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富镍LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)正极材料改性研究进展
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作者 王恩通 高淑娟 《电池》 CAS 北大核心 2024年第4期584-588,共5页
锂离子电池用富镍正极材料LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)具有高能量密度、高安全性等优点。受容量衰减、循环寿命和热稳定性等方面的限制,该材料进一步的改性成为当前研究的热点。针对LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)材料的改性研... 锂离子电池用富镍正极材料LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)具有高能量密度、高安全性等优点。受容量衰减、循环寿命和热稳定性等方面的限制,该材料进一步的改性成为当前研究的热点。针对LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)材料的改性研究主要集中在离子掺杂、表面包覆和结构设计等方面。离子掺杂能改善结构稳定性和电化学性能,特别是过渡金属离子的掺杂有助于延长循环寿命和提高结构稳定性;表面包覆改性可增强电化学稳定性和抗氧化性能,延长循环寿命和提高抗极化能力;结构设计可优化晶体结构、提高传导性能和缓解应力,提高循环稳定性、容量保持率和功率密度。 展开更多
关键词 锂离子电池 LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) 富镍正极材料 改性 电池性能
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MgF_(2)助剂对MgAl_(1.9)Ga_(0.1)O_(4)透明陶瓷的制备与光学性能的影响
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作者 吕朝阳 徐勇 +3 位作者 杨久延 涂广升 涂兵田 王皓 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2024年第5期531-538,共8页
MgAl_(1.9)Ga_(0.1)O_(4)透明陶瓷具有优异的光学性能,其制备依赖于高质量坯体的凝胶注模成型和长时间的无压预烧。本研究选择MgF_(2)为烧结助剂,并通过瞬时液相调节无压预烧的致密化过程。采用干压成型、无压预烧和热等静压烧结制备了... MgAl_(1.9)Ga_(0.1)O_(4)透明陶瓷具有优异的光学性能,其制备依赖于高质量坯体的凝胶注模成型和长时间的无压预烧。本研究选择MgF_(2)为烧结助剂,并通过瞬时液相调节无压预烧的致密化过程。采用干压成型、无压预烧和热等静压烧结制备了不同尺寸的MgAl_(1.9)Ga_(0.1)O_(4)透明陶瓷样品,并系统分析了MgF_(2)对材料显微结构、光学和机械性能的影响。研究表明:MgF_(2)在~1230℃熔化形成的液相促使陶瓷的致密度与晶粒尺寸增大,后续烧结过程中残留的MgF_(2)氧化为MgO并固溶进入MgAl_(1.9)Ga_(0.1)O_(4)晶格。添加质量分数0.2%MgF_(2)的2.04 mm厚透明陶瓷样品在紫外和可见光区域具有76.5%~83.4%的直线透过率和较高的光学质量。此外,该陶瓷的特征抗弯强度为167.1 MPa,与细晶MgAl2O4透明陶瓷相近,但是前者的Weibull模数(8.81±0.29)更高。本研究为制备光学性能良好的大尺寸MgAl_(1.9)Ga_(0.1)O_(4)透明陶瓷提供了新的选择。 展开更多
关键词 透明陶瓷 MgAl_(1.9)Ga_(0.1)O_(4) MgF_(2) 瞬时液相烧结 光学性能
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基于密度泛函理论及虚晶近似的(PrxSm1?x)2(Co0.7Cu0.2Fe0.1)17 (x = 0~0.2)磁性研究
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作者 何刚 朱晓宇 +1 位作者 竹文坤 何嵘 《材料科学》 2024年第6期791-800,共10页
Sm2Co17作为第二代高磁密度材料得到广泛关注,研究表明,基于Sm2Co17的镨(Pr)、铜(Cu)、铁(Fe)四元掺杂能显著提升其磁性能,为研究不同镨掺杂浓度对Sm2Co17磁性影响,本文基于第一性原理密度泛函理论、平面波赝势及虚晶近似法,结合CASTEP... Sm2Co17作为第二代高磁密度材料得到广泛关注,研究表明,基于Sm2Co17的镨(Pr)、铜(Cu)、铁(Fe)四元掺杂能显著提升其磁性能,为研究不同镨掺杂浓度对Sm2Co17磁性影响,本文基于第一性原理密度泛函理论、平面波赝势及虚晶近似法,结合CASTEP软件包,使用LDA + U并进行自旋极化计算,研究了镨(Pr)、铜(Cu)、铁(Fe)元素替位掺杂Sm2Co17体系:(PrxSm1−x)2(Co0.7Cu0.2Fe0.1)17的体系能量、分态密度、波尔磁矩等性质,研究表明,(PrxSm1−x)2(Co0.7Cu0.2Fe0.1)17体系的总态密度在−40 eV附近主要由S轨道贡献,总态密度在−20 eV附近主要由P轨道贡献,镨(Pr)掺杂对D轨道和F轨道贡献最大,铜(Cu)、铁(Fe)元素掺杂对S轨道、P轨道和F轨道贡献较大,而F轨道贡献则来自于镨(Pr)且其自旋向下的密度远高于其自旋向上的密度,同时,随着镨元素掺杂比例的提高,体系总能量在逐步降低,说明体系更加稳定,同时,随着掺杂比例的不断变化,体系的波尔磁矩结果呈现波动特性,在x = 0.1时,(PrxSm1−x)2(Co0.7Cu0.2Fe0.1)17呈现出更低的体系总能量和更高的波尔磁矩,说明镨(Pr)掺杂比例10%时(PrxSm1−x)2(Co0.7Cu0.2Fe0.1)17体系具有更优的磁性能,本文的研究有助于优化钐钴四元掺杂永磁体的设计。 展开更多
关键词 第一性原理 虚晶近似 波尔磁矩 (PrxSm1?x)2(Co0.7Cu0.2Fe0.1)17
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微量石墨烯包覆对LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)电化学性能的影响
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作者 刘雷斌 张淑娴 +2 位作者 刘炫漓 李玲 邓凌峰 《电池工业》 CAS 2024年第2期72-77,共6页
使用Hummers法得到氧化石墨烯,再通过还原氧化石墨烯制备石墨烯。使用高温固相法制备LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)正极材料,将石墨烯加入乙醇溶液中,与增稠分散剂羧甲基纤维素钠(CMC)混合得到石墨烯溶液。利用液相自聚集法将石墨烯... 使用Hummers法得到氧化石墨烯,再通过还原氧化石墨烯制备石墨烯。使用高温固相法制备LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)正极材料,将石墨烯加入乙醇溶液中,与增稠分散剂羧甲基纤维素钠(CMC)混合得到石墨烯溶液。利用液相自聚集法将石墨烯溶液微量包覆在LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)表面。通过SEM、XRD以及电化学测试系统对石墨烯/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)复合材料进行表征和测试。结果表明,0.8%-石墨烯/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)复合材料性能最佳,首次充电比容量最大值达到222.85 mAh/g,首次充放电比容量最大值达到208.93 mAh/g,库仑效率为93.75%。 展开更多
关键词 石墨烯 LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) 微量包覆 电化学性能
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Mechanical properties and acoustic emission characteristics of soft rock with different water contents under dynamic disturbance 被引量:1
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作者 Yujing Jiang Lugen Chen +4 位作者 Dong Wang Hengjie Luan Guangchao Zhang Ling Dong Bin Liang 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第3期135-148,共14页
Uniaxial compression tests and cyclic loading acoustic emission tests were conducted on 20%,40%,60%,80%,dry and saturated muddy sandstone by using a creep impact loading system to investigate the mechanical properties... Uniaxial compression tests and cyclic loading acoustic emission tests were conducted on 20%,40%,60%,80%,dry and saturated muddy sandstone by using a creep impact loading system to investigate the mechanical properties and acoustic emission characteristics of soft rocks with different water contents under dynamic disturbance.The mechanical properties and acoustic emission characteristics of muddy sandstones at different water contents were analysed.Results of experimental studies show that water is a key factor in the mechanical properties of rocks,softening them,increasing their porosity,reducing their brittleness and increasing their plasticity.Under uniaxial compression,the macroscopic damage characteristics of the muddy sandstone change from mono-bevel shear damage and‘X’type conjugate bevel shear damage to a roadway bottom-drum type damage as the water content increases.Dynamic perturbation has a strengthening effect on the mechanical properties of samples with 60%and less water content,and a weakening effect on samples with 80%and more water content,but the weakening effect is not obvious.Macroscopic damage characteristics of dry samples remain unchanged,water samples from shear damage and tensile–shear composite damage gradually transformed into cleavage damage,until saturation transformation monoclinic shear damage.The evolution of acoustic emission energy and event number is mainly divided into four stages:loading stage(Ⅰ),dynamic loading stage(Ⅱ),yield failure stage(Ⅲ),and post-peak stage(Ⅳ),the acoustic emission characteristics of the stages were different for different water contents.The characteristic value of acoustic emission key point frequency gradually decreases,and the damage degree of the specimen increases,corresponding to low water content—high main frequency—low damage and high water content—low main frequency—high damage. 展开更多
关键词 Dynamic disturbance Soft rock Cyclic loading Acoustic emission Water content
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基于新型Contention网络的滚动轴承早期故障诊断方法研究
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作者 赵俊豪 郑煜 +1 位作者 王英 王凯 《机械设计与制造工程》 2024年第3期87-91,共5页
针对滚动轴承早期故障诊断问题,为了同时建模振动信号中的高频和低频特征,实现高精度诊断,提出了一种新的模型Contention。它以一种互补的方式集成了空洞卷积和自注意力机制的优点,具有同时捕捉高频和低频信息的能力。为了验证其诊断能... 针对滚动轴承早期故障诊断问题,为了同时建模振动信号中的高频和低频特征,实现高精度诊断,提出了一种新的模型Contention。它以一种互补的方式集成了空洞卷积和自注意力机制的优点,具有同时捕捉高频和低频信息的能力。为了验证其诊断能力,首先,在完整信息原则下将振动信号连续构造成数据集;其次,搭建Contention网络并训练,其最终测试集准确度可达100%,t-SNE显示随网络层次的深入特征被明显聚类;最后,设置对照实验,将该模型与传统RNN、CNN、Transformer模型对比,证明该模型具备突出的诊断能力。 展开更多
关键词 contention网络 空洞卷积 自注意力机制 滚动轴承 早期故障诊断
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热轧变形量对Al0.4Mg0.2Mn0.1Sn阳极合金电化学性能的影响
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作者 陈庆伦 何立子 +2 位作者 李力爽 王美洋 王宇钦 《轻合金加工技术》 CAS 2024年第2期39-44,49,共7页
添加适量的Mg、Mn和Sn等合金元素制备了性能良好的Al0.4Mg0.2Mn0.1Sn阳极合金。采用析氢速率测试、电化学测试、恒流放电测试、显微组织和腐蚀形貌观察,分析不同热轧变形量对该阳极合金活性的影响。结果表明:适当的热轧变形量使阳极合... 添加适量的Mg、Mn和Sn等合金元素制备了性能良好的Al0.4Mg0.2Mn0.1Sn阳极合金。采用析氢速率测试、电化学测试、恒流放电测试、显微组织和腐蚀形貌观察,分析不同热轧变形量对该阳极合金活性的影响。结果表明:适当的热轧变形量使阳极合金组织均匀,晶粒宽度变小,晶粒细化;适当的热轧变形量提升了该阳极合金的电化学性能,降低了腐蚀速率,改善了腐蚀形貌。Al0.4Mg0.2Mn0.1Sn阳极合金在60%热轧变形量下,自腐蚀速率最低,为0.167 mL(min·cm^(2));在60 mA/cm^(2)电流密度下的放电电压达到1.27 V,最大功率密度为53.65 mW/cm^(2)。 展开更多
关键词 Al0.4Mg0.2Mn0.1Sn阳极合金 热轧变形量 析氢 电化学性能:放电电压
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四甲氧基硅烷和乙烯基三甲氧基硅烷改善LiNi_(0.8)Co_(0.1)Mn_(0.1)|石墨@SiO电池的宽温域性能
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作者 王文炼 范伟贞 《广州化工》 CAS 2024年第20期64-67,共4页
硅基材料可以提高锂离子电池的能量密度,但硅粒子的体积膨胀问题严重,是大规模应用前必须解决的难题。开发合适的功能添加剂,以构建稳定的界面膜,是改善上述问题的有效策略。本文在电解液中引入四甲氧基硅烷(TMOS)和乙烯基三甲氧基硅烷(... 硅基材料可以提高锂离子电池的能量密度,但硅粒子的体积膨胀问题严重,是大规模应用前必须解决的难题。开发合适的功能添加剂,以构建稳定的界面膜,是改善上述问题的有效策略。本文在电解液中引入四甲氧基硅烷(TMOS)和乙烯基三甲氧基硅烷(VTES),与氟代碳酸乙烯酯配合,构建了稳定的界面膜,体积膨胀问题得到抑制。含双键的VTCE构建更稳定的界面膜,电池的低温放电、高温(60℃)日历老化性能、常温(25℃)循环和高温(45℃)循环分别提升了8.8%、48.2%、12.6%、21.4%。VTCE有效改善了LiNi_(0.8)Co_(0.1)Mn_(0.1)|石墨@SiO电池的宽温域工作能力,是一种有应用前景的功能添加剂。 展开更多
关键词 四甲氧基硅烷 乙烯基三甲氧基硅烷 LiNi_(0.8)Co_(0.1)Mn_(0.1)
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Digital twin driven and intelligence enabled content delivery in end-edge-cloud collaborative 5G networks
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作者 Bo Yi Jianhui Lv +2 位作者 Xingwei Wang Lianbo Ma Min Huang 《Digital Communications and Networks》 SCIE CSCD 2024年第2期328-336,共9页
The rapid development of 5G/6G and AI enables an environment of Internet of Everything(IoE)which can support millions of connected mobile devices and applications to operate smoothly at high speed and low delay.Howeve... The rapid development of 5G/6G and AI enables an environment of Internet of Everything(IoE)which can support millions of connected mobile devices and applications to operate smoothly at high speed and low delay.However,these massive devices will lead to explosive traffic growth,which in turn cause great burden for the data transmission and content delivery.This challenge can be eased by sinking some critical content from cloud to edge.In this case,how to determine the critical content,where to sink and how to access the content correctly and efficiently become new challenges.This work focuses on establishing a highly efficient content delivery framework in the IoE environment.In particular,the IoE environment is re-constructed as an end-edge-cloud collaborative system,in which the concept of digital twin is applied to promote the collaboration.Based on the digital asset obtained by digital twin from end users,a content popularity prediction scheme is firstly proposed to decide the critical content by using the Temporal Pattern Attention(TPA)enabled Long Short-Term Memory(LSTM)model.Then,the prediction results are input for the proposed caching scheme to decide where to sink the critical content by using the Reinforce Learning(RL)technology.Finally,a collaborative routing scheme is proposed to determine the way to access the content with the objective of minimizing overhead.The experimental results indicate that the proposed schemes outperform the state-of-the-art benchmarks in terms of the caching hit rate,the average throughput,the successful content delivery rate and the average routing overhead. 展开更多
关键词 Digital twin IoE content delivery CACHING ROUTING
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Surface and Content Validity of the Mentoring Function Scale for Novice Nurses
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作者 Aimi Furukawa Yasuko Hosoda 《Open Journal of Nursing》 2024年第8期401-411,共11页
This study aimed to examine the surface and content validity of the Mentoring Function Scale for Novice Nurses, used to assess the mentoring of entry-level nurses, and to refine the scale items. In Study 1, six nurse ... This study aimed to examine the surface and content validity of the Mentoring Function Scale for Novice Nurses, used to assess the mentoring of entry-level nurses, and to refine the scale items. In Study 1, six nurse education researchers, selected using convenience sampling, with five or more years of nursing experience and experience teaching novice nurses, were invited to an expert meeting in July 2015. A group interview was conducted that lasted approximately 120 minutes. Study 2 examined the content validity index. Between September and November 2015, we distributed a self-administered questionnaire survey to 11 participants selected by convenience sampling. The participants included five nurse education researchers with a minimum of five years of nursing experience and experience teaching novice nurses, as well as six clinical nurses with a master’s degree or higher. Finally, 81 questionnaire items were retained from the initial 125 items. The 81-item Mentoring Function Scale for Novice Nurses had higher content validity than the original scale. To further increase the scale’s applicability, future studies should assess its reliability, construct validity, and criterion-related validity. 展开更多
关键词 Novice Nurses Mentoring Function Surface and content Validity Item-Level content Validity Index
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A Survey of Digital Content Required for STD Prevention Education Taught by School Nurses
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作者 Tomoko Nakamura 《Health》 2024年第4期350-370,共21页
Purpose: In recent years, there has been concern in Japan about the increase in STDs among adolescents aged 15 - 19. In order to prevent STDs and guide adolescents toward desirable sexual behavior, this study’s goal ... Purpose: In recent years, there has been concern in Japan about the increase in STDs among adolescents aged 15 - 19. In order to prevent STDs and guide adolescents toward desirable sexual behavior, this study’s goal was to examine the actual state of STD prevention education taught by school nurses as part of the school curriculum, as well as the kinds of digital content they wish to have for teaching on the subject. Method: An anonymous, self-administered questionnaire was distributed by email and leaflet. Targeting the 100 valid responses received from the surveyed school nurses, descriptive statistics were made for each survey item and comparisons were made between the early- and mid-career groups based on years of experience. Results: 70.0% of respondents reported teaching about STDs in Health & Physical Education classes. School nurses in the early-career group used ready-made materials, while the mid-career group used both ready-made and self-made materials. 95% of respondents reported that they had little or no knowledge of STDs, while 84% reported that they were “good” or “fairly good” at teaching classes on sexuality. Both groups reported difficulty with the topics of “phimosis” and “nocturnal emissions” in the physiological category, “sexual behavior” in the “sex-adjacent” category, and “sexual and reproductive issues” in the psychosocial category. Respondents expressed a need for digital content covering the topics of “sexual violence”, “sexual abuse”, “sexually transmitted diseases”, and “how to turn down sex”. The mid-career group desired digital content for more items than the early-career group, with significant differences in the pathogens involved in sexually transmitted diseases and sex-adjacent items. 32.0% of respondents answered that they had done self-study for sex education classes in the past three years, and both groups desired self-study on “sexually transmitted diseases”, with the mid-career group significantly higher than the early-career group on “cervical cancer & HPV”, “emergency contraceptives”, and “media literacy”. Conclusion: Health & Physical Education is the main subject that covers STDs, and pre-existing materials are commonly used. It is expected that this is due to nurses’ busy schedules and the fact that only one school nurse is assigned to each school. The data collected suggested that nurse teachers want categorized digital content that can be used in the classes they are responsible for, rather than educational content on topics they are not comfortable with. In addition, given the changing environment surrounding sex, it was clear that they wish to understand the realities and needs of the high school students they teach, and desire self-study opportunities to improve their teaching methods. 展开更多
关键词 High School Students Sexually Transmitted Diseases Digital content School Nurses
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Quantitative characterizations of anisotropic dynamic properties in organic-rich shale with different kerogen content
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作者 Jian-Yong Xie Yan-Ping Fang +4 位作者 Xing-Hua Wu Jian'er Zhao Jun-Cheng Dai Jun-Xing Cao Ji-Xin Deng 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期855-865,共11页
Understanding the quantitative responses of anisotropic dynamic properties in organic-rich shale with different kerogen content(KC)is of great significance in hydrocarbon exploration and development.Conducting control... Understanding the quantitative responses of anisotropic dynamic properties in organic-rich shale with different kerogen content(KC)is of great significance in hydrocarbon exploration and development.Conducting controlled experiments with a single variable is challenging for natural shales due to their high variations in components,diagenesis conditions,or pore fluid.We employed the hot-pressing technique to construct 11 well-controlled artificial shale with varying KC.These artificial shale samples were successive machined into prismatic shape for ultrasonic measurements along different directions.Observations revealed bedding perpendicular P-wave velocities are more sensitive to the increasing KC than bedding paralleling velocities due to the preferential alignments of kerogen.All elastic stiffnesses except C_(13)are generally decreasing with the increasing KC,the variation of C_(1) and C_(33)on kerogen content are more sensitive than those of C_(44)and C_(66).Apparent dynamic mechanical parameters(v and E)were found to have linear correlation with the true ones from complete anisotropic equations independent of KC,which hold value towards the interpretation of well logs consistently across formations,Anisotropic mechanical parameters(ΔE and brittlenessΔB)tend to decrease with the reducing KC,withΔB showing great sensitivity to KC variations.In the range of low KC(<10%),the V_(P)/V_(S) ratio demonstrated a linearly negative correlation with KC,and the V_(P)/V_(S) ratio magnitude of less than 1.75may serve as a significant characterization for highly organic-rich(>10%)shale,compilation of data from natural organic rich-shales globally verified the similar systematic relationships that can be empirically used to predict the fraction of KC in shales. 展开更多
关键词 Elastic properties Organic shale ANISOTROPY Kerogen content Physical modeling
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Longitudinal dependence of the forecast accuracy of the ionospheric total electron content in the equatorial zone
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作者 Artem Kharakhashyan Olga Maltseva 《Geodesy and Geodynamics》 EI CSCD 2024年第5期528-541,共14页
The longitudinal dependence of the behavior of ionospheric parameters has been the subject of a number of works where significant variations are discovered.This also applies to the prediction of the ionospheric total ... The longitudinal dependence of the behavior of ionospheric parameters has been the subject of a number of works where significant variations are discovered.This also applies to the prediction of the ionospheric total electron content(TEC),which neural network methods have recently been widely used.However,the results are mainly presented for a limited set of meridians.This paper examines the longitudinal dependence of the TEC forecast accuracy in the equatorial zone.In this case,the methods are used that provided the best accuracy on three meridians:European(30°E),Southeastern(110°E)and American(75°W).Results for the stations considered are analyzed as a function of longitude using the Jet Propulsion Laboratory Global Ionosphere Map(JPL GIM)for 2015.These results are for 2 h ahead and 24 h ahead forecast.It was found that in this case,based on the metric values,three groups of architectures can be distinguished.The first group included long short-term memory(LSTM),gated recurrent unit(GRU),and temporal convolutional networks(TCN)models as a part of unidirectional deep learning models;the second group is based on the recurrent models from the first group,which were supplemented with a bidirectional algorithm,increasing the TEC forecasting accuracy by 2-3 times.The third group,which includes the bidirectional TCN architecture(BiTCN),provided the highest accuracy.For this architecture,according to data obtained for 9 equatorial stations,practical independence of the TEC prediction accuracy from longitude was observed under the following metrics(Mean Absolute Error MAE,Root Mean Square Error RMSE,Mean Absolute Percentage Error MAPE):MAE(2 h)is 0.2 TECU approximately;MAE(24 h)is 0.4 TECU approximately;RMSE(2 h)is less than 0.5 TECU except Niue station(RMSE(2 h)is 1 TECU approximately);RMSE(24 h)is in the range of 1.0-1.7 TECU;MAPE(2 h)<1%except Darwin station,MAPE(24 h)<2%.This result was confirmed by data from additional 5 stations that formed latitudinal chains in the equatorial part of the three meridians.The complete correspondence of the observational and predicted TEC values is illustrated using several stations for disturbed conditions on December 19-22,2015,which included the strongest magnetic storm in the second half of the year(min Dst=-155 nT). 展开更多
关键词 IONOSPHERE Total electron content Forecasting BiGRU BiLSTM BiTCN Temporal convolution
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Selection and application of four QTLs for grain protein content in modern wheat cultivars
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作者 Zihui Liu Xiangjun Lai +4 位作者 Yijin Chen Peng Zhao Xiaoming Wang Wanquan Ji Shengbao Xu 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第8期2557-2570,共14页
The grain protein content(GPC)is the key parameter for wheat grain nutritional quality.This study conducted a resampling GWAS analysis using 406 wheat accessions across eight environments,and identified four previousl... The grain protein content(GPC)is the key parameter for wheat grain nutritional quality.This study conducted a resampling GWAS analysis using 406 wheat accessions across eight environments,and identified four previously reported GPC QTLs.An analysis of 87 landraces and 259 modern cultivars revealed the loss of superior GPC haplotypes,especially in Chinese cultivars.These haplotypes were preferentially adopted in different agroecological zones and had broad effects on wheat yield and agronomic traits.Most GPC QTLs did not significantly reduce yield,suggesting that high GPC can be achieved without a yield penalty.The results of this study provide a reference for future GPC breeding in wheat using the four identified QTLs. 展开更多
关键词 BREEDING grain protein content haplotype selection and application WHEAT
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Re-usable Cd_(0.9)Zn_(0.1)S-ZnO@C/PVDF piezo-photocatalytic film with exceptional hydrogen evolution capability triggered by the synergetic advantages of piezoelectricity and S-Scheme heterojunction
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作者 Ping Su Dong Zhang +7 位作者 Minghui Zhu Tengteng Liang Nan Yang Huaihao Zhao Dafeng Zhang Junchang Liu Peiqing Cai Xipeng Pu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期164-176,共13页
Piezoelectric materials have advantages of fine-tuning photocatalytic performance through harvesting mechanical energy and open a new avenue in facilitating green catalytic reaction.Herein,polyvinylidene fluoride(PVDF... Piezoelectric materials have advantages of fine-tuning photocatalytic performance through harvesting mechanical energy and open a new avenue in facilitating green catalytic reaction.Herein,polyvinylidene fluoride(PVDF),a flexible piezoelectric material,was introduced to synthesize a novel Cd_(0.9)Zn_(0.1)S-ZnO@C/PVDF(CZS-ZO@C/PVDF)piezo-photocatalytic film by spin coating and immersion phase conversion method.Benefiting from the piezoelectricity of PVDF and the internal electric field(IEF)of CZS-ZO@C Step-scheme(S-Scheme)heterojunction,CZS-ZO@C/PVDF was able to induce a hydrogen generation rate of 34.9 mmol g^(−1)h^(−1)activated by ultrasound and visible light(U-L),which is∼17.5 times of Cd_(0.9)Zn_(0.1)S/PVDF(CZS/PVDF)and∼7.4 times of the photocatalysis rate activated by visible light only(L).Piezoelectric measurements and COMSOL simulation illustrated the excellent piezoelectricity of CZS-ZO@C/PVDF film,which exhibits a piezoelectric coefficient(d33)of 9.9 pm V−1 and a piezoelectric potential of 874 mV(under 0.5 MPa).The reaction mechanism for the exceptional piezo-photocatalytic performance was finally disclosed through density functional theory(DFT)calculation and electrochemical tests.This study enriches the application scope of piezoelectric materials in sustainable energy catalysis and provides a new direction to develop efficient piezoelectric photocatalysts. 展开更多
关键词 Piezo-photocatalysis HETEROJUNCTION Cd_(0.9)Zn_(0.1)S Zno@c PVDF
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A Study on the Correlation between Salivary Cortisol Content and Anxiety and Depression in Pregnant and Postpartum Women
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作者 Qiuping Wang Shujuan Luo +1 位作者 Jinrui Zhang Yujuan Fan 《Open Journal of Obstetrics and Gynecology》 2024年第2期250-258,共9页
Objective: To analyze the correlation between salivary cortisol content and anxiety and depression in pregnant and postpartum women. Method: 300 pregnant and postpartum women who were admitted from January 2021 to Dec... Objective: To analyze the correlation between salivary cortisol content and anxiety and depression in pregnant and postpartum women. Method: 300 pregnant and postpartum women who were admitted from January 2021 to December 2021 were selected as the research subjects. They were all tested with the Hamilton Anxiety Scale (HAMA) and the Edinburgh Postnatal Depression Scale (EPDS). 40 pregnant women with anxiety and depression were selected as the observation group, and 50 normal pregnant women were selected as the control group, adopting logistic regression analysis to investigate the correlation between salivary cortisol and postpartum anxiety and depression during pregnancy. Result: The salivary cortisol levels in the observation group were significantly higher than those in the control group before bedtime, after waking up the next day, 15 minutes after waking up, 30 minutes after waking up, 60 minutes after waking up, and 1 hour before lunch (p < 0.05). Maternal depression and anxiety were not related to age, weight, gestational age, negative events, or history of adverse pregnancy and childbirth (p > 0.05). Maternal depression and anxiety are closely related to salivary cortisol levels and educational background (p Conclusion: There is a close correlation between anxiety and depression and an increase in cortisol levels, suggesting that the salivary cortisol awakening response during pregnancy has a predictive effect on the occurrence of postpartum depression. 展开更多
关键词 Salivary Cortisol content ANXIETY DEPRESSION MATERNAL
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Multi-omics analysis reveals the pivotal role of phytohormone homeostasis in regulating maize grain water content
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作者 Yuanliang Liu Manman Li +5 位作者 Jianju Liu Suining Deng Yan Zhang Yuanfeng Xia Baoshen Liu Mingliang Xu 《The Crop Journal》 SCIE CSCD 2024年第4期1081-1092,共12页
Grain water content(GWC)is a key determinant for mechanical harvesting of maize(Zea mays).In our previous research,we identified a quantitative trait locus,qGWC1,associated with GWC in maize.Here,we examined near-isog... Grain water content(GWC)is a key determinant for mechanical harvesting of maize(Zea mays).In our previous research,we identified a quantitative trait locus,qGWC1,associated with GWC in maize.Here,we examined near-isogenic lines(NILs)NILL and NILH that differed at the qGWC1 locus.Lower GWC in NILL was primarily attributed to reduced grain water weight(GWW)and smaller fresh grain size,rather than the accumulation of dry matter.The difference in GWC between the NILs became more pronounced approximately 35 d after pollination(DAP),arising from a faster dehydration rate in NILL.Through an integrated analysis of the transcriptome,proteome,and metabolome,coupled with an examination of hormones and their derivatives,we detected a marked decrease in JA,along with an increase in cytokinin,storage forms of IAA(IAA-Glu,IAA-ASP),and IAA precursor IPA in immature NILL kernels.During kernel development,genes associated with sucrose synthases,starch biosynthesis,and zein production in NILL,exhibited an initial up-regulation followed by a gradual down-regulation,compared to those in NILH.This discovery highlights the crucial role of phytohormone homeostasis and genes related to kernel development in balancing GWC and dry matter accumulation in maize kernels. 展开更多
关键词 Grain water content Maize kernel Phytohormone homeostasis
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Predictability of the upper ocean heat content in a Community Earth System Model ensemble prediction system
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作者 Ting Liu Wenxiu Zhong 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第1期1-10,共10页
Upper ocean heat content(OHC)has been widely recognized as a crucial precursor to high-impact climate variability,especially for that being indispensable to the long-term memory of the ocean.Assessing the predictabili... Upper ocean heat content(OHC)has been widely recognized as a crucial precursor to high-impact climate variability,especially for that being indispensable to the long-term memory of the ocean.Assessing the predictability of OHC using state-of-the-art climate models is invaluable for improving and advancing climate forecasts.Recently developed retrospective forecast experiments,based on a Community Earth System Model ensemble prediction system,offer a great opportunity to comprehensively explore OHC predictability.Our results indicate that the skill of actual OHC predictions varies across different oceans and diminishes as the lead time of prediction extends.The spatial distribution of the actual prediction skill closely resembles the corresponding persistence skill,indicating that the persistence of OHC serves as the primary predictive signal for its predictability.The decline in actual prediction skill is more pronounced in the Indian and Atlantic oceans than in the Pacific Ocean,particularly within tropical regions.Additionally,notable seasonal variations in the actual prediction skills across different oceans align well with the phase-locking features of OHC variability.The potential predictability of OHC generally surpasses the actual prediction skill at all lead times,highlighting significant room for improvement in current OHC predictions,especially for the North Indian Ocean and the Atlantic Ocean.Achieving such improvements necessitates a collaborative effort to enhance the quality of ocean observations,develop effective data assimilation methods,and reduce model bias. 展开更多
关键词 ocean heat content prediction skill retrospective forecast experiment
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Experimental and numerical analyses of the effect of fibre content on the close-in blast performance of a UHPFRC beam
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作者 Junbo Yan Qiyue Zhang +4 位作者 Yan Liu Yingliang Xu Zhenqing Shi Fan Bai Fenglei Huang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期242-261,共20页
Limited research has been conducted on the influences of fiber content on close-in blasting characteristics for ultrahigh-performance fiber-reinforced concrete(UHPFRC)beams.This paper aims to address this knowledge ga... Limited research has been conducted on the influences of fiber content on close-in blasting characteristics for ultrahigh-performance fiber-reinforced concrete(UHPFRC)beams.This paper aims to address this knowledge gap through experimental and mesoscale numerical methods.Experiments were conducted on ten UHPFRC beams built with varying steel fiber volumetric fractions subjected to close-in explosive conditions.Additionally,this study considered other parameters,such as the longitudinal reinforcement type and ratio.In the case of UHPFRC beams featuring normal-strength longitudinal reinforcement of diametersΦ12,Φ16,andΦ20,a reduction in maximum displacement by magnitudes of19.6%,19.5%,and 17.4%was observed,respectively,as the volumetric fractions of fiber increased from1.0%to 2.5%.In addition,increasing the longitudinal reinforcement ratio and using high-strength steel longitudinal reinforcement both significantly reduced the deformation characteristics and increase the blasting resistances of UHPFRC beams.However,the effects on the local crushing and spalling damage were not significant.A mesoscale finite element model,which considers the impacts of fiber parameters on UHPFRC beam behaviors,was also established and well correlated with the test findings.Nevertheless,parametric analyses were further conducted to examine the impacts of the steel fiber content and length and the hybrid effects of various types of microfibers and steel fibers on the blasting performance of UHPFRC beams. 展开更多
关键词 Blast performance Close-in blast Fiber content Mesoscale approach UHPFRC beams
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High-throughput molecular gut content analysis of aphids identifies plants relevant for potato virus Y epidemioiogy
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作者 William Jacob Pitt William Rodney Cooper +2 位作者 Derek Pouchnik Heather Headrick Punya Nachappa 《Insect Science》 SCIE CAS CSCD 2024年第5期1489-1502,共14页
Aphids are phloem-feeding insects that reduce crop productivity due to feeding and transmission of plant viruses.When aphids disperse across the landscape to colonize new host plants,they will often probe on a wide va... Aphids are phloem-feeding insects that reduce crop productivity due to feeding and transmission of plant viruses.When aphids disperse across the landscape to colonize new host plants,they will often probe on a wide variety of nonhost plants before settling on a host suitable for feeding and reproduction.There is limited understanding of the diversity of plants that aphids probe on within a landscape,and characterizing this diversity can help us better understand host use patterns of aphids.Here,we used gut content analysis(GCA)to identify plant genera that were probed by aphid vectors of potato virus Y(PVY).Aphids were trapped weekly near potato fields during the growing seasons of 2020 and 2021 in San Luis Valley in Colorado.High-throughput sequencing of plant barcoding genes,trnF and ITS2,from 200 individual alate(i.e.,winged)aphids representing nine vector species of PVY was performed using the PacBio sequencing platform,and sequences were identi-fied to genus using NCBI BLASTn.We found that 34.7%of aphids probed upon presumed PVY host plants and that two of the most frequently detected plant genera,Solanum and Brassica,represent important crops and weeds within the study region.We found that 75%of aphids frequently probed upon PVY nonhosts including many species that are outside of their reported host ranges.Additionally,19%of aphids probed upon more than one plant species.This study provides the first evidence from high-throughput molecular GCA of aphids and reveals host use patterns that are relevant for PVY epidemiology. 展开更多
关键词 APHIDS EPIDEMIOLOGY gut content analysis insect ecology plant-insect in-teractions plant disease
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