β-Na YF4:Yb3+,Er3+ microrods were synthesized through hydrothermal methods. Polyethylene glycol with molecular weight of 6000 was used as surfactant. A series of transparent silica gel films with upconversion lumines...β-Na YF4:Yb3+,Er3+ microrods were synthesized through hydrothermal methods. Polyethylene glycol with molecular weight of 6000 was used as surfactant. A series of transparent silica gel films with upconversion luminescence property was prepared through sol-gel method; the prepared β-Na YF4:Yb3+,Er3+ microrods were used as activator. The silica gel films show strong upconversion emission under excitation of 980-nm laser beam.展开更多
In this work, a simple method to modulate the crystal phase and morphology with a large amount of K＋ions codoping is proposed. The phase changes to the mixture of β-Na YF4 and β-KYF4 with increasing the content of...In this work, a simple method to modulate the crystal phase and morphology with a large amount of K＋ions codoping is proposed. The phase changes to the mixture of β-Na YF4 and β-KYF4 with increasing the content of K^＋ions to 80 mol%.When it exceeds 80 mol%, β-Na YF4 disappears gradually and β-KYF4 dominates with a poor crystalline. In addition, the morphology changes from nanosphere to nanoplate, and then to nanoprism, which indicates that a higher content of K^＋ions favors the growth rates along [0001] than the [10-10] of the nanocrystals. Additionally, the upconversion（UC） luminescence properties and the ratio of red/green（R/G） UC intensity of samples with different phases and morphologies are detected,which makes it possible to tune the UC fluorescence by varying the concentration of K^＋ions.展开更多
基金Supported by the National Natural Science Foundation of China(No.61308085)
文摘β-Na YF4:Yb3+,Er3+ microrods were synthesized through hydrothermal methods. Polyethylene glycol with molecular weight of 6000 was used as surfactant. A series of transparent silica gel films with upconversion luminescence property was prepared through sol-gel method; the prepared β-Na YF4:Yb3+,Er3+ microrods were used as activator. The silica gel films show strong upconversion emission under excitation of 980-nm laser beam.
基金supported by the National High Technology Research and Development Program of China(Grant No.2013AA032205)the National Natural Science Foundation of China(Grant No.51272022)the Fundamental Research Funds for the Central Universities,China(Grant No.2012JBZ001)
文摘In this work, a simple method to modulate the crystal phase and morphology with a large amount of K＋ions codoping is proposed. The phase changes to the mixture of β-Na YF4 and β-KYF4 with increasing the content of K^＋ions to 80 mol%.When it exceeds 80 mol%, β-Na YF4 disappears gradually and β-KYF4 dominates with a poor crystalline. In addition, the morphology changes from nanosphere to nanoplate, and then to nanoprism, which indicates that a higher content of K^＋ions favors the growth rates along [0001] than the [10-10] of the nanocrystals. Additionally, the upconversion（UC） luminescence properties and the ratio of red/green（R/G） UC intensity of samples with different phases and morphologies are detected,which makes it possible to tune the UC fluorescence by varying the concentration of K^＋ions.
