The effect of a rotating magnetic field(RMF)on the distribution of Al_(2)O_(3)particles with an Al melt was studied by means of simulation and experiment.The results show that Al_(2)O_(3)particles(diameter of 1-10μm,...The effect of a rotating magnetic field(RMF)on the distribution of Al_(2)O_(3)particles with an Al melt was studied by means of simulation and experiment.The results show that Al_(2)O_(3)particles(diameter of 1-10μm,1wt.%)are significantly agglomerated at the top of ingots when subjected to an RMF,and their distribution is influenced by both the intensity and the duration of RMF application.The optimal separation efficiency is achieved with the magnetic intensity of 12 mT for 120 s.The number of the particles at the bottom and the middle decreases by 64.5%and 69.7%,respectively,while that at the top increases by 242.5%compared to the condition without an RMF.However,if further increase the intensity or the duration of RMF,it can induce turbulent flows that draw some of the separated Al_(2)O_(3)particles back into the melt,reducing separation efficiency.The calculation results show that as the magnetic intensity increases from 6 mT to 18 mT,the velocity difference between the particles and the Al melt flow quadruples,increasing from 0.013 m·s^(-1)to 0.066 m·s^(-1).Driven by this velocity difference,centrifugal motion,and secondary circulation,Al_(2)O_(3)particles tend to migrate upwards within the melt,facilitating the separation of impurity particles and enhancing the purity of the melt.展开更多
The effects of rare earth doping on the formation process of α-FeOOH crystallite and the properties of γ-Fe2O3 magnetic powder were investigated. The growth of needle α FeOOH crystallite was completed by the basic ...The effects of rare earth doping on the formation process of α-FeOOH crystallite and the properties of γ-Fe2O3 magnetic powder were investigated. The growth of needle α FeOOH crystallite was completed by the basic process. The experimental results show that the rare earth doping can increase the aspect axial ratio of needle α-FeOOH grains. its anti-sintering capability during the heat-treatment and the thermostability of γ-Fe2O3 magnetic properties. The magnetic properties of γ-Fe2O3 doping with rare earth are as follows: the coercivity Hc=36.3 kA/m (445 Oe), the ratio saturation magnetization σs=90.4μWbm/kg (72 emu/g), the ratio remanent magnetization σr=54 μWbm/kg (43 emu/g), and the temperature coefficient of remanent magnetization of γ-Fe2O3 doping with 0.1 mol% Dy can reach -5 ×10-4℃-1.展开更多
Superwetting materials have drawn unprecedented attention in the treatment of oily wastewater due to their preferable anti-fouling property and selective oil/water separation.However,it is still a challenge to fabrica...Superwetting materials have drawn unprecedented attention in the treatment of oily wastewater due to their preferable anti-fouling property and selective oil/water separation.However,it is still a challenge to fabricate multifunctional and environmentally friendly materials,which can be stably applied to purify the actual complicated wastewater.Here,a Ag/Ag/α-Fe_(2)O_(3) heterostructure anchored copper mesh was intentionally synthesized using a facile two-step hydrothermal method.The resultant mesh with superhydrophilicity and underwater superoleophobicity was capable of separating various oil/water mixtures with superior separation efficiency and high permeationflux driven by gravity.Benefiting from the joint effects of the smaller band gap of Ag/α-Fe_(2)O_(3) heterojunction,inherent antibacterial capacity of Ag/α-Fe_(2)O_(3) and Ag nanoparticles,favorable conductive substrate,as well as the hierarchical structure with superwettability,such mesh presented remarkably enhanced degradation capability toward organic dyes under visible light irradiation and antibacterial activity against both Escherichia coli(E.coli)and Staphylococcus aureus(S.aureus)compared with the pure Ag/α-Fe_(2)O_(3) coated mesh.Impressively,the mesh exhibited bifunctional water purification performance,in which organic dyes were eliminated simultaneously from water during oil/water separation in onefiltration process.More importantly,this mesh behaved exceptional chemical resistance,mechanical stability and long-term reusability.Therefore,this material with multifunctional integration may hold promising potential for steady water purification in practice.展开更多
The photocatalytic degradation of reactive blue 19(RB19)dye was investigated in a slurry system using ultraviolet(UV)and light-emitting diode(LED)lamps as light sources and using magnetic tungsten trioxide nanophotoca...The photocatalytic degradation of reactive blue 19(RB19)dye was investigated in a slurry system using ultraviolet(UV)and light-emitting diode(LED)lamps as light sources and using magnetic tungsten trioxide nanophotocatalysts(α-Fe_(2)O_(3)/WO_(3)and WO_(3)/NaOH)as photocatalysts.The effects of different parameters including irradiation time,initial concentration of RB19,nanophotocatalyst dosage,and pH were examined.The magnetic nanophotocatalysts were also characterized with different methods including scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDS),transmission electron microscopy(TEM),X-ray diffraction(XRD),photoluminescence(PL),differen-tial reflectance spectroscopy(DRS),Fourier transform infrared spectroscopy(FTIR),and vibrating sample magnetometry(VSM).The XRD and FTIR analyses confirmed the presence of tungsten trioxide on the iron oxide nanoparticles.The VSM analysis confirmed the magnetic ability of the new synthesized nanophotocatalyst α-Fe_(2)O_(3)/WO_(3)with 39.6 emu/g of saturation magnetization.The reactor performance showed consid-erable improvement in the α-Fe_(2)O_(3)-modified nanophotocatalyst.The impact of visible light was specifically investigated,and it was compared with UV-C light under the same experimental conditions.The reusability of the magnetic nanophotocatalyst α-Fe_(2)O_(3)/WO_(3)was tested during six cycles,and the magnetic materials showed an excellent removal efficiency after six cycles,with just a 7%decline.展开更多
The magnetic properties,microstructure and magnetic hardening of sintered (Nd_(1-x)Dy_x)_(16)Fe_(77.2)B_(6.8) and Nd_(16)Fe_(77.2)B_(6.8)+ywt-%Dy_2O_3 magnets have been stud- ied.As an addition of Dy to the magnet dur...The magnetic properties,microstructure and magnetic hardening of sintered (Nd_(1-x)Dy_x)_(16)Fe_(77.2)B_(6.8) and Nd_(16)Fe_(77.2)B_(6.8)+ywt-%Dy_2O_3 magnets have been stud- ied.As an addition of Dy to the magnet during smelting,Dy atoms may enter the matrix phase Nd_2Fe_(14)B,so as to enhance H_A,refine grains and improve boundary struc- ture,as well as to increase H_(ci)of the magnet.If Dy_2O_3 is added to powder material prior to sintering,Dy atoms diffuse into the epitaxial layer of grains of matrix phase causing enhancement of K′_1,also refinement of grains and improvement of boundary structure.The NdFeB based permanent magnets with higher H_(ci) and greater(BH)_m may be produced by adding about 2—3 wt-% Dy_2O_3 which make a favourable condition for lower cost.展开更多
基金support of the National Natural Science Foundation of China(Nos.52171135 and 51971048).
文摘The effect of a rotating magnetic field(RMF)on the distribution of Al_(2)O_(3)particles with an Al melt was studied by means of simulation and experiment.The results show that Al_(2)O_(3)particles(diameter of 1-10μm,1wt.%)are significantly agglomerated at the top of ingots when subjected to an RMF,and their distribution is influenced by both the intensity and the duration of RMF application.The optimal separation efficiency is achieved with the magnetic intensity of 12 mT for 120 s.The number of the particles at the bottom and the middle decreases by 64.5%and 69.7%,respectively,while that at the top increases by 242.5%compared to the condition without an RMF.However,if further increase the intensity or the duration of RMF,it can induce turbulent flows that draw some of the separated Al_(2)O_(3)particles back into the melt,reducing separation efficiency.The calculation results show that as the magnetic intensity increases from 6 mT to 18 mT,the velocity difference between the particles and the Al melt flow quadruples,increasing from 0.013 m·s^(-1)to 0.066 m·s^(-1).Driven by this velocity difference,centrifugal motion,and secondary circulation,Al_(2)O_(3)particles tend to migrate upwards within the melt,facilitating the separation of impurity particles and enhancing the purity of the melt.
文摘The effects of rare earth doping on the formation process of α-FeOOH crystallite and the properties of γ-Fe2O3 magnetic powder were investigated. The growth of needle α FeOOH crystallite was completed by the basic process. The experimental results show that the rare earth doping can increase the aspect axial ratio of needle α-FeOOH grains. its anti-sintering capability during the heat-treatment and the thermostability of γ-Fe2O3 magnetic properties. The magnetic properties of γ-Fe2O3 doping with rare earth are as follows: the coercivity Hc=36.3 kA/m (445 Oe), the ratio saturation magnetization σs=90.4μWbm/kg (72 emu/g), the ratio remanent magnetization σr=54 μWbm/kg (43 emu/g), and the temperature coefficient of remanent magnetization of γ-Fe2O3 doping with 0.1 mol% Dy can reach -5 ×10-4℃-1.
基金This work was financially supported by the Shandong Provincial Natural Science Foundation(ZR2020QB116)the Excellent Young Talents Foundation in Universities of Anhui Province(gxyq2021223)the Key Research Project of Natural Science in Universities of Anhui Province.(KJ2020A0749).
文摘Superwetting materials have drawn unprecedented attention in the treatment of oily wastewater due to their preferable anti-fouling property and selective oil/water separation.However,it is still a challenge to fabricate multifunctional and environmentally friendly materials,which can be stably applied to purify the actual complicated wastewater.Here,a Ag/Ag/α-Fe_(2)O_(3) heterostructure anchored copper mesh was intentionally synthesized using a facile two-step hydrothermal method.The resultant mesh with superhydrophilicity and underwater superoleophobicity was capable of separating various oil/water mixtures with superior separation efficiency and high permeationflux driven by gravity.Benefiting from the joint effects of the smaller band gap of Ag/α-Fe_(2)O_(3) heterojunction,inherent antibacterial capacity of Ag/α-Fe_(2)O_(3) and Ag nanoparticles,favorable conductive substrate,as well as the hierarchical structure with superwettability,such mesh presented remarkably enhanced degradation capability toward organic dyes under visible light irradiation and antibacterial activity against both Escherichia coli(E.coli)and Staphylococcus aureus(S.aureus)compared with the pure Ag/α-Fe_(2)O_(3) coated mesh.Impressively,the mesh exhibited bifunctional water purification performance,in which organic dyes were eliminated simultaneously from water during oil/water separation in onefiltration process.More importantly,this mesh behaved exceptional chemical resistance,mechanical stability and long-term reusability.Therefore,this material with multifunctional integration may hold promising potential for steady water purification in practice.
基金The work was supported by the Fund of Kharazmi University(Grant No.22073).
文摘The photocatalytic degradation of reactive blue 19(RB19)dye was investigated in a slurry system using ultraviolet(UV)and light-emitting diode(LED)lamps as light sources and using magnetic tungsten trioxide nanophotocatalysts(α-Fe_(2)O_(3)/WO_(3)and WO_(3)/NaOH)as photocatalysts.The effects of different parameters including irradiation time,initial concentration of RB19,nanophotocatalyst dosage,and pH were examined.The magnetic nanophotocatalysts were also characterized with different methods including scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDS),transmission electron microscopy(TEM),X-ray diffraction(XRD),photoluminescence(PL),differen-tial reflectance spectroscopy(DRS),Fourier transform infrared spectroscopy(FTIR),and vibrating sample magnetometry(VSM).The XRD and FTIR analyses confirmed the presence of tungsten trioxide on the iron oxide nanoparticles.The VSM analysis confirmed the magnetic ability of the new synthesized nanophotocatalyst α-Fe_(2)O_(3)/WO_(3)with 39.6 emu/g of saturation magnetization.The reactor performance showed consid-erable improvement in the α-Fe_(2)O_(3)-modified nanophotocatalyst.The impact of visible light was specifically investigated,and it was compared with UV-C light under the same experimental conditions.The reusability of the magnetic nanophotocatalyst α-Fe_(2)O_(3)/WO_(3)was tested during six cycles,and the magnetic materials showed an excellent removal efficiency after six cycles,with just a 7%decline.
文摘The magnetic properties,microstructure and magnetic hardening of sintered (Nd_(1-x)Dy_x)_(16)Fe_(77.2)B_(6.8) and Nd_(16)Fe_(77.2)B_(6.8)+ywt-%Dy_2O_3 magnets have been stud- ied.As an addition of Dy to the magnet during smelting,Dy atoms may enter the matrix phase Nd_2Fe_(14)B,so as to enhance H_A,refine grains and improve boundary struc- ture,as well as to increase H_(ci)of the magnet.If Dy_2O_3 is added to powder material prior to sintering,Dy atoms diffuse into the epitaxial layer of grains of matrix phase causing enhancement of K′_1,also refinement of grains and improvement of boundary structure.The NdFeB based permanent magnets with higher H_(ci) and greater(BH)_m may be produced by adding about 2—3 wt-% Dy_2O_3 which make a favourable condition for lower cost.
