压烧结法制备Ag-30vol%Ti_(3)SiC_(2)复合材料,Ti_(3)SiC_(2)颗粒均匀分布于Ag基体上,无团聚和扩散现象。分别在3、6、8和10 kV的放电电压下,对Ag-30vol%Ti_(3)SiC_(2)复合材料进行了电弧烧蚀试验。结果表明,随着放电电压的增加,电弧能量增加,电弧扩散更加明显,烧蚀面积逐渐增大,烧蚀坑越来越深。Ag-30vol%Ti_(3)SiC_(2)材料表面形成喷溅、凸起、气孔和“龟裂”的显微形貌。经过电弧烧蚀后,Ag-30vol%Ti_(3)SiC_(2)复合材料发生分解,并氧化生成AgO、Ag_(2)O、SiO_(2)和TiO_(2)。 展开更多
关键词 ag-30vol%Ti_(3)SiC_(2)复合材料 电接触材料 电弧烧蚀机理 显微组织 氧化
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Ag_(3)PO_(4)/Cu_(2)O复合材料的制备及其性能研究
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作者 高雅 徐泽忠 +1 位作者 张凌云 王心怡 《佳木斯大学学报(自然科学版)》 CAS 2024年第4期166-169,共4页
对磷酸银复合材料制备及光催化性能进行了研究。讨论了水热温度、反应溶液的酸碱度等对Cu_(2)O制备的影响。同时,比较了不同摩尔百分比Ag_(3)PO_(4)含量的Ag_(3)PO_(4)/Cu_(2)O复合材料的光催化降解活性。结果显示,球状Cu_(2)O颗粒制备... 对磷酸银复合材料制备及光催化性能进行了研究。讨论了水热温度、反应溶液的酸碱度等对Cu_(2)O制备的影响。同时,比较了不同摩尔百分比Ag_(3)PO_(4)含量的Ag_(3)PO_(4)/Cu_(2)O复合材料的光催化降解活性。结果显示,球状Cu_(2)O颗粒制备条件为:温度100℃,pH值为10。采用直接沉淀法Ag_(3)PO_(4)纳米颗粒能够均匀附着Cu_(2)O表面,达到最佳复合效果。Ag_(3)PO_(4)/Cu_(2)O复合材料光催化活性高于纯Cu_(2)O,随着Ag_(3)PO_(4)的摩尔百分量的增加,复合光催化剂的催化性能先是增强后逐渐减弱。60%Ag_(3)PO_(4)/Cu_(2)O时,催化活性最强,90 min内罗丹明B几乎完全降解。 展开更多
关键词 ag_(3)Po_(4)/Cu_(2)o复合材料 光催化 罗丹明B 直接沉淀法
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生物炭及其老化对农田NH_(3)挥发及N_(2)O排放的影响 被引量:1
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作者 张聪 王震洪 《生态学报》 CAS CSCD 北大核心 2024年第4期1418-1428,共11页
生物炭具有减缓农田NH_(3)挥发和N_(2)O排放的重要潜力,但在施入环境后常常存在“老化”现象,这为其缓解全球变暖的长期有效性带来了不确定性。为了探明生物炭的长期效应,人工加速模拟了自然界中水分、温度、氧气、土壤矿物质及微生物... 生物炭具有减缓农田NH_(3)挥发和N_(2)O排放的重要潜力,但在施入环境后常常存在“老化”现象,这为其缓解全球变暖的长期有效性带来了不确定性。为了探明生物炭的长期效应,人工加速模拟了自然界中水分、温度、氧气、土壤矿物质及微生物多种老化因素,结合多元表征手段对比不同老化方式对生物炭性质的影响,利用主成分分析法建立新的生物炭性质综合指标来反映老化强度。再通过大田控制试验,采用原位通气法和静态箱-气相色谱法监测夏玉米生长周期内老化前后生物炭施用对农田NH_(3)挥发和N_(2)O排放的影响,为生物炭的可持续应用提供科学依据。结果表明,老化过程增加了原生物炭(BC)的氧含量、比表面积(SBET)、总孔容(Vt)及含氧官能团数量,降低了灰分、碱性、碳含量、平均孔径及其芳香性,各老化作用强度排序为:氧化老化生物炭(OBC)>矿化老化生物炭(KBC)>微生物老化生物炭(MBC)>干湿循环老化生物炭(WBC)>冻融循环老化生物炭(FBC)>BC。生物炭的添加减少了13.57%-29.50%的NH_(3)挥发量。与BC相比,OBC和KBC分别显著降低了14.71%和9.38%的NH_(3)挥发(P<0.05),MBC降低了3.38%的NH_(3)挥发(P>0.05)。相反,WBC和FBC分别增加了4.55%和2.72%的NH_(3)挥发(P>0.05)。同时,生物炭的添加降低了22.36%-40.43%的N_(2)O排放量。其中,BC减排效果最优,老化作用均削弱了原生物炭对N_(2)O的减排效应。与BC相比,OBC和KBC显著增加了30.34%和26.36%的N_(2)O排放量(P<0.05),MBC、FBC和WBC分别增加了19.96%、18.29%和10.92%的N_(2)O排放量(P>0.05)。综上,不同老化方式会对生物炭的理化性质造成不同改变,进而影响土壤气态氮释放。通过对比不同的老化方式,OBC影响最为显著,其次为KBC,MBC居中,WBC和FBC的影响最弱。 展开更多
关键词 生物炭 老化 NH_(3)挥发 N_(2)o排放
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One-pot hydrothermal fabrication of α-Fe_2O_3@C nanocomposites for electrochemical energy storage 被引量:9
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作者 Maiyong Zhu Jiarui Kan +4 位作者 Jianmei Pan Wenjie Tong Qi Chen Jiacheng Wang Songjun Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第1期1-8,共8页
A facile hydrothermal method was developed for the preparation of Fe_2O_3@C nanocomposites using FeCl_3·6H_2O as iron source and glucose as carbon source under alkaline condition. The morphology and structure of ... A facile hydrothermal method was developed for the preparation of Fe_2O_3@C nanocomposites using FeCl_3·6H_2O as iron source and glucose as carbon source under alkaline condition. The morphology and structure of the as-prepared product were identified by transmission electron microscopy(TEM), high resolution transmission electron microscopy(HRTEM), field-emission scanning electron microscopy(FESEM),X-ray diffraction(XRD), Raman spectroscopy, Fourier Transform infrared spectroscopy(FTIR), and thermogravimetric analysis(TGA). The as-prepare α-Fe_2O_3@C nanocomposites were employed for supercapacitor electrode material. The synergistic combination of carbon electrical double-layer capacitance and α-Fe_2O_3 pseudo-capacitance established such nanocomposites as versatile platform for high performance supercapacitors. The synthesis method developed here is expected to obtain other metal oxide/carbon composite. 展开更多
关键词 α-fe2o3 Carbon HYDRoTHERMAL PSEUDoCAPACIToR
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时效处理对Cu-Y_(2)O_(3)-Ti复合材料组织及性能的影响
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作者 秦永强 韦国宣 +4 位作者 罗来马 庄翌 马冰 张一帆 吴玉程 《材料热处理学报》 CAS CSCD 北大核心 2024年第5期25-31,共7页
以Cu、Y、Ti和CuO粉末为原料,采用机械合金化(MA)和热还原的方法制备了Cu-Y_(2)O_(3)-Ti复合粉末。然后经放电等离子烧结(SPS)技术制备了Cu-Y_(2)O_(3)-Ti复合材料,并对材料进行了900℃固溶1 h和不同温度时效2 h的处理。采用光学显微镜(... 以Cu、Y、Ti和CuO粉末为原料,采用机械合金化(MA)和热还原的方法制备了Cu-Y_(2)O_(3)-Ti复合粉末。然后经放电等离子烧结(SPS)技术制备了Cu-Y_(2)O_(3)-Ti复合材料,并对材料进行了900℃固溶1 h和不同温度时效2 h的处理。采用光学显微镜(OM)、扫描电镜(SEM)、X射线衍射仪(XRD)、能谱仪(EDS)、拉伸试验和导电率测量仪等研究了不同温度时效处理对Cu-Y_(2)O_(3)-Ti复合材料组织及性能的影响。结果表明:随着时效温度的升高,Cu-Y_(2)O_(3)-Ti复合材料的晶粒和第二相尺寸增大,导电率降低,最大应变和抗拉强度先增大后减小。Cu-Y_(2)O_(3)-Ti复合材料经900℃固溶1 h+400℃时效2 h后,综合性能最优,其具有良好塑性的同时,抗拉强度和导电率分别达到326.4 MPa和73.0%IACS。 展开更多
关键词 Cu-Y_(2)o_(3)-Ti复合材料 弥散强化 固溶时效 力学性能
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Bi2O3/CaFe2O4Z型异质结材料光催化降解氧氟沙星
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作者 叶红勇 杜佳 +2 位作者 杨培渊 王明辉 左广玲 《南阳理工学院学报》 2024年第4期114-119,共6页
利用溶剂热法合成了Z型异质结Bi2O3/CaFe2O4复合催化剂。采用多种表征手段对其晶体结构、形貌和性能进行了表征,并以氧氟沙星(OFX)为降解对象考察了Bi2O3/CaFe2O4复合催化剂的光催化活性。结果表明:Bi2O3负载在CaFe2O4表面,构建了Z型异... 利用溶剂热法合成了Z型异质结Bi2O3/CaFe2O4复合催化剂。采用多种表征手段对其晶体结构、形貌和性能进行了表征,并以氧氟沙星(OFX)为降解对象考察了Bi2O3/CaFe2O4复合催化剂的光催化活性。结果表明:Bi2O3负载在CaFe2O4表面,构建了Z型异质结构,这种结构能加速无效光生载流子的复合,促进有效光生载流子的分离,提升Bi2O3/CaFe2O4复合催化剂的可见光催化活性;Bi2O3/CaFe2O4复合催化剂对OFX的降解效果明显优于纯Bi2O3和CaFe2O4。在Bi2O3负载量为5%时,Bi2O3/CaFe2O4对OFX的降解效果最好,降解率可达78.7%,经过4次循环,依然可达到62.5%,说明其理化性能稳定,能够长期稳定循环使用。 展开更多
关键词 ag3Po4 CaFe2o4 光催化 氧氟沙星
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Microstructure and evolution of(TiB_2+Al_2O_3)/NiAl composites prepared by self-propagation high-temperature synthesis 被引量:3
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作者 宋晓杰 崔洪芝 +1 位作者 曹丽丽 P.Y.GULYAEV 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第7期1878-1884,共7页
(TiB2+Al2O3)/NiAl composites were synthesized by self-propagation high-temperature synthesis, and their phase compositions, microstructures and evolution modes were studied. The microstructures and shapes vary with... (TiB2+Al2O3)/NiAl composites were synthesized by self-propagation high-temperature synthesis, and their phase compositions, microstructures and evolution modes were studied. The microstructures and shapes vary with the TiB2+Al2O3 content in the NiAl matrix. TiB2 particles take a great variety of elementary shapes such as white bars, plates, herringbones, regular cubes and cuboids. These results outline a strategy of self-assembly processes in real time to build diversified microstructures. Some TiB2 grains in sizes of 2-5μm are embeded in Al2O3 clusters, while a small number of TiB2 particles disperse in the NiAl matrix. It is believed that the higher the TiB2+Al2O3 content is, the more the regular shapes and homogeneous distributions of TiB2 and Al2O3 will be present in the NiAl matrix. 展开更多
关键词 (TiB2+Al2o3)/NiAl composites self-propagation high-temperature synthesis MICRoSTRUCTURE evolution mechanism
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Preparation and magnetic property of multi-walled carbon nanotube/α-Fe_2O_3 composites
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作者 陈传盛 刘天贵 +4 位作者 陈小华 林良武 刘其城 夏清 宁振武 《中国有色金属学会会刊:英文版》 CSCD 2009年第6期1567-1571,共5页
In order to attain new functional nanomaterials with good magnetic property,multi-walled carbon nanotubes/hematite (MWNTs/α-Fe2O3)composites were synthesized using the co-deposition method.MWNTs/α-Fe2O3 composites w... In order to attain new functional nanomaterials with good magnetic property,multi-walled carbon nanotubes/hematite (MWNTs/α-Fe2O3)composites were synthesized using the co-deposition method.MWNTs/α-Fe2O3 composites were characterized by X-ray diffractometry(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Raman spectroscopy and vibrating sample magnetometry(VSM).The experimental results show that the structure and magnetic properties of the MWNTs/α-Fe2O3 composites are related to the heat treatment temperature.MWNTs are modified byα-Fe2O3 nano-particles andα-Fe2O3 nanorods with a diameter of 10-50 nm after being treated at 450℃.When the heat treatment temperature exceeds 600 ℃,MWNTs are only modified by Fe3O4 particles.Furthermore,the MWNTs composites treated at 450 ℃and 600℃have good magnetic behaviour. 展开更多
关键词 多壁碳纳米管 复合材料 α-fe2o3 磁特性 MWNTS 扫描电子显微镜 透射电子显微镜 热处理温度
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Na_(2)CO_(3)·10H_(2)O-Na_(2)HPO_(4)·12H_(2)O/SiO_(2)复合定形相变材料的制备及应用 被引量:1
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作者 王璇 李再超 +2 位作者 吴亚楠 唐炳涛 张宇昂 《精细化工》 EI CAS CSCD 北大核心 2024年第3期623-629,656,共8页
以Na_(2)CO_(3)·10H_(2)O(SCD)、Na_(2)HPO_(4)·12H_(2)O(DHPD)为相变主体制备了共晶体系,通过绘制凝固点变化图与DSC测试共同确定在m(SCD)∶m(DHPD)=4∶6时形成共晶,FTIR和XRD结果显示,2种水合盐间没有发生化学反应,但其晶... 以Na_(2)CO_(3)·10H_(2)O(SCD)、Na_(2)HPO_(4)·12H_(2)O(DHPD)为相变主体制备了共晶体系,通过绘制凝固点变化图与DSC测试共同确定在m(SCD)∶m(DHPD)=4∶6时形成共晶,FTIR和XRD结果显示,2种水合盐间没有发生化学反应,但其晶型结构发生改变。通过添加质量分数为2%的Na2SiO3·9H_(2)O作为成核剂降低体系的过冷度,且经历50次相变循环体系未出现相分离,相变焓值仅下降0.25%。进一步使用质量分数为25%的气相SiO_(2)作为支撑材料,采用浸渍法制备了相变前后形状稳定的共晶水合盐/SiO_(2)定形相变材料(SSPCM)。所得SSPCM的相变温度为24.08℃,相变焓值为146.6J/g,过冷度为0.55℃,热导率为0.4571W/(m·K)。同保温泡沫相比,其可将模拟房内部中心温度的升温时间延长了1.81倍,降温时间延长了0.39倍。 展开更多
关键词 Na_(2)Co_(3)·10H_(2)o Na_(2)HPo_(4)·12H_(2)o 共晶水合盐 复合相变材料 建筑节能 功能材料
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A Decisive Study on Dielectric Response of Bi2O3/Polystyrene &Bi2O3/PVDF Composite as Flexible Electrodes for Energy Storage
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作者 Dinesh Kumar Yadav Anju Yadav +2 位作者 Sushil Kumar Jain Narendra Jakhar Balram Tripathi 《Open Journal of Composite Materials》 CAS 2023年第1期1-11,共11页
In this manuscript a comparative study on Bi<sub>2</sub>O<sub>3</sub>/polystyrene and Bi<sub>2</sub>O<sub>3</sub>/PVDF composites has been executed via analysis of struc... In this manuscript a comparative study on Bi<sub>2</sub>O<sub>3</sub>/polystyrene and Bi<sub>2</sub>O<sub>3</sub>/PVDF composites has been executed via analysis of structural, bonding, surface morphology and dielectric response of composites for energy storage. The composites have been synthesized using solution cast method by varying concentrations of Bi<sub>2</sub>O<sub>3</sub> (BO = 1 - 5 mw%) into polystyrene (PS) and polyvinylidene fluoride (PVDF) polymers respectively. X-ray diffraction confirms the generation of crystallinity, Fourier transform infrared (FT-IR) spectroscopy confirms bonding behavior and scanning electron microscopy (SEM) confirms uniform distribution of Bi<sub>2</sub>O<sub>3</sub> (BO) in PS and PVDF polymers. Impedance spectroscopy has been employed for determination of dielectric response of the fabricated composites. The dielectric constant has been found to be increased as 1.4 times of pristine PS to BO<sub>5%</sub>PS<sub>95%</sub> composites and 1.8 times of pristine PVDF to BO<sub>5%</sub>PVDF<sub>95%</sub> composites respectively. These high dielectric composite electrodes are useful for flexible energy storage devices. 展开更多
关键词 Bismuth oxide (Bi2o3) Polymer composites Surface Morphology Dielectric Constant Energy Storage
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Preparation of Z-scheme WO_3(H_2O)_(0.333)/Ag_3PO_4 composites with enhanced photocatalytic activity and durability 被引量:8
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作者 Zhen Li Xia Wang +3 位作者 Jinfeng Zhang Changhao Liang Luhua Lu Kai Dai 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第3期326-334,共9页
Ag3PO4 is widely used in the field of photocatalysis because of its unique activity. However, photocorrosion limits its practical application. Therefore, it is very urgent to find a solution to improve the light corro... Ag3PO4 is widely used in the field of photocatalysis because of its unique activity. However, photocorrosion limits its practical application. Therefore, it is very urgent to find a solution to improve the light corrosion resistance of Ag3PO4. Herein, the Z-scheme WO3(H2O)0.333/Ag3PO4 composites are successfully prepared through microwave hydrothermal and simple stirring. The WO3(H2O)0.333/Ag3PO4 composites are characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and UV-Vis spectroscopy. In the degradation of organic pollutants, WO3(H2O)0.333/Ag3PO4 composites exhibit excellent performance under visible light. This is mainly attributed to the synergy of WO3(H2O)0.333 and Ag3PO4. Especially, the photocatalytic activity of 15%WO3(H2O)0.333/Ag3PO4 is the highest, and the methylene blue can be completely degraded in 4 min. In addition, the stability of the composites is also greatly enhanced. After five cycles of testing, the photocatalytic activity of 15%WO3(H2O)0.333/Ag3PO4 is not obviously decreased. However, the degradation efficiency of Ag3PO4 was only 20.2%. This indicates that adding WO3(H2O)0.333 can significantly improve the photoetching resistance of Ag3PO4. Finally, Z-scheme photocatalytic mechanism is investigated. 展开更多
关键词 PHoToCATALYSIS ag3Po4 Wo3(H2o)0.333 composites Z-scheme
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Photoluminescence behavior and visible light photocatalytic activity of ZnO,ZnO/ZnS and ZnO/ZnS/α-Fe_2O_3 nanocomposites 被引量:5
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作者 Gaurav HITKARI Sandhya SINGH Gajanan PANDEY 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第7期1387-1397,共11页
In order to achieve effective, economic, and easily achievable photocatalyst for the degradation of dye methyl orange(MeO), ZnO, ZnO/ZnS and ZnO/ZnS/α-Fe2O3 nanocomposites were prepared by simple chemical synthetic... In order to achieve effective, economic, and easily achievable photocatalyst for the degradation of dye methyl orange(MeO), ZnO, ZnO/ZnS and ZnO/ZnS/α-Fe2O3 nanocomposites were prepared by simple chemical synthetic route in the aqueous medium. Phase, crystallinity, surface structure and surface behavior of the synthesized materials were determined by X-ray diffraction(XRD) and Brunauer-Emmett-Teller analysis(BET) techniques. XRD study established formation of good crystalline ZnO, ZnO/ZnS and ZnO/ZnS/α-Fe2O3 nanomaterials. By using intensity of constituent peaks in the XRD pattern, the compositions of nanocomposites were determined. From the BET analysis, the prepared materials show mesoporous behavior, type Ⅳ curves along with H4 hysteresis. The ZnO/ZnS/α-Fe2O3 composite shows the largest surface area among three materials. From the UV-visible spectra, the band gap energy of the materials was determined. Photoluminescence spectra(PL) were used to determine the emission behavior and surface defects in the materials. In PL spectra, the intensity of UV peak of ZnO/ZnS is lowered than that of ZnO while in case of ZnO/ZnS/α-Fe2O3, the intensity further decreased. The visible emission spectra of ZnO/ZnS increased compared with ZnO while in ZnO/ZnS/α-Fe2O3 it is further increased compared with ZnO/ZnS. The as-synthesized materials were used as photocatalysts for the degradation of dye MeO. The photo-degradation data revealed that the ZnO/ZnS/α-Fe2O3 is the best photocatalyst among three specimens for the degradation of dye MeO. The decrease of intensity of UV emission peak and the increase of intensity of visible emission cause the decrease of recombination of electrons and holes which are ultimately responsible for the highest photocatalytic activity of ZnO/ZnS/α-Fe2O3. 展开更多
关键词 nanocomposite ZNo ZNS α-fe2o3 CALCINATIoN optical properties photocatalytic activity
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Properties of Hot-Pressed Al_2O_3-Fe Composites 被引量:4
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作者 M.M.El-Sayed Seleman, Xudong SUN and Liang ZUO Department of Materials Science and Engineering, Northeastern University, Shenyang 110006, China K.A.Khalil Powder Metallurgy Institute, Central South University, Changsha 410083, China 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第5期538-542,共5页
Alumina-(0 similar to 20 vol. pct) iron composites were fabricated by hot-pressing of well-mixed-alumina and iron powders at 1400 degreesC and 30 MPa for 30 min. Hot-pressed bodies with nearly theoretical density were... Alumina-(0 similar to 20 vol. pct) iron composites were fabricated by hot-pressing of well-mixed-alumina and iron powders at 1400 degreesC and 30 MPa for 30 min. Hot-pressed bodies with nearly theoretical density were obtained for addition up to 10 vol. pct Fe, but relative density decreased gradually with further increase in Fe addition. The materials exhibit a homogeneous dispersion of Fe. Fracture strength of the composites exhibits a maximum value of 604 MPa at 15 vol. pct Fe, which is 1.5 times that of alumina alone. Fracture toughness increases with the increase in Fe content, reaching 7.5 MPa.m(1/2) at 20 vol. pct Fe. The theoretical values of fracture toughness was calculated and compared with the experimental one. Toughening mechanisms of the composites are also discussed. 展开更多
关键词 FE Properties of Hot-Pressed Al2o3-fe composites AL
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Aluminum matrix composites reinforced by in situ Al_2O_3 and Al_3Zr particles fabricated via magnetochemistry reaction 被引量:3
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作者 赵玉涛 张松利 陈刚 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第11期2129-2133,共5页
Aluminum matrix composites reinforced by in situ Al2O3 and Al3Zr particles are fabricated from A356-Zr(CO3)2 system via magnetochemistry reaction,and the morphologies,sizes and distributions of the in situ particles a... Aluminum matrix composites reinforced by in situ Al2O3 and Al3Zr particles are fabricated from A356-Zr(CO3)2 system via magnetochemistry reaction,and the morphologies,sizes and distributions of the in situ particles as well as the microstructures,mechanical mechanisms of the composites are investigated by XRD,SEM,TEM and in situ tensile tests.The results indicate that with the pulsed magnetic field assistance,the morphologies of the in situ particles are mainly with ball-shape,the sizes are in nanometer scale and the distributions in the matrix are uniform.The interfaces between the in situ particles and the aluminum matrix are net and no interfacial outgrowth is observed.These are due to the strong vibration induced by the applied magnetic field in the aluminum melt,which in turn,accelerates the melt reactions.The effects of the magnetic field on the above contributions are discussed in detail. 展开更多
关键词 aluminum matrix composites magnetochemistry reaction Al2o3 AL3ZR in situ tensile
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Synthesis of Hierarchically Porous FAU/γ-Al2O3 Composites with Different Morphologies via Directing Agent Induced Method 被引量:2
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作者 Wang Jia Zhao Tianbo +3 位作者 Li Zunfeng Zong Baoning Du Zexue Zeng Jianli 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2016年第3期22-34,共13页
Zeolite FAU composites with a macro/meso-microporous hierarchical structure were hydrothermally synthesized using macro-mesoporous γ-Al_2O_3 monolith as the substrate by means of the liquid crystallization directing... Zeolite FAU composites with a macro/meso-microporous hierarchical structure were hydrothermally synthesized using macro-mesoporous γ-Al_2O_3 monolith as the substrate by means of the liquid crystallization directing agent(LCDA) induced method. No template was needed throughout the synthesis processes. The structure and porosity of zeolite composites were analyzed by means of X-ray powder diffraction(XRD), scanning electron microscopy(SEM) and N_2adsorption-desorption isotherms. The results showed that the supported zeolite composites with varied zeolitic crystalline phases and different morphologies can be obtained by adjusting the crystallization parameters, such as the crystallization temperature, the composition and the alkalinity of the precursor solution. The presence of LCDA was defined as a determinant for synthesizing the zeolite composites. The mechanisms for formation of the hierarchically porous FAU zeolite composites in the LCDA induced synthesis process were discussed. The resulting monolithic zeolite with a trimodal-porous hierarchical structure shows potential applicability where facile diffusion is required. 展开更多
关键词 monolithic FAU/γ-Al2o3 composites hierarchically PoRoUS different morphologies directing agENT INDUCED METHoD
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Preparation and Magnetism of Gd_2O_3/X-NBR Composites 被引量:1
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作者 曹建莉 刘力 +3 位作者 吴小飞 温世鹏 金日光 张立群 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第z2期335-339,共5页
Series of Gd2O3/X-NBR composites were prepared by in-situ reaction at different temperatures (100 and 160℃) and different processing time. The influence of processing time and processing temperature on dispersion of ... Series of Gd2O3/X-NBR composites were prepared by in-situ reaction at different temperatures (100 and 160℃) and different processing time. The influence of processing time and processing temperature on dispersion of Gd2O3 was investigated, and the relationship between magnetic property and temperature was also discussed. The results show that, the mass magnetizability (xg) descends as temperature rising. Processing temperature and time do not exhibit evidenced effects on the mass magnetizability (xg). All the composites show to be antiferromagnetic. 展开更多
关键词 GD2o3 X-NBR MagNETISM composite rare earths
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金属氧化物对Ag-Ti_(3)SiC_(2)复合材料润湿性的影响研究
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作者 杨李林 黄晓晨 +2 位作者 凌德彬 郑浩 王佳杰 《安徽化工》 CAS 2024年第2期70-74,87,共6页
采用热压烧结法制备Ag-Ti_(3)SiC_(2)-MeO复合材料。体积分数为Ag-20%Ti_(3)SiC_(2)-10%MeO(La_(2)O_(3)、Bi_(2)O_(3)、CeO_(2)和In_(2)O_(3))的致密度分别为92.3%、99.44%、89.56%和91.4%。体积分数为Ag-20%Ti_(3)SiC_(2)-5%MeO(La_(2... 采用热压烧结法制备Ag-Ti_(3)SiC_(2)-MeO复合材料。体积分数为Ag-20%Ti_(3)SiC_(2)-10%MeO(La_(2)O_(3)、Bi_(2)O_(3)、CeO_(2)和In_(2)O_(3))的致密度分别为92.3%、99.44%、89.56%和91.4%。体积分数为Ag-20%Ti_(3)SiC_(2)-5%MeO(La_(2)O_(3)、Bi_(2)O_(3)、CeO_(2)和In_(2)O_(3))致密度分别为96.82%、98.87%、92.79%和95.55%。增加MeO有助于提高Ag-Ti_(3)SiC_(2)-MeO复合材料的润湿性,Ag-20%Ti_(3)SiC_(2)-5%MeO(La_(2)O_(3)、Bi_(2)O_(3)、CeO_(2)和In_(2)O_(3))的接触角分别为60.4°、60.5°、66°和51°。 展开更多
关键词 ag-Ti_(3)SiC_(2)复合材料 润湿性 接触角 金属氧化物
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Morphology and Frictional Characteristics Under Electrical Currents of Al_2O_3/Cu Composites Prepared by Internal Oxidation 被引量:7
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作者 刘瑞华 宋克兴 +3 位作者 贾淑果 徐晓峰 郜建新 国秀花 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2008年第3期281-288,共8页
Two Al2O3/Cu composites containing 0.24 wt.% Al2O3 and 0.60 wt.% Al2O3 separately are prepared by internal oxidation. Effects of sliding speed and pressure on the frictional characteristics of the composites and coppe... Two Al2O3/Cu composites containing 0.24 wt.% Al2O3 and 0.60 wt.% Al2O3 separately are prepared by internal oxidation. Effects of sliding speed and pressure on the frictional characteristics of the composites and copper against brass are investigated and compared. The changes in morphology of the sliding surface and subsurface are examined with scanning electron microscope (SEM) and energy dispersive X-ray spectrum (EDS). The results show that the wear resistance of the Al2O3/Cu composites is superior to that of copper under the same conditions, Under a given electrical current, the wear rate of Al2O3/Cu composites decreases as the Al2O3-content increases, However, the wear rates of the Al2O3/Cu composites and copper increase as the sliding speed and pressure increase under dry sliding condition. The main wear mechanisms for Al2O3/Cu composites are of abrasion and adhesion; for copper, it is adhesion, although wear by oxidation and electrical erosion can also be observed as the speed and pressure rise. 展开更多
关键词 Al2o3/Cu composite internal oxidation friction and wear surface morphology current carder
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