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Demonstration of a small‐scale power generator using supercritical CO_(2) 被引量:1
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作者 Ligeng Li Hua Tian +7 位作者 Xin Lin Xianyu Zeng Yurong Wang Weilin Zhuge Lingfeng Shi Xuan Wang Xingyu Liang Gequn Shu 《Carbon Energy》 SCIE EI CAS CSCD 2024年第4期269-290,共22页
The supercritical CO_(2)(sCO_(2))power cycle could improve efficiencies for a wide range of thermal power plants.The sCO_(2)turbine generator plays an important role in the sCO_(2)power cycle by directly converting th... The supercritical CO_(2)(sCO_(2))power cycle could improve efficiencies for a wide range of thermal power plants.The sCO_(2)turbine generator plays an important role in the sCO_(2)power cycle by directly converting thermal energy into mechanical work and electric power.The operation of the generator encounters challenges,including high temperature,high pressure,high rotational speed,and other engineering problems,such as leakage.Experimental studies of sCO_(2)turbines are insufficient because of the significant difficulties in turbine manufacturing and system construction.Unlike most experimental investigations that primarily focus on 100 kW‐or MW‐scale power generation systems,we consider,for the first time,a small‐scale power generator using sCO_(2).A partial admission axial turbine was designed and manufactured with a rated rotational speed of 40,000 rpm,and a CO_(2)transcritical power cycle test loop was constructed to validate the performance of our manufactured generator.A resistant gas was proposed in the constructed turbine expander to solve the leakage issue.Both dynamic and steady performances were investigated.The results indicated that a peak electric power of 11.55 kW was achieved at 29,369 rpm.The maximum total efficiency of the turbo‐generator was 58.98%,which was affected by both the turbine rotational speed and pressure ratio,according to the proposed performance map. 展开更多
关键词 GENERATOR performance map power generation supercritical CO_(2) TURBINE
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Multi-objective optimization and evaluation of supercritical CO_(2) Brayton cycle for nuclear power generation 被引量:1
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作者 Guo-Peng Yu Yong-Feng Cheng +1 位作者 Na Zhang Ping-Jian Ming 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第2期183-209,共27页
The supercritical CO_(2) Brayton cycle is considered a promising energy conversion system for Generation IV reactors for its simple layout,compact structure,and high cycle efficiency.Mathematical models of four Brayto... The supercritical CO_(2) Brayton cycle is considered a promising energy conversion system for Generation IV reactors for its simple layout,compact structure,and high cycle efficiency.Mathematical models of four Brayton cycle layouts are developed in this study for different reactors to reduce the cost and increase the thermohydraulic performance of nuclear power generation to promote the commercialization of nuclear energy.Parametric analysis,multi-objective optimizations,and four decision-making methods are applied to obtain each Brayton scheme’s optimal thermohydraulic and economic indexes.Results show that for the same design thermal power scale of reactors,the higher the core’s exit temperature,the better the Brayton cycle’s thermo-economic performance.Among the four-cycle layouts,the recompression cycle(RC)has the best overall performance,followed by the simple recuperation cycle(SR)and the intercooling cycle(IC),and the worst is the reheating cycle(RH).However,RH has the lowest total cost of investment(C_(tot))of$1619.85 million,and IC has the lowest levelized cost of energy(LCOE)of 0.012$/(kWh).The nuclear Brayton cycle system’s overall performance has been improved due to optimization.The performance of the molten salt reactor combined with the intercooling cycle(MSR-IC)scheme has the greatest improvement,with the net output power(W_(net)),thermal efficiencyη_(t),and exergy efficiency(η_(e))improved by 8.58%,8.58%,and 11.21%,respectively.The performance of the lead-cooled fast reactor combined with the simple recuperation cycle scheme was optimized to increase C_(tot) by 27.78%.In comparison,the internal rate of return(IRR)increased by only 7.8%,which is not friendly to investors with limited funds.For the nuclear Brayton cycle,the molten salt reactor combined with the recompression cycle scheme should receive priority,and the gas-cooled fast reactor combined with the reheating cycle scheme should be considered carefully. 展开更多
关键词 Supercritical CO_(2)Brayton cycle Nuclear power generation Thermo-economic analysis Multi-objective optimization Decision-making methods
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Quantification of CO_(2) Emissions from Three Power Plants in China Using OCO-3 Satellite Measurements
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作者 Yang YANG Minqiang ZHOU +3 位作者 Wei WANG Zijun NING Feng ZHANG Pucai WANG 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第11期2276-2288,共13页
Coal-fired power plants are a major carbon source in China. In order to assess the evaluation of China's carbon reduction progress with the promise made on the Paris Agreement, it is crucial to monitor the carbon ... Coal-fired power plants are a major carbon source in China. In order to assess the evaluation of China's carbon reduction progress with the promise made on the Paris Agreement, it is crucial to monitor the carbon flux intensity from coal-fired power plants. Previous studies have calculated CO_(2) emissions from point sources based on Orbiting Carbon Observatory-2 and-3(OCO-2 and OCO-3) satellite measurements, but the factors affecting CO_(2) flux estimations are uncertain. In this study, we employ a Gaussian Plume Model to estimate CO_(2) emissions from three power plants in China based on OCO-3 XCO_(2) measurements. Moreover, flux uncertainties resulting from wind information, background values,satellite CO_(2) measurements, and atmospheric stability are discussed. This study highlights the CO_(2) flux uncertainty derived from the satellite measurements. Finally, satellite-based CO_(2) emission estimates are compared to bottom-up inventories.The satellite-based CO_(2) emission estimates at the Tuoketuo and Nongliushi power plants are ~30 and ~10 kt d^(-1) smaller than the Open-Data Inventory for Anthropogenic Carbon dioxide(ODIAC) respectively, but ~10 kt d^(-1) larger than the ODIAC at Baotou. 展开更多
关键词 OCO-3 power plant CO_(2) emission Gaussian Plume Model
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A Review on Technologies for the Use of CO2 as a Working Fluid in Refrigeration and Power Cycles
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作者 Orelien T. Boupda Hyacinthe D. Tessemo +3 位作者 Isidore B. Nkounda Fongang Francklin G. Nyami Frederic Lontsi Thomas Djiako 《Energy and Power Engineering》 2024年第6期217-256,共40页
The use of carbon dioxide as a working fluid has been the subject of extensive studies in recent years, particularly in the field of refrigeration where it is at the heart of research to replace CFC and HCFC. Its ther... The use of carbon dioxide as a working fluid has been the subject of extensive studies in recent years, particularly in the field of refrigeration where it is at the heart of research to replace CFC and HCFC. Its thermodynamic properties make it a fluid of choice in the efficient use of energy at low and medium temperatures in engine cycles. However, the performance of transcritical CO2 cycles weakens under high temperature and pressure conditions, especially in refrigeration systems;On the other hand, this disadvantage becomes rather interesting in engine cycles where CO2 can be used as an alternative to the organic working fluid in small and medium-sized electrical systems for low quality or waste heat sources. In order to improve the performance of systems operating with CO2 in the field of refrigeration and electricity production, research has made it possible to develop several concepts, of which this article deals with a review of the state of the art, followed by analyzes in-depth and critical of the various developments to the most recent modifications in these fields. Detailed discussions on the performance and technical characteristics of the different evolutions are also highlighted as well as the factors affecting the overall performance of the systems studied. Finally, perspectives on the future development of the use of CO2 in these different cycles are presented. 展开更多
关键词 Refrigeration Cycle power Cycle System Performance Transcritical CO2 Cycles Working Fluid
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“双碳”目标下火电厂CO_(2)计量技术研究现状与展望 被引量:2
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作者 张安安 周奇 +3 位作者 李茜 丁宁 杨超 马岩 《发电技术》 CSCD 2024年第1期51-61,共11页
中国电力行业CO_(2)排放量是CO_(2)排放的主要来源,其中火电厂CO_(2)排放量在电力行业中占比最大。在“双碳”目标下,CO_(2)计量技术可以实现对火电厂中CO_(2)排放量的直观判断,为火电厂CO_(2)减排提供重要支撑,促进火电厂参与碳交易,... 中国电力行业CO_(2)排放量是CO_(2)排放的主要来源,其中火电厂CO_(2)排放量在电力行业中占比最大。在“双碳”目标下,CO_(2)计量技术可以实现对火电厂中CO_(2)排放量的直观判断,为火电厂CO_(2)减排提供重要支撑,促进火电厂参与碳交易,带动区域经济发展。结合国内外政策,讨论了目前通用CO_(2)计量方法的实施进展,总结归纳了以碳核算为主、碳监测为辅的火电厂CO_(2)计量方法存在的问题,并对火电厂CO_(2)计量技术应用的重难点进行了分析。最后,对火电厂CO_(2)计量技术的发展及应用进行了展望。 展开更多
关键词 火电厂 双碳 CO_(2)计量 碳核算 碳监测
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电厂粉煤灰、炉渣和污泥复合陶粒对低浓度Pb^(2+)的吸附特性
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作者 杨毅 高敏轩 +3 位作者 陈元 赵睿 舒麒麟 刘伟 《环境科学研究》 CAS CSCD 北大核心 2024年第2期407-414,共8页
针对重金属污染具有来源广、危害大等特点,通过以电厂废物(粉煤灰、炉渣)和脱水污泥为原料制备一种高效且价廉的陶粒吸附剂,采用吸附影响因素实验、解吸再生实验、吸附动力学模型和等温吸附模型的拟合以及陶粒表征分析,探究陶粒对Pb^(2+... 针对重金属污染具有来源广、危害大等特点,通过以电厂废物(粉煤灰、炉渣)和脱水污泥为原料制备一种高效且价廉的陶粒吸附剂,采用吸附影响因素实验、解吸再生实验、吸附动力学模型和等温吸附模型的拟合以及陶粒表征分析,探究陶粒对Pb^(2+)的吸附特性,同时为实现废物资源化利用提供新思路.结果表明:陶粒去除Pb^(2+)的较佳吸附条件为粒径4 mm、pH 4.5~5.0、吸附时间360 min、吸附温度25℃.陶粒再生所用较佳解吸剂为0.5 mol/L的HCl溶液,较佳解吸时间和次数分别为120 min和5次,解吸5次后陶粒对Pb^(2+)的去除率为92.67%.此吸附过程更好地遵循了准二级动力学模型和Freundlich等温吸附模型.陶粒上的O-H、Si-O和金属氧化键在吸附Pb^(2+)的过程中起主要作用.陶粒吸附Pb^(2+)后,出现了新的物相Pb_(2)Cl_(3)OH和PbO,陶粒与Pb^(2+)之间发生化学吸附,为自发进行的放热反应.陶粒处理实际废水中Pb^(2+)的去除率可达93.70%,Pb^(2+)浓度由3.74 mg/L降至0.24 mg/L.研究显示,电厂粉煤灰、炉渣和污泥复合陶粒对Pb^(2+)具有一定的去除效果,可为以固体废物为原料制备的吸附剂在重金属废水处理应用中提供数据支撑. 展开更多
关键词 电厂废物 污泥 陶粒 Pb^(2+) 表征分析 吸附特性
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Ag/Bi_(2)O_(3)纳米块自供能紫外探测器的制备及性能
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作者 方向明 周起成 +3 位作者 孙宇 乔志铭 耿秋丹 高世勇 《光学精密工程》 EI CAS CSCD 北大核心 2024年第5期653-660,共8页
为了实现在无外部供能下对紫外光的有效探测,基于Ag修饰的Bi_(2)O_(3)纳米块(Ag/Bi_(2)O_(3))纳米块制备了自供能紫外探测器。通过煅烧法制备Bi_(2)O_(3)纳米块,随后采用室温溶液法在其表面沉积Ag纳米粒子,进而成功制备了Ag/Bi_(2)O_(3... 为了实现在无外部供能下对紫外光的有效探测,基于Ag修饰的Bi_(2)O_(3)纳米块(Ag/Bi_(2)O_(3))纳米块制备了自供能紫外探测器。通过煅烧法制备Bi_(2)O_(3)纳米块,随后采用室温溶液法在其表面沉积Ag纳米粒子,进而成功制备了Ag/Bi_(2)O_(3)纳米块,且对所制备样品的晶体结构和微观形貌等进行了表征。结果表明,Ag/Bi_(2)O_(3)纳米块的平均尺寸约为1μm,且Ag纳米粒子随机分布在Bi_(2)O_(3)纳米块表面。将涂覆Ag/Bi_(2)O_(3)纳米块的FTO作为工作电极,并进一步构建了自供能紫外探测器。在365 nm的紫外光照射下,Ag/Bi_(2)O_(3)纳米块紫外探测器能在零偏压下实现对紫外光的快速检测,这证实其具有自供能特性。相比于Bi_(2)O_(3)纳米块紫外探测器,Ag/Bi_(2)O_(3)纳米块紫外探测器的光电流得到明显提升,上升和下降时间分别缩短至29.1 ms和40.2 ms,并具有良好的循环稳定性。 展开更多
关键词 紫外探测器 Bi_(2)O_(3)纳米块 AG纳米粒子 自供能探测
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基于Bi_(2)O_(3)/g-C_(3)N_(4)复合材料的自供能紫外探测器的制备及性能研究
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作者 方向明 周起成 +3 位作者 郭庄鹏 朱恩科 郝瑜睿 高世勇 《光子学报》 EI CAS CSCD 北大核心 2024年第7期107-115,共9页
为了获得高性能的自供能紫外探测器,结合热聚法和溶液法成功制备了Bi_(2)O_(3)/g-C_(3)N_(4)复合材料,并对其微观形貌、晶体结构、元素组成及价态进行了表征。结果表明,Bi_(2)O_(3)呈蜂窝状结构的块体,其附着在具有层状结构的g-C_(3)N_... 为了获得高性能的自供能紫外探测器,结合热聚法和溶液法成功制备了Bi_(2)O_(3)/g-C_(3)N_(4)复合材料,并对其微观形貌、晶体结构、元素组成及价态进行了表征。结果表明,Bi_(2)O_(3)呈蜂窝状结构的块体,其附着在具有层状结构的g-C_(3)N_(4)纳米片上。基于该异质结制备了无需外加偏压即能工作的紫外探测器。在紫外光照射下,Bi_(2)O_(3)/g-C_(3)N_(4)光电探测器能够立即产生光电流并达到最大稳定值约0.43μA,相比于Bi_(2)O_(3)纳米块紫外探测器,其光电流提升了约1.05倍。值得注意的是,Bi_(2)O_(3)/g-C_(3)N_(4)紫外探测器还展现出了快的响应速度(约181.7 ms),并且其光电流与入射光强也具有良好的线性关系,表明该器件对不同强度的紫外光均能实现快速且稳定的探测。 展开更多
关键词 紫外探测器 自供能 Bi_(2)O_(3)纳米块 g-C_(3)N_(4)纳米片 异质结
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粉煤灰矿化电厂烟气CO_(2)技术及关键科学问题
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作者 秦波涛 冯乐乐 邵旭 《煤炭学报》 EI CAS CSCD 北大核心 2024年第2期1161-1173,共13页
燃煤发电是我国能源安全的重要保障,但烟气中会排放大量CO_(2),同时,也会产生大量粉煤灰。利用粉煤灰矿化封存电厂烟气CO_(2),并将矿化产物进行综合利用,可达到大宗固废处置与CO_(2)长效封存的双重目的。目前,粉煤灰矿化电厂烟气CO_(2)... 燃煤发电是我国能源安全的重要保障,但烟气中会排放大量CO_(2),同时,也会产生大量粉煤灰。利用粉煤灰矿化封存电厂烟气CO_(2),并将矿化产物进行综合利用,可达到大宗固废处置与CO_(2)长效封存的双重目的。目前,粉煤灰矿化电厂烟气CO_(2)技术仍存在矿化效率低、反应时间长、CO_(2)处理量小等不足,其对应的关键科学问题和技术瓶颈亟待解决。简要介绍了粉煤灰矿化烟气CO_(2)的基本原理,分析了不同反应条件对粉煤灰碱土金属离子浸出和CO_(2)矿化反应效率的影响机制,对比了CO_(2)直接矿化反应工艺、碱土金属预浸出工艺、CO_(2)预吸收工艺等3种流程的优缺点,提出了包含粉煤灰碱土金属离子高效浸出、CO_(2)矿化反应过程强化、粉煤灰矿化CO_(2)智能装备、矿化效果综合评价等方面的粉煤灰高效矿化烟气CO_(2)技术体系,总结了粉煤灰矿化CO_(2)产物的物理化学性质,提出了粉煤灰矿化CO_(2)产物高值化综合利用的构想。最后,凝练出了粉煤灰碱土金属离子快速浸出与CO_(2)高效矿化特性、粉煤灰矿化CO_(2)大型反应器中多相混合与反应规律、粉煤灰浆液矿化CO_(2)产物性质的调控机制等3个关键科学问题,指明了基础研究-关键技术与装备研发-工程应用全链条的攻关方向,为粉煤灰高效矿化烟气CO_(2)及产物综合利用提供了参考,对于双碳目标实现和固废综合利用具有重要意义。 展开更多
关键词 电厂烟气 粉煤灰 二氧化碳 矿化 固废利用
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多种构型超临界CO_(2)循环热力学解构分析与参数优化
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作者 张斌 刘嘉楷 +1 位作者 张逸飞 辛团团 《节能技术》 CAS 2024年第2期143-149,共7页
新型超临界CO_(2)(S-CO_(2))循环可通过流程改良提高效率,构型复杂多样。为了直观阐明各种流程改良措施对循环效率提升的作用机制,本文将预压缩、后压缩、再压缩、间冷、再热等五种构型的S-CO_(2)循环解构为若干热功转换过程,建立各解... 新型超临界CO_(2)(S-CO_(2))循环可通过流程改良提高效率,构型复杂多样。为了直观阐明各种流程改良措施对循环效率提升的作用机制,本文将预压缩、后压缩、再压缩、间冷、再热等五种构型的S-CO_(2)循环解构为若干热功转换过程,建立各解构过程与循环效率之间的关联方程,进而开展流程参数优化。研究结果表明,预压缩、后压缩和再压缩方案均是通过增加压缩耗功,减少吸热量实现循环效率提升,其中再压缩方案效果最优,再压缩流量优化后循环效率提高5.1%;采用部分间冷方案,可有效降低压缩功耗,同时避免高品位热量贬值,间冷压力优化后循环效率提高2.2%;再热方案在不改变压缩耗功的前提下,增加透平出功,再热压力优化后循环效率提高1.9%;最后,循环联用再压缩、间冷和再热三种节能措施,可使效率提高9.3%。 展开更多
关键词 超临界CO_(2)循环 流程改良 热力学优化 过程解构分析 热功等效转换
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Recent advances in NiO/Ga_(2)O_(3) heterojunctions for power electronics 被引量:1
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作者 Xing Lu Yuxin Deng +2 位作者 Yanli Pei Zimin Chen Gang Wang 《Journal of Semiconductors》 EI CAS CSCD 2023年第6期24-38,共15页
Beta gallium oxide(β-Ga_(2)O_(3)) has attracted significant attention for applications in power electronics due to its ultrawide bandgap of ~ 4.8 eV and the large critical electric field of 8 MV/cm. These properties ... Beta gallium oxide(β-Ga_(2)O_(3)) has attracted significant attention for applications in power electronics due to its ultrawide bandgap of ~ 4.8 eV and the large critical electric field of 8 MV/cm. These properties yield a high Baliga's figures of merit(BFOM) of more than 3000. Though β-Ga_(2)O_(3) possesses superior material properties, the lack of p-type doping is the main obstacle that hinders the development of β-Ga_(2)O_(3)-based power devices for commercial use. Constructing heterojunctions by employing other p-type materials has been proven to be a feasible solution to this issue. Nickel oxide(NiO) is the most promising candidate due to its wide band gap of 3.6–4.0 eV. So far, remarkable progress has been made in NiO/β-Ga_(2)O_(3) heterojunction power devices. This review aims to summarize recent advances in the construction, characterization, and device performance of the NiO/β-Ga_(2)O_(3) heterojunction power devices. The crystallinity, band structure, and carrier transport property of the sputtered NiO/β-Ga_(2)O_(3) heterojunctions are discussed. Various device architectures, including the NiO/β-Ga_(2)O_(3) heterojunction pn diodes(HJDs), junction barrier Schottky(JBS) diodes, and junction field effect transistors(JFET), as well as the edge terminations and super-junctions based on the NiO/β-Ga_(2)O_(3) heterojunction, are described. 展开更多
关键词 gallium oxide(Ga_(2)O_(3)) nickel oxide(NiO) HETEROJUNCTION power devices
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面向余热回收的超临界CO_(2)动力循环高级[火用]分析 被引量:1
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作者 姜悦茂 王顺森 +2 位作者 吴杰鹏 颜晓江 宋立明 《西安交通大学学报》 EI CAS CSCD 北大核心 2024年第2期43-55,共13页
针对常规[火用]分析方法不能揭示部件总[火用]损中那部分是由自身不可逆性造成的以及有多少可以通过优化而避免的问题,对面向余热回收的超临界CO_(2)动力循环进行了高级[火用]分析,找出[火用]损来源,探究部件真实提升潜能。首先,从热力... 针对常规[火用]分析方法不能揭示部件总[火用]损中那部分是由自身不可逆性造成的以及有多少可以通过优化而避免的问题,对面向余热回收的超临界CO_(2)动力循环进行了高级[火用]分析,找出[火用]损来源,探究部件真实提升潜能。首先,从热力学、经济与紧凑性3个角度对回热式循环余热回收系统进行了多目标优化,进行了热经济与常规[火用]分析;继而,将每个部件的[火用]损细分为内源可避免、内源不可避免、外源可避免与外源不可避免4部分,进行了高级[火用]分析;最后,比较了常规[火用]与高级[火用]分析结果,揭示了常规[火用]分析方法的局限性。结果表明,经优化后系统净发电量、平准化度电成本与单位功率面积分别为6.24 MW、4.48美分/(kW·h)与0.19 m^(2)/kW;回热器总[火用]损率最高,约为36.7%。由于关键设备技术限制,系统极限[火用]效率相比理想工况低约7%,系统总[火用]损主要由部件自身不可逆性产生,其中有42.9%可通过部件改进而减少。在不同燃机工况下,透平具有最高的内源可避免[火用]损率。 展开更多
关键词 余热回收 超临界CO_(2)动力循环 多目标优化 热经济分析 高级[火用]分析
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Preface to Special Issue on Towards High Performance Ga_(2)O_(3) Electronics: Epitaxial Growth and Power Devices(Ⅰ)
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作者 Genquan Han Shibing Long +2 位作者 Yuhao Zhang Yibo Wang Zhongming Wei 《Journal of Semiconductors》 EI CAS CSCD 2023年第6期4-6,共3页
There is currently great optimism within the electronics community that gallium oxide(Ga_(2)O_(3)) ultra-wide bandgap semiconductors have unprecedented prospects for eventually revolutionizing a rich variety of power ... There is currently great optimism within the electronics community that gallium oxide(Ga_(2)O_(3)) ultra-wide bandgap semiconductors have unprecedented prospects for eventually revolutionizing a rich variety of power electronic applications. Specially, benefiting from its ultra-high bandgap of around 4.8 eV, it is expected that the emerging Ga_(2)O_(3) technology would offer an exciting platform to deliver massively enhanced device performance for power electronics and even completely new applications. 展开更多
关键词 Epitaxial Growth and power Devices Preface to Special Issue on Towards High Performance Ga_(2)O_(3)Electronics power
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A landscape of β-Ga_(2)O_(3) Schottky power diodes
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作者 Man Hoi Wong 《Journal of Semiconductors》 EI CAS CSCD 2023年第9期47-56,共10页
β-Ga_(2)O_(3) Schottky barrier diodes have undergone rapid progress in research and development for power electronic applications.This paper reviews state-of-the-art β-Ga_(2)O_(3) rectifier technologies,including ad... β-Ga_(2)O_(3) Schottky barrier diodes have undergone rapid progress in research and development for power electronic applications.This paper reviews state-of-the-art β-Ga_(2)O_(3) rectifier technologies,including advanced diode architectures that have enabled lower reverse leakage current via the reduced-surface-field effect.Characteristic device properties including onresistance,breakdown voltage,rectification ratio,dynamic switching,and nonideal effects are summarized for the different devices.Notable results on the high-temperature resilience of β-Ga_(2)O_(3) Schottky diodes,together with the enabling thermal packaging solutions,are also presented. 展开更多
关键词 β-Ga_(2)O_(3) Schottky diodes power device edge termination nickel oxide
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基于分级气化的燃烧前CO_(2)捕集发电系统及性能分析
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作者 李济超 韩巍 +2 位作者 马文静 叶旖茵 金红光 《动力工程学报》 CAS CSCD 北大核心 2024年第8期1253-1263,1297,共12页
为实现煤炭高效低碳化发电,提出了一种基于分级气化和化学回热的燃烧前CO_(2)捕集发电系统。该系统将煤气化过程解耦为600℃的热解过程和1400℃的气化过程,利用燃气轮机的排烟余热来驱动热解过程,此外利用合成气的显热驱动热解气重整。... 为实现煤炭高效低碳化发电,提出了一种基于分级气化和化学回热的燃烧前CO_(2)捕集发电系统。该系统将煤气化过程解耦为600℃的热解过程和1400℃的气化过程,利用燃气轮机的排烟余热来驱动热解过程,此外利用合成气的显热驱动热解气重整。将新系统与参比系统进行热力学性能比较,分析了不同关键参数对新系统性能的影响。结果表明:在90%碳捕集率下,新系统的净发电效率、效率和度电CO_(2)排放量分别为39.97%、38.94%和85.27 g/(kW·h),相较于参考系统,分别提高了2.33个百分点、2.34个百分点和降低了5.27 g/(kW·h);新系统性能提升的主要原因在于其气化过程的不可逆损失大幅减少,为参比系统的62.13%;当气化温度为1200℃、水碳比为1.4、碳捕集率为80%时,系统净发电效率最高,可达41.3%;随着碳捕集率的增加,净发电效率及度电CO_(2)排放量均降低,其中度电CO_(2)排放量最低可达51.1 g/(kW·h)。 展开更多
关键词 二氧化碳捕集 煤气化 [火用]效率 净发电效率 化学回热
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2.83-kV double-layered NiO/β-Ga_(2)O_(3) vertical p-n heterojunction diode with a power figure-of-merit of 5.98 GW/cm^(2)
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作者 Tingting Han Yuangang Wang +4 位作者 Yuanjie Lv Shaobo Dun Hongyu Liu Aimin Bu Zhihong Feng 《Journal of Semiconductors》 EI CAS CSCD 2023年第7期28-31,共4页
This work demonstrates high-performance NiO/β-Ga_(2)O_(3) vertical heterojunction diodes(HJDs)with double-layer junc-tion termination extension(DL-JTE)consisting of two p-typed NiO layers with varied lengths.The bott... This work demonstrates high-performance NiO/β-Ga_(2)O_(3) vertical heterojunction diodes(HJDs)with double-layer junc-tion termination extension(DL-JTE)consisting of two p-typed NiO layers with varied lengths.The bottom 60-nm p-NiO layer fully covers theβ-Ga_(2)O_(3) wafer,while the geometry of the upper 60-nm p-NiO layer is 10μm larger than the square anode elec-trode.Compared with a single-layer JTE,the electric field concentration is inhibited by double-layer JTE structure effectively,resulting in the breakdown voltage being improved from 2020 to 2830 V.Moreover,double p-typed NiO layers allow more holes into the Ga_(2)O_(3) drift layer to reduce drift resistance.The specific on-resistance is reduced from 1.93 to 1.34 mΩ·cm^(2).The device with DL-JTE shows a power figure-of-merit(PFOM)of 5.98 GW/cm^(2),which is 2.8 times larger than that of the conven-tional single-layer JTE structure.These results indicate that the double-layer JTE structure provides a viable way of fabricating high-performance Ga_(2)O_(3) HJDs. 展开更多
关键词 β-Ga_(2)O_(3) breakdown voltage heterojunction diode(HJD) junction termination extension(JTE) power figure-of-merit(PFOM)
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电力行业CO_(2)排放量预测及减排路径——以徐州市为例
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作者 吴蒙 王晓青 +4 位作者 杨旅涵 张谷春 肖哓虎 徐辉 秦云虎 《江苏师范大学学报(自然科学版)》 CAS 2024年第1期46-50,共5页
基于1996—2022年《徐州统计年鉴》数据,分析徐州市电力行业CO_(2)排放特征,参考宾婵佳等的方法测算徐州市电力行业CO_(2)排放量,运用BP神经网络模型对2022—2030年徐州市电力行业CO_(2)排放量进行预测.结果表明:1995—2021年徐州市电... 基于1996—2022年《徐州统计年鉴》数据,分析徐州市电力行业CO_(2)排放特征,参考宾婵佳等的方法测算徐州市电力行业CO_(2)排放量,运用BP神经网络模型对2022—2030年徐州市电力行业CO_(2)排放量进行预测.结果表明:1995—2021年徐州市电力行业CO_(2)排放量为1002.684~4462.032万t;单位煤耗CO_(2)排放系数从1995年的1.027 t/MWh上升到1998年的1.043 t/MWh,再下降到2021年的0.820 t/MWh.不同情景下,徐州市电力行业CO_(2)排放量的预测值与实际值的独立样本t检验结果表明,运用BP神经网络模型预测电力行业CO_(2)排放量是可行的.预测结果显示,到2030年,徐州市电力行业CO_(2)排放量在基准情景下为5382.358万t,低碳情景下为4481.523万t,强化低碳情景下为4077.167万t.提出了徐州市电力行业可从发电端、电网端和消费端实施碳减排措施. 展开更多
关键词 徐州市 电力行业 CO_(2)排放 BP神经网络模型
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TiO_(2)-微晶纤维素的制备及其净化电力绝缘油的性能
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作者 杨雪 张春波 +2 位作者 孙东平 王浩然 孙墨杰 《化学研究与应用》 CAS 北大核心 2024年第6期1295-1301,共7页
电力用绝缘油是许多一、二次电气设备的关键绝缘介质,油品的老化是其产生一系列氧化产物的结果,将导致绝缘油的绝缘、灭弧性能降低,不仅会对电网造成冲击还可能出现火灾等重大安全事故。本文采用水热合成法,将亲水TiO_(2),纳米颗粒固载... 电力用绝缘油是许多一、二次电气设备的关键绝缘介质,油品的老化是其产生一系列氧化产物的结果,将导致绝缘油的绝缘、灭弧性能降低,不仅会对电网造成冲击还可能出现火灾等重大安全事故。本文采用水热合成法,将亲水TiO_(2),纳米颗粒固载在微晶纤维素(MCC)上,制备出具有高吸附性能的改性纤维素集尘体材料,并应用于静电吸附技术中净化处理脏污变压器油。通过油品净化效果测试得出,TiO_(2),改性纤维素集尘体材料在水热温度为180℃、水热时间为20h条件下,MCC与钛酸四丁酯加人量的最佳摩尔比为1:2.5。将该条件下合成的TiO_(2),改性纤维素制备成集尘体材料,结合静电净油反应器处理脏污变压器油。测试结果:净化后的油品各主要指标均优于单独使用静电净油反应器,且均达到220kV运行油国家标准。 展开更多
关键词 TiO_(2) MCC 吸附材料 电力绝缘油
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动态省级电力CO_(2)排放因子对区域碳达峰路径的影响
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作者 贾敏 张立 +10 位作者 张哲 宋晓晖 姜玲玲 蔡博峰 赵良 芦新波 张泽宸 郑海涛 汤铃 王金南 舒印彪 《中国工程科学》 CSCD 北大核心 2024年第4期121-133,共13页
电力CO_(2)排放因子是精准核算消费端间接排放的重要参数,也是准确量化消费端CO_(2)排放路径的核心指标。本文首次探究了2020—2035年省级电力CO_(2)排放因子的时空特征并与官方来源因子进行对比,全面整合了历史直接排放数据以及精准量... 电力CO_(2)排放因子是精准核算消费端间接排放的重要参数,也是准确量化消费端CO_(2)排放路径的核心指标。本文首次探究了2020—2035年省级电力CO_(2)排放因子的时空特征并与官方来源因子进行对比,全面整合了历史直接排放数据以及精准量化电力消费间接排放的重要性,详细预测了不同情景下2020—2035年省级电力消费间接排放及各省排放路径并量化不同时空精度电力CO_(2)排放因子对各省排放路径的影响。研究表明:(1)2020—2035年,各省电力CO_(2)排放因子呈现持续下降趋势,而现有公开的电力CO_(2)排放因子与本研究省级水平相比存在差异;(2)2010—2020年,电力净调入省份的电力消费间接排放及其占比逐渐增加,北京、上海、浙江等省份占比最高;(3)在情景1和情景3(全国、省级维度因子固定不变情景)下,各省的电力消费间接排放和总排放显著高于情景2和情景4(全国、省级维度因子动态变化情景)的估算结果;情景1和情景2(全国维度因子固定不变、动态变化情景)与情景3和情景4(省级维度因子固定不变、动态变化情景)中的估算结果差异较大;对于如北京、上海、广东等电力消费间接排放占比较大的省份,选取不同空间精度的电力CO_(2)排放因子对其排放总量影响较为明显,进一步导致相关达峰年的偏移。研究结论对支撑各省碳达峰路径规划、降低电力消费间接排放预测的不确定性具有参考价值。 展开更多
关键词 电力CO_(2)排放因子 碳达峰 排放路径 电力消费间接排放 省级维度
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Fast-speed self-powered PEDOT:PSS/α-Ga_(2)O_(3)nanorod array/FTO photodetector with solar-blind UV/visible dual-band photodetection 被引量:1
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作者 Ming-Ming Fan Kang-Li Xu +1 位作者 Ling Cao Xiu-Yan Li 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第4期721-726,共6页
Theα-Ga2 O_(3)nanorod array is grown on FTO by hydrothermal and annealing processes.And a self-powered PEDOT:PSS/α-Ga_(2)O_(3)nanorod array/FTO(PGF)photodetector has been demonstrated by spin coating PEDOT:PSS on th... Theα-Ga2 O_(3)nanorod array is grown on FTO by hydrothermal and annealing processes.And a self-powered PEDOT:PSS/α-Ga_(2)O_(3)nanorod array/FTO(PGF)photodetector has been demonstrated by spin coating PEDOT:PSS on theα-Ga_(2)O_(3)nanorod array.Successfully,the PGF photodetector shows solar-blind UV/visible dual-band photodetection.Our device possesses comparable solar-blind UV responsivity(0.18 mA/W at 235 nm)and much faster response speed(0.102 s)than most of the reported self-poweredα-Ga_(2)O_(3)nanorod array solar-blind UV photodetectors.And it presents the featured and distinguished visible band photoresponse with a response speed of 0.136 s at 540 nm.The response time is also much faster than the other non-self-poweredβ-Ga_(2)O_(3)DUV/visible dual-band photodetectors due to the fast-speed separation of photogenerated carries by the built-in electric field in the depletion regions of PEDOT:PSS/α-Ga_(2)O_(3)heterojunction.The results herein may prove a promising way to realize fast-speed self-poweredα-Ga_(2)O_(3)photodetectors with solar-blind UV/visible dual-band photodetection by simple processes for the applications of multiple-target tracking,imaging,machine vision and communication. 展开更多
关键词 fast speed self powered solar-blind UV/visible photodetection PEDOT:PSS/α-Ga_(2)O_(3)/FTO
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